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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5165
STRENGTH AND DURABILITY STUDY ON CONCRETE USING DIFFERENT
TYPES OF BINDERS (OPC & PPC)
R. Mirudubashini1, K.S. Elango2
1PG student, KPR Institute of Engineering and Technology, Coimbatore, Tamilnadu, India
2Assistant Professor, KPR Institute of Engineering and Technology, Coimbatore, Tamilnadu, India
----------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - This paper reports the strength and durability
behaviour of concrete made with different types of binders
such as OPC & PPC. Portland Pozzolana Cement(PPC)isakind
of Blended Cement which is produced by either intergrinding
of OPC clinker along with gypsum and pozzolanic materials in
certain proportions or grinding the OPC clinker, gypsum and
Pozzolanic materials separately and thoroughly blending
them in certain proportions. In this paper, the concrete of
grade M 30 was used and tested for various mechanical
properties such as compressive strength, split tensile strength
and flexural strength, durability properties such as salt
resistance, sulphate resistance and acid resistance. The test
results were arrived and discussed elaborately. It has been
noticed that concrete made of PPC binder demonstrates
satisfied mechanicaland durabilitypropertieswhencompared
to conventional concrete. Furthermore, theresultsprovedthat
PPC binder can be effectively used in construction as a
replacement of OPC for sustainable development.
Key Words: Ordinary Portland Cement, Portland Pozzolana
Cement, binder, strength, durability.
1. INTRODUCTION
In the modern construction, concrete is one of the most
important building materials because of its strength and
durability to cost ratio. Concrete, usually Portland cement
concrete, is a composite material composed of fine and
coarse aggregate bonded together with a
fluid cement (cement paste) that hardens over time most
frequently a lime-based cement binder, such as Portland
cement, but sometimes with other hydraulic cements, such
as a calcium aluminate cement. Itisdistinguishedfromother
non-cementitious types of concrete,all bindingsomeform of
aggregate together, including asphalt concrete with
a bitumen binder, which isfrequentlyusedfor roadsurfaces,
and polymer concretes that use polymers as a binder.
Durability is defined as the capability of concrete to resist
weathering action, chemical attack and abrasion while
maintaining its desired engineering properties. It normally
refers to the duration or life span of trouble-free
performance.
Jamkar et al. (2013) found that the fly ash fineness plays a
vital role in the durability property also the author noticed
that increase in the fineness increased both workability and
compressive strength. It was also observed that finer
particles resulted in increasing the rate of reaction needing
less heating time to achieve a given strength [1]. Abdullah
Anwar et.al (2014) represented that the optimal percentage
for replacement of cementwithcementitiousmaterial would
lead to the production of carbon dioxide and solving the
environmental pollution by cement production there by
enhances the urban surroundings [2]. R.Bansal et al. (2015)
studied that the replacement is of fly ashwithcementhaving
been studied for partial replacement of fly ash with cement
at 10%, 20%, 30%. It was observed that 10%replacementof
fly ash was 20% and 50% decreasethecompressivestrength
at the age of 7 and 28 days respectively.In20%replacement,
7% and 11% increase of compressivestrengthwasobserved
at the age of 7 and 28 days respectively. In 30% replacement
23% and 19% increase the compressive strength was
observed at the age of 7and 28 days respectively [3].
Siddique (2003) investigated that fly ash replacing fine
aggregate shows increase in strength. It has been also
noticed that the rate of increase of strength decreases with
increase in fly ash content. At 50% replacements of fine
aggregate by fly ash, compressive strength of concrete
increased by 51.5% and 67.1% at 28 and 365 days
respectively [4]. Elango & his associate (2016) investigated
that Pozzalona cement (PPC) binder using different
aggregate sizes. PPC is not new to the world and is a better
alternative to OPC as it gives better performance of concrete
in terms of strength and durability. Moreover, it helps in
disposing fly ash and conserves mineral resources in the
sense that lesser amount of limestone is used. The
compressive strength split tensile strength and flexural
strength of PPC mix specimens are slightly lesser than OPC
mix specimens due to less heat of hydration [5].
