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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 04 | Apr 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 55
EXPERIMENTAL INVESTIGATION OF FORMULATION AND
CHARACTERIZATION OF BIOCRETES
X.KANI MOZHI1, Mr. C. RAVI2
1M. E (Structural Engineering), Department of Civil Engineering College, Tiruchirappalli, Tamil Nadu, India
2Professor& Head Department of Civil Engineering College, Tiruchirappalli, Tamil Nadu, India
----------------------------------------------------------------------***---------------------------------------------------------------------
ABSTRACT-The development of construction industries
provides more benefits to the society and the people. This
study is used to improve the engineering properties of
cement concrete with the help of oyster shell. The properties
of freshly made materials are tested at a fixed water-cement
ratio (0.45) and at five different weight ratios with partial
replacement of course aggregate. The hardened properties
and the durability are tested and various engineering
properties are investigated. Present scenario in construction
field, all around the world is facing a serious problem with
price hike of raw materials. So, they are much concerned to
reduce the consumption of readily available raw materials.
Usage of biocrete is an innovative idea to achieve this
requirement. Because of its strength and weight, the speed
of construction is quick and the installation becomes easy.
The benefits of biocrete is endless, which are good in
strength and reduction in weight is noticed which in turn
saves cost, high load bearing strength and high durability.
In this project, the bio-concretes are formulated using bio
waste materials such as oyster shell in various percentages
mixed with concrete. The design mix proportion used is
1:0.75:1.5 at which 5%, 10%, 20% of biocrete waste is
partially replaced with coarse aggregate in concrete.
Compressive strength test, split tensile test and flexural
strength tests are conducted and partially replaced
specimens are compared with the control concrete to
explore the potential use of these materials in the field.
1. INTRODUCTION
The disposal of solid wastes is major problem
around the world. Recycling and use of these waste
materials is increasing worldwide, especially in
construction fields. In construction industries use of
recycled materials and waste is becoming more popular
due to shortage of natural mineral resources and
increasing waste disposal cost. However, with the use of
waste in engineering applications, a need for further
understanding of their engineering behavior is required.
The coastal wastes from coastal area are usually disposed
as waste product which becomes an environmental
hazard. Light weight aggregates have wide application in
various field in civil engineering. In environmental
engineering bacteria, in waste water treatment facilities
can be grown and fixed on their surface in a dispersive
manner in soil engineering and horticulture due to
richness in pores they can be used for holding water. Light
weight aggregates with low density and water absorption
rate, respectively are desired to reduce construction
objects deadweight and to promote the workability of light
weight aggregate mortar.
In Taiwan oyster shell are the byproduct of
shelled oyster consumption, and the yield in 2009 was
approximately 34,000MT. The total quantity of “waste
oyster shell” produced globally after shelling is
approximately 200,000MT per year: however only a very
small portion of this enormous fishery waste is recovered
and reused (e.g., fertilizer for soil crops or handicrafts).
Instead, most of the waste oyster shell is discarded or
buried, which can result in sewage, offensive odors, or the
breeding of mosquitos and flies. These problems influence
the quality of the local living environment and cause
environment sanitation, pollution and production
problems.
Therefore, this research work is tailored towards
the possibility of using oyster shell as replacement for
coarse aggregate at different level in production of high
strength concrete.
2. MATERIALS
2.1 Cement
Ordinary Portland Cement of 53 grade confining
to IS 8112 was used throughout the work. The Fine
aggregates sued throughout out the work comprised of
river sand with maximum size of 4.75mm conforming to
zone II as per IS 383-1970 with specific gravity of 2.6.
Then Coarse aggregates used consisted of machine
crushed stone angular in shape and passing through
20mm IS sieve and retained on 4.75mm IS sieve with
specific gravity of 2.66.
Table-1 Properties of Cement
S.No property Cement
1 Initial Setting time 30 minutes
2 Final Setting time 447 minutes
3 Consistency 30%
4 Specific Gravity 3.13
2.2 Water
A tap water available in the concrete laboratory was
used in preparation of concrete. The qualities of water
samples are uniform and potable. PH value lies between 6
to 8 and the water us free from organic matter and the
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 04 | Apr 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 56
solid content should be within the permissible limit as per
IS 456 2000 and conforming to IS 3025-1964.
2.3 Physical Properties of Sand, Oyster shells and
Coarse aggregate
2.3.1 Sand
Sand is used as fine aggregates in mortars and
concrete. Natural river sand is the most preferred choice
as a fine aggregate material. River sand is the natural
weathering of rocks and over a period of million years. It is
obtained from the river beds. River sand is becoming a
scarce commodity now.
