SlideShare a Scribd company logo
AUFBAU PRINCIPLE AND
ITS DEVIATIONS
WHAT IS AUFBAU PRINCIPLE?
Aufbau is a German word that means
“Building Up.”
Aufbau Principle states that when electrons
organize themselves in different energy shells
or orbits, they occupy the lower energy shells
at first and gradually make their way to the
higher energy levels.
SEQUENCE OF ENERGY SHELLS
GRADUALLY OCCUPIED BY ELECTRONS
FOLLOWING AUFBAU PRINCIPLE
1s
2s 2p
3s 3p 3d
4s 4p 4d 4f
5s 5p 5d
6s 6p
7s
1s
2s
2p 3s
3p
4s 3d
4p
5s 4d
5p
6s 4f
5d
6p 7s
SOME EXAMPLES
• H(1)=1s1
• He(2)=1s2
• Li(3)=1s22s1
• Na(11)=1s22s22p63s1
• Ar(18)=1s22s22p63s23p6
DEVIATIONS OF AUFBAU PRINCIPLE
Some elements do not follow the general rule of
Aufbau Principle because for such elements
the stability is determined by the presence of
either a half filled or a fully filled orbital.
Hence such elements gain more stability in the
presence of np3
,np6,(n-1)d5,(n-1)d10,(n-1)f7,(n-
1)f14 in their electronic configuration.
ELEMENTS THAT DEVIATE FROM
AUFBAU PRINCIPLE
Cr(24)=1s22s22p63s23p64s23d4 (WRONG)
=1s22s22p63s23p64s13d5 (CORRECT)
Cu(29)=1s22s22p63s23p64s23d9 (WRONG)
=1s22s22p63s23p64s13d10 (CORRECT)
Mo(42)=1s22s22p63s23p64s23d104p65s24d4 (WRONG)
=1s22s22p63s23p64s23d104p65s14d5 (CORRECT)
Ag(47)=1s22s22p63s23p64s23d104p65s24d9 (WRONG)
=1s22s22p63s23p64s23d104p65s14d10 (CORRECT)
Au(79)= 1s22s22p63s23p64s23d104p65s24d105p66s24f145d9
(WRONG)
=1s22s22p63s23p64s23d104p65s24d105p66s14f145d10 (CORRECT)
IMPORTANT THINGS TO REMEMBER
WHILE WRITING AUFBAU PRINCIPLE
• 1.NEVER PUT SPACES BETWEEN THE DENOTIONS
OF THE ORBITS AND ORBITALS. IT SHOULD NEVER
BE WRITTEN LIKE 1s 2s 2p or 1s,2s,2p. IT SHOULD
ALWAYS BE WRITTEN LIKE 1s2s2p.
• 2.AFTER WRITING THE SEQUENCE OF ENERGY
LEVELS ACCORDING TO AUFBAU PRINCIPLE, ONE
HAS TO ARRANGE THE ENERGY LEVELS AGAIN
ACCORDING TO THE ASCENDING ORDER OF
SHELLS IRRESPECTIVE OF THE ENERGY. EXAMPLE:
Va(23)=1s22s22p63s23p64s23d3
=1s22s22p63s23p63d34s2
Aufbau principle and its deviations

More Related Content

What's hot

Nuclear chemistry
Nuclear chemistry Nuclear chemistry
Nuclear chemistry
swapnil jadhav
 
hund's rule
hund's rulehund's rule
hund's rule
vxiiayah
 
Ionic Bonding
Ionic BondingIonic Bonding
Three principles to locate electrons
Three principles to locate electronsThree principles to locate electrons
Three principles to locate electrons
Jimnaira Abanto
 
Quantum Numbers
Quantum NumbersQuantum Numbers
Quantum Numbers
walt sautter
 
Lecture 5.1- Atomic Orbitals
Lecture 5.1- Atomic OrbitalsLecture 5.1- Atomic Orbitals
Lecture 5.1- Atomic Orbitals
Mary Beth Smith
 
Quantum Numbers
Quantum NumbersQuantum Numbers
Quantum Numbers
Sidra Javed
 
Atomic Orbitals
Atomic OrbitalsAtomic Orbitals
Atomic Orbitals
Jimnaira Abanto
 
Chemical bonding
Chemical bondingChemical bonding
Chemical bonding
Jimnaira Abanto
 
Ionic Compounds
Ionic CompoundsIonic Compounds
Ionic CompoundsOhMiss
 
Orbital shape-orientationt
Orbital shape-orientationtOrbital shape-orientationt
Orbital shape-orientationt
1971995
 