Elango & his associate(2017)foundthatPortlandPozzolana
Cement is a kind of blended cement which is produced by
either inter grinding of OPC clinker along with gypsum and
pozzolanic materials in certain proportions or grinding the
OPC clinker, gypsum and Pozzolanic materials separately
and thoroughly blending them in certain proportions.
Pozzolana is a natural or artificial material containing silica
in a reactive form [6]. Maheswaran et al. (2018) studied that
PPC mix specimens shows higher porosity and permeability
when compared to conventional control mix, whereas the
density values are vice versa. This is because, greater the
porosity reduces the density of the mix. PC mix specimens
shows better resistance against chemical solution because
pozzolanic material present in PPC results in pore
refinement [7].
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5166
2. MATERIALS
2.1 Cement
The Ordinary Portland Cement (OPC) of 53 grade
conforming to IS 12269 - 2013 and Portland Pozzolana
Cement conforming to IS: 1489 (1) -1991 used in this study
was procured from the local market. The physical property
tests were carried out as per IS 4031-1988 (Reaffirmed
2014) and the experimental results are given in Table 1.
Table -1: Physical properties of Cement
S.No Test conducted
Experimental
Results
(OPC)
Experimenta
l
Results
(PPC)
1 Specific gravity 3.13 2.95
2 Fineness 92 95
3
Consistency
(%)
31 34
4
Initial setting
time
32 min 50 min
5
Final setting
time
286 min 125 min
2.2 Fine aggregate
Manufactured sand (M-sand) is used as a fine aggregate
and it was procured from local quarry. Tests for fine
aggregate was carried out in the laboratory as per IS 383-
1970 (Reaffirmed 2011) and presented in Table 2. The fine
aggregate used in this project belongs to grading zone II and
fall under the category of medium sand.
Table -2: Physical properties of Fine aggregate
S.No Test conducted
Experimental
Results
1 Specific gravity 2.56
2 Fineness modulus 2.76
2.3 Coarse aggregate
Crushed blue granite metal (coarse aggregate) of size 20
mm used in the presentworkwascollectedfromlocalquarry.
Physical property tests were carried out in accordance with
IS 2386-1963 (Reaffirmed 2011) and presented in Table 3.
Table -3: Physical properties of Coarse aggregate
S.No Test conducted
Experimental
Results
1 Specific gravity 2.8
2 Water absorption value (%) 1.2
3 Impact value (%) 8.50
4 Crushing value (%) 23.65
5 Abrasion value (%) 25.50
2.4 Water
Mixing water used in the study satisfied the quality
standards of drinking water and it was taken from KPR
Institute of Engineering and Technology, Coimbatore,
Tamilnadu.
2.5 Mix proportion
The concrete mix design was performed according to IS
10262: 2009. M 30 grade of concrete mix design was carried
out and the quantity of materials arrived are presented in
Table 4.
Table -4: Mix proportion
S.No Materials kg/m3
1 Cement 448
2 Fine aggregate 635
3 Coarse aggregate 1041
4 Water 197
5 W/C ratio 0.45
3. EXPERIMENTAL PROGRAM
To determine the mechanical properties of the concrete,
tests such as compressive strength test, split tensile test and
flexural test were carried out. Moreover 12 numbersofcube
specimen of size 150 mm x 150 mm x 150 mm, Cylinder
specimen size of 150 mm dia. and 300 mm height, prism
specimen of size 100 mm x 100 mm x 500 mm were casted
and tested for 7 days and 28 days. Furthermore 18 numbers
of cube specimens were casted to study the durability
properties such as salt resistance, sulphate resistance and
acid resistance test. Sodium Chloride (NaCl) was used to
study the salt resistance of the specimens. Hydrochloricacid
(HCl) and Magnesium Sulphate (MgSO4) was used for acid
and sulphate attack study.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5167
4. RESULTS AND DISCUSSION
4.1 Mechanical Properties
Compressive strength, split tensile strengthandflexural
strength test results of OPC and PPC binder concrete are
presented in Table 5 and graphically represented in Chart
1-3.