2.3.2 Oyster Shell
Oyster shell farming in the sea. Large quantity of
Oyster shell is waste result in the vicinity of an oyster
container freight station because the shells are discarded
during processing
Fig.1 Oyster shell
Table-2 Properties of Sand & Oyster shell
Properties of
aggregates
Sand Oyster Shells
Specific gravity 2.64 2.1
Absorption rate (%) 2.38 7.66
Finenessmodulus
(FM)
2.84 2.75
Dryness-rodded unit
weight(kg/m3)
1750 1051
2.3.3 Coarse Aggregate
Aggregates are inert granular materials such as sand,
gravel, or crushed stone that along with water and
Portland cement, are an essential ingredient in concrete.
Aggregates, which account for 60 to 75 percent of the total
volume of concrete are divided into two distinct
categories-fine and coarse aggregates.
Table-3 Properties of Coarse aggregate
Specific gravity 2.74
Fineness modulus 6.9
Absorption rate (%) 1.52
Drynessrodded unit weight(kg/m3) 1744
Fig.2 Fine and Coarse aggregates
2.4 Batching and Mixing of Materials
Batching of materials was done by weight. The
percentage addition of Ordinary Portland Cement (OPC)
by biocretes were 0%, 5%, 10% and 20%. The 0%
addition was to serve as control concrete for other
samples.
2.5 Concrete Mix Design
The Indian standard suggested a technique of concrete
mix design. This mix design process is enclosed in IS
10262-82. The concrete is used in this research work was
made using Binder, Sand and Gravel. The concrete mix
proportion was 1:0.75:1.5 by weight.
2.6 Casting Sample
Concrete Cubic specimens’ size 150mm X 150mm X
150mm and cylinder specimens’ size 150mm X 300mm
were casted for determine all strength. The concrete was
mixed, placed and compacted in three layers. This samples
were de-moulded after 24 hours and kept in curing tank
for 28 days as required.
3. RESULT AND DISCUSSION
3.1 Testing of Compressive Strength
Table-4 Compressive Strength Result
Addition of
oyster
shell
Compressive Strength (fck) N/mm2
7th day 14th day 28th day
0% 16.48 21.30 28.02
5% 16.69 23.20 29.30
10% 19.20 25.50 30.42
20% 15.10 23.16 27.38
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 04 | Apr 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 57
Chart-1: Compressive strength for various mix
proportions of biocretes at 7th, 14th and 28th day test
3.2 Testing of Split Tensile Strength
Table-5 Tensile Strength Result
Addition of
oyster
shell
Tensile Strength (fck) N/mm2
7th day 14th day 28th day
0% 1.1 1.3 1.85
5% 1.23 1.51 1.73
10% 1.3 1.62 1.61
20% 1.2 1.3 1.52
Chart-2: Split Tensile strength for various mix
proportions of biocretes at 7th, 14th and 28th day test
3.3 Testing of Flexural Strength
Table-6 Flexural Strength Result
Addition of
oyster
shell
Compressive Strength (fck)
N/mm2
14th day 28th day
0% 3.6 4.96
5% 4.1 5.6
10% 4.6 6.1
20% 4.2 5.4
Chart-3: Flexural strength for various mix
proportions of biocretesat 14th and 28th day test
4. CONCLUSIONS
1. The Compressive strength, Tensile strength and
Flexural strength of concrete achieved good strength up to
10% addition of oyster shell. Further addition of oyster
shell is decrease in the compressive tensile and flexural
strength is noted.
2. Based on this experiment it is concluded that
the mix can be made by replacing oyster shell for coarse
aggregate without decreasing strength. 10%of
replacement of oyster shell for coarse aggregate has
produced maximum compressive strength.
3. The comparison with ordinary concrete with
oyster shell replaced concrete gave better performance in
strength. Thus, results in increasing the strength of the
concrete by replacing the oyster shell for coarse aggregate.
4. Hence, the demand for coarse aggregate can be
reduced.
0
5
10
15
20
25
30
35
0% 5% 10% 20%
7 D
14 D
28 D
% of oyster shell
0
0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
1.8
0% 5% 10% 20%
7 D
14 D
28 D
% of oyster shell% of oyster shell
0
1
2
3
4
5
6
7
0% 5% 10% 20%
14 D
28 D
% of oyster shell% of oyster shell
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 04 | Apr 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 58
REFERANCE
1. Falade, F.;Ikponmwosa, E. E.; and Ojediran, N.
I.,(2010).Behavior of Lightweight Concrete Containing
Periwinkle Shells at Elevated Temperature. Journal of
Engineering Science and Technology. 5 (4): pp. 379 – 390
2. Gil-Lim Yoon, Byung-Takkim (2003); Chemical-
Mechanical and characteristics of crushed oyster shell.