Quantum and-electronic-configuration
Quantum and-electronic-configurationQuantum and-electronic-configuration
Quantum and-electronic-configuration
Padme Amidala
 
Electrons in Atoms
Electrons in AtomsElectrons in Atoms
Electrons in Atoms
Currituck County High School
 
Molecular structure and bonding
Molecular structure and bondingMolecular structure and bonding
Molecular structure and bonding
Chris Sonntag
 
Ionic bonding
Ionic bondingIonic bonding
Ionic bonding
DRSURYAKANTBORUL
 

What's hot (20)

Nuclear chemistry
Nuclear chemistry Nuclear chemistry
Nuclear chemistry
 
Electronic structure
Electronic structureElectronic structure
Electronic structure
 
hund's rule
hund's rulehund's rule
hund's rule
 
Ionic Bonding
Ionic BondingIonic Bonding
Ionic Bonding
 
Vsepr theory
Vsepr theoryVsepr theory
Vsepr theory
 
Formal charge show
Formal charge showFormal charge show
Formal charge show
 
Quantum numbers
Quantum numbersQuantum numbers
Quantum numbers
 
Three principles to locate electrons
Three principles to locate electronsThree principles to locate electrons
Three principles to locate electrons
 
Quantum Numbers
Quantum NumbersQuantum Numbers
Quantum Numbers
 
Lecture 5.1- Atomic Orbitals
Lecture 5.1- Atomic OrbitalsLecture 5.1- Atomic Orbitals
Lecture 5.1- Atomic Orbitals
 
Electron affinity
Electron affinityElectron affinity
Electron affinity
 
Quantum Numbers
Quantum NumbersQuantum Numbers
Quantum Numbers
 
Atomic Orbitals
Atomic OrbitalsAtomic Orbitals
Atomic Orbitals
 
Chemical bonding
Chemical bondingChemical bonding
Chemical bonding
 
Ionic Compounds
Ionic CompoundsIonic Compounds
Ionic Compounds
 
Orbital shape-orientationt
Orbital shape-orientationtOrbital shape-orientationt
Orbital shape-orientationt
 
Quantum and-electronic-configuration
Quantum and-electronic-configurationQuantum and-electronic-configuration
Quantum and-electronic-configuration
 
Electrons in Atoms
Electrons in AtomsElectrons in Atoms
Electrons in Atoms
 
Molecular structure and bonding
Molecular structure and bondingMolecular structure and bonding
Molecular structure and bonding
 
Ionic bonding
Ionic bondingIonic bonding
Ionic bonding
 

Viewers also liked

Ionization Potential
Ionization PotentialIonization Potential
Ionization Potential
mqudratullahsaqib
 
Periodic trend sweek11
Periodic trend sweek11Periodic trend sweek11
Periodic trend sweek11
sjafry
 
Pauli's exclusion principle
Pauli's exclusion principlePauli's exclusion principle
Pauli's exclusion principle
Eran Sinbar
 
The Heisenberg Uncertainty Principle[1]
The Heisenberg Uncertainty Principle[1]The Heisenberg Uncertainty Principle[1]
The Heisenberg Uncertainty Principle[1]guestea12c43
 
Bohr Theory
Bohr TheoryBohr Theory
Bohr Theory
Gargi Education
 
Bohr’s model for hydrogen atom
Bohr’s model for hydrogen atomBohr’s model for hydrogen atom
Bohr’s model for hydrogen atom
Pusan National University
 

Viewers also liked (7)

Ionization Potential
Ionization PotentialIonization Potential
Ionization Potential
 
Periodic trend sweek11
Periodic trend sweek11Periodic trend sweek11
Periodic trend sweek11
 
Pauli's exclusion principle
Pauli's exclusion principlePauli's exclusion principle
Pauli's exclusion principle
 
The Heisenberg Uncertainty Principle[1]
The Heisenberg Uncertainty Principle[1]The Heisenberg Uncertainty Principle[1]
The Heisenberg Uncertainty Principle[1]
 
Bohr Theory
Bohr TheoryBohr Theory
Bohr Theory
 
2g spectrum scam ..
2g spectrum scam ..2g spectrum scam ..
2g spectrum scam ..
 
