This brief article covers the best practices for biodiesel storage and was published in April 2012 in Biofuels International Magazine.

1. biodiesel storage biofuels
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What considerations are necessary when storing biodiesel?
Good biodiesel
storage practices
M
aintaining quality include the establishment they can only prevent further marketers – including major
in biodiesel of new tests that detect oxidation from occurring. oil companies – are increasing
storage starts with the presence of saturated The need for oxidation their requirement for oxidation
buying quality mono-glycerides – thought to stability is a function of how stability. Requests for 8+
product. Purchase only contribute to filter plugging long the fuel will be stored hours Rancimat Induction
from reputable suppliers problems at temperatures and under what conditions. Period are no longer unusual
and insist on a Certificate above the cloud point of the Biodiesel made today, blended and are easily achievable
of Analysis for all receipts. fuel. The new quality tests with diesel and shipped to a with high quality biodiesel
The US’ National Biodiesel include the Cold Soak Filter high volume truck stop, will not fuels and anti-oxidants.
Board has set up an ISO-type Blocking Test, the Cold Soak need much oxidation stability. Many buyers are now asking
quality management system Filtration Test, ASTM D7501 This situation is very rare. that the type and amount of
for biodiesel producers and in the US and the Cold Soak Biodiesel that is to be stored biodiesel anti-oxidant used
marketers, known as BQ9000. Test, IP 387 in Europe. for longer periods, such as be shown on the producer’s
Good housekeeping and In addition, several a B20 blend stored at a city Certificate of Analysis. Note
regular inspections are a biodiesel producers have fuel depot, a construction that all biodiesel anti-oxidants
must. Water sumps must be made substantial investments site or on the farm or a B5 will provide an initial boost in
drained and filters changed in cold filtration, resin blend delivered to a home stability, but some are subject
regularly in order to ensure absorption technology and heating application, will require to quick stability losses,
quality product. Biodiesel is even biodiesel distillation significant oxidation stability. especially when the fuel is
an excellent solvent and it will that can remove stubborn Since it is normally impossible stored under the stress of
quickly remove existing sludge, contaminants such as sterol to determine the destination heat and humidity. Therefore
varnish and other deposits glucosides. Establishment of daily biodiesel production, it is recommended biodiesel
that are often found in old of these new quality tests biodiesel producers and fuel stability be checked regularly
petroleum fuel storage tanks. and refining technologies
If using existing petroleum have greatly reduced field
storage tanks for biodiesel, complaints on cold weather
these must be cleaned filter fouling. Despite these
thoroughly prior to the first fill improvements, filter plugging
with biodiesel and be prepared and sludge formation may
to change filters as the tank still occur – particularly when
adjusts to the solvency the fuel is cold. However,
parameters of biodiesel. biodiesel marketers must not
These same solvency be too quick to blame the
characteristics will also affect biodiesel for such problems Severe injector piston deposits after use of oxidized B20
elastomeric compounds as sometimes the filter
so consider choices for plugging can also be caused
pump seals, line gaskets by contaminants in the diesel.
and hoses with biodiesel in
mind. Also, never use yellow Stability
metals such as copper, brass
or zinc (galvanised pipe) Biodiesel is biodegradable,
with biodiesel as they will and that is a good thing, but
quickly catalyse oxidation. it also means it is subject to
oxidation. Maintaining nitrogen
Contaminants blanketing is impractical
downstream of the biodiesel
Biodiesel producers and producer, so chemical anti-
industry supporters have oxidants are usually added
worked hard to indentify and at the biodiesel producer
prevent quality issues that site. It is important to add
have sometimes challenged these chemistries as early as
biodiesel users in the past. possible as they do not reverse
Recent industry efforts existing oxidation. Instead Fouled B20 storage tank filter
biofuels international supplement april 2012 11

2. biofuels corrosion
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for fuel stored more than just
a few weeks as additional
technology news biofuels
technology news biofuels
characteristics compared to
ultra low sulphur diesel. In
anti-oxidant dosage may be order to remove sulphur and
Xebec Adsorption
Xebec Adsorption
needed. This best practice
will do much to reduce Dow Water & Process
Dow Water & Process aromatics, diesel is highly
hydro-treated so it is essentially
branches out to the UK
problems and customer
branches out to the UK
complaints downstream. expands biodiesel solutions
expands biodiesel solutions non-polar in chemical
character and solvency.