Korean institute of ocean science and technology and G.S
construction and engineering, pp.825-834
3. Yang EI, Yi ST, Leem YM. Effect of oyster shell
substituted for fine aggregate on concrete characteristics;
part I. Fundamental properties. CemConr Res
205;359(11)2175-82.
4. Ephraim Gbinu K.S Performance of high strength
concrete using oyster shell Ash as partial replacement of
cement, Department of Civil Engineering, River State
University, Nigeria. pp (33-38)
5. Zhong,B., Zhou,Q., Chan,CYu,Y,(2012)Structure and
property characterization of oyster shell cementing
material, chin.J.struct. Chem.31(1) 85-92.

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The design mix proportion used is 1:0.75:1.5 at which 5%, 10%, 20% of biocrete waste is partially replaced with coarse aggregate in concrete. Compressive strength test, split tensile test and flexural strength tests are conducted and partially replaced specimens are compared with the control concrete to explore the potential use of these materials in the field. 1. INTRODUCTION The disposal of solid wastes is major problem around the world. Recycling and use of these waste materials is increasing worldwide, especially in construction fields. In construction industries use of recycled materials and waste is becoming more popular due to shortage of natural mineral resources and increasing waste disposal cost. However, with the use of waste in engineering applications, a need for further understanding of their engineering behavior is required. The coastal wastes from coastal area are usually disposed as waste product which becomes an environmental hazard. Light weight aggregates have wide application in various field in civil engineering. In environmental engineering bacteria, in waste water treatment facilities can be grown and fixed on their surface in a dispersive manner in soil engineering and horticulture due to richness in pores they can be used for holding water. Light weight aggregates with low density and water absorption rate, respectively are desired to reduce construction objects deadweight and to promote the workability of light weight aggregate mortar. In Taiwan oyster shell are the byproduct of shelled oyster consumption, and the yield in 2009 was approximately 34,000MT. The total quantity of “waste oyster shell” produced globally after shelling is approximately 200,000MT per year: however only a very small portion of this enormous fishery waste is recovered and reused (e.g., fertilizer for soil crops or handicrafts). Instead, most of the waste oyster shell is discarded or buried, which can result in sewage, offensive odors, or the breeding of mosquitos and flies. These problems influence the quality of the local living environment and cause environment sanitation, pollution and production problems. Therefore, this research work is tailored towards the possibility of using oyster shell as replacement for coarse aggregate at different level in production of high strength concrete. 2. MATERIALS 2.1 Cement Ordinary Portland Cement of 53 grade confining to IS 8112 was used throughout the work. The Fine aggregates sued throughout out the work comprised of river sand with maximum size of 4.75mm conforming to zone II as per IS 383-1970 with specific gravity of 2.6. Then Coarse aggregates used consisted of machine crushed stone angular in shape and passing through 20mm IS sieve and retained on 4.75mm IS sieve with specific gravity of 2.66. Table-1 Properties of Cement S.No property Cement 1 Initial Setting time 30 minutes 2 Final Setting time 447 minutes 3 Consistency 30% 4 Specific Gravity 3.13 2.2 Water A tap water available in the concrete laboratory was used in preparation of concrete. The qualities of water samples are uniform and potable. PH value lies between 6 to 8 and the water us free from organic matter and the
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 04 | Apr 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 56 solid content should be within the permissible limit as per IS 456 2000 and conforming to IS 3025-1964. 