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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 03 | Mar 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 4597
Comparison of Desalination by Reverse Osmosis and Solar Powered
Methods
Hanna P R1, Lubna C H 2
1P.G Student, Department of Civil Engineering, Malabar College of Engineering and Technology,
Desamangalam, Thrissur, Kerala, India
2Assistant Professor, Department of Civil Engineering, Malabar College of Engineering and Technology,
Desamangalam, Thrissur, Kerala, India
---------------------------------------------------------------------***----------------------------------------------------------------------
Abstract - Water is the source of life, the basis of human
survival, and the principal material base to guarantee the
economy substantial development of a country. With
increasing global population, the gap between the supply and
demand for water is widening and is reaching such alarming
levels that in some part of the world, it is posing a threat to
human existence. The fresh water scarcity is a growing
problem all over the world because only 1% of earth’swateris
fresh water available for human to drink. The US geological
survey found that 96.5% of earth’s water is locatedinseasand
oceans and 1.7% of earth’s water is located in theicecaps. The
remaining percentage is made up of brackish water, slightly
salty water found as surface water in estuaries and as
groundwater in salty aquifers. The need for fresh water is at
the top of the international agenda of critical problems, at
least as firmly as climate change. India as a country has 16%
of the world’s population and 4% of its fresh water resources.
In recent years, the increasing threat to water qualityisdue to
human activities has become a matter of great concern.
Problems present today are caused by contamination and by
over exploitation, or by combination of both, which are faced
by many Indian states.
This project deals with comparison of conventional method of
desalination ie by solar powered desalination and a
technological method of desalinationbyReverse osmosis. With
current technology; it requires great amounts of energy to
desalinate ocean water on a scale large enough to meet the
needs of a whole city. For this reason, most cities stick with
traditional sources of freshwater, such as underground
aquifers, rivers, lakes, andrunofffromsnowpack. Somepeople,
like those in rural Indian villages, use an alternative to
burning oil for desalination-solar power. Today, reverse
osmosis (RO) membranes are the leading technology for
desalination because of their strong separation capabilities
and exhibiting a great potential for treatment of waters
worldwide. Reverse osmosis (RO) desalination is a treatment
process for production of fresh, low salinity potable water
from saline water sources via membrane separation. The
mineral/salt content of the water is usually measured by the
water quality parameter named total dissolved solids (TDS).
Keywords: Desalination, Reverse Osmosis, Membrane
Process, , fouling.
1. INTRODUCTION
Reverse osmosis (RO) membranes are the leading
technology for desalination because of their strong
separation capabilities and exhibiting a great potential for
treatment of waters worldwide.Thisprocesswasintroduced
near 1970s but did not attain commercial status as other
desalination processes, partly because membranes suitable
for the processes were not available at reasonable prices. In
many situations, the energy is available at minimal cost, so
membrane distillation will not be as costly as typical
desalination processes which are more energy intensive. It
also means that theoretically a high water recovery for sea
water desalination (of the order of 80 per cent) is possible,
compared with a typical 35-40 percentfortheROtechnique.
The ability to work withnear-saturatedsolutionsalsomeans
that the method can be used to enhance industrial salt
recovery processes and sea water conversion processes.
1.1 OBJECTIVES
The project deals with comparison of conventional method
of desalination ie by solar powered desalination and a
technological method of desalination by Reverse osmosis.
With current technology, it requiresgreatamountsof energy
to desalinate ocean water on a scale large enough to meet
the needs of a whole city. For this reason, most cities stick
with traditional sources of freshwater, such as underground
aquifers, rivers, lakes, and runoff from snowpack. Some
people, like those in rural Indian villages, use an alternative
to burning oil for desalination-solar power.
1.2 SCOPE OF THE PROJECT
Today, reverse osmosis (RO) membranes are the leading
technology for desalination because of their strong
separation capabilities and exhibiting a great potential for
treatment of waters worldwide. Reverse osmosis (RO)
desalination is a treatment process for production of fresh,
low salinity potable water from saline water sources via
membrane separation. Themineral/saltcontentofthe water
is usually measured by the water quality parameter named
total dissolved solids (TDS). Reverse Osmosis (RO) is a
process that uses semipermeable spiral wound membranes
to separate and remove dissolved solids, organic, pyrogens,
submicron colloidal matter, color, nitrate and bacteria from
water. Feed water is delivered under pressure through the
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 03 | Mar 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 4598
semi permeable membrane, where water permeates the
minute pores of the membrane and is delivered as purified
water called permeates water.
