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ELECTROLYSIS
+

- + - +
- + - + - + - +
+

Module C2
Splitting up ionic compounds (F)
Molten compounds
Ionic solutions & discharge rules
Q = It and OILRIG
Brine and purifying copper
SPLITTING UP IONIC COMPOUNDS 1
Cl- ION
Na+ ION

Ionic compounds (eg sodium chloride) are made from:
POSTIVE IONS (atoms which LOST negative electrons)
NEGATIVE IONS (atoms which GAINED negative electrons)
As these ions have OPPOSITE CHARGES they attract each
other strongly to form IONIC BONDS
SPLITTING UP IONIC COMPOUNDS 2
2 ways to split up the ions:

MELT

+

- + - +
- + - + - + - +
+

800°C

- +
+ - +
+ -

-

+

-

DISSOLVE

+

-

+ - +
+

+ -

-

-

+

20°C

H2O
SEPARATING THE IONS 1

+

_

Metal
ELECTRODE

ELECTRON
Battery pulls
electrons off one
electrode and
pushes them
onto the other

This IS SHORT OF
electrons so becomes
POSITIVELY CHARGED
“ANODE”

This HAS EXTRA
electrons so becomes
NEGATIVELY CHARGED
“CATHODE”
SEPARATING THE IONS 2

+
MOLTEN IONIC
COMPOUND

-

+ -

+ ANODE

+

+

-

+

-

+

+

+

- CATHODE

When the battery is switched on,
the + IONS move to the – CATHODE
the – IONS move to the + ANODE
This gives a way to SPLIT UP IONIC COMPOUNDS: “ELECTROLYSIS”
Example 1: Splitting up MOLTEN SODIUM CHLORIDE (salt)

- =

Cl-

chloride ION,
extra 1 electron

Cl

chlorine ATOM, Cl Cl
NEUTRAL

Cl2
molecule

+

Cl
Cl-

ClCl

ClCl

- chloride IONS
lose their extra
electrons and
turn into neutral
chlorine ATOMS

ClCl

At ANODE:
Clthen:
Cl + Cl

e- + Cl
Cl2 (gas)

Both together:

2Cl- → 2e- + Cl2
Example 1: Splitting up MOLTEN SODIUM CHLORIDE (salt)
+ = Na+

sodium ION,
missing1 electron

Na

sodium ATOM,
NEUTRAL

+
+ sodium IONS
gain an extra
electron and turn
into neutral
sodium ATOMS

At CATHODE: Na+ + e-

Na
Na+

Na
Na+

Na
Na+

Na
Na+

Na

molten sodium
metal sinks to
bottom
Example 1: Splitting up MOLTEN SODIUM CHLORIDE (salt)
- CATHODE

+ ANODE

ELECTRONS

SODIUM
metal Na

CHLORINE
gas Cl2

Cl-

MOLTEN
SODIUM
CHLORIDE

At ANODE:
Cle- + Cl
Cl + Cl

Cl2 (gas)

Na+

At CATHODE:
Na+ + eNa
Example 2: Splitting up MOLTEN LEAD BROMIDE PbBr 2
- CATHODE

+ ANODE

ELECTRONS

LEAD
Metal Pb

BROMINE
gas Br2

Br-

MOLTEN
LEAD
BROMIDE

At ANODE:
Bre- + Br
Br + Br
Br2 (gas)

Pb2+

At CATHODE:
Pb2+ + 2eBoth together:

2Br- → 2e- + Br2

Pb
What happens when the ionic compounds are dissolved
in water?
Here, water molecules break up into HYDROGEN IONS, H+
and HYDROXIDE IONS OH-

H2O  H+ + OHSo, in an ionic solution (eg sodium chloride solution), there will be
FOUR types of ion present:
TWO from the ionic compound and TWO from the water ( H+
SODIUM CHLORIDE
SOLUTION NaCl (aq)
H+
OH-

ClNa+

OHH+

H+

Na+
Cl

-

-

OH

Na+
Cl-

+ OH-)
IONIC SOLUTION

H+
OH

OH-

Cl-

+

Na

H+

+

Na

Cl-

H+
Na+

OHCl-

Which ions gain or lose electrons (“get discharged”)
and which stay in solution?
IONIC SOLUTIONS: At the CATHODE
Na

+

sodium ION,
missing 1
electron

H+

+

hydrogen ION,
missing 1
electron

As HYDROGEN is
LESS REACTIVE
than SODIUM, it is
discharged.
The
sodium ions stay in
solution.

