2. 2
Agenda
AGA Gas AB
Laws, regulations and rules
Gases
Risks
Handling
Storage of gas cylinders
Colour marking of gas cylinders
Gas equipment
Training
Summary
5. 5
”Solve the problems of customers. Give themthe opportunity to increase profitability,
safety and quality in theiroperations. Help them to introduce new, better
technology.”
G USTAF DALÈN, President of AGA 1909-1937
6. 6
AGA Gas AB– part of The Linde Group
• 50.000 employees in more than 100 countries
• Turnover 2011 – 100 billion SEK
AG A, Linde o ch BO C
7. 7Page 7
The Linde Group Today
Result of world´s biggest gas fusion Merging of Linde Gas, AGA and BOC
with three principal operations:
Industry Gases Engineering Healthcare
8. 8
Industry Gases are ourmain focus
OtherGases
Specialty Gases
Medical Gases
AirGases • Nitrogen
• Oxygen
• Acetylene
• Helium
• Propane
• HiQ High Purity Gases
• HiQ Specialty Mixtures
• Temperatures: from -269 o
C up to +3.500 o
C
• Pressure: from 0 to 300 bar
• Purity: up to 99,99999%
• Medical Oxygen
• Nitrous oxide
• NO-mixtures
Working Areas
• Carbon dioxide & -monoxide
• Hydrogen
• Refigerants
• Argon
• Inert Gases (Kr, Ne, Xe)
• Methane
11. 11
Requirements of employerand users
Lag om skydd mot olyckor– Law about protection against accidents
Arbetsmiljölagen – Law about working environment
Lag om brandfarliga och explosiva varor– Law about flammables and
explosives
Kemiska arbetsmiljörisker (AFS 2011:19) – Risks in chemical work
environment
Gaser(AFS 1997:7) – Gases
Gasflaskor(AFS 2001:4) – Gas cylinders
Användning av tryckbärande anordningar (AFS 2002:1) – Use of pressurised
devices
Brandfarlig gas i lös behållare (SÄIFS 1998:7) – Flammable gas in a cylinder
Arbete i explosionsfarlig miljö (AFS 2003:3) – Working in explosive
environment
Explosionsfarlig miljö vid hantering av brandfarliga gaseroch vätskor
(SRVFS 2004:7) – Handling of explosive gases and liquids in an explosive
12. 12
Regulations of Swedish WorkEnvironment
Authority AFS 1997:7
1 § These regulations applies to all operations using gas.
3 § In all operations where gas is used a riskassessment needs to be done. Any change in
process, equipment oroperating conditions -> new riskassessment needs to be done.
4 § Working with gas can only be managed or performed by a person with enough knowledge
about the gas, about the risks when using gases and how to avoid these risks.
13. 13
Responsibilty of Gas Superintendent
• Gas storage roomlocked and not accessible for unauthorized persons
• Always a person attending at unloading/loading of gas deliveries
• Safety signs according to legislations where gas cylinders are stored
• Combustible gases (i e acetylen, LPG) should not be stored together with combustion supporting gases
(i e oxygen, nitrous oxide), this also includes empty cylinder
• Store cylinders vertically and securely to prevent themfromtoppling
• Make sure that protection hood stays on cylinder
• Inside and outside of gas storage roomis clean
• That staff are using safety shoes and clothes when working with gas
• That handling of gases are according to regulations
14. 14
Who appoints gas superintendent
A person who is in charge of flammable products
A signatory
A suitable gas superintendent:
● Working in the daily operations
● Has knowledge and experience of working with gas
15. 15
RiskAssessment
Documented (Best before date 2004)
Should be the basis of:
• Actions
• Programfor continuos inspections
• Register of gases and how dangerous they are
• Information about possible risks
• Competence of staff working with gases
• Routines and instructions forworking with gases
• Design of working area
• Storage/Handling
• Warning signs
• Documentation of explosive protection
• Plan of emergency
17. 17
RiskAssessment Matrix
1 2 3 4 5
>1 time per
1 month 5
1 time per
1 month-1 year 4
1 time per
1 year-10 year 3
1 time per
10 year-100
year
2
<1 time per
100 year 1
Health
Transient mild
discomfort
Single injured,
lasting
discomfort
Single severe
injured,
severe
discomfort
Single death,
several
severe
injured
Several deaths ,
tens severe
injured
Environment
No actual damage.
Small
propagation.
No cleanup.
Transient, brief
damage
Small
propagation.
Simple
cleanup.
Prolonged damage.
Small to big
propagation.
Simple cleanup.
Permanent damage.
Small
propagation.
Difficult cleanup.
Permanent damage.
Big
propagation.
Difficult cleanup.
Property <0,1 million SEK 0,1-1,0 million SEK 1-5 million SEK 5-20 million SEK >20 million SEK
Midddle risk
High risk
Low risk
18. 18
When not following the legislation…
Consequenses
Compensation from insurance company is based on legal requirements.
19. 19
Risk- and safety services
Safety Engineers at AGA Gas AB:
Jan Fransson
Magnus Olsson
Give a status of your gas system
Show the way to a safety gas system
25. 25
How much gas in a cylinder?