2. MATERIALS AND METHODS
The osmosis flow is reversed in the RO process. By applying
hydraulic pressure to the high-concentration side of the
solution, it forces solvents to filter through the membrane,
against a pressure gradient into the lower-concentrate
solution. In RO, using a mechanical pump, pressure is
applied(350psi) to a solution via one side of the semi-
permeable membrane to overcome inherent osmotic
pressure. The process also removes soluble and particulate
matter, including salt from seawaterindesalinationfrom the
solution of interest.
When pressure applied on the concentratedsideofthesemi-
permeable membrane beyond the osmotic pressure of the
solution, the solvent begins to flow toward the less
concentrated side. Solvent from the concentrated solution
(water) passes through the membrane to the solution of
lower concentration; thus, the concentration of solute in the
side where the pressure is applied becomes higher. Because
RO depends on a diffusive mechanism, separation efficiency
varies based on solute concentration (TDS), pressure
applied, and water temperature. High-pressure pumpsinRO
systems force water through the pores of the membranes
(permeate), and the remaining water with higher
concentrations of solutes is pushed out as wastewater
(brine)
2.1 Membrane (Polyamide membrane)
Polyamide membrane is used for reverse osmosis by
considering that the membrane should be inexpensive,have
longer and stable life, membrane should be easily
manufactured with good salt rejectioni.e.slightlypermeable
to salt. They should have highwaterfluxi.ehighlypermeable
to water and less susceptible to fouling. They should permit
the flow of large amounts of water through the membrane
relative to the volume they occupy. The membrane should
chemically, physically and thermally stable in saline waters.
They need to be strong enough to withstand high pressures
and variable feed water quality.
Fig 1: RO membrane
Fig2: Reverse osmosis setup
2.2 Solar Powered Desalination
With current technology, it requiresgreatamountsof energy
to desalinate ocean water on a scale large enough to meet
the needs of a whole city. For this reason, most cities stick
with traditional sources of freshwater, such as
underground aquifers, rivers, lakes etc. Some people, like
those in rural Indian villages, use an alternative to burning
oil for desalination-solarpower.Followingaretheprocedure
for solar powered desalination:
1. Collect the saltwater sample in a measuring bowl and add
few drops of beetroot essence to impart red color(red
infrared color, for large scale, food colorings can be used).
2. To make desalinators take 6 small bolws, where 3 for low
salinity marked as D1,D2,D3. Add additional 3 tablespoon of
salt to it and mark as high salinity desalinators as D1,D2,D3.
3. Place each of your six small cups inside each of the six
bowls. Position the cups in the middle of the bottom of the
bowls.
4. Cover the top of each bowl with a large piece of plastic
wrap. Leave extra around the edges. Press down slightly
with your fingers into the middle of each piece of plastic so
that it sags down toward the cup as in the figure:
Fig3: Desalinator setup
Table 1: Desalinated Water Quality Parameters
Paramet
ers
Method
of
analysis
Unit Value
Solar
desalin
ation
Value
RO
method
Std
limit(I
S3025)
1 PH PH
paper
- 7.5 7.2 6.5-8.5
2 Alkalinity Titrimet
ric
method
Mg/l 72 81 200
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 03 | Mar 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 4599
3 Hardness
-Calcium
EDTA
Titration
Mg/l 43 38 75
4 Megnesui
m
EDTA
Titration
Mg/l 10 20 30
5 Chloride Argento
metric
method
Mg/l 70 65 250
6 Iron Phenath
roline
Method
Mg/l 0.16 0.13 0.3
3. CONCLUSION
The efficiency of reverse osmosis method of desalination is
95% as compared to 88% of solar powered desalination.