At CATHODE: 2H+ + 2e-

H

Hydrogen ATOM,
NEUTRAL

which
ions?

Na+

H+

H
H+

Na+

H2
IONIC SOLUTIONS: At the CATHODE – halogen compounds
Cl-

chloride ION,
extra 1 electron

hydroxide ION,
O H from water
extra electron

chlorine ATOM,
NEUTRAL

Cl

+

H

O

O H

Cl
Cl-

H

ClCl

O

O H
ClCl

which
ions?

ClCl

At ANODE:

If the – ion is a
HALOGEN (Cl, Br, I)
it is discharged and
chlorine (or Br or I)
is given off and the
OH - ions stay in
solution

2Cl-

2e- + Cl2
IONIC SOLUTIONS: CATHODE – non halogen compounds
nitrate ION, extra
NO3 1 electron

hydroxide ION, OHO H from water, extra
electron

O

Oxygen
atom

+
NO3
H

-

O

NO3H

O

which
ions?

NO3-

O H
NO3-

If the – ion is NOT a halogen
(eg nitrate, sulphate etc) then
the HYDROXIDE ions from the
water are discharged to make
WATER and OXYGEN gas.
The other ions stay in solution.

O H

At CATHODE: 4OH-

2H2O + O2 + 4e-
RULES FOR IONIC SOLUTIONS
+ ANODE
Attracts – ions (‘Anions’)

- CATHODE
Attracts + ions (‘Cations’)

If – ions are HALOGENS ie

If + ions (metals) are MORE
REACTIVE than hydrogen

chloride Clbromide Br

K, Na, Ca, Mg, Zn, Fe

-

iodide Ithe HALOGEN is produced.
If – ions are NOT HALOGENS
Eg sulphate SO4 ,
2-

Then HYDROGEN is
produced
If + ions (metals) are LESS
REACTIVE than hydrogen

nitrate NO3-

Cu, Ag, Au

carbonate CO32-

Then the METAL is produced

OXYGEN is produced.
(REACTIVITY: K+ Na+ Ca2+ Mg2+ Al3+ Zn2+ Fe3+ H+ Cu2+ Ag+ Au3+ )
Ions

Cathode (-) Anode (+)

potassium chloride molten

K+ Cl-

potassium

chlorine

aluminium oxide

molten

Al3+ O2-

aluminium

oxygen

copper chloride

solution

Cu2+ Cl- H+ OH-

copper

chlorine

sodium bromide

solution

Na+ Br- H+ OH-

hydrogen

bromine

silver nitrate

solution

Ag+ NO3- H+ OH-

silver

oxygen

potassium chloride solution

K+ Cl- H+ OH-

hydrogen

chlorine

zinc sulphate

Zn+ SO42- H+ OH-

hydrogen

oxygen

Compound

State

solution

(REACTIVITY: K+ Na+ Ca2+ Mg2+ Al3+ Zn2+ Fe3+ H+ Cu2+ Ag+ Au3+ )
ELECTROLYSIS makes a CIRCUIT
Complete electric circuit:
Current carried by:

ELECTRONS in electrodes/wires
+
+

-

IONS in the electrolyte
-

To DOUBLE the MASS of substance
discharged at electrodes:
2 x CURRENT (2x batt. voltage)
2 x TIME current flows for
(Q = I t)
OILRIG