200 bar
50 litres Atmospheric pressure
10 000 litres = 10 m3
200 x 50 = 10 000 litres = 10 m3
26. 26
Condensed gases is liquid in the cylinder
LPG
95% Propane C3H8 - 42 °C
5% Butane C4H10 ± 0 °C
Carbon dioxide CO2 - 78 °C
Nitrous oxide N2O - 88 °C
27. 27
Kryos is from greeklanguage, meaning very cold
Liquid gases = Cryogenic gases
29. 29
Absorbed gas
Acetylene is a special case
Acetylene C2H2 - 84 °C
Can not be stored in high pressure due to riskof
spontaneously decay:
• Porous mass
• Acetone
• Acetylene solved (absorbed) in acetone
30. 30
Light and heavy gases
Hydrogen 0,07
Helium 0,14
Acetylene 0,91
Nitrogen 0,97
Air 1,0
Oxygen 1,11
Argon 1,38
Carbon dioxide 1,53
LPG (propane) 1,56
31. 31
Gas cylinders
Gas
Phase of the gas
Pressure of gas (bar)
Temp riskforbursting
valve
Excess pressure
protection
Weight gas compare to air
Dissolved in
acetone in a
porous mass
17
100 °C
No
Somewhat
lighter
Gas
200
350 °C
No
Somewhat heavier
Liquid
50
100 °C
Bursting disc
Heavier
Liquid
7
100 °C
Safety valve
Heavier
Acetylene
Oxygen +
otherairgases
Carbon dioxide LPG
33. 33
Oxygen O 2
Nitrogen N2
Argon Ar
Helium He
Hydrogen H2
Carbon dioxide
CO 2
Nitrous gas N2O
LPG C3H8
Acetylene C2H2
Combustible
Combustion
supporting gas Inert/asphyxiating
Permanent
Condensed
Absorbed
Risks with gases
34. 34
Risks with with gases
• High pressure
• Inert/asphyxiating gas
• Fire and explosion
• Poisonous gas
• Low temperature
35. 35
Asphyxiating – Invisible danger
Most accidents with asphyxia happends because rules
have not been followed.
Typical causes could be:
● Deviated from current working environment rules.
● Training and control of work not sufficient.
● Defiencies in supervision team.
KVÄVNINGSRISK
AFS 1997:7 6 § In working area the ventilation
should be good enough that oxygen content
normally is not less than 20%. When oxygen
content in a working area is below 18% breathing
apparatus should be used.
40. 40
• Wear personal protective equipment (PPE) i.e. safety
shoes and gloves, gas detector
• Read safety data sheet
• Handle cylinders gently
• Protect cylinder from high temperature and mechanical
impact
• Store cylinders vertically and securely to prevent them
from toppling
• When transporting gas cylinder use a cart
• Open valve carefully
• Make sure that oxygen is not in contact with grease
• Liquid gases always a risk of frost-bite if contact with
skin – wear correct PPE
Handling of gas cylinders
41. 41
• Handle and store in well-ventilated spaces
• Not stored in sealed container
• Use personal protective equipment
• In contact with skin –> frost-bite
Carbon dioxide – Handling dry ice
42. 42
LPG
Pressure and liquid volume at different temperature for a filled LPG-cylinder
15 °C
7 bar
50 °C
18 bar
65 °C
24 bar
44. 44
What is suitable
working clothes?
• Safety googles/Visor
• Gloves
• Boots
• Covered working clothes
Personal safety – liquid gases
45. 45
1. Frost-bites are treated as burns
- Water!
- Do not put any bandage orsimilaron the
wound! Can cause more damage.
2. If necessary go to hospital
How to treat frost-bite?
47. 47
Handling liquid gases
What is missing?
Always pant legs outside boot
shafts!
1. Safety googles / visor
2. Gloves
3. Protect environment to damages
4. Personal gas detector
What else to remember?
49. 49
Combustion gas – what does the law says?
§ Handling and storage should be with precaution to
avoid riskforfire.
§ Storage roomperformed in a safety way, preventing
fire to occur.
§ Equipment installed carefully and with competence.
50. 50
Actions when fire
Warn staff and evacuate the area
Call 112
If possible with safety respect
Shut off gas cylinders, take away cylinders
Cool cylinders with waterfroma safe space
Markgas cylinders that has been in a fire, contact AGA
51. 51
Actions when gas leaking out of cylinder
Close the valve of gas cylinder
Ventilate the area
Evacuate
If a bigger gas leakage – rope off the area
Alarm rescue department if a big gas leakage
Identify what was causing the gas leakage –
change broken part
If gas is liquid or cold – measure gas content in
lower areas
53. 53
• Separate combustible gases
fromothers gases
• Well closed cylinders
• Protect against abnormal
heating
• Well ventilated area
• Store cylinders inaccessible
forunauthorized people
• Warning signs
Storage of gas cylinders
Gas
storage
Acetylene Oxygen
55. 55
Colourmarking – safety
• Colour marking according to european standard
– EN 1089-3
• The colour of the cylinder breast informs about the property
of the gas in the cylinder
• Identification of gas property from a long distance
• Important for emergency personnel
56. 56
Cylindercolours
Colourof cylindernot regulated by standard. AGA has choosed following colours:
Black
Industrial
gases
Acetylene Food gases Specialty gases Medical gases
Maroon Green Silvergrey White
59. 59
What information on cylinderlabel?