Feed water containing suspended particles, organic matter
as well as inorganic salt may deposit on the membrane and
fouling will occur or damage the membrane because of
applied pressure and size of particles. Therefore thepriority
to remove these by way of pretreatment will determine the
RO efficiency. Hence RO membrane performance can be
checked to avoid the irreversible damages to the RO
membrane. In fact success of RO system depends upon
efficiency of the pre-treatment. Solar powered desalination
is eco friendly and cheap as compared to reverse osmosis
method and can be used for both commercial, domestical
and industrial purposes. On the other hand reverse osmosis
method have more efficiency due to its technical support, it
is more applicable in industries as well as commercial
purposes.
REFERENCES
[1]Sunil J. Wimalawansa, “Purification of Contaminated
Water with Reverse Osmosis: Effective SolutionofProviding
Clean Water for Human Needs in Developing Countries”
International Journal of Emerging TechnologyandAdvanced
Engineering,Volume 3, Issue 12, December 2013)
[2]Garud R. M., Kore S. V., Kore V. S., Kulkarni G. S., “A Short
Review on Process and Applications of Reverse Osmosis,
Universal Journal of Environmental Research and
Technology”, Volume 1, Issue 3: 233-238
[3]Y. Li and K. Tian, “Application of vacuum membrane
distillationin water treatment,” Journal of Sustainable
Development,vol. 2, no. 3, pp. 183–186, 2009.
[4]B. L. Pangarkar, P. V. Thorat, S. B. Parjane, and R. M.
Abhang, “Performance evaluation of vacuum membrane
distillation for desalination by using a flat sheet membrane,”
Desalinationand Water Treatment, vol. 21, no. 1-3, , 2010.
[5]L. F. Greenlee, D. F. Lawler, B.D.Freeman,B.Marrot,andP.
Moulin,“ Reverse osmosis desalination:water
sources,technology,andtoday’schallenges,”WaterResearch,
vol. 43,no. 9, 2009.
[6]T. Abraham and A. Luthra, “Socio-economic andtechnical
assessment ofphotovoltaicpoweredmembranedesalination
processes for India,” Desalination, vol. 268, no. 1–3, 2011.
[7]R. Kumar, R. D. Singh, and K. D. Sharma, “Water resources
of India,” Current Science, vol. 89, no. 5, pp. 794–811, 2005.

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IRJET -Comparison of Desalination by Reverse Osmosis and Solar Powered Methods

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 03 | Mar 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 4597 Comparison of Desalination by Reverse Osmosis and Solar Powered Methods Hanna P R1, Lubna C H 2 1P.G Student, Department of Civil Engineering, Malabar College of Engineering and Technology, Desamangalam, Thrissur, Kerala, India 2Assistant Professor, Department of Civil Engineering, Malabar College of Engineering and Technology, Desamangalam, Thrissur, Kerala, India ---------------------------------------------------------------------***---------------------------------------------------------------------- Abstract - Water is the source of life, the basis of human survival, and the principal material base to guarantee the economy substantial development of a country. With increasing global population, the gap between the supply and demand for water is widening and is reaching such alarming levels that in some part of the world, it is posing a threat to human existence. The fresh water scarcity is a growing problem all over the world because only 1% of earth’swateris fresh water available for human to drink. The US geological survey found that 96.5% of earth’s water is locatedinseasand oceans and 1.7% of earth’s water is located in theicecaps. The remaining percentage is made up of brackish water, slightly salty water found as surface water in estuaries and as groundwater in salty aquifers. The need for fresh water is at the top of the international agenda of critical problems, at least as firmly as climate change. India as a country has 16% of the world’s population and 4% of its fresh water resources. In recent years, the increasing threat to water qualityisdue to human activities has become a matter of great concern. Problems present today are caused by contamination and by over exploitation, or by combination of both, which are faced by many Indian states. This project deals with comparison of conventional method of desalination ie by solar powered desalination and a technological method of desalinationbyReverse osmosis. With current technology; it requires great amounts of energy to desalinate ocean water on a scale large enough to meet the needs of a whole city. For this reason, most cities stick with traditional sources of freshwater, such as underground