Table -5: Mechanical properties of various binders
Age of
test
(days)
Compressive
strength
(MPa)
Split tensile
strength
(MPa)
Flexural
strength
(MPa)
OPC PPC OPC PPC OPC PPC
7 24.26 22.25 2.52 2.15 3.84 3.30
28 39.87 35.35 4.16 3.35 4.51 4.12
Chart-1: Compressive strength
Chart- 2: Split tensile strength
Chart.-3: Flexural strength
The test results indicated that, at the age of 28 days mix
made with PPC exhibited 11.3%lessercompressivestrength
than conventional control mix OPC. Similarly, 19.4% lesser
split tensile strength was noticed in PPC mix than OPC.
Regardless of flexural strength, PPC mix has demonstrated
8.6% lesser flexural strength than conventional control mix
OPC. This can be attributed to the fact that pozzolanic
material present in PPC would lead to less heat of hydration
that result in lesser strength gain at earlier ages.
4.2 Durability properties
Table 6 shows the effect of weight loss and loss in
strength of OPC and PPC mix immersed in sodium chloride
(NaCl), magnesium sulphate (MgSO4) and Hydrochloricacid
(HCl) solution in at the age of 56 days. Test results shows
that OPC and PPC specimens shows betterresistanceagainst
chemical attack. Furthermore, visual observation reveals
that minor physical deterioration has occurred at the edges
for the specimens immersed in MgSO4 and HCl solution.
Regardless of colour change slight whitish formation was
appeared on the surface of the specimens immersed in
MgSO4 solution due to the displaced calcium precipitates
mainly as gypsum. Specimens immersed in acid solution
exhibits solution exhibits slight reddish colour formation on
the surface due to the presence of iron content (Fe2O3) in fly
ash and presence of free lime and iron content in the
hydrated cement matrix. Specimens subjected to chemical
attack are shown in Fig 1.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5168
Fig.-1: Specimens subjected to chemical attack
Table -6: Durability properties of various binders
Tests conducted
Weight loss
(%)
Strength
loss (%)
OPC PPC OPC PPC
Salt attack 0.71 0.65 4.27 3.25
Sulphate attack 0.82 0.72 4.49 4.05
Acid attack 1.21 1.05 5.20 4.65
5. CONCLUSIONS
Mechanical properties such as compressive strength,
split tensile strength, flexural strength, durability properties
such as salt resistance, sulphate resistance and acid
resistance were found and based on the test results the
following conclusions can be drawn.
1) Compressive strength, split tensile strength and
flexural strength of PPC mix specimens are slightly lesser
than OPC mix specimens due to less heat of hydration.
2) PPC mix specimens showed better resistance against
chemical solution because pozzolanic material present in
PPC results in pore refinement.
3) Specimens immersed in MgSO4 solution have
demonstrated whitish formation because of displaced
calcium precipitates mainly as gypsum. Similarly,specimens
immersed in acid solution exhibits solution slight reddish
colour formation on the surface due to the presence of iron
content (Fe2O3) in fly ash and presence of free limeandiron
content in the hydrated cement matrix
4) Concrete made with PPC as binder satisfies the
strength and durability requirements with adequate
properties and it can be used for sustainable construction.
ACKNOWLEDGEMENT
The authors express their sincere thanks to the
Management and Principal of KPR Institute of Engineering
and Technology, Coimbatore, Tamilnadu, India for the
facilities and support provided to carryouttheexperimental
work.
REFERENCES
[1] S.S. Jamkar, Y.M. Ghugal andS.V.Patankar(2013),“Effect
of fly ash fineness on workability and compressive
strength of geopolymer concrete”, The Indian Concrete
Journal.
[2] Abdullah Anwar (2014),“StudyofCompressiveStrength
of Concrete by Partial Replacement of Cement with
Marble Dust Powder”, Ird Indian, Vol. 02, Issue-3, pp.
