Bio-Based Material Applications by Daniel Gao, DSM
•
2 likes•864 views
Daniel's talk will cover the myths of bioplastics and degradation, how bioplastics can allevieate the problem of plastic pollution, and how they can be best used to not cause harm to the environment. Daniel Gao majored in Biomass Science and Technology at South China University of Technology, where his research focused on applications of bio-based materials. He has had three papers published internationally and issued two patents (one pending). He currently works as an Account Manager in the DSM engineering plastic department, and is in charge of business maintenance and development in South China and Zhejiang province. As a member of DSM Sustainability Ambassadors, he joined One Young World Summit in Bogota in 2017, focusing on the UN Sustainable Development Goals, participates in DSM sustainability activities and is responsible for promoting sustainable product portfolio solutions.
Recommended
Recommended
More Related Content
What's hot
What's hot (20)
Similar to Bio-Based Material Applications by Daniel Gao, DSM
Similar to Bio-Based Material Applications by Daniel Gao, DSM (20)
More from Green Initiatives 绿色倡议
More from Green Initiatives 绿色倡议 (20)
Recently uploaded
Recently uploaded (20)
Bio-Based Material Applications by Daniel Gao, DSM
- 1. For Internal Use Only Bio-based Material Applications and Sustainability as a Business Growth Driver at DSM Presenter: Daniel Gao Account Manager, DSM 2018, August
- 2. • Bio-based materials brief info. • Biomass research and its high valued conversion and utilization-my postgraduate study sharing • Bio-based driven business in DSM Content
- 3. For Internal Use Only Bio-based Materials Bio-based materials: new materials that are produced from renewable bioresources, including crops, trees, other plants, and their residues by biological, chemical, and physical methods Mainly related to green energy issues, products such as biogas, fuel ethanol, biodiesel and bioplastics
- 4. For Internal Use Only Huge bioresources in plant cell wall
- 5. For Internal Use Only High value products from bio-based raw materials
- 6. For Internal Use Only High valued products from bio-based raw materials
- 7. For Internal Use Only Agricultural filmPackaging film Biodegradable Film PVA/cellulose, PLA/starch (chitosan) blending biodegradable films
- 8. For Internal Use Only Bio-based hydrogels application facial mask food contact lens Body tissues Controlled drug carrier
- 9. For Internal Use Only Drug load Drug release Acetylsalicylic acid Drug Delivery Bio-based hydrogels application— controlled drug release Intelligent hydrogels with temperature/pH sensitive stomach intestines
- 10. For Internal Use Only Porous hydrogel netwroks Drug controlled release demo
- 11. For Internal Use Only EcoPaXX® bio-based polyamide 410 High bio-based content (70%) ASTM proven Carbon neutral from cradle to gate Validated LCA report by PE International EcoPaXX has the potential to be used in recycling loops Recyclable like other thermoplastics
- 12. Page For Internal Use Only EcoPaXX is 70% bio-based • EcoPaXX, a polyamide 4.10, consists of 2 types of building blocks: – Short ones, uniquely produced by DSM: building block-4 (DAB) – Long ones, produced by Mother Nature: building block-10 (castor oil) • Presently 70% of the polymer is derived from castor oil (ASTM proven) • U.S. Department of Agriculture lists DSM EcoPaXX polyamide 410 grades in “BioPreferred” Catalog of bio-based products • Renewable resources are not competing with the food chain: Easily grows on poor soils in mainly India, China, Brazil Externally validated bio-genic content (ASTM)
- 13. For Internal Use Only EcoPaXX Chemistry • CasEcoPaXX is polyamide 410 synthesized from 1,4-diaminobutane (DSM product) and sebacic acid tor beans HO O N O N H H n HO O N O N H H n H H EcoPaXX 4 10 44 1010 uniquely produced by DSM: building block-4 (DAB) Long-chain 10-block from castor oil
- 14. For Internal Use Only EcoPaXX is carbon neutral EcoPaXX is Carbon Neutral from cradle to gate Externally validated • DSM measurements externally validated by PE International (LCA: ISO14044, C-footprint: PAS2050) • EcoPaXX has a significantly lower carbon footprint than PA66 • EcoPaXX has a lower footprint than PA6.10 due to: – Higher biogenic carbon content of EcoPaXX – 4-Diamin has a lower CO2 footprint than 6-Diamin
- 15. For Internal Use Only DSM In-house Expertise Life Cycle Assessment (LCA) • DSM has an in-house LCA department • A compilation and evaluation of the inputs and outputs and the potential environmental impacts of a product, process or service through its life cycle. • We use LCA as a decision support tool along the whole value chain. Life Cycle of a Product • Three standard assessments methods via SimaPro: - IPCC 2007 GWP 100a: Carbon foot print - ReCiPe: Eco footprint - EPD Environmental Product Declaration
- 16. For Internal Use Only Castor plants like sandy soil Harvest of the seeds Castor plants do not need irrigation Castor plants growing Castor oilNo fit for human nor animal consumption EcoPaXX - carbon neutral from cradle to gate Understanding the supply chain
- 17. For Internal Use Only Land development Castor bean farming Castor bean processing Castor oil processing Polymerization GHG emissions of land use change Natural ecosystem Arable land Castor beans Castor oil Sebacic acid EcoPaXX® GHG emissions from farmingFertilizer Caustic, sulfuric acid Castor meal 2- Octanol Diaminobutane Hexane Fertilizer Fuel EcoPaXX - carbon neutral from cradle to gate From plant to polymer
