SUPERCONDUCTIVITY 
Submitted By : 
Hemanshi Kalra
What is superconductivity? 
 Superconductivity is a phenomenon of exactly 
zero electrical resistance and expulsion 
of magnetic fields occurring in 
certain materials when cooled below a 
characteristic critical temperature. 
It was discovered by Dutch 
physicist Heike Kamerlingh 
Onnes on April 8,1911 in 
Leiden.
Meissner Effect 
 When a material makes the 
transition from the normal 
to superconducting state, it 
actively excludes magnetic 
fields from its interior. 
 It was discovered by German 
physicists Walther 
Meissner and Robert 
Ochsenfeld .
A magnet levitating above a superconductor cooled 
by liquid nitrogen.
The BCS Theory 
Electron-Lattice Interactions 
 A passing electron attracts the lattice, causing a slight ripple toward its path. 
 Another electron passing in the opposite direction is attracted to that 
displacement. 
BCS theory suggests that superconductors have zero electrical resistance 
below critical temperatures because at such temperatures the electrons pass 
unhindered through the crystal lattice and therefore lose energy. The theory 
states that the supercurrent in a superconductor is carried by many million 
bound electron pairs, called Cooper Pairs.
High TC Super conductors. 
In a super conductor if the transition temperature is high ie.,greater 
than 20K, then it is called as high-temperature super conductors. 
In 1986, Muller and Bednorz discovered high tempertaure super 
conductor in Ceramics.
Superconducting Materials
Metal and Alloys 
• Some metals become superconductors 
at extremely low temperatures 
• Some of these include mercury, lead, tin, 
aluminum, lead, niobium, cadmium, 
gallium, zinc, and zirconium 
• Unfortunately, the critical temperatures 
are too low for practical application 
• Metal alloys like Nb-Ti, and Nb-Zr are 
usually Type II superconductors 
• Metal Alloys have higher critical 
temperatures and magnetic fluxes than 
pure metals. 
• As a consequence of their properties, 
they are more useful for practical 
applications than pure metals
Iron Based Superconductors 
 Iron-based superconductors contain 
layers of iron and a pnictide such as 
arsenic or phosphorus .This is 
currently the family with the second 
highest critical temperature, behind 
the cuprates. 
 The crystalline material, known 
chemically as LaOFeAs, stacks iron 
and arsenic layers, where the 
electrons flow, between planes 
of lanthanum and oxygen. 
Crystal structure of LaFeAsO, one of 
the ferropnictide compounds
Cuprates 
 Cuprate superconductors are 
generally considered to be two-dimensional 
materials with their 
superconducting properties 
determined by electrons moving 
within weakly coupled copper-oxide 
(CuO2) layers. Neighboring layers 
containing ions such 
as lanthanum, barium, strontium, or 
other atoms act to stabilize the 
structure and dope electrons or holes 
onto the copper-oxide layers. 
 Cuprates Superconducting materials. 
HgBa2Ca2Cu3Ox (critical temperature to 133 K) 
Bi2Sr2Ca2Cu3O10(BSCCO) (critical temperature to 110 K) 
YBa2Cu3O7 (YBCO) (critical temperature to 92 K.)
Organic Superconductors 
 Superconductivity in low dimensional organic materials was first suggested by 
Little in 1965. 
 C60 by itself is a very poor conductor. By doping this compound with electron 
donors such as alkaline metals, which provide the conduction electrons, 
superconductivity can be induced. K3C60 has a Tc of 19 K 
 Other superconductors in which conductivity arises in 
the pi-electrons of unsaturated bonds have also been 
discovered. 
 Scientists have created the first organic 
superconductor based on a simple aromatic molecule, 
picene (C22H14), doped with an alkali metal.Depending 
on the potassium content, the materials Tc varies from 
7 to 18K.
Applications 
 Superconducting levitation: 
Maglev Trains (On Track with superconductivity)
Medical Diagnosis
Power Cables 
Superconducting wires carry up to five times the 
current carried by copper wires with the same 
cross section. 
Superconducting cables are cooled to remove 
the resistance to the flow of electricity, cutting 
down on the losses that typically occur during 
transmission. 
Communications 
HTS filters will enhance signal-to noise 
ratios in cellular communications systems 
leading to reliable communication services 
with fewer spaced cell towers.
Limitations 
 For presently known practical superconductors, the temperature is much 
below 77 Kelvin, the temperature of liquid nitrogen. Keeping them below 
that temperature involves a lot of expensive cryogenic technology. 
 Scientists are working on designing superconductors that can operate at 
room temperature. 