Bohr’s model for hydrogen atom
Bohr’s model for hydrogen atomBohr’s model for hydrogen atom
Bohr’s model for hydrogen atom
 

Recently uploaded

2024.06.01 Introducing a competency framework for languag learning materials ...
2024.06.01 Introducing a competency framework for languag learning materials ...2024.06.01 Introducing a competency framework for languag learning materials ...
2024.06.01 Introducing a competency framework for languag learning materials ...
Sandy Millin
 
The French Revolution Class 9 Study Material pdf free download
The French Revolution Class 9 Study Material pdf free downloadThe French Revolution Class 9 Study Material pdf free download
The French Revolution Class 9 Study Material pdf free download
Vivekanand Anglo Vedic Academy
 
GIÁO ÁN DẠY THÊM (KẾ HOẠCH BÀI BUỔI 2) - TIẾNG ANH 8 GLOBAL SUCCESS (2 CỘT) N...
GIÁO ÁN DẠY THÊM (KẾ HOẠCH BÀI BUỔI 2) - TIẾNG ANH 8 GLOBAL SUCCESS (2 CỘT) N...GIÁO ÁN DẠY THÊM (KẾ HOẠCH BÀI BUỔI 2) - TIẾNG ANH 8 GLOBAL SUCCESS (2 CỘT) N...
GIÁO ÁN DẠY THÊM (KẾ HOẠCH BÀI BUỔI 2) - TIẾNG ANH 8 GLOBAL SUCCESS (2 CỘT) N...
Nguyen Thanh Tu Collection
 
Language Across the Curriculm LAC B.Ed.
Language Across the  Curriculm LAC B.Ed.Language Across the  Curriculm LAC B.Ed.
Language Across the Curriculm LAC B.Ed.
Atul Kumar Singh
 
Sectors of the Indian Economy - Class 10 Study Notes pdf
Sectors of the Indian Economy - Class 10 Study Notes pdfSectors of the Indian Economy - Class 10 Study Notes pdf
Sectors of the Indian Economy - Class 10 Study Notes pdf
Vivekanand Anglo Vedic Academy
 
CLASS 11 CBSE B.St Project AIDS TO TRADE - INSURANCE
CLASS 11 CBSE B.St Project AIDS TO TRADE - INSURANCECLASS 11 CBSE B.St Project AIDS TO TRADE - INSURANCE
CLASS 11 CBSE B.St Project AIDS TO TRADE - INSURANCE
BhavyaRajput3
 
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
siemaillard
 
The Roman Empire A Historical Colossus.pdf
The Roman Empire A Historical Colossus.pdfThe Roman Empire A Historical Colossus.pdf
The Roman Empire A Historical Colossus.pdf
kaushalkr1407
 
Polish students' mobility in the Czech Republic
Polish students' mobility in the Czech RepublicPolish students' mobility in the Czech Republic
Polish students' mobility in the Czech Republic
Anna Sz.
 
How to Make a Field invisible in Odoo 17
How to Make a Field invisible in Odoo 17How to Make a Field invisible in Odoo 17
How to Make a Field invisible in Odoo 17
Celine George
 
Ethnobotany and Ethnopharmacology ......
Ethnobotany and Ethnopharmacology ......Ethnobotany and Ethnopharmacology ......
Ethnobotany and Ethnopharmacology ......
Ashokrao Mane college of Pharmacy Peth-Vadgaon
 
Chapter 3 - Islamic Banking Products and Services.pptx
Chapter 3 - Islamic Banking Products and Services.pptxChapter 3 - Islamic Banking Products and Services.pptx
Chapter 3 - Islamic Banking Products and Services.pptx
Mohd Adib Abd Muin, Senior Lecturer at Universiti Utara Malaysia
 
How to Split Bills in the Odoo 17 POS Module
How to Split Bills in the Odoo 17 POS ModuleHow to Split Bills in the Odoo 17 POS Module
How to Split Bills in the Odoo 17 POS Module
Celine George
 
Operation Blue Star - Saka Neela Tara
Operation Blue Star   -  Saka Neela TaraOperation Blue Star   -  Saka Neela Tara
Operation Blue Star - Saka Neela Tara
Balvir Singh
 
Unit 8 - Information and Communication Technology (Paper I).pdf
Unit 8 - Information and Communication Technology (Paper I).pdfUnit 8 - Information and Communication Technology (Paper I).pdf
Unit 8 - Information and Communication Technology (Paper I).pdf
Thiyagu K
 
Overview on Edible Vaccine: Pros & Cons with Mechanism
Overview on Edible Vaccine: Pros & Cons with MechanismOverview on Edible Vaccine: Pros & Cons with Mechanism
Overview on Edible Vaccine: Pros & Cons with Mechanism
DeeptiGupta154
 