2321-5747.
[3] R.Bansal, V.Singh and Ravi .K. Pareek (2015) “Effect on
Compressive Strength with Partial Replacement of
FlyAsh.” International Journal on Emerging
Technologies, Vol..06, Issue -1, pp 1-6.
[4] R. Siddique (2003), “Properties of concrete
incorporating high volumes of class F fly ash and san
fibers.” Vol.34, Issue-1, pp. 37-42.
[5] K.S. Elango & V. Revathi (2016) , “Properties of PPC
Binder Pervious Concrete”, Construction International
Journal of Advanced Engineering Technology, Vol.07 ,
Issue 2, pp. 91–99.
[6] K.S. Elango & V. Revathi (2017), “Fal-G Binder Pervious
Concrete”, Construction andBuildingMaterials,Vol.140,
pp. 91–99.
[7] S. Maheswaran. B. Nandhagopalaguhan, P. Niveditha, K.
Pasupathi, Elango. K.S (2018), “Experimental Study on
Pervious Concrete with Pebbles as a Coarse Aggregate”,
International Journal for Innovative ResearchinScience
& Technology, Vol. 4, Issue 11, pp. 26-30.
[8] B Siva Prasad, T Sahithi (2018) , “An Experimental
Investigation on Durability Studies of Concrete by using
Different Types of Cements (OPC, PPC & PSC),
International Research Journal Of Engineering And
Technology, Vol.5, Issue 11, pp.1538-1544.
[9] IS 10262: 2009, “Concrete Mix Proportioning –
Guidelines”, Bureau of Indian Standards, New Delhi,
India.
[10] IS 456: 2000, “Plain and reinforced concrete – Code of
practice”, Bureau of Indian Standards, New Delhi, India.
[11] IS 12269: 2013, “Ordinary Portland cement 53 grade –
Specification”, Bureau of Indian Standards, New Delhi,
India.
[12] IS 4031: 1988,” Methods of physical tests for hydraulic
cement”, Bureau of Indian Standards, New Delhi, India.
[13] IS 383:1970, “Coarse and fine aggregate for concrete –
Specification”, Bureau of Indian Standards, New Delhi,
India.
[14] IS 2386: 1963, “Methods of tests for aggregates for
concrete”, Bureau of Indian Standards, New Delhi, India

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IRJET- Strength and Durability Study on Concrete using Different Types of Binders (OPC & PPC)

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5165 STRENGTH AND DURABILITY STUDY ON CONCRETE USING DIFFERENT TYPES OF BINDERS (OPC & PPC) R. Mirudubashini1, K.S. Elango2 1PG student, KPR Institute of Engineering and Technology, Coimbatore, Tamilnadu, India 2Assistant Professor, KPR Institute of Engineering and Technology, Coimbatore, Tamilnadu, India ----------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - This paper reports the strength and durability behaviour of concrete made with different types of binders such as OPC & PPC. Portland Pozzolana Cement(PPC)isakind of Blended Cement which is produced by either intergrinding of OPC clinker along with gypsum and pozzolanic materials in certain proportions or grinding the OPC clinker, gypsum and Pozzolanic materials separately and thoroughly blending them in certain proportions. In this paper, the concrete of grade M 30 was used and tested for various mechanical properties such as compressive strength, split tensile strength and flexural strength, durability properties such as salt resistance, sulphate resistance and acid resistance. The test results were arrived and discussed elaborately. It has been noticed that concrete made of PPC binder demonstrates satisfied mechanicaland durabilitypropertieswhencompared to conventional concrete. Furthermore, theresultsprovedthat PPC binder can be effectively used in construction as a replacement of OPC for sustainable development. Key Words: Ordinary Portland Cement, Portland Pozzolana Cement, binder, strength, durability. 