Structural diagrams,condensed structures and line structures of hydrocarbons.How to identify a substance as Organic and inorganic ?.How to classify hydrocarbons? What is the difference between alkanes,alkenes and alkynes?
Structural diagrams,condensed structures and line structures of hydrocarbons.How to identify a substance as Organic and inorganic ?.How to classify hydrocarbons? What is the difference between alkanes,alkenes and alkynes?
more chemistry contents are available
1. pdf file on Termmate: https://www.termmate.com/rabia.aziz
2. YouTube: https://www.youtube.com/channel/UCKxWnNdskGHnZFS0h1QRTEA
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photo redox reactions
An outline of stereochemistry in simple terms.
I wish it will be understandable and useful.
Just go through it and enjoy learning.
Rejoice in learning friends.
Basic concepts of organic chemistry such as structural formulas, different kinds of representation, types of isomerism, examples, alkanes, alkenes, alkynes etc.
more chemistry contents are available
1. pdf file on Termmate: https://www.termmate.com/rabia.aziz
2. YouTube: https://www.youtube.com/channel/UCKxWnNdskGHnZFS0h1QRTEA
3. Facebook: https://web.facebook.com/Chemist.Rabia.Aziz/
4. Blogger: https://chemistry-academy.blogspot.com/
photo redox reactions
An outline of stereochemistry in simple terms.
I wish it will be understandable and useful.
Just go through it and enjoy learning.
Rejoice in learning friends.
Basic concepts of organic chemistry such as structural formulas, different kinds of representation, types of isomerism, examples, alkanes, alkenes, alkynes etc.
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Enterprise Excellence is Inclusive Excellence.pdfKaiNexus
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Implicitly or explicitly all competing businesses employ a strategy to select a mix
of marketing resources. Formulating such competitive strategies fundamentally
involves recognizing relationships between elements of the marketing mix (e.g.,
price and product quality), as well as assessing competitive and market conditions
(i.e., industry structure in the language of economics).
1. Bettelheim / Brown / Campbell / Farrell / Torres
William H. Brown Beloit College www.cengage.com/chemistry/bettelheim
Introduction to General, Organic, and Biochemistry 11e
1
Chapter 11
Alkanes
3. Alkanes
Alkanes: Hydrocarbons that contain only carbon-carbon
single bonds.
• The first two alkanes are methane and ethane.
• Alipathic hydrocarbons: Compound belonging to the
organic class in which atoms are connected via single,
double or triple bond to for nonaromatic compounds
3
4. Alkanes
Line-angle formula
• A line represents a carbon-carbon bond.
• A vertex and a line terminus represent a carbon atom.
• Hydrogen atoms are not shown in line-angle formulas.
4
6. Constitutional Isomerism
Constitutional isomers: Compounds that have the same
molecular formula but different structural formulas (a
different connectivity of their atoms).
• For the molecular formulas CH4, C2H6, and C3H8, only
one structural formula is possible. There are no
constitutional isomers for these molecular formulas.
• For the molecular formula C4H10, two constitutional
isomers are possible.
6
11. IUPAC Names
The name of an alkane with a branched chain of carbon
atom consists of:
• a parent name: the longest chain of carbon atoms.
• substituent names: the groups bonded to the parent
chain.
11
12. IUPAC Names
The IUPAC name of an alkane with an unbranched chain
of carbon atoms consists of two parts:
(1) A prefix shows the number of carbon atoms in the
chain.
(2) The suffix -ane: shows that the compound is a
saturated hydrocarbon.
12
13. Alkyl Groups
Alkyl group: A substituent group derived from an alkane
by removal of a hydrogen atom (Table 11.3).
• Commonly represented by the symbol R-.
• Named by dropping the -ane from the name of the
parent alkane and adding the suffix -yl.
13
14. IUPAC Names
1. The name for an alkane with an unbranched chain of
carbon atoms consists of a prefix showing the number of
carbon atoms and the ending -ane.
2. For branched-chain alkanes, the longest chain of carbon
atoms is the parent chain and its name is the root name.
3. Give each substituent on the parent chain a name and a
number. Use a hyphen to connect the number to the
name.
14
15. IUPAC Names
4. If there is one substituent, number the parent chain from
the end that gives the substituent the lower number.
15
16. IUPAC Names
5. If the same substituent occurs more than once:
• Number the parent chain from the end that gives the
lower number to the substituent encountered first.
• Indicate the number of times the substituent occurs by
a prefix di-, tri-, tetra-, penta-, hexa-, and so on.
• Use a comma to separate position numbers.
16
17. IUPAC Names
6. If there are two or more different substituents:
• List them in alphabetical order.
• Number the chain from the end that gives the lower
number to the substituent encountered first.
• If there are different substituents at equivalent
positions on opposite ends of the parent chain, give
the substituent of lower alphabetical order the lower
number.