Cl-

Cl-

Cl-

Cl-

Oxidation is loss,
reduction is gain
‘OILRIG’

Na+

Na+

Na+

Na+

- ions LOSING electrons
+ ions GAINING electrons
to become atoms is called to become atoms is called
‘OXIDATION’
‘REDUCTION’
(even though oxygen may
not be involved)
INDUSTRIAL USES OF ELECTROLYSIS
1. To extract reactive metals such as ALUMINIUM, sodium,
magnesium etc from their compounds. This is EXPENSIVE
due to the large amounts of electrical energy needed.
Aluminium is extracted from bauxite (Al2O3).
2. Electrolysis of BRINE (salt solution) to produce
see below
CHLORINE (for disinfectants and plastics)
HYDROGEN (for ammonia fertilisers, margarine)
SODIUM HYDROXIDE (for soap and cleaning agents)
3. Purifying copper. The copper for wiring etc needs to be
more pure than that produced in a blast furnace. see below
Electrolysis is used to convert impure copper to pure
copper
INDUSTRIAL ELECTROLYSIS OF BRINE
Chlorine gas

Hydrogen gas

BRINE
(NaCl solution)

CATHODE
H+ and Na+

ANODE
OH- and Cl2Cl

-

2H+ + 2e-

2e + Cl2
-

OH- left in solution
so concentration
grows

Sodium chloride
solution (neutral)
slowly changed to
sodium hydroxide
solution (alkaline)

H2

Na+ left in solution
so concentration
grows
Industrial chlorine production from electrolysis of
brine
PURIFYING COPPER
IMPURE COPPER
ANODE

Copper atoms
from impure
copper are
OXIDISED to
copper ions

PURE COPPER
CATHODE

Copper sulphate
CuSO4 solution
Cu2+

Cu
Cu2+

Cu2+

Cu

Copper ions transported
from anode to cathode

Copper ions
from impure
copper are
REDUCED to
copper atoms

As the atoms of the impurities are not
transported, the copper that builds up on the
anode is extremely pure.
IMPURE
COPPER
ANODE

PURE
COPPER
CATHODE

IMPURE
COPPER
ANODE

PURE
COPPER
CATHODE

Over time, the impure anode dissolves away and the
impurities sink to the bottom. The pure cathode grows as
more pure copper is deposited on it.
Why will the concentration of the solution stay the same?