aquifers, rivers, lakes, andrunofffromsnowpack. Somepeople, like those in rural Indian villages, use an alternative to burning oil for desalination-solar power. Today, reverse osmosis (RO) membranes are the leading technology for desalination because of their strong separation capabilities and exhibiting a great potential for treatment of waters worldwide. Reverse osmosis (RO) desalination is a treatment process for production of fresh, low salinity potable water from saline water sources via membrane separation. The mineral/salt content of the water is usually measured by the water quality parameter named total dissolved solids (TDS). Keywords: Desalination, Reverse Osmosis, Membrane Process, , fouling. 1. INTRODUCTION Reverse osmosis (RO) membranes are the leading technology for desalination because of their strong separation capabilities and exhibiting a great potential for treatment of waters worldwide.Thisprocesswasintroduced near 1970s but did not attain commercial status as other desalination processes, partly because membranes suitable for the processes were not available at reasonable prices. In many situations, the energy is available at minimal cost, so membrane distillation will not be as costly as typical desalination processes which are more energy intensive. It also means that theoretically a high water recovery for sea water desalination (of the order of 80 per cent) is possible, compared with a typical 35-40 percentfortheROtechnique. The ability to work withnear-saturatedsolutionsalsomeans that the method can be used to enhance industrial salt recovery processes and sea water conversion processes. 1.1 OBJECTIVES The project deals with comparison of conventional method of desalination ie by solar powered desalination and a technological method of desalination by Reverse osmosis. With current technology, it requiresgreatamountsof energy to desalinate ocean water on a scale large enough to meet the needs of a whole city. For this reason, most cities stick with traditional sources of freshwater, such as underground aquifers, rivers, lakes, and runoff from snowpack. Some people, like those in rural Indian villages, use an alternative to burning oil for desalination-solar power. 1.2 SCOPE OF THE PROJECT Today, reverse osmosis (RO) membranes are the leading technology for desalination because of their strong separation capabilities and exhibiting a great potential for treatment of waters worldwide. Reverse osmosis (RO) desalination is a treatment process for production of fresh, low salinity potable water from saline water sources via membrane separation. Themineral/saltcontentofthe water is usually measured by the water quality parameter named total dissolved solids (TDS). Reverse Osmosis (RO) is a process that uses semipermeable spiral wound membranes to separate and remove dissolved solids, organic, pyrogens, submicron colloidal matter, color, nitrate and bacteria from water. Feed water is delivered under pressure through the
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 03 | Mar 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 4598 semi permeable membrane, where water permeates the minute pores of the membrane and is delivered as purified water called permeates water. 2. MATERIALS AND METHODS The osmosis flow is reversed in the RO process. By applying hydraulic pressure to the high-concentration side of the solution, it forces solvents to filter through the membrane, against a pressure gradient into the lower-concentrate solution. In RO, using a mechanical pump, pressure is applied(350psi) to a solution via one side of the semi- permeable membrane to overcome inherent osmotic pressure. The process also removes soluble and particulate matter, including salt from seawaterindesalinationfrom the solution of interest. When pressure applied on the concentratedsideofthesemi- permeable membrane beyond the osmotic pressure of the solution, the solvent begins to flow toward the less concentrated side. Solvent from the concentrated solution (water) passes through the membrane to the solution of lower concentration; thus, the concentration of solute in the side where the pressure is applied becomes higher. Because RO depends on a diffusive mechanism, separation efficiency varies based on solute concentration (TDS), pressure applied, and water temperature. High-pressure pumpsinRO systems force water through the pores of the membranes (permeate), and the remaining water with higher concentrations of solutes is pushed out as wastewater (brine) 2.1 Membrane (Polyamide membrane) Polyamide membrane is used for reverse osmosis by