1. INTRODUCTION In the modern construction, concrete is one of the most important building materials because of its strength and durability to cost ratio. Concrete, usually Portland cement concrete, is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens over time most frequently a lime-based cement binder, such as Portland cement, but sometimes with other hydraulic cements, such as a calcium aluminate cement. Itisdistinguishedfromother non-cementitious types of concrete,all bindingsomeform of aggregate together, including asphalt concrete with a bitumen binder, which isfrequentlyusedfor roadsurfaces, and polymer concretes that use polymers as a binder. Durability is defined as the capability of concrete to resist weathering action, chemical attack and abrasion while maintaining its desired engineering properties. It normally refers to the duration or life span of trouble-free performance. Jamkar et al. (2013) found that the fly ash fineness plays a vital role in the durability property also the author noticed that increase in the fineness increased both workability and compressive strength. It was also observed that finer particles resulted in increasing the rate of reaction needing less heating time to achieve a given strength [1]. Abdullah Anwar et.al (2014) represented that the optimal percentage for replacement of cementwithcementitiousmaterial would lead to the production of carbon dioxide and solving the environmental pollution by cement production there by enhances the urban surroundings [2]. R.Bansal et al. (2015) studied that the replacement is of fly ashwithcementhaving been studied for partial replacement of fly ash with cement at 10%, 20%, 30%. It was observed that 10%replacementof fly ash was 20% and 50% decreasethecompressivestrength at the age of 7 and 28 days respectively.In20%replacement, 7% and 11% increase of compressivestrengthwasobserved at the age of 7 and 28 days respectively. In 30% replacement 23% and 19% increase the compressive strength was observed at the age of 7and 28 days respectively [3]. Siddique (2003) investigated that fly ash replacing fine aggregate shows increase in strength. It has been also noticed that the rate of increase of strength decreases with increase in fly ash content. At 50% replacements of fine aggregate by fly ash, compressive strength of concrete increased by 51.5% and 67.1% at 28 and 365 days respectively [4]. Elango & his associate (2016) investigated that Pozzalona cement (PPC) binder using different aggregate sizes. PPC is not new to the world and is a better alternative to OPC as it gives better performance of concrete in terms of strength and durability. Moreover, it helps in disposing fly ash and conserves mineral resources in the sense that lesser amount of limestone is used. The compressive strength split tensile strength and flexural strength of PPC mix specimens are slightly lesser than OPC mix specimens due to less heat of hydration [5]. Elango & his associate(2017)foundthatPortlandPozzolana Cement is a kind of blended cement which is produced by either inter grinding of OPC clinker along with gypsum and pozzolanic materials in certain proportions or grinding the OPC clinker, gypsum and Pozzolanic materials separately and thoroughly blending them in certain proportions. Pozzolana is a natural or artificial material containing silica in a reactive form [6]. Maheswaran et al. (2018) studied that PPC mix specimens shows higher porosity and permeability when compared to conventional control mix, whereas the density values are vice versa. This is because, greater the porosity reduces the density of the mix. PC mix specimens shows better resistance against chemical solution because pozzolanic material present in PPC results in pore refinement [7].
