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Hydrogen bond is the attractive interaction of a
hydrogen atom with an electronegative atom , such
as nitrogen, oxygen or fluorine. That comes from
another molecular chemical group.
HYDROGEN BOND
Hydrogen must be covalently bonded with another
electronegative atom to create the bond.
These bonds can occur between molecules or with the
different parts of a single molecule .
Hydrogen bond is stronger than van der waals force
but weaker than covalent bond or ionic bond.
This types of bond occurs in both inorganic molecules
such as water and organic molecules such as DNA.
THERE ARE TWO TYPES OF HYDROGEN
BONDS :
INTERMOLECULAR HYDROGEN BOND
INTERAMOLECULAR HYDROGEN BOND
TYPES OF HYDROGEN BOND
This type of h-bond occurs when hydrogen
bonding is between hydrogen atom of one
molecule and an atom of the
electronegative element of another
molecule.
INTERMOLECULER H- BOND
Intermolecular example
 Hydrogen bond between the molecules of hydrogen fluoride.
 Hydrogen bond in or water molecules.
This type of h-bond occurs when hydrogen
bonding is between hydrogen atom
and an atom of the electronegative
element of same molecule.
INTERAMOLECULER H- BOND
Intramolecular example
 o-nitrophenol
 salicilaldehyde.
H-BOND IN WATER
 The most ubiquitous , and perhaps simplest example of a
hydrogen bond is found between water molecules.
 It can form a h-bond with other water molecules ,this can
go up to four h-bonding in with single molecule.
 Liquid waters high boiling point is due to high number of
h-bonds each molecule can form relative to its low
molecular mass.
 Owing to the difficulty of breaking these bonds water has
a very high boiling point, melting point and viscosity
compared to other similar liquids not conjoined by
hydrogen bonds.
H-BOND IN DNA
 Hydrogen bonding plays an important role in determining
the tree dimensional structures adopted by proteins and
nucleic bases.
 The double helical structure of DNA for example is due to
largely hydrogen bonding between the base pairs, which
links one complementary strand to the other and enable
replication
HISTORY
• In the book “the nature of the chemical bond.” Linus Pauling
credits T.S.Moore and T.F.Winmill with the first mention of the
hydrogen bond in 1912
• Moore and Winmill used the hydrogen bond to account for the
fact that trimethylammonium hydroxide is a weaker base than
tetramethylammonium hydroxide.
• The description of hydrogen bonding in its more well known
setting,water came some years later in 1920 from Latimer and
Rodebush

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HYDROGEN BOND .pptx

  • 1. Hydrogen bond is the attractive interaction of a hydrogen atom with an electronegative atom , such as nitrogen, oxygen or fluorine. That comes from another molecular chemical group. HYDROGEN BOND
  • 2. Hydrogen must be covalently bonded with another electronegative atom to create the bond. These bonds can occur between molecules or with the different parts of a single molecule . Hydrogen bond is stronger than van der waals force but weaker than covalent bond or ionic bond. This types of bond occurs in both inorganic molecules such as water and organic molecules such as DNA.
  • 3. THERE ARE TWO TYPES OF HYDROGEN BONDS : INTERMOLECULAR HYDROGEN BOND INTERAMOLECULAR HYDROGEN BOND TYPES OF HYDROGEN BOND
  • 4. This type of h-bond occurs when hydrogen bonding is between hydrogen atom of one molecule and an atom of the electronegative element of another molecule. INTERMOLECULER H- BOND
  • 5. Intermolecular example  Hydrogen bond between the molecules of hydrogen fluoride.  Hydrogen bond in or water molecules.
  • 6. This type of h-bond occurs when hydrogen bonding is between hydrogen atom and an atom of the electronegative element of same molecule. INTERAMOLECULER H- BOND
  • 9.  The most ubiquitous , and perhaps simplest example of a hydrogen bond is found between water molecules.  It can form a h-bond with other water molecules ,this can go up to four h-bonding in with single molecule.  Liquid waters high boiling point is due to high number of h-bonds each molecule can form relative to its low molecular mass.  Owing to the difficulty of breaking these bonds water has a very high boiling point, melting point and viscosity compared to other similar liquids not conjoined by hydrogen bonds.
  • 11.  Hydrogen bonding plays an important role in determining the tree dimensional structures adopted by proteins and nucleic bases.  The double helical structure of DNA for example is due to largely hydrogen bonding between the base pairs, which links one complementary strand to the other and enable replication
  • 12. HISTORY • In the book “the nature of the chemical bond.” Linus Pauling credits T.S.Moore and T.F.Winmill with the first mention of the hydrogen bond in 1912 • Moore and Winmill used the hydrogen bond to account for the fact that trimethylammonium hydroxide is a weaker base than tetramethylammonium hydroxide. • The description of hydrogen bonding in its more well known setting,water came some years later in 1920 from Latimer and Rodebush

Editor's Notes

  1. Tetrahedral configuration of water molecules