Synthetic Fiber Construction in lab .pptx
Synthetic Fiber Construction in lab .pptxSynthetic Fiber Construction in lab .pptx
Synthetic Fiber Construction in lab .pptx
Pavel ( NSTU)
 
TESDA TM1 REVIEWER FOR NATIONAL ASSESSMENT WRITTEN AND ORAL QUESTIONS WITH A...
TESDA TM1 REVIEWER  FOR NATIONAL ASSESSMENT WRITTEN AND ORAL QUESTIONS WITH A...TESDA TM1 REVIEWER  FOR NATIONAL ASSESSMENT WRITTEN AND ORAL QUESTIONS WITH A...
TESDA TM1 REVIEWER FOR NATIONAL ASSESSMENT WRITTEN AND ORAL QUESTIONS WITH A...
EugeneSaldivar
 
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
siemaillard
 
Fish and Chips - have they had their chips
Fish and Chips - have they had their chipsFish and Chips - have they had their chips
Fish and Chips - have they had their chips
GeoBlogs
 

Recently uploaded (20)

2024.06.01 Introducing a competency framework for languag learning materials ...
2024.06.01 Introducing a competency framework for languag learning materials ...2024.06.01 Introducing a competency framework for languag learning materials ...
2024.06.01 Introducing a competency framework for languag learning materials ...
 
The French Revolution Class 9 Study Material pdf free download
The French Revolution Class 9 Study Material pdf free downloadThe French Revolution Class 9 Study Material pdf free download
The French Revolution Class 9 Study Material pdf free download
 
GIÁO ÁN DẠY THÊM (KẾ HOẠCH BÀI BUỔI 2) - TIẾNG ANH 8 GLOBAL SUCCESS (2 CỘT) N...
GIÁO ÁN DẠY THÊM (KẾ HOẠCH BÀI BUỔI 2) - TIẾNG ANH 8 GLOBAL SUCCESS (2 CỘT) N...GIÁO ÁN DẠY THÊM (KẾ HOẠCH BÀI BUỔI 2) - TIẾNG ANH 8 GLOBAL SUCCESS (2 CỘT) N...
GIÁO ÁN DẠY THÊM (KẾ HOẠCH BÀI BUỔI 2) - TIẾNG ANH 8 GLOBAL SUCCESS (2 CỘT) N...
 
Language Across the Curriculm LAC B.Ed.
Language Across the  Curriculm LAC B.Ed.Language Across the  Curriculm LAC B.Ed.
Language Across the Curriculm LAC B.Ed.
 
Sectors of the Indian Economy - Class 10 Study Notes pdf
Sectors of the Indian Economy - Class 10 Study Notes pdfSectors of the Indian Economy - Class 10 Study Notes pdf
Sectors of the Indian Economy - Class 10 Study Notes pdf
 
CLASS 11 CBSE B.St Project AIDS TO TRADE - INSURANCE
CLASS 11 CBSE B.St Project AIDS TO TRADE - INSURANCECLASS 11 CBSE B.St Project AIDS TO TRADE - INSURANCE
CLASS 11 CBSE B.St Project AIDS TO TRADE - INSURANCE
 
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
 
The Roman Empire A Historical Colossus.pdf
The Roman Empire A Historical Colossus.pdfThe Roman Empire A Historical Colossus.pdf
The Roman Empire A Historical Colossus.pdf
 
Polish students' mobility in the Czech Republic
Polish students' mobility in the Czech RepublicPolish students' mobility in the Czech Republic
Polish students' mobility in the Czech Republic
 
How to Make a Field invisible in Odoo 17
How to Make a Field invisible in Odoo 17How to Make a Field invisible in Odoo 17
How to Make a Field invisible in Odoo 17
 
Ethnobotany and Ethnopharmacology ......
Ethnobotany and Ethnopharmacology ......Ethnobotany and Ethnopharmacology ......
Ethnobotany and Ethnopharmacology ......
 
