Lipids are a diverse group of organic compounds that include triglycerides, phospholipids, waxes, cholesterol, and steroids. They are non-polar and do not dissolve in water. Triglycerides are a common type of lipid composed of a glycerol molecule bonded through ester bonds to three fatty acid molecules. Lipids serve several important functions in living things including long-term energy storage in tissues like adipose and plant oils, buoyancy for marine animals, insulation beneath skin, and production of metabolic water during respiration.
1. Lipids: a large and varied group of organic compounds. Lipids include: Triglycerides Phospholipids Waxes Cholesterol and Steroids Lipids are all non-polar and do not dissolve in water
2. Triglycerides are one of the most common types of lipids Triglycerides consist of one molecule of glycerol bonded to three fatty acid molecules Each fatty acid is linked to the glycerol molecule by an ester bond C C C H OH H H H H OH OH Glycerol Hydroxyl groups
3. Fatty Acids: General Formula: CH 3 (CH 2 ) n C O OH Carboxyl group H C C C H H H H H H C C C H H H H H H C O OH CH 3 CH 2
4. Can be drawn as: H C C C H H H H H H C C C H H H H H H C O OH C O OH
5. Forming a monoglyceride: + H 2 O This is a condensation reaction C C C H OH H H H H OH O H C O OH C C C H OH H H H H OH O C O Ester bond Hydroxyl group and carboxyl group react
6. A triglyceride: Can be drawn as: C C C H O H H H H O O C O C O C O Glycerol Fatty acid Fatty acid Fatty acid Ester bond
7. To split these ester bonds and separate a fatty acid from glycerol we need to add a molecule of water + H 2 O This is a hydrolysis reaction C C C H OH H H H H OH O C O C C C H OH H H H H OH O H C O OH
8. Uses of Lipids in Living Things 1. Long-term energy stores Human Adipose Tissue Plant Oils
9. 2. Buoyancy for marine animals: lipids are less dense than water so help animals float 3. Insulation: a layer of fat beneath the skin cuts down heat loss
10. 4. Production of water: fatty acids produce a lot of metabolic water when they are oxidised during respiration Camels’ humps are made of fat e.g. C 17 H 35 COOH + 26 O 2 18 CO 2 + 18 H 2 O (a typical fatty acid)
11. Homework : Compare the relative advantages and disadvantages to an organism of using carbohydrates and lipids as energy stores To be handed in on a separate sheet of paper.