 Type II superconductors in particular are extremely brittle, limiting their 
range of practical applications. Although Type I superconductors generally 
are not as brittle. 
 The other major limitation of superconductors is their sensitivity to 
changing magnetic fields, meaning that AC current will not work effectively 
with superconductors.
Superconductivity

Superconductivity

  • 1.
  • 2.
    What is superconductivity?  Superconductivity is a phenomenon of exactly zero electrical resistance and expulsion of magnetic fields occurring in certain materials when cooled below a characteristic critical temperature. It was discovered by Dutch physicist Heike Kamerlingh Onnes on April 8,1911 in Leiden.
  • 4.
    Meissner Effect When a material makes the transition from the normal to superconducting state, it actively excludes magnetic fields from its interior.  It was discovered by German physicists Walther Meissner and Robert Ochsenfeld .
  • 5.
    A magnet levitatingabove a superconductor cooled by liquid nitrogen.
  • 6.
    The BCS Theory Electron-Lattice Interactions  A passing electron attracts the lattice, causing a slight ripple toward its path.  Another electron passing in the opposite direction is attracted to that displacement. BCS theory suggests that superconductors have zero electrical resistance below critical temperatures because at such temperatures the electrons pass unhindered through the crystal lattice and therefore lose energy. The theory states that the supercurrent in a superconductor is carried by many million bound electron pairs, called Cooper Pairs.
  • 9.
    High TC Superconductors. In a super conductor if the transition temperature is high ie.,greater than 20K, then it is called as high-temperature super conductors. In 1986, Muller and Bednorz discovered high tempertaure super conductor in Ceramics.
  • 10.
  • 11.
    Metal and Alloys • Some metals become superconductors at extremely low temperatures • Some of these include mercury, lead, tin, aluminum, lead, niobium, cadmium, gallium, zinc, and zirconium • Unfortunately, the critical temperatures are too low for practical application • Metal alloys like Nb-Ti, and Nb-Zr are usually Type II superconductors • Metal Alloys have higher critical temperatures and magnetic fluxes than pure metals. • As a consequence of their properties, they are more useful for practical applications than pure metals
  • 12.
    Iron Based Superconductors  Iron-based superconductors contain layers of iron and a pnictide such as arsenic or phosphorus .This is currently the family with the second highest critical temperature, behind the cuprates.  The crystalline material, known chemically as LaOFeAs, stacks iron and arsenic layers, where the electrons flow, between planes of lanthanum and oxygen. Crystal structure of LaFeAsO, one of the ferropnictide compounds
  • 13.
    Cuprates  Cupratesuperconductors are generally considered to be two-dimensional materials with their superconducting properties determined by electrons moving within weakly coupled copper-oxide (CuO2) layers. Neighboring layers containing ions such as lanthanum, barium, strontium, or other atoms act to stabilize the structure and dope electrons or holes onto the copper-oxide layers.  Cuprates Superconducting materials. HgBa2Ca2Cu3Ox (critical temperature to 133 K) Bi2Sr2Ca2Cu3O10(BSCCO) (critical temperature to 110 K) YBa2Cu3O7 (YBCO) (critical temperature to 92 K.)
  • 14.
    Organic Superconductors Superconductivity in low dimensional organic materials was first suggested by Little in 1965.  C60 by itself is a very poor conductor. By doping this compound with electron donors such as alkaline metals, which provide the conduction electrons, superconductivity can be induced. K3C60 has a Tc of 19 K  Other superconductors in which conductivity arises in the pi-electrons of unsaturated bonds have also been discovered.  Scientists have created the first organic superconductor based on a simple aromatic molecule, picene (C22H14), doped with an alkali metal.Depending on the potassium content, the materials Tc varies from 7 to 18K.
  • 15.
    Applications  Superconductinglevitation: Maglev Trains (On Track with superconductivity)
  • 16.
  • 17.
    Power Cables Superconductingwires carry up to five times the current carried by copper wires with the same cross section. Superconducting cables are cooled to remove the resistance to the flow of electricity, cutting down on the losses that typically occur during transmission. Communications HTS filters will enhance signal-to noise ratios in cellular communications systems leading to reliable communication services with fewer spaced cell towers.
  • 18.
    Limitations  Forpresently known practical superconductors, the temperature is much below 77 Kelvin, the temperature of liquid nitrogen. Keeping them below that temperature involves a lot of expensive cryogenic technology.  Scientists are working on designing superconductors that can operate at room temperature.  Type II superconductors in particular are extremely brittle, limiting their range of practical applications. Although Type I superconductors generally are not as brittle.  The other major limitation of superconductors is their sensitivity to changing magnetic fields, meaning that AC current will not work effectively with superconductors.