1. Product name
2. Product information
3. Warning symbol(s)
4. Material number
5. Transport information
6. Safety information
1 2 3 4
5 6
61. 61
Gas equipment
• Gas panels
• Point of use
• Cylinder regulators
• Flame barrier C2H2
• Setback protection C2H2
• Central gas supply system
62. 62
Continous supervision
AFS 2002:1 Use of pressurised devices, central gas supply system
• Control
• That controls and ev inspections are performed
• Function control
• Gas panels, point of uses, setback protection (C2H2) etc
• Leak detection and ocular inspection of pipe system
• Recommendation 2 times/year when combustible gases
• Known defiencies corrected
• Control of risk assessment, safety inspections, reports of incident
• Marking, visible
• Media, flow direction, safety sign
• Instructions for operation
• Flowchart, updated
63. 63
Continous supervision, continued
• Ocular control/change of hose (both high and low pressure hose)
• Control of gas system according to supplier both daily and yearly
inspections
• Control that gas cylinders are chained
• Controll of setback protection (C2H2) every 24st month
Part or all of supervision of gas system can be done by another company
but it is the responsibility of the ownerof the gas systemthat the
supervision is done.
66. 66
Training
AGA Gas ABoffers following trainings:
1) Open courses at AGA Gas AB:
● Safety handling of gas
● Gas safety according to laws, regulations and rules
● Superintendent training for a bigger gas system
2) Courses at customersite
More information at: www.aga.se orfrom yourlocal sales representative
67. 67
Summary
• Gas superintendent
• Competent staff
• Riskassessment
• Be aware of risks with gases: high pressure, asphyxiating, poisonous, combustible, coldness
• Correct handling and storage of gas cylinders: chained, separate combustible gases from
othergases, well ventilated working areas, personal protective equipment, gas detector
• Colourmarking of gas cylinders, especielly yellow and red colours
• Continous supervision /yearly maintenance of gas equioment
• Continous training
70. 70
Contact information AGA Gas AB
• Melina van Meer
• 0767-244 786
• melina.van.meer@se.aga.com
• www.aga.se
• gasorder@se.aga.com
Editor's Notes
Lag (1988:868) om brandfarliga och explosiva varorLagens syfte är att hindra att sådana varor orsakar brand eller explosion som inte är avsedd samt att förebygga och begränsa skador på liv, hälsa, miljö eller egendom genom brand eller explosion vid hantering av sådana varor. Med hantering avses i bl a förvaring, transport och användning av dessa varor.
Med tillståndshavaren avses företagets VD eller ”den som tecknar firman”. Denne kan dock delegera ansvaret till ”gasföreståndare” som upprättar instruktioner och kontrollerar att dessa efterföljs.
Enligt lagen ska den som hanterar brandfarliga eller explosiva varor vidta de åtgärder och de försiktighetsmått som behövs för att förhindra brand eller explosion som inte är avsedd och för att förebygga och begränsa skador på liv, hälsa, miljö eller egendom genom brand eller explosion.
När gas övergår från flytande till gasfas sker en volymutvidgning. Volymutvidgningen är olika för olika gaser och beror också av tryck och temperatur.
1 liter flytande oxygen ger 842 liter gas
1 liter flytande nitrogen ger 681 liter gas
1 liter flytande argon ger 825 liter gas
Beakta den risk som uppstår om flytande gas läcker ut och förgasas.
Till stora förbrukare är det effektivt att leverera gasen i flytande form i tankbilar. En enda tankbil kan till exempel transportera 20.000 liter eller mera flytande oxygen. Om motsvarande mängd skulle transporteras komprimerad gas i flaskor skulle det gå åt 11 lastbilar.
Gasolflaskan är försedd med en säkerhetsventil, som öppnar och släpper ut lite gas om trycket inne i flaskan blivit för högt (vilket det kan bli om flaskan utsätts för värme). Ventilen stängs automatiskt, när trycket sjunkit under risknivån. Om flaskan förvaras liggande kan säkerhetsventilen komma att hamna under vätskenivån och om den behöver utlösa släpper den ut vätska istället. Trycksänkningen blir inte lika effektiv och gasolvätskan, som hinner släppas ut, förgasas till stora mängder gas.
Tänk speciellt på detta när du transporterar en gasolflaska i din bil!
Färgen på flaskan påverkas inte av den nya standarden. AGA behåller svart för industrigaser, silver för specialgaser och vitt för medicinska gaser. En nyhet är att gaser för livsmedelsindustrin får en grön flaskkropp.
Även för specialgaser är färgmärkningen av rengaser densamma som för industrigaser. Flaskan är silverfärgad istället för svart.