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5166 2. MATERIALS 2.1 Cement The Ordinary Portland Cement (OPC) of 53 grade conforming to IS 12269 - 2013 and Portland Pozzolana Cement conforming to IS: 1489 (1) -1991 used in this study was procured from the local market. The physical property tests were carried out as per IS 4031-1988 (Reaffirmed 2014) and the experimental results are given in Table 1. Table -1: Physical properties of Cement S.No Test conducted Experimental Results (OPC) Experimenta l Results (PPC) 1 Specific gravity 3.13 2.95 2 Fineness 92 95 3 Consistency (%) 31 34 4 Initial setting time 32 min 50 min 5 Final setting time 286 min 125 min 2.2 Fine aggregate Manufactured sand (M-sand) is used as a fine aggregate and it was procured from local quarry. Tests for fine aggregate was carried out in the laboratory as per IS 383- 1970 (Reaffirmed 2011) and presented in Table 2. The fine aggregate used in this project belongs to grading zone II and fall under the category of medium sand. Table -2: Physical properties of Fine aggregate S.No Test conducted Experimental Results 1 Specific gravity 2.56 2 Fineness modulus 2.76 2.3 Coarse aggregate Crushed blue granite metal (coarse aggregate) of size 20 mm used in the presentworkwascollectedfromlocalquarry. Physical property tests were carried out in accordance with IS 2386-1963 (Reaffirmed 2011) and presented in Table 3. Table -3: Physical properties of Coarse aggregate S.No Test conducted Experimental Results 1 Specific gravity 2.8 2 Water absorption value (%) 1.2 3 Impact value (%) 8.50 4 Crushing value (%) 23.65 5 Abrasion value (%) 25.50 2.4 Water Mixing water used in the study satisfied the quality standards of drinking water and it was taken from KPR Institute of Engineering and Technology, Coimbatore, Tamilnadu. 2.5 Mix proportion The concrete mix design was performed according to IS 10262: 2009. M 30 grade of concrete mix design was carried out and the quantity of materials arrived are presented in Table 4. Table -4: Mix proportion S.No Materials kg/m3 1 Cement 448 2 Fine aggregate 635 3 Coarse aggregate 1041 4 Water 197 5 W/C ratio 0.45 3. EXPERIMENTAL PROGRAM To determine the mechanical properties of the concrete, tests such as compressive strength test, split tensile test and flexural test were carried out. Moreover 12 numbersofcube specimen of size 150 mm x 150 mm x 150 mm, Cylinder specimen size of 150 mm dia. and 300 mm height, prism specimen of size 100 mm x 100 mm x 500 mm were casted and tested for 7 days and 28 days. Furthermore 18 numbers of cube specimens were casted to study the durability properties such as salt resistance, sulphate resistance and acid resistance test. Sodium Chloride (NaCl) was used to study the salt resistance of the specimens. Hydrochloricacid (HCl) and Magnesium Sulphate (MgSO4) was used for acid and sulphate attack study.
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5167 4. RESULTS AND DISCUSSION 4.1 Mechanical Properties Compressive strength, split tensile strengthandflexural strength test results of OPC and PPC binder concrete are presented in Table 5 and graphically represented in Chart 1-3. Table -5: Mechanical properties of various binders Age of test (days) Compressive strength (MPa) Split tensile strength (MPa) Flexural strength (MPa) OPC PPC OPC PPC OPC PPC 7 24.26 22.25 2.52 2.15 3.84 3.30 28 39.87 35.35 4.16 3.35 4.51 4.12 Chart-1: Compressive strength Chart- 2: Split tensile strength Chart.-3: Flexural strength The test results indicated that, at the age of 28 days mix made with PPC exhibited 11.3%lessercompressivestrength than conventional control mix OPC. Similarly, 19.4% lesser split tensile strength was noticed in PPC mix than OPC. Regardless of flexural strength, PPC mix has demonstrated 8.6% lesser flexural strength than conventional control mix OPC. This can be attributed to the fact that pozzolanic material present in PPC would lead to less heat of hydration that result in lesser strength gain at earlier ages. 4.2 Durability properties Table 6 shows the effect of weight loss and loss in strength of OPC and PPC mix immersed in sodium chloride (NaCl), magnesium sulphate (MgSO4) and Hydrochloricacid (HCl) solution in at the age of 56 days. Test results shows that OPC and PPC specimens shows betterresistanceagainst chemical attack. Furthermore, visual observation reveals that minor physical deterioration has occurred at the edges for the specimens immersed in MgSO4 and HCl solution. Regardless of colour change slight whitish formation was appeared on the surface of the specimens immersed in MgSO4 solution due to the displaced calcium precipitates mainly as gypsum. Specimens immersed in acid solution exhibits solution exhibits slight reddish colour formation on the surface due to the presence of iron content (Fe2O3) in fly ash and presence of free lime and iron content in the hydrated cement matrix. Specimens subjected to chemical attack are shown in Fig 1.