17
18. IUPAC Names
7. Do not include the prefixes di-, tri-, tetra-, and so on or the
hyphenated prefixes sec- and tert- in alphabetizing;
• Alphabetize the names of substituents first, and then
insert these prefixes. In the following example, the
alphabetizing parts are ethyl and methyl, not ethyl and
dimethyl.
18
20. Common Names
Common names; an older system
• The number of carbon atoms determines the name.
• The first three alkanes are methane, ethane, and
propane.
• All alkanes with the molecular formula C4H10 are named
butanes, all those with the molecular formula C5H12 are
named pentanes, etc.
• For alkanes beyond propane, iso shows that one end of
an otherwise unbranched chain terminates in (CH3)2CH-
For more complex alkanes, use the IUPAC system.
20
21. Sources of Alkanes
Natural gas
• 90 to 95 percent methane.
• 5 to 10 percent ethane, and
• A mixture of other relatively low-boiling alkanes, chiefly
propane, butane, and 2-methylpropane (isobutane).
Petroleum
• A thick, viscous liquid mixture of thousands of
compounds, most of them hydrocarbons formed from
the decomposition of marine plants and animals.
• Fuel automobiles, aircrafts and trains
• Provide most greases and lubricants for machineries
• Provide 90% or organic raw materials for fibers,
plastics, detergents, drugs etc.
21
22. Synthesis of Alkanes
• Fractional distillation: fundamental separation
process of refining petroleum.
• Each fraction contains a mixture of hydrocarbons
that boils within a particular range
22
24. Cycloalkanes
Cyclic hydrocarbon: A hydrocarbon that contains carbon
atoms joined to form a ring.
Cycloalkane: A cyclic hydrocarbon in which all carbons of
the ring are saturated (have only carbon-carbon single
bonds).
Cycloalkanes with ring sizes of from 3 to over 30 carbon
atoms are found in nature.
• Five-membered (cyclopentane) and six-membered
(cyclohexane) rings are especially abundant in nature.
24
25. Cycloalkanes
Nomenclature
• To name a cycloalkane, prefix the name of the
corresponding open-chain alkane with cyclo-, and
name each substituent on the ring.
• If there is only one substituent on the ring, there is no
need to give it a location number.
• If there are two substituents, number the ring
beginning with the substituent of lower alphabetical
order.
25
27. Bettelheim / Brown / Campbell / Farrell / Torres
William H. Brown Beloit College www.cengage.com/chemistry/bettelheim
Introduction to General, Organic, and Biochemistry 11e
What are the shapes of
Alkanes and Cycloalkanes?
27
28. Conformations of Alkanes
Conformation: Any three-dimensional arrangement of
atoms in a molecule that results by rotation about a single
bond.
• Figure 11-4 Three conformations for a butane molecule.
28
29. Conformations of Alkanes
• For any alkanes, except for methane, there is an infinite
number of conformations.
• Majority of molecules will be the least crowded (Most stable).
• Fewest will be in the most crowded conformation.
29
30. Cycloalkanes
• Conformations of cyclopentane and cyclohexane because
they are the carbon rings most commonly found in nature.
• Non-planar or puckered conformations are favored in all
cycloalkanes
• Why? Conformation that is farthest apart.
30
32. Cyclohexane
The most stable conformation of a cyclohexane ring is the
chair conformation.
• All bond angles are approximately 109.5°.
32
33. Cyclohexane
In a chair conformation,
• six C-H bonds are equatorial (extends from the ring
perpendicular to the imaginary axis of the ring).
• six C-H bonds are axial (extends from the ring parallel
to the imaginary axis).
• Figure 11-6 Chair conformation of cyclohexane
33
34. Cyclohexane
The more stable conformation of a substituted
cyclohexane ring has substituent group(s) equatorial
rather than axial.
Figure 11-7 Methylcyclohexane. The axial methyl group is
parallel to two axial hydrogens on the same side of the
ring.
34
35. Cis/Trans Isomers
1. Same molecular formula
2. Same connectivity of their atoms
3. Different arrangement of their atoms in space.
Cis (Same side): on the same side of the ring.
Trans (Across): on the opposite side of the ring,
• In drawing cis-trans isomers of disubstituted
cyclopentanes, we can view a cyclopentane ring edge-on.
35
36. Cis-Trans Isomers
• Alternatively, we can view the cyclopentane ring from
above. Substituents are shown by solid wedges
(above) or dashed wedges (below).
36
37. Cis-Trans Isomerism
• To determine cis-trans isomers in disubstituted
cyclohexanes, we can view a cyclohexane ring either
as a planar hexagon or viewed from above.
• Because cis-trans isomers differ in the orientation of
their atoms in space, they are stereoisomers.
• Cis-trans isomers are one type of stereoisomer.
• In Chapter 15, we study another type called
enantiomers.