Chapter 3 - Islamic Banking Products and Services.pptx
Chapter 3 - Islamic Banking Products and Services.pptxChapter 3 - Islamic Banking Products and Services.pptx
Chapter 3 - Islamic Banking Products and Services.pptx
 
How to Split Bills in the Odoo 17 POS Module
How to Split Bills in the Odoo 17 POS ModuleHow to Split Bills in the Odoo 17 POS Module
How to Split Bills in the Odoo 17 POS Module
 
Operation Blue Star - Saka Neela Tara
Operation Blue Star   -  Saka Neela TaraOperation Blue Star   -  Saka Neela Tara
Operation Blue Star - Saka Neela Tara
 
Unit 8 - Information and Communication Technology (Paper I).pdf
Unit 8 - Information and Communication Technology (Paper I).pdfUnit 8 - Information and Communication Technology (Paper I).pdf
Unit 8 - Information and Communication Technology (Paper I).pdf
 
Overview on Edible Vaccine: Pros & Cons with Mechanism
Overview on Edible Vaccine: Pros & Cons with MechanismOverview on Edible Vaccine: Pros & Cons with Mechanism
Overview on Edible Vaccine: Pros & Cons with Mechanism
 
Synthetic Fiber Construction in lab .pptx
Synthetic Fiber Construction in lab .pptxSynthetic Fiber Construction in lab .pptx
Synthetic Fiber Construction in lab .pptx
 
TESDA TM1 REVIEWER FOR NATIONAL ASSESSMENT WRITTEN AND ORAL QUESTIONS WITH A...
TESDA TM1 REVIEWER  FOR NATIONAL ASSESSMENT WRITTEN AND ORAL QUESTIONS WITH A...TESDA TM1 REVIEWER  FOR NATIONAL ASSESSMENT WRITTEN AND ORAL QUESTIONS WITH A...
TESDA TM1 REVIEWER FOR NATIONAL ASSESSMENT WRITTEN AND ORAL QUESTIONS WITH A...
 
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa
 
Fish and Chips - have they had their chips
Fish and Chips - have they had their chipsFish and Chips - have they had their chips
Fish and Chips - have they had their chips
 

Aufbau principle and its deviations

  • 2. WHAT IS AUFBAU PRINCIPLE? Aufbau is a German word that means “Building Up.” Aufbau Principle states that when electrons organize themselves in different energy shells or orbits, they occupy the lower energy shells at first and gradually make their way to the higher energy levels.
  • 3. SEQUENCE OF ENERGY SHELLS GRADUALLY OCCUPIED BY ELECTRONS FOLLOWING AUFBAU PRINCIPLE 1s 2s 2p 3s 3p 3d 4s 4p 4d 4f 5s 5p 5d 6s 6p 7s
  • 4. 1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f 5d 6p 7s
  • 5. SOME EXAMPLES • H(1)=1s1 • He(2)=1s2 • Li(3)=1s22s1 • Na(11)=1s22s22p63s1 • Ar(18)=1s22s22p63s23p6
  • 6. DEVIATIONS OF AUFBAU PRINCIPLE Some elements do not follow the general rule of Aufbau Principle because for such elements the stability is determined by the presence of either a half filled or a fully filled orbital. Hence such elements gain more stability in the presence of np3 ,np6,(n-1)d5,(n-1)d10,(n-1)f7,(n- 1)f14 in their electronic configuration.
  • 7. ELEMENTS THAT DEVIATE FROM AUFBAU PRINCIPLE Cr(24)=1s22s22p63s23p64s23d4 (WRONG) =1s22s22p63s23p64s13d5 (CORRECT) Cu(29)=1s22s22p63s23p64s23d9 (WRONG) =1s22s22p63s23p64s13d10 (CORRECT) Mo(42)=1s22s22p63s23p64s23d104p65s24d4 (WRONG) =1s22s22p63s23p64s23d104p65s14d5 (CORRECT) Ag(47)=1s22s22p63s23p64s23d104p65s24d9 (WRONG) =1s22s22p63s23p64s23d104p65s14d10 (CORRECT) Au(79)= 1s22s22p63s23p64s23d104p65s24d105p66s24f145d9 (WRONG) =1s22s22p63s23p64s23d104p65s24d105p66s14f145d10 (CORRECT)
  • 8. IMPORTANT THINGS TO REMEMBER WHILE WRITING AUFBAU PRINCIPLE • 1.NEVER PUT SPACES BETWEEN THE DENOTIONS OF THE ORBITS AND ORBITALS. IT SHOULD NEVER BE WRITTEN LIKE 1s 2s 2p or 1s,2s,2p. IT SHOULD ALWAYS BE WRITTEN LIKE 1s2s2p. • 2.AFTER WRITING THE SEQUENCE OF ENERGY LEVELS ACCORDING TO AUFBAU PRINCIPLE, ONE HAS TO ARRANGE THE ENERGY LEVELS AGAIN ACCORDING TO THE ASCENDING ORDER OF SHELLS IRRESPECTIVE OF THE ENERGY. EXAMPLE: Va(23)=1s22s22p63s23p64s23d3 =1s22s22p63s23p63d34s2