considering that the membrane should be inexpensive,have longer and stable life, membrane should be easily manufactured with good salt rejectioni.e.slightlypermeable to salt. They should have highwaterfluxi.ehighlypermeable to water and less susceptible to fouling. They should permit the flow of large amounts of water through the membrane relative to the volume they occupy. The membrane should chemically, physically and thermally stable in saline waters. They need to be strong enough to withstand high pressures and variable feed water quality. Fig 1: RO membrane Fig2: Reverse osmosis setup 2.2 Solar Powered Desalination With current technology, it requiresgreatamountsof energy to desalinate ocean water on a scale large enough to meet the needs of a whole city. For this reason, most cities stick with traditional sources of freshwater, such as underground aquifers, rivers, lakes etc. Some people, like those in rural Indian villages, use an alternative to burning oil for desalination-solarpower.Followingaretheprocedure for solar powered desalination: 1. Collect the saltwater sample in a measuring bowl and add few drops of beetroot essence to impart red color(red infrared color, for large scale, food colorings can be used). 2. To make desalinators take 6 small bolws, where 3 for low salinity marked as D1,D2,D3. Add additional 3 tablespoon of salt to it and mark as high salinity desalinators as D1,D2,D3. 3. Place each of your six small cups inside each of the six bowls. Position the cups in the middle of the bottom of the bowls. 4. Cover the top of each bowl with a large piece of plastic wrap. Leave extra around the edges. Press down slightly with your fingers into the middle of each piece of plastic so that it sags down toward the cup as in the figure: Fig3: Desalinator setup Table 1: Desalinated Water Quality Parameters Paramet ers Method of analysis Unit Value Solar desalin ation Value RO method Std limit(I S3025) 1 PH PH paper - 7.5 7.2 6.5-8.5 2 Alkalinity Titrimet ric method Mg/l 72 81 200
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 03 | Mar 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 4599 3 Hardness -Calcium EDTA Titration Mg/l 43 38 75 4 Megnesui m EDTA Titration Mg/l 10 20 30 5 Chloride Argento metric method Mg/l 70 65 250 6 Iron Phenath roline Method Mg/l 0.16 0.13 0.3 3. CONCLUSION The efficiency of reverse osmosis method of desalination is 95% as compared to 88% of solar powered desalination. Feed water containing suspended particles, organic matter as well as inorganic salt may deposit on the membrane and fouling will occur or damage the membrane because of applied pressure and size of particles. Therefore thepriority to remove these by way of pretreatment will determine the RO efficiency. Hence RO membrane performance can be checked to avoid the irreversible damages to the RO membrane. In fact success of RO system depends upon efficiency of the pre-treatment. Solar powered desalination is eco friendly and cheap as compared to reverse osmosis method and can be used for both commercial, domestical and industrial purposes. On the other hand reverse osmosis method have more efficiency due to its technical support, it is more applicable in industries as well as commercial purposes. REFERENCES [1]Sunil J. Wimalawansa, “Purification of Contaminated Water with Reverse Osmosis: Effective SolutionofProviding Clean Water for Human Needs in Developing Countries” International Journal of Emerging TechnologyandAdvanced Engineering,Volume 3, Issue 12, December 2013) [2]Garud R. M., Kore S. V., Kore V. S., Kulkarni G. S., “A Short Review on Process and Applications of Reverse Osmosis, Universal Journal of Environmental Research and Technology”, Volume 1, Issue 3: 233-238 [3]Y. Li and K. Tian, “Application of vacuum membrane distillationin water treatment,” Journal of Sustainable Development,vol. 2, no. 3, pp. 183–186, 2009. [4]B. L. Pangarkar, P. V. Thorat, S. B. Parjane, and R. M. Abhang, “Performance evaluation of vacuum membrane distillation for desalination by using a flat sheet membrane,” Desalinationand Water Treatment, vol. 21, no. 1-3, , 2010. [5]L. F. Greenlee, D. F. Lawler, B.D.Freeman,B.Marrot,andP. Moulin,“ Reverse osmosis desalination:water sources,technology,andtoday’schallenges,”WaterResearch, vol. 43,no. 9, 2009. [6]T. Abraham and A. Luthra, “Socio-economic andtechnical assessment ofphotovoltaicpoweredmembranedesalination processes for India,” Desalination, vol. 268, no. 1–3, 2011. [7]R. Kumar, R. D. Singh, and K. D. Sharma, “Water resources of India,” Current Science, vol. 89, no. 5, pp. 794–811, 2005.