The type of oxidation stability Contaminants and products
Canada-based
Canada-based as a new
test is also emerging environment,’ Tony Hales,
After acquiring Rohm
After acquiring Rohm It also provides Amberlite
of oxidation and hydrolysis
environment,’ Tony Hales, It also provides Amberlite
purification, separation,
issue. The Rancimat Induction
purification, separation,
Xebec project director, says.
Xebec project director, says. and Haas in July this
and Haas in July this tend to be polar in nature a
BD10DRY technology, so
BD10DRY technology, a
dehydration, and still the
Period (EN14112) is Fuel Filteroffers veoxidized B20
Xebec fouled standard they are and cost-effective
simple quite soluble in B100.
and Xebec offers by standard
dehydration,performed and
dominant test
ve
sizes of biogas upgrading year Dow Water &
year Dow Water & simple and cost-effective
solution for biodiesel
When biodiesel and diesel
filtration equipment
filtration equipment
sizes of biogas upgrading
systems from 200 m3/h up Process Solutions has
Process Solutions has solution for biodiesel
purication designed to
often cited in national and once they have occurred. It
systems from 200 m3/h up Water promotes corrosion are blended, these materials
purication designed to
manufacturer Xebec
manufacturer Xebec
international specifications. to 2,000 m3 /h, and combines
is therefore3 incumbent on the
to 2,000 m /h, and combines expanded its portfolio
expanded itsbiodiesel
and oxidation in portfolio can quickly process yield. in
maximise form sediments
maximise process yield.
Adsorption has opened best marketer recovery, purity
fuel in class and especially of solutions, including theFor 50 years Dow Water &
Adsorption has openedis
However, the PetroOxy test
best in class recovery, purity
and biodiesel consumer to
and microbial growth in both
of solutions, including new biodiesel blend. This
For 50 years Dow Water &
againingsales office to
new favour among some the energy consumption. biodiesel and diesel. Desiccant
biodiesel capabilities. Process Solutions has been
sediment formation can happen
a producers andoffice to –
new sales regulators and energy consumption. biodiesel capabilities. Process Solutions has been
These systems are either
consider how much oxidation breather vents are a good idea at any time innovative water
providing of year. Similar
provide enhanced These systems are either providing innovative water
provide enhanced Both
particularly in Europe. skid-mounted or containerised
stability is required in the It now offers the Downitrogen
for B100 storage when and process solutions to both
instances of sediment formation
service to thein helping skid-mounted or containerised It now offers the Dow and process solutions to both
tests are useful UK
service to the UK with an extremely small
biodiesel and diesel in order to Amberlystis not available.
blanketing BD20 solid communities and industries
and filter plugging, especially in
with an extremely small Amberlyst BD20 solid communities and industries
biogas stability issues.
prevent market. footprint, offer free operation.
ensure trouble high up- catalystno better ‘best practice’
There is FFA esterication alike. A differentiated
cold weather, were observed in
biogas market. footprint, offer high up- catalyst FFA esterication alike. A differentiated
It is well known that diesel time and low maintenance technology thatfuels than to
for storage of all offers pure dieselunit oflow sulphur
business when The Dow
time and low maintenance technology that offers business unit of The Dow
This new suffer from stability
will also initiative is in Water
and operations cost. inspect for and remove water.
