Gunpowder and early firearms developed in the 13th-14th centuries in Europe. Black powder, the first propellant, consists of potassium nitrate, sulfur, and charcoal that burns rapidly to propel projectiles. Smokeless powder was later developed and does not produce smoke, using nitrocellulose as its base. It burns more efficiently in rifles and pistols. Black powder leaves residue while smokeless powder grains can sometimes be found at wound sites as evidence.