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Introduction
LECTURE-1
By Prof. BRK Gupta
Department of Physics, GLA University Mathura
The Quantum Mechanics
 All matter (particles) has wave-like properties
 so-called particle-wave duality
 Particle-waves are described in a probabilistic manner
 electron doesn’t whiz around the nucleus, it has a probability distribution describing
where it might be found
 allows for seemingly impossible “quantum tunneling”
 Some properties come in dual packages: can’t know both simultaneously to
arbitrary precision
 called the Heisenberg Uncertainty Principle
 not simply a matter of measurement precision
 position/momentum and energy/time are example pairs
 The act of “measurement” fundamentally alters the system
 called entanglement: information exchange alters a particle’s state
Crises in physics that demanded QM
3
Why don’t atoms disintegrate in nanoseconds?
◦ if electron is “orbiting”, it’s accelerating (wiggling)
◦ wiggling charges emit electromagnetic radiation (energy)
◦ loss of energy would cause prompt decay of orbit
• Why don’t hot objects emit more ultraviolet
light than they do?
– classical theory suggested a “UV
catastrophe,” leading to obviously
nonsensical infinite energy radiating from
hot body
– Max Planck solved this problem by
postulating light quanta (now often called the
father of quantum mechanics)
Contd...
Why was red light incapable of knocking
electrons out of certain materials, no
matter how bright
◦ yet blue light could readily do so even at
modest intensities
◦ called the photoelectric effect
◦ Einstein explained in terms of photons, and
won Nobel Prize
What caused spectra of atoms to
contain discrete “lines”
◦ it was apparent that only a small set
of optical frequencies (wavelengths)
could be emitted or absorbed by
atoms
Each atom has a distinct “fingerprint”
Light only comes off at very specific
wavelengths
◦ or frequencies
◦ or energies
Note that hydrogen (bottom), with only
one electron and one proton, emits
several wavelengths
Next
Photon energy ???

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L 1 introduction

  • 1. Introduction LECTURE-1 By Prof. BRK Gupta Department of Physics, GLA University Mathura
  • 2. The Quantum Mechanics  All matter (particles) has wave-like properties  so-called particle-wave duality  Particle-waves are described in a probabilistic manner  electron doesn’t whiz around the nucleus, it has a probability distribution describing where it might be found  allows for seemingly impossible “quantum tunneling”  Some properties come in dual packages: can’t know both simultaneously to arbitrary precision  called the Heisenberg Uncertainty Principle  not simply a matter of measurement precision  position/momentum and energy/time are example pairs  The act of “measurement” fundamentally alters the system  called entanglement: information exchange alters a particle’s state
  • 3. Crises in physics that demanded QM 3 Why don’t atoms disintegrate in nanoseconds? ◦ if electron is “orbiting”, it’s accelerating (wiggling) ◦ wiggling charges emit electromagnetic radiation (energy) ◦ loss of energy would cause prompt decay of orbit • Why don’t hot objects emit more ultraviolet light than they do? – classical theory suggested a “UV catastrophe,” leading to obviously nonsensical infinite energy radiating from hot body – Max Planck solved this problem by postulating light quanta (now often called the father of quantum mechanics)
  • 4. Contd... Why was red light incapable of knocking electrons out of certain materials, no matter how bright ◦ yet blue light could readily do so even at modest intensities ◦ called the photoelectric effect ◦ Einstein explained in terms of photons, and won Nobel Prize
  • 5. What caused spectra of atoms to contain discrete “lines” ◦ it was apparent that only a small set of optical frequencies (wavelengths) could be emitted or absorbed by atoms Each atom has a distinct “fingerprint” Light only comes off at very specific wavelengths ◦ or frequencies ◦ or energies Note that hydrogen (bottom), with only one electron and one proton, emits several wavelengths