Fun chirality
Ph.D. Ksenia Kozlovskaya
Moscow State University
1
1. Chirality - WTF?
2. Chirality in everyday life.
3. Chirality in science:
3.1 Math
3.2 Astronomy
3.3 Chemistry
3.4 Biology
3.5 Crystallography
2
Chirality is the lack of right-left
symmetry.
Chiral objects has no mirror
planes.
Enantiomers (optical isomers)
are chiral objects that are
mirror images of one another.
3
1. Chirality - WTF?
(с) http://physicsworld.com/
4
2. Enantiomers in everyday life.
There are right
and left ways to tie
a simple knot.
Our hands, shoes
and ears are
enantiomers.
Architects like to
create buildings-
enantiomers.
5
2. Chirality in the everyday life.
That is the enantiomer for this car?
6
2. Chirality in the everyday life.
In a sense, left and right-hand drive cars are enantiomers.
Spinning top is a symmetrical object moving on the
asymmetrical helix path.
7
2. Chirality in everyday life.
Spinning top is a symmetrical object moving on the
asymmetrical helix path.
8
2. Chirality in everyday life.
Fan blades are cut from the helical surface. That happens if
you replace them with mirror blades?
9
2. Chirality in everyday life.
Fan blades are cut from the helical surface. If you replace
them with mirror blades, the fan will turn into a vacuum
cleaner.
10
2. Chirality in everyday life.
1. Chirality - WTF?
2. Chirality in everyday life.
3. Chirality in science:
3.1 Math
3.2 Astronomy
3.3 Chemistry
3.4 Biology
3.5 Crystallography
11
12
3.1 Chirality in mathematics.
If objects are chiral in a space of n dimensions, they
can be combined in a space of n+1 dimensions.
13
3.1 Chirality in mathematics
and literature.
Gottfrieb Plattner got into 4-
dimentional world, and after
return he discovers that he is
now left-handed, and his
internal anatomy has
apparently inverted left and
right.
14
3.1 Chirality in
mathematics.
Spirals
If you've seen something
in mathematics, most
likely you’ll find it in a real
world.
15
3.1 Chirality in
mathematics.
2D Spirals
Are the galaxies chiral?
16
3.1 Chirality in mathematics. 3D Spirals
© http://blog.atlasrfidstore.com/
Right and Left circular polarized waves are enantiomers.
17
3.1 Chirality in
mathematics. 3D Spirals
Like humans, snails can be right-
handed and left-handed.
1. Chirality - WTF?
2. Chirality in everyday life.
3. Chirality in science:
3.1 Math
3.2 Astronomy
3.3 Chemistry
3.4 Biology
3.5 Crystallography
18
The Sun is a sphere. It’s symmetrical.
The Sun is rotating sphere, but rotating
sphere is still symmetrical
But Sun is rotating sphere with magnetic
moment! And it made sun chiral.
Sometimes the Sun's magnetic axis
changes direction, and Sun turns into its
own enantiomer.
N
S
19
3.1 Chirality in mathematics and astronomy
The Earth’s shape called
Geoid. Geoid is chiral.
20
3.2 Chirality in
Astronomy. The Earth
1. Chirality - WTF?
2. Chirality in everyday life.
3. Chirality in science:
3.1 Math
3.2 Astronomy
3.3 Chemistry
3.4 Biology
3.5 Crystallography
21
3.3 Chirality in chemistry
22
Methane СH4 Methanol СН3ОН Ethanol С2Н5ОН Amyl C5H11OH
23
3.3 Chirality in chemistry
This is a chiral structure with asymmetric
carbon atom.
And this is a meso-tartaric
acid, it’s symmetrical again.
24
3.3 Chirality in chemistry
How to define if the molecular
structure are right or left-handed?
Right crystal rotate the plane of
polarization (of polarized light) in a
clockwise.
Left crystal rotate the plane of
polarization in a counter-clockwise.
25
3.3 Chirality in chemistry
3.3 Chirality in chemistry
26
1. Chirality - WTF?
2. Chirality in everyday life.
3. Chirality in science:
3.1 Math
3.2 Astronomy
3.3 Chemistry
3.4 Biology
3.5 Crystallography
27
The majority of biological molecules are
chiral.
Мost of the amino acids on Earth are right-
handed, but the most of shugars are left-
handed.
Perhaps, somewhere in the universe there
is life with the left- amino acids and right-
handed sugars.
28
3.3 Chirality in Biology
© http://www.astrochem.org/
You can sense the chirality, smelling
orange and lemon. Their smells are
chiral molecules.
29
3.3 Chirality in Biology
The smell of mint and smell of
caraway are enantiomers too.
1. Chirality - WTF?
2. Chirality in everyday life.
3. Chirality in science:
3.1 Math
3.2 Astronomy
3.3 Chemistry
3.4 Biology
3.5 Crystallography
30
Symmetry of all existing crystals can
be described by 230 space groups.
Chiral crystals occur in 77 (33%) of
them.
31
3.4 Chirality in
Crystallography
In some cases crystal structure is
symmetrical, but magnetic structure in
the same crystal is chiral.
32
3.4 Chirality in
Crystallography
(с) Dr Andrew S. Wills
Conclusion
I showed you only a small part of the
chiral effects in nature.
There are chirality in:
- Elementary particles physics;
- Cosmology;
- Origins of life.
Handedness is a fundamental property
of physical objects and physical laws,
such as size, weight and electric charge.
33

Fun chirality

  • 1.
    Fun chirality Ph.D. KseniaKozlovskaya Moscow State University 1
  • 2.