2.3 Physical Properties of Sand, Oyster shells and Coarse aggregate 2.3.1 Sand Sand is used as fine aggregates in mortars and concrete. Natural river sand is the most preferred choice as a fine aggregate material. River sand is the natural weathering of rocks and over a period of million years. It is obtained from the river beds. River sand is becoming a scarce commodity now. 2.3.2 Oyster Shell Oyster shell farming in the sea. Large quantity of Oyster shell is waste result in the vicinity of an oyster container freight station because the shells are discarded during processing Fig.1 Oyster shell Table-2 Properties of Sand & Oyster shell Properties of aggregates Sand Oyster Shells Specific gravity 2.64 2.1 Absorption rate (%) 2.38 7.66 Finenessmodulus (FM) 2.84 2.75 Dryness-rodded unit weight(kg/m3) 1750 1051 2.3.3 Coarse Aggregate Aggregates are inert granular materials such as sand, gravel, or crushed stone that along with water and Portland cement, are an essential ingredient in concrete. Aggregates, which account for 60 to 75 percent of the total volume of concrete are divided into two distinct categories-fine and coarse aggregates. Table-3 Properties of Coarse aggregate Specific gravity 2.74 Fineness modulus 6.9 Absorption rate (%) 1.52 Drynessrodded unit weight(kg/m3) 1744 Fig.2 Fine and Coarse aggregates 2.4 Batching and Mixing of Materials Batching of materials was done by weight. The percentage addition of Ordinary Portland Cement (OPC) by biocretes were 0%, 5%, 10% and 20%. The 0% addition was to serve as control concrete for other samples. 2.5 Concrete Mix Design The Indian standard suggested a technique of concrete mix design. This mix design process is enclosed in IS 10262-82. The concrete is used in this research work was made using Binder, Sand and Gravel. The concrete mix proportion was 1:0.75:1.5 by weight. 2.6 Casting Sample Concrete Cubic specimens’ size 150mm X 150mm X 150mm and cylinder specimens’ size 150mm X 300mm were casted for determine all strength. The concrete was mixed, placed and compacted in three layers. This samples were de-moulded after 24 hours and kept in curing tank for 28 days as required. 3. RESULT AND DISCUSSION 3.1 Testing of Compressive Strength Table-4 Compressive Strength Result Addition of oyster shell Compressive Strength (fck) N/mm2 7th day 14th day 28th day 0% 16.48 21.30 28.02 5% 16.69 23.20 29.30 10% 19.20 25.50 30.42 20% 15.10 23.16 27.38
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 04 | Apr 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 57 Chart-1: Compressive strength for various mix proportions of biocretes at 7th, 14th and 28th day test 3.2 Testing of Split Tensile Strength Table-5 Tensile Strength Result Addition of oyster shell Tensile Strength (fck) N/mm2 7th day 14th day 28th day 0% 1.1 1.3 1.85 5% 1.23 1.51 1.73 10% 1.3 1.62 1.61 20% 1.2 1.3 1.52 Chart-2: Split Tensile strength for various mix proportions of biocretes at 7th, 14th and 28th day test 3.3 Testing of Flexural Strength Table-6 Flexural Strength Result Addition of oyster shell Compressive Strength (fck) N/mm2 14th day 28th day 0% 3.6 4.96 5% 4.1 5.6 10% 4.6 6.1 20% 4.2 5.4 Chart-3: Flexural strength for various mix proportions of biocretesat 14th and 28th day test 4. CONCLUSIONS 1. The Compressive strength, Tensile strength and Flexural strength of concrete achieved good strength up to 10% addition of oyster shell. Further addition of oyster shell is decrease in the compressive tensile and flexural strength is noted. 2. Based on this experiment it is concluded that the mix can be made by replacing oyster shell for coarse aggregate without decreasing strength. 10%of replacement of oyster shell for coarse aggregate has produced maximum compressive strength. 3. The comparison with ordinary concrete with oyster shell replaced concrete gave better performance in strength. Thus, results in increasing the strength of the concrete by replacing the oyster shell for coarse aggregate. 4. Hence, the demand for coarse aggregate can be reduced. 0 5 10 15 20 25 30 35 0% 5% 10% 20% 7 D 14 D 28 D % of oyster shell 0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 0% 5% 10% 20% 7 D 14 D 28 D % of oyster shell% of oyster shell 0 1 2 3 4 5 6 7 0% 5% 10% 20% 14 D 28 D % of oyster shell% of oyster shell
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 04 | Apr 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 58 REFERANCE 1. Falade, F.;Ikponmwosa, E. E.; and Ojediran, N. I.,(2010).Behavior of Lightweight Concrete Containing Periwinkle Shells at Elevated Temperature. Journal of Engineering Science and Technology. 5 (4): pp. 379 – 390 2. Gil-Lim Yoon, Byung-Takkim (2003); Chemical- Mechanical and characteristics of crushed oyster shell. Korean institute of ocean science and technology and G.S construction and engineering, pp.825-834 3. Yang EI, Yi ST, Leem YM. Effect of oyster shell substituted for fine aggregate on concrete characteristics; part I. Fundamental properties. CemConr Res 205;359(11)2175-82. 4. Ephraim Gbinu K.S Performance of high strength concrete using oyster shell Ash as partial replacement of cement, Department of Civil Engineering, River State University, Nigeria. pp (33-38) 5. Zhong,B., Zhou,Q., Chan,CYu,Y,(2012)Structure and property characterization of oyster shell cementing material, chin.J.struct. Chem.31(1) 85-92.