- 18. For Internal Use Only EcoPaXX® PA410 – High Performance Engineering Plastic • Best combination of stiffness and elongation at break/ductility: very good mechanical properties, especially stiffness-toughness combination • Superior retention of stiffness and strength after conditioning: Highest “conditioned” modulus of all aliphatic polyamides – weight reduction possible • Dimensions: Absorbs 30% less moisture than PA66 → superior dimensional stability • Hydrolysis & Chemical resistance: display excellent resistance to hydrolysis ageing & outperforming PA66 on chemical resistance • Surface: superior surface appearance, even with high GF content • Ease of processing: Broad processing window, 20% lower cycle time compared to conventional polyamides • Biobased: 70% biobased Temperature Indicators: Melting Point: 250 C HDT: 240 C CUT: 150-180 C RTI: 150 C
- 19. For Internal Use Only EcoPaXX PA410 – Key Markets Packaging/ Extrusion • High temp. resistant packaging • Abrasive brushes Consumer goods • Drinking water contact parts, e.g. faucets • Conveyor systems • Window Profile • Sports & Leisure (skiboots) Automotive • Cooling/thermal management • Engine Cover • Crankshaft Covers • Interior/exterior parts • EPS Gears Electrical & Electronics • Auto connectors • Appliances connectors • Power Insulators • Frames in electronic devices
- 20. For Internal Use Only EcoPaXX – A versatile material recognized by global players EcoPaXX engine cover for Mercedes, BMW, Bentley EcoPaXX crank shaft cover: winner of the SPE Award EcoPaXX Fuel vapor seperators for Ferrari & Maserati EcoPaXX shoe frame – Salomon EcoPaXX in thermal breaks EcoPaXX in T-Connector for coolant hose
- 21. Page CONFIDENTIAL For Internal Use Only Proven success EcoPaXX inside Bentley, twin-turbo V8 BMW M5, twin-turbo V8 Daimler A-class Daimler CLA BMW M5
- 22. Project FOR INTERNAL USE ONLY Picture FOR INTERNAL USEONLY For Internal Use Only Application: Crankshaft Covers Industry: Automotive Products: Stanyl PA46, EcoPaXX PA410 • 50% less weight and up to 25% lower system/part costs compared to metal • Better creep & fatigue resistance than PPA and PPS • Temperature resistance up to 150-200 C • Good compatibility with FKM/LSR rubbers ForTii and Xytron to be used in case of more strict chemical resistance or dimensional stability requirements Crankshaft Covers FKM Compatability with Stanyl PA46 or EcoPaXX PA410 Product Grade(s): Stanyl TW209F8 EcoPaXX Q-HG10 Value proposition (vs incumbent solution)
- 23. CONFIDENTIAL Power Insulator – Laptop and phone chargers Thin-walled V2 and V0 with mechanical robustness Page 22 Project Application: Power Insulator Industry: Electronics Product grade: EcoPaXX Q-KV, Q-KS Value proposition (vs PA66) • UL Flammability : V-0 at 0.2mm • Customer needs an UF material for the internal insulator of a power supply. Specialty PA6 and PA66 materials fail in HI-POT tests, PA66 GF too stiff • EcoPaXX Q-KV has been tested successfully in this application. Customer likes the elongation at yield, and the material passes the HI-POT tests • Combination of lower water uptake & dielectric properties Product Grade(s): Q-KV (V2) Q-KS (V0) Power Insulator
- 24. Project FOR INTERNAL USE ONLY Picture FOR INTERNAL USEONLY For Internal Use Only Application: Faucets Industry: Water Management (B&C) Products: EcoPaXX PA410 • No water leakage in lifetime cycle test up to 1 million cycles • Superior hydrolysis resistance: extremely low decrease in strength after 60C and 90C water contact • Passes all major drinking water approvals, like NSF61, KTW, W270 etc. EcoPaXX has been approved for contact with drinking water Faucets Mixing Valve Lower risk of part failure & water leakage Product Grade(s): EcoPaXX Q-DWX6 EcoPaXX Q-DWX10 Value proposition (vs incumbent material)
- 25. CONFIDENTIAL Eyewear frames Eco-friendly eyeframes, with excellent surface appearance Page 24 Project Application: Eyewear Frames Industry: Eyewear Product grade: EcoPaXX Q-Y Value proposition (vs TR90) • Withstands the impact at extremely low temperature • High resilience • Less dynamic/static creep • Good bending fatigue behavior at low temperature of -10 oC • Lower carbon footprint / bio-based materialProduct Grade(s): Q-Y Q-FP4 Q150-D
- 26. Project FOR INTERNAL USE ONLY Picture FOR INTERNAL USEONLY For Internal Use Only Application: Mountaineering shoe chassis Industry: Sports & Leisure Products: EcoPaXX PA410 • EcoPaXX enables to produce a chassis with an intricate design that is light, has the necessary mix of flexibility and rigidity, retains its properties at very low temperatures typical of mountain environments, and has reduced moisture uptake • EcoPaXX is carbon neutral from cradle to gate Mountaineering shoe chassis Reliable Solutions with EcoPaXX PA410 Product Grade(s): EcoPaXX Q-HG6 Value proposition (vs incumbent material)
- 28. Page For Internal Use Only Convert plant based materials into a variety of renewable building blocks Leading to a platform of high performance bio- based polymers Plants, seeds and agricultural waste Decovery® resins
- 29. Page For Internal Use Only Plant-based Water-borne Solvent-borne Fossil Plant-basedresin Water Other
- 30. Page For Internal Use Only Enables our customers to make the highest quality paints Performance Using safe ingredients as much as possible and contains low VOCs Health Based on renewable materials, reducing the carbon footprint Sustainability
- 31. We connect our unique competences in Life Sciences and Materials Sciences to create solutions that nourish, protect and improve performance Mission Our purpose is to create brighter lives for people today and generations to come