    1. Chirality -WTF? 2. Chirality in everyday life. 3. Chirality in science: 3.1 Math 3.2 Astronomy 3.3 Chemistry 3.4 Biology 3.5 Crystallography 2
  • 3.
    Chirality is thelack of right-left symmetry. Chiral objects has no mirror planes. Enantiomers (optical isomers) are chiral objects that are mirror images of one another. 3 1. Chirality - WTF? (с) http://physicsworld.com/
  • 4.
    4 2. Enantiomers ineveryday life. There are right and left ways to tie a simple knot. Our hands, shoes and ears are enantiomers. Architects like to create buildings- enantiomers.
  • 5.
    5 2. Chirality inthe everyday life. That is the enantiomer for this car?
  • 6.
    6 2. Chirality inthe everyday life. In a sense, left and right-hand drive cars are enantiomers.
  • 7.
    Spinning top isa symmetrical object moving on the asymmetrical helix path. 7 2. Chirality in everyday life.
  • 8.
    Spinning top isa symmetrical object moving on the asymmetrical helix path. 8 2. Chirality in everyday life.
  • 9.
    Fan blades arecut from the helical surface. That happens if you replace them with mirror blades? 9 2. Chirality in everyday life.
  • 10.
    Fan blades arecut from the helical surface. If you replace them with mirror blades, the fan will turn into a vacuum cleaner. 10 2. Chirality in everyday life.
  • 11.
    1. Chirality -WTF? 2. Chirality in everyday life. 3. Chirality in science: 3.1 Math 3.2 Astronomy 3.3 Chemistry 3.4 Biology 3.5 Crystallography 11
  • 12.
    12 3.1 Chirality inmathematics. If objects are chiral in a space of n dimensions, they can be combined in a space of n+1 dimensions.
  • 13.
    13 3.1 Chirality inmathematics and literature. Gottfrieb Plattner got into 4- dimentional world, and after return he discovers that he is now left-handed, and his internal anatomy has apparently inverted left and right.
  • 14.
    14 3.1 Chirality in mathematics. Spirals Ifyou've seen something in mathematics, most likely you’ll find it in a real world.
  • 15.
    15 3.1 Chirality in mathematics. 2DSpirals Are the galaxies chiral?
  • 16.
    16 3.1 Chirality inmathematics. 3D Spirals © http://blog.atlasrfidstore.com/ Right and Left circular polarized waves are enantiomers.
  • 17.
    17 3.1 Chirality in mathematics.3D Spirals Like humans, snails can be right- handed and left-handed.
  • 18.
    1. Chirality -WTF? 2. Chirality in everyday life. 3. Chirality in science: 3.1 Math 3.2 Astronomy 3.3 Chemistry 3.4 Biology 3.5 Crystallography 18
  • 19.
    The Sun isa sphere. It’s symmetrical. The Sun is rotating sphere, but rotating sphere is still symmetrical But Sun is rotating sphere with magnetic moment! And it made sun chiral. Sometimes the Sun's magnetic axis changes direction, and Sun turns into its own enantiomer. N S 19 3.1 Chirality in mathematics and astronomy
  • 20.
    The Earth’s shapecalled Geoid. Geoid is chiral. 20 3.2 Chirality in Astronomy. The Earth
  • 21.
    1. Chirality -WTF? 2. Chirality in everyday life. 3. Chirality in science: 3.1 Math 3.2 Astronomy 3.3 Chemistry 3.4 Biology 3.5 Crystallography 21
  • 22.
    3.3 Chirality inchemistry 22
  • 23.
    Methane СH4 MethanolСН3ОН Ethanol С2Н5ОН Amyl C5H11OH 23 3.3 Chirality in chemistry
  • 24.
    This is achiral structure with asymmetric carbon atom. And this is a meso-tartaric acid, it’s symmetrical again. 24 3.3 Chirality in chemistry
  • 25.
    How to defineif the molecular structure are right or left-handed? Right crystal rotate the plane of polarization (of polarized light) in a clockwise. Left crystal rotate the plane of polarization in a counter-clockwise. 25 3.3 Chirality in chemistry
  • 26.
    3.3 Chirality inchemistry 26
  • 27.
    1. Chirality -WTF? 2. Chirality in everyday life. 3. Chirality in science: 3.1 Math 3.2 Astronomy 3.3 Chemistry 3.4 Biology 3.5 Crystallography 27
  • 28.
    The majority ofbiological molecules are chiral. Мost of the amino acids on Earth are right- handed, but the most of shugars are left- handed. Perhaps, somewhere in the universe there is life with the left- amino acids and right- handed sugars. 28 3.3 Chirality in Biology © http://www.astrochem.org/
  • 29.
    You can sensethe chirality, smelling orange and lemon. Their smells are chiral molecules. 29 3.3 Chirality in Biology The smell of mint and smell of caraway are enantiomers too.
  • 30.
    1. Chirality -WTF? 2. Chirality in everyday life. 3. Chirality in science: 3.1 Math 3.2 Astronomy 3.3 Chemistry 3.4 Biology 3.5 Crystallography 30
  • 31.
    Symmetry of allexisting crystals can be described by 230 space groups. Chiral crystals occur in 77 (33%) of them. 31 3.4 Chirality in Crystallography
  • 32.
    In some casescrystal structure is symmetrical, but magnetic structure in the same crystal is chiral. 32 3.4 Chirality in Crystallography (с) Dr Andrew S. Wills
  • 33.
    Conclusion I showed youonly a small part of the chiral effects in nature. There are chirality in: - Elementary particles physics; - Cosmology; - Origins of life. Handedness is a fundamental property of physical objects and physical laws, such as size, weight and electric charge. 33