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Electrolysis revision

  • 1. ELECTROLYSIS + - + - + - + - + - + - + + Module C2 Splitting up ionic compounds (F) Molten compounds Ionic solutions & discharge rules Q = It and OILRIG Brine and purifying copper
  • 2. SPLITTING UP IONIC COMPOUNDS 1 Cl- ION Na+ ION Ionic compounds (eg sodium chloride) are made from: POSTIVE IONS (atoms which LOST negative electrons) NEGATIVE IONS (atoms which GAINED negative electrons) As these ions have OPPOSITE CHARGES they attract each other strongly to form IONIC BONDS
  • 3. SPLITTING UP IONIC COMPOUNDS 2 2 ways to split up the ions: MELT + - + - + - + - + - + - + + 800°C - + + - + + - - + - DISSOLVE + - + - + + + - - - + 20°C H2O
  • 4. SEPARATING THE IONS 1 + _ Metal ELECTRODE ELECTRON Battery pulls electrons off one electrode and pushes them onto the other This IS SHORT OF electrons so becomes POSITIVELY CHARGED “ANODE” This HAS EXTRA electrons so becomes NEGATIVELY CHARGED “CATHODE”
  • 5. SEPARATING THE IONS 2 + MOLTEN IONIC COMPOUND - + - + ANODE + + - + - + + + - CATHODE When the battery is switched on, the + IONS move to the – CATHODE the – IONS move to the + ANODE This gives a way to SPLIT UP IONIC COMPOUNDS: “ELECTROLYSIS”
  • 6. Example 1: Splitting up MOLTEN SODIUM CHLORIDE (salt) - = Cl- chloride ION, extra 1 electron Cl chlorine ATOM, Cl Cl NEUTRAL Cl2 molecule + Cl Cl- ClCl ClCl - chloride IONS lose their extra electrons and turn into neutral chlorine ATOMS ClCl At ANODE: Clthen: Cl + Cl e- + Cl Cl2 (gas) Both together: 2Cl- → 2e- + Cl2
  • 7. Example 1: Splitting up MOLTEN SODIUM CHLORIDE (salt) + = Na+ sodium ION, missing1 electron Na sodium ATOM, NEUTRAL + + sodium IONS gain an extra electron and turn into neutral sodium ATOMS At CATHODE: Na+ + e- Na Na+ Na Na+ Na Na+ Na Na+ Na molten sodium metal sinks to bottom
  • 8. Example 1: Splitting up MOLTEN SODIUM CHLORIDE (salt) - CATHODE + ANODE ELECTRONS SODIUM metal Na CHLORINE gas Cl2 Cl- MOLTEN SODIUM CHLORIDE At ANODE: Cle- + Cl Cl + Cl Cl2 (gas) Na+ At CATHODE: Na+ + eNa
  • 9. Example 2: Splitting up MOLTEN LEAD BROMIDE PbBr 2 - CATHODE + ANODE ELECTRONS LEAD Metal Pb BROMINE gas Br2 Br- MOLTEN LEAD BROMIDE At ANODE: Bre- + Br Br + Br Br2 (gas) Pb2+ At CATHODE: Pb2+ + 2eBoth together: 2Br- → 2e- + Br2 Pb
  • 10. What happens when the ionic compounds are dissolved in water? Here, water molecules break up into HYDROGEN IONS, H+ and HYDROXIDE IONS OH- H2O  H+ + OHSo, in an ionic solution (eg sodium chloride solution), there will be FOUR types of ion present: TWO from the ionic compound and TWO from the water ( H+ SODIUM CHLORIDE SOLUTION NaCl (aq) H+ OH- ClNa+ OHH+ H+ Na+ Cl - - OH Na+ Cl- + OH-)
  • 11. IONIC SOLUTION H+ OH OH- Cl- + Na H+ + Na Cl- H+ Na+ OHCl- Which ions gain or lose electrons (“get discharged”) and which stay in solution?
  • 12. IONIC SOLUTIONS: At the CATHODE Na + sodium ION, missing 1 electron H+ + hydrogen ION, missing 1 electron As HYDROGEN is LESS REACTIVE than SODIUM, it is discharged. The sodium ions stay in solution. At CATHODE: 2H+ + 2e- H Hydrogen ATOM, NEUTRAL which ions? Na+ H+ H H+ Na+ H2
  • 13. IONIC SOLUTIONS: At the CATHODE – halogen compounds Cl- chloride ION, extra 1 electron hydroxide ION, O H from water extra electron chlorine ATOM, NEUTRAL Cl + H O O H Cl Cl- H ClCl O O H ClCl which ions? ClCl At ANODE: If the – ion is a HALOGEN (Cl, Br, I) it is discharged and chlorine (or Br or I) is given off and the OH - ions stay in solution 2Cl- 2e- + Cl2