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5168 Fig.-1: Specimens subjected to chemical attack Table -6: Durability properties of various binders Tests conducted Weight loss (%) Strength loss (%) OPC PPC OPC PPC Salt attack 0.71 0.65 4.27 3.25 Sulphate attack 0.82 0.72 4.49 4.05 Acid attack 1.21 1.05 5.20 4.65 5. CONCLUSIONS Mechanical properties such as compressive strength, split tensile strength, flexural strength, durability properties such as salt resistance, sulphate resistance and acid resistance were found and based on the test results the following conclusions can be drawn. 1) Compressive strength, split tensile strength and flexural strength of PPC mix specimens are slightly lesser than OPC mix specimens due to less heat of hydration. 2) PPC mix specimens showed better resistance against chemical solution because pozzolanic material present in PPC results in pore refinement. 3) Specimens immersed in MgSO4 solution have demonstrated whitish formation because of displaced calcium precipitates mainly as gypsum. Similarly,specimens immersed in acid solution exhibits solution slight reddish colour formation on the surface due to the presence of iron content (Fe2O3) in fly ash and presence of free limeandiron content in the hydrated cement matrix 4) Concrete made with PPC as binder satisfies the strength and durability requirements with adequate properties and it can be used for sustainable construction. ACKNOWLEDGEMENT The authors express their sincere thanks to the Management and Principal of KPR Institute of Engineering and Technology, Coimbatore, Tamilnadu, India for the facilities and support provided to carryouttheexperimental work. REFERENCES [1] S.S. Jamkar, Y.M. Ghugal andS.V.Patankar(2013),“Effect of fly ash fineness on workability and compressive strength of geopolymer concrete”, The Indian Concrete Journal. [2] Abdullah Anwar (2014),“StudyofCompressiveStrength of Concrete by Partial Replacement of Cement with Marble Dust Powder”, Ird Indian, Vol. 02, Issue-3, pp. 2321-5747. [3] R.Bansal, V.Singh and Ravi .K. Pareek (2015) “Effect on Compressive Strength with Partial Replacement of FlyAsh.” International Journal on Emerging Technologies, Vol..06, Issue -1, pp 1-6. [4] R. Siddique (2003), “Properties of concrete incorporating high volumes of class F fly ash and san fibers.” Vol.34, Issue-1, pp. 37-42. [5] K.S. Elango & V. Revathi (2016) , “Properties of PPC Binder Pervious Concrete”, Construction International Journal of Advanced Engineering Technology, Vol.07 , Issue 2, pp. 91–99. [6] K.S. Elango & V. Revathi (2017), “Fal-G Binder Pervious Concrete”, Construction andBuildingMaterials,Vol.140, pp. 91–99. [7] S. Maheswaran. B. Nandhagopalaguhan, P. Niveditha, K. Pasupathi, Elango. K.S (2018), “Experimental Study on Pervious Concrete with Pebbles as a Coarse Aggregate”, International Journal for Innovative ResearchinScience & Technology, Vol. 4, Issue 11, pp. 26-30. [8] B Siva Prasad, T Sahithi (2018) , “An Experimental Investigation on Durability Studies of Concrete by using Different Types of Cements (OPC, PPC & PSC), International Research Journal Of Engineering And Technology, Vol.5, Issue 11, pp.1538-1544. [9] IS 10262: 2009, “Concrete Mix Proportioning – Guidelines”, Bureau of Indian Standards, New Delhi, India. [10] IS 456: 2000, “Plain and reinforced concrete – Code of practice”, Bureau of Indian Standards, New Delhi, India. [11] IS 12269: 2013, “Ordinary Portland cement 53 grade – Specification”, Bureau of Indian Standards, New Delhi, India. [12] IS 4031: 1988,” Methods of physical tests for hydraulic cement”, Bureau of Indian Standards, New Delhi, India. [13] IS 383:1970, “Coarse and fine aggregate for concrete – Specification”, Bureau of Indian Standards, New Delhi, India. [14] IS 2386: 1963, “Methods of tests for aggregates for concrete”, Bureau of Indian Standards, New Delhi, India