biodiesel producers the and ultra low sulphur grades
Chemical Company, Dow
This new initiative is in and operations cost. biodiesel producers the Chemical Company, Dow
response to time. And just like
issues over the growing The solutions Xebec exibility to produce were introduced into the US
Water & Process Solutions
response to the growing The solutions Xebec exibility to produce Water & Process Solutions
biodiesel, there is uncertainty
market in the UK for biogas Like all fuels, biodiesel
provides include natural 1+1=3?
biodiesel from inexpensive market a broad portfolioyears.
offers during the last 15 of
market inlong UK diesel fuel will
on how the the for biogas provides include natural
can absorb atmospheric biodiesel from inexpensive offers a broad portfolio of
Maintaining proper oxidation
upgrading to renewable gas and biogas purication, low-quality feed stocks ion exchange resins, reverse
upgrading to renewable gas and biogas purication, low-quality feed stocks ion exchange resins, reverse
natural gas,Petroleum refiners,
be stored. a carbon neutral condensation water, so
natural gas dehydration, withoutunusualcing the purity
It is not sacri to observe stability, plus regular filter
osmosis membranes,
natural gas, a carbon neutral
like biodiesel producers, natural gas dehydration, without sacricing the purity osmosis membranes,
fuel source. The ofce will hydrogen producers, marketers
biodiesel purication for needed inlife and performance
good filter the end product. and water separation system
ultraltration membranes
fuel source. The ofce will
can ensure only a minimum hydrogen purication for be needed in biodiesel product.
separate the end and is ultraltration membranes
handle all sales, marketing, fuel cell and industrial must
and users of biodiesel in The Ambersep BD19 diesel inspection, is essential to
and electrodeionization
handleof stability. marketing,
level all sales, The result fuel cell and industrial and drain storage tanks and BD19 is
The Ambersep then see and electrodeionization
technical and after-sales of applications, to check
extra vigilant and specialised a feedstock purication prevent problemsstrong
products, with with storage
technical and after-sales diesel applications, and specialised a feedstock purication products, with strong
support for the UK. and
inadequate biodiesel water sumps regularly. Water
solutions for other gases. filter plugging in the storage
technology, a pre-treatment and handling of number of
positions in a biodiesel. l
support for fuel filter plugging,
stability is and UK.
the solutions for other gases.
is a particularly troublesome technology, a pre-treatment positions in a number of
‘The UK Europe are Xebec also offers compressed step that contains the bio/petro
tank specially designed to be major application areas,
‘The UK and Europe arethe
shorter filter life and even Xebec also offers can and
compressed step specially designed to be major application areas,
poised to fully develop the air treatment as it
contaminant solutions. To diesel blend. This can happen
used together with Amberlyst including industrial and
poised to fully develop the air treatmentand participate
solutions. To used together with Amberlyst For more information: and
including industrial
use of greenadding to injector
potential of gas. Biomethane will catalyse
date, Xebec has supplied in either wholesale or consumer
BD20 catalyst technology This article was water, industrial
municipal written by Phil
use of green gas. Biomethane
deposits, corrosion and micro date, Xebec has supplied BD20 catalyst technology municipal water, industrial
injected into the National Gas more than chemical reactions
in harmful 8,000 adsorption storage tanks. The reason is
that extends life time and processes, pharmaceuticals,
Bureman, senior industry technical
injected into the issues that
National Gas more the fuel contaminants
with than 8,000 adsorption that biodiesel, life time ester,
that extends operability ofand processes, pharmaceuticals,
Grid problems –
bio is a huge step forward systems to more than 1,300 improves the being an consultant for biofuels at Nalco – An
power, residential water and
Ecolab Company, www.nalco.com and
Grid is a expensive to remedy
huge step forward
can be the industry and the systems to moreoxidation.
and products of than 1,300 improves the operability of
has relatively polarprocess.
solvency power, residential water
for both customers worldwide. ● the downstream waste and water reuse. ●
for both the industry and the customers worldwide. ● the downstream process. waste and water reuse. ●
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12 april 2012 biofuels international supplement
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