  • 14. IONIC SOLUTIONS: CATHODE – non halogen compounds nitrate ION, extra NO3 1 electron hydroxide ION, OHO H from water, extra electron O Oxygen atom + NO3 H - O NO3H O which ions? NO3- O H NO3- If the – ion is NOT a halogen (eg nitrate, sulphate etc) then the HYDROXIDE ions from the water are discharged to make WATER and OXYGEN gas. The other ions stay in solution. O H At CATHODE: 4OH- 2H2O + O2 + 4e-
  • 15. RULES FOR IONIC SOLUTIONS + ANODE Attracts – ions (‘Anions’) - CATHODE Attracts + ions (‘Cations’) If – ions are HALOGENS ie If + ions (metals) are MORE REACTIVE than hydrogen chloride Clbromide Br K, Na, Ca, Mg, Zn, Fe - iodide Ithe HALOGEN is produced. If – ions are NOT HALOGENS Eg sulphate SO4 , 2- Then HYDROGEN is produced If + ions (metals) are LESS REACTIVE than hydrogen nitrate NO3- Cu, Ag, Au carbonate CO32- Then the METAL is produced OXYGEN is produced.
  • 16. (REACTIVITY: K+ Na+ Ca2+ Mg2+ Al3+ Zn2+ Fe3+ H+ Cu2+ Ag+ Au3+ ) Ions Cathode (-) Anode (+) potassium chloride molten K+ Cl- potassium chlorine aluminium oxide molten Al3+ O2- aluminium oxygen copper chloride solution Cu2+ Cl- H+ OH- copper chlorine sodium bromide solution Na+ Br- H+ OH- hydrogen bromine silver nitrate solution Ag+ NO3- H+ OH- silver oxygen potassium chloride solution K+ Cl- H+ OH- hydrogen chlorine zinc sulphate Zn+ SO42- H+ OH- hydrogen oxygen Compound State solution (REACTIVITY: K+ Na+ Ca2+ Mg2+ Al3+ Zn2+ Fe3+ H+ Cu2+ Ag+ Au3+ )
  • 17. ELECTROLYSIS makes a CIRCUIT Complete electric circuit: Current carried by: ELECTRONS in electrodes/wires + + - IONS in the electrolyte - To DOUBLE the MASS of substance discharged at electrodes: 2 x CURRENT (2x batt. voltage) 2 x TIME current flows for (Q = I t)
  • 18. OILRIG Cl- Cl- Cl- Cl- Oxidation is loss, reduction is gain ‘OILRIG’ Na+ Na+ Na+ Na+ - ions LOSING electrons + ions GAINING electrons to become atoms is called to become atoms is called ‘OXIDATION’ ‘REDUCTION’ (even though oxygen may not be involved)
  • 19. INDUSTRIAL USES OF ELECTROLYSIS 1. To extract reactive metals such as ALUMINIUM, sodium, magnesium etc from their compounds. This is EXPENSIVE due to the large amounts of electrical energy needed. Aluminium is extracted from bauxite (Al2O3). 2. Electrolysis of BRINE (salt solution) to produce see below CHLORINE (for disinfectants and plastics) HYDROGEN (for ammonia fertilisers, margarine) SODIUM HYDROXIDE (for soap and cleaning agents) 3. Purifying copper. The copper for wiring etc needs to be more pure than that produced in a blast furnace. see below Electrolysis is used to convert impure copper to pure copper
  • 20. INDUSTRIAL ELECTROLYSIS OF BRINE Chlorine gas Hydrogen gas BRINE (NaCl solution) CATHODE H+ and Na+ ANODE OH- and Cl2Cl - 2H+ + 2e- 2e + Cl2 - OH- left in solution so concentration grows Sodium chloride solution (neutral) slowly changed to sodium hydroxide solution (alkaline) H2 Na+ left in solution so concentration grows
  • 21. Industrial chlorine production from electrolysis of brine
  • 22. PURIFYING COPPER IMPURE COPPER ANODE Copper atoms from impure copper are OXIDISED to copper ions PURE COPPER CATHODE Copper sulphate CuSO4 solution Cu2+ Cu Cu2+ Cu2+ Cu Copper ions transported from anode to cathode Copper ions from impure copper are REDUCED to copper atoms As the atoms of the impurities are not transported, the copper that builds up on the anode is extremely pure.
  • 23. IMPURE COPPER ANODE PURE COPPER CATHODE IMPURE COPPER ANODE PURE COPPER CATHODE Over time, the impure anode dissolves away and the impurities sink to the bottom. The pure cathode grows as more pure copper is deposited on it. Why will the concentration of the solution stay the same?