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THE EFFECTS OF AN INSULATED HEMA COLUMN
NICK HUANG
PRODUCTION INTERN
2016 BIMAX INC.
BACKGROUND
Reactor 1
 Mitsubishi
 Less MEHQ
 Light ends less stable than DOW
 Less polymer buildup
Reactor 4
 DOW
 More EGDMA
 Significantly more MEHQ
 Substantial polymer buildup
BACKGROUND
The Process
 Distillation
 Cutting the deck
 Separating components by boiling points
 Affected by temperature, vacuum, column type
 Blending
 Cuts from past batches
BACKGROUND
Various cut windows Fractionation
OUR GOAL
 Improve fractionation
 Observe effects on clean out
 Quicker turn around
 Polymerization
 Identify relationships between output
and insulation
 Pot & head temp, vacuum, fractionation,
polymer build up
 Make changes accordingly
 Lower reactor/jacket or column temp
PROCEDURE
 Clean reactor 1 & 4
 Run 2 batches with super clean out
 Ordered materials from McMaster
 Pipe/R-30 fiber glass insulation
 Wrapped columns and head
 Thermocouple on side of columns
 Skin temp ~ 58oC
DATA
 4 Batches for reactor 1
 Distillation time reduced by ~30 hours
 6 Batches for reactor 4
 Distillation time reduced by ~20 hours
DATA
DATA
 Polymer data for 4 batches
OBSERVATIONS
 Insulated, lower pot temp
 Improve fractionation
 Maintain/reduce the level of polymer
Several scenarios
 Insulated, normal pot temp
 Reduction in distillation time
 Reduced fouling
 Diminished fractionation
MOVING FORWARD
 Run more batches
 Meticulously cleaned out
 Monitor cleanliness
 Run numerous batches with reduced pot temp
 Improve fractionation
 Spend more time in cut 1 window
 Observe affect on fouling

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HEMA Presentation

  • 1. THE EFFECTS OF AN INSULATED HEMA COLUMN NICK HUANG PRODUCTION INTERN 2016 BIMAX INC.
  • 2. BACKGROUND Reactor 1  Mitsubishi  Less MEHQ  Light ends less stable than DOW  Less polymer buildup Reactor 4  DOW  More EGDMA  Significantly more MEHQ  Substantial polymer buildup
  • 3. BACKGROUND The Process  Distillation  Cutting the deck  Separating components by boiling points  Affected by temperature, vacuum, column type  Blending  Cuts from past batches
  • 5. OUR GOAL  Improve fractionation  Observe effects on clean out  Quicker turn around  Polymerization  Identify relationships between output and insulation  Pot & head temp, vacuum, fractionation, polymer build up  Make changes accordingly  Lower reactor/jacket or column temp
  • 6. PROCEDURE  Clean reactor 1 & 4  Run 2 batches with super clean out  Ordered materials from McMaster  Pipe/R-30 fiber glass insulation  Wrapped columns and head  Thermocouple on side of columns  Skin temp ~ 58oC
  • 7. DATA  4 Batches for reactor 1  Distillation time reduced by ~30 hours  6 Batches for reactor 4  Distillation time reduced by ~20 hours
  • 9. DATA  Polymer data for 4 batches
  • 10. OBSERVATIONS  Insulated, lower pot temp  Improve fractionation  Maintain/reduce the level of polymer Several scenarios  Insulated, normal pot temp  Reduction in distillation time  Reduced fouling  Diminished fractionation
  • 11. MOVING FORWARD  Run more batches  Meticulously cleaned out  Monitor cleanliness  Run numerous batches with reduced pot temp  Improve fractionation  Spend more time in cut 1 window  Observe affect on fouling

Editor's Notes

  1. Packed column, plate column, explain MEHQ, high/low boilers, what is done to HEMA (blends etc.) MEHQ = Inhibitor, decreases rate of reaction/polymerization EGDMA
  2. Packed column, plate column, explain MEHQ, high/low boilers, what is done to HEMA (blends etc.) Show cut data What’s in HEMA
  3. What did we expect it to do? To speed up the distillation, since the temp of the column is ~2 degrees high
  4. Elaborate on polymer
  5. only run 4 – 6 batches. Need more to get a better idea. Operators says it seems the same
  6. Temperature affecting polymer
  7. No where near finished with experiment. Need another 6 months