Presentation delivered March 4, 2015 by Amir Ghavibazoo, Ph.D., at the California Asphalt Pavement Association joint Los Angeles-High Desert Technical Committee meeting in Fontana.
Asphalt Rubber Blend, Interaction, Properties and Test Methods
1.
2. Terms and Glossary
Asphalt Rubber Binder (ASTM D8 – 13b):
“A blend of asphalt cement, reclaimed tire rubber, and certain
additives in which the rubber component is at least 15 % by
weight of the total blend and has reacted in the hot asphalt
cement sufficiently to cause swelling of the rubber particles”
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3. Terms and Glossary
• Asphalt Rubber Interaction:
– The act of physical blending of CRM in asphalt at elevated
temperature which results in swelling of CRM particles and develops
physical properties of asphalt
• Interaction/reaction Temperature:
– The temperature at which the CRM and Asphalt are blended
• Mixing Temperature:
– The temperate of mixing aggregate and binder
• Compaction Temperature
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4. Caltrans Specification-Composition
Typical proportion of Asphalt Rubber per Caltrans:
•80% Asphalt binder
•2% Asphalt modifier (extender oil)
•18% CRM
Proportion of CRM
•75% CRM from scrap tiers (100% passing
No. 8 sieve)
•25% High natural rubber CRM (100%
passing No. 10 sieve)
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5. Caltrans Specification-Interaction
Interaction Temperature Profile
•Mixing temperature
•Asphalt rubber binder: 375°F – 425°F
•Aggregate: 300°F-325°F
•Compaction temperature
•290°F - 320°F
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•Per Caltrans, interaction
temperature is: 375°F – 425°F for
first 6 hours
•Temperature drops to 275°F after 6
hours for another 18 hours
7. Property Development of Asphalt
Rubber
• Dynamic Shear Rheometer (DSR)
– Plate Geometry: 25 mm
– Gap Size: 2 mm
– Temperature: 147°F (64°C)
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8. Property Development of Asphalt
Rubber
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Property development of asphalt
rubber is time and temperature
dependant
These trends are independent from
material type and concentration
9. Disintegration/Dissolution Test
• Sieve #200 (75µm) was used
• Passing CRM particles considered as dissolved/disintegrated
• Asphalt binder was dissolved into TCE and drained through sieve #200
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10. CRM Status in Asphalt
•CRM dissolves in asphalt
•Dissolution is almost independent from
CRM concentration
•Dissolution of CRM highly depends on
interaction temperature
•At 420°F, CRM dissolution can reach to more
than 60% within 4 hours
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11. Property Development Vs. CRM Status
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•Physical properties of asphalt is
mainly governed by status of CRM
particles
•Swelling improves the physical
properties
•Dissolution deteriorate physical
properties
12. CRM particles status in asphalt
Swelling process
Disintegration/Dissolution process
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MagdyAbdelrahman,TRB2006
13. Is the mechanism of
dissolution/disintegration the
same for all interaction
temperatures
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15. Effect of Mixing Temperature on
Oxidization
•For conventional asphalt:320°F
•For asphalt rubber: 375°F to 420°F
•Addition of CRM to asphalt reduces its aging susceptibility and prevent it from
oxidization
•BUT, increasing the interaction temperature significantly increases the
oxidization level of the asphalt binder
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16. Conclusion
• Asphalt rubber has a very dynamic nature
• Its properties are highly temperature dependant
• By regulating the interaction temperature, it is possible to satisfy specification’s
requirements, using almost any type of binder
• Better controls on interaction time and temperature will lead to better consistency
of the construction process and long term performance of the roads
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the physical exchange between asphalt cement and CRM when blended together at elevated temperatures which includes swelling of the rubber particles and development of specified physical properties of the asphalt and CRM blend to meet requirements. Although often referred to as reaction, interaction is not a chemical reaction but rather a physical interaction in which the CRM absorbs aromatic oils and light fractions (small volatile or active molecules) from the asphalt cement, and releases some of the similar oils used in rubber compounding into the asphalt cement. The interaction may be more appropriately defined as polymer swell.