37
38. Cis-Trans Isomerism
• Stereocenter: tetrahedral atom, most commonly
carbon at which exchange of two groups produces a
stereoisomer.
• Configuration: refers to the arrangement of atoms
about a stereocenter
• Cis or trans configuration
38
39. Physical Properties
The most important physical property of alkanes and
cycloalkanes is their almost complete lack of polarity.
• The electronegativity difference between carbon and
hydrogen is 2.5 - 2.1 = 0.4 on the Pauling scale.
• Given this small difference, we classify a C-H bond as
nonpolar covalent.
• Alkanes are nonpolar compounds and the only
interaction between their molecules are the very weak
London dispersion forces.
39
40. Melting Points
Melting and boiling points:
• Boiling points of alkanes are lower than those of
almost any other type of compound of the same
molecular weight.
• In general, both boiling and melting points of alkanes
increase with increasing molecular weight.
• Longer the carbon chain length, higher its boiling point
• Due to increase in surface area = increase London
dispersion force
40
42. Physical Properties
• Alkanes that are constitutional isomers are different
compounds and have different physical and chemical
properties.
42
Increase in branching
Lower boiling point
43. Physical Properties
Solubility: a case of “like dissolves like”.
• Alkanes are not soluble in water because they are
unable to form hydrogen bonds with water.
• Liquid alkanes are soluble in each other.
• Alkanes are also soluble in other nonpolar organic
compounds, such as toluene and diethyl ether.
Density
• The average density of the liquid alkanes listed in Table
11-4 is about 0.7 g/mL; that of higher-molecular-weight
alkanes is about 0.8 g/mL.
• All liquid and solid alkanes are less dense than water
(1.0 g/mL) and, because they are both less dense and
insoluble, they float on water.
43
44. Reactions
Oxidation (combustion)
• Oxidation of hydrocarbons, including alkanes and
cycloalkanes, is the basis for their use as energy
sources for heat [natural gas, liquefied petroleum gas
(LPG), and fuel oil] and power (gasoline, diesel fuel,
and aviation fuel).
44
45. Reactions of Alkanes
Reaction with halogens (halogenation) (F, Cl, Br)
• Halogenation of an alkane is a substitution reaction.
45
46. Bettelheim / Brown / Campbell / Farrell / Torres
William H. Brown Beloit College www.cengage.com/chemistry/bettelheim
Introduction to General, Organic, and Biochemistry 11e
What are some important
Haloalkanes?
46
47. The Chlorofluorocarbons
Chlorofluorocarbons (CFCs)
• Manufactured under the trade name Freon.
• CFCs are nontoxic, nonflammable, odorless, and
noncorrosive.
• Among the CFCs most widely used were CCl3F (Freon-
11) and CCl2F2 (Freon-12).
CFCs were used as;
• Heat-transfer agents in refrigeration systems (replaced
ammonia and sulfur dioxide).
• Industrial cleaning solvents to prepare surfaces for
coatings and to remove cutting oils from millings.
• Propellants for aerosol sprays.
47
48. CFC Replacements
Chlorofluorocarbons (CFCs) cause destruction of the
Earth’s stratospheric ozone layer.
The most prominent replacements are the
hydrofluorocarbons (HFCs) and the
hydrochlorofluorocarbons (HCFCs).
• These compounds are chemically more reactive than
CFCs and are destroyed before they reach the
stratosphere.
48
49. Solvents
• Several low molecular weight haloalkanes are
excellent solvents in which to carry out organic
reactions and to use as cleaners and degreasers.
• Carbon tetrachloride was the first to find wide range
of application but has been discontinued because it is
now known as both toxic and carcinogen
• Most widely used haloalkane solvent is
dichloromethane, CH2Cl2
49
If both IUPAC is given, IUPAC first followed by common name
Two major source of alkanes are natural gas and petroleum
The longer the carbon chain is, higher its boiling point, higher temperature required for it to evaporate
1-sec-butyl-3-nitrocyclohexane
Each carbon atom is freely rotating forming different conformations.Farthest apart are the most stable
Majority is in least crowded and fewest is the most crowded
Cyclohexane and cyclopentane because they are the most commonly found in nature
Stereo center: tetrahedral atom, most commonly carbon at which two groups produces a stereoisomer.
Increase in branching the lower the boiling point
Most important chemical property of alkanes and cycloalkanes are ther inertnessUnreactive under normal ionic reaction
React with Oxygen (oxidation in the form of combustion to form CO2 and H20)
Fluorine, chlorine and bromine to form halogenated carbons
Methane major component of natural gas
Propane major component of LPG or bottled gas
Dark room at room temperature.
Heat to 100degree Celsius or expose to light (Substitution reaction)
Because of their inertness, it doesn’t decompose in the stratosphere in which they absorb ultraviolet radiation from the sun.increase in UV light promotes destruction of crops and agricultural species as well as increase incidence of skin cancer in light skinned individuals