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International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 
E-ISSN: 2321-9637 
Performance characteristics Analysis of Diesel Engine 
Using Biodiesel derived from Cashew Nut Shell Liquid 
125 
(CNSL) As a Alternative Fuel 
Mr. Rajeesh.S1, Dr. S V Prakash2 & Mr. Girish V Kulkarni3 
Department of Mechanical Engineering, M S Ramaiah Institute of Technology, Bangalore 1, 2, 3 
Email: s.rajeesh@gmail.com 1, yagprash@hotmail.com 2, gvkulkarni@gmail.com 3 
Abstract: The world is confronted with the twin crises of fossil fuel depletion and environmental degradation. The 
indiscriminate extraction and consumption of fossil fuels have led to a reduction in petroleum reserves. Petroleum 
based fuels are obtained from limited reserves. These finite reserves are highly concentrated in certain regions of the 
world. Therefore, those countries not having these resources are facing a foreign exchange crisis, mainly due to the 
import of crude petroleum oil. Hence it is necessary to look for alternative fuels, which can be produced from 
resources available within the country. Although vegetative oils can be used as fuel for diesel engines, their high 
viscosities, low volatilities and poor cold flow properties have prompted investigations of its various derivatives. 
The present paper investigates the use of the Cashew Nut Shell Liquid (CNSL) Biodiesel As a Alternative 
Fuel through experimental analysis of engine performance. All these are carried out on a of a compression ignition 
engine fuelled with various blends of biodiesel. The research by experimentation of these biodiesel fuels in an IC 
Engine offers a range of edible and non edible oils apart from methyl esters as substitute for the diesel fuel and 
promotes future possibilities of Biodiesel as an alternative fuels for transportation sector. In this study, biodiesel 
derived from CNSL blended with diesel has been chosen for testing and analysis. Several engine performance tests 
have been carried out and initial results have been tabulated. The experiments disclose that the use of blends of 
CNSL and diesel as a fuel reduces the overall diesel consumption and hence dependency on diesel. Among the 
blends tested against diesel (B10, B15, B20),the blend B15( 15%CNSL and 85% Diesel) proved to be superior, 
displaying better engine performance characteristics, in comparison with diesel and the other blends. 
Keyword: Cashew Nut Shell Liquid (CNSL), blend of ethanol with biofuels, Engine Performance 
Characteristics 
. 
1. INTRODUCTION TO BIODIESEL 
The predicted shortage of fossil fuel has encouraged 
the search for substitutes for petroleum derivatives. 
This search has resulted in an alternative fuel called 
"biodiesel". Bio-diesel is an alternative to petroleum-based 
fuels derived from vegetable oils, animal fats, 
and used waste cooking oil including triglycerides. 
Since the petroleum crises in 1970s, the rapidly 
increasing prices and uncertainties concerning 
petroleum availability, a growing concern of the 
environment and the effect of greenhouse gases 
during the last decades, has revived more and more 
interests in the use of biodiesel as a substitute of 
fossil fuels [1]. Bio-diesel production is a very 
modern and technological area for researchers due to 
the relevance that it is winning everyday because of 
the increase in the petroleum prices and the 
environmental advantages biodiesel offers over 
diesel. Accordingly, many researchers around the 
world have dealt with these issues and in many cases 
devised unique solutions. Countless legislative and 
regulatory efforts around the world have helped pave 
the way toward the widespread application of the 
concept [2]. 
2. BIODIESEL 
The major components of vegetable oils and 
animal fats are triacylglycerols (TAG; often also 
called triglycerides). Chemically, TAG are esters of 
fatty acids (FA) with glycerol (1,2,3-propanetriol; 
glycerol is often also called glycerine). The TAG of 
vegetable oils and animal fats typically contain 
several different FA. Thus, different FA can be 
attached to one glycerol backbone. The different FA 
that are contained in the TAG comprise the FA 
profile (or FA composition) of the vegetable oil or 
animal fat. Because different FA have different 
physical and chemical properties, the FA profile is 
probably the most important parameter influencing
International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 
E-ISSN: 2321-9637 
126 
the corresponding properties of a vegetable oil or 
animal fat. [2]. 
3. HISTORY OF BIODIESEL 
The use of vegetable oils as alternative fuels 
has been around for one hundred years when the 
inventor of the diesel engine Rudolph Diesel first 
tested peanut oil, in his compression-ignition engine. 
In the 1930s and 1940s vegetable oils were used as 
diesel fuels from time to time, but usually only in 
emergency situations. In 1940 first trials with 
vegetable oil methyl and ethyl esters were carried out 
in France and, at the same time, scientists in Belgium 
were using palm oil ethyl ester as a fuel for buses. 
Not much was done until the late 1970s and early 
1980s, when concerns about high petroleum prices 
motivated extensive experimentation with fats and 
oils as alternative fuels. Bio-diesel (mono alkyl 
esters) started to be widely produced in the early 
1990s and since then production has been increasing 
steadily. In the European Union (EU), bio-diesel 
began to be promoted in the 1980s as a means to 
prevent the decline of rural areas while 3 responding 
to increasing levels of energy demand. However, it 
only began to be widely developed in the second half 
of the 1990s [1]. 
Objectives: 
The objectives of the study are: 
 To evaluate the performance analysis of 
compression ignition engine fuelled with 
different blends of biodiesel extracted from 
methyl esters. 
 To compare optimized biodiesel and diesel 
performance and emission characteristics. 
 Use of the Cashew Nut Shell Liquid (CNSL) 
Biodiesel and Cashew Nut Shell Liquid 
(CNSL) blended with ethanol As a 
Alternative Fuel for transportation sector. 
4. PROPERTIES OF THE SAMPLES TESTED 
Table 1 Properties of Samples Tested 
Review of Related Literature: 
A lot of work has been done on Performance 
Analysis of Diesel Engine Using Cashew Nut Shell 
Liquid (CNSL) Biodiesel. Limited amount of work is 
done on the Performance Analysis of Diesel Engine 
Using Cashew Nut Shell Liquid (CNSL) blended 
with ethanol as a Alternative Fuel. 
In India, the high content of glycerin and 
free fatty acid in CSNL prevents their use in biodiesel 
preparation. But through fuel production process 
optimization (by blending of ethanol), CSNL oils are 
affordable for biodiesel production. Cost associated 
with biodiesel is reduced due to the low cost of the 
CSNL oils (approximately Rs 25 per liter). 
Research Methodology: 
To meet the main aim and the specific 
objectives of the study a quantitative research 
methodology study along with a comprehensive 
literature review were employed. A lot of work has 
been done on transesterification of edible  Non 
edible oils. Limited amount of work is done on 
Cashew Nut Shell Liquid (CNSL). Limited amount 
of work has been done on the engine performance 
analysis fuelled with biodiesel derived from CNSL 
and CNSL mixed with ethonal. 
5. BIODIESEL PREPRATION 
METHODOLOGY 
Biodiesel preparation 
· Cashew Nut Shell Liquid (CNSL) was blended 
with diesel in three different proportions creating 
three different blends of one litre each. 
· All blends were made using a magnetic stirrer in 
which the different percentages by volume of 
CNSL and diesel were stirred continuously for 7-8 
hours and then allowed to stand for at least 3-4 
hours to ensure no separation of the constituents 
occurred. 
· Blend B10 was obtained by mixing 10% by 
volume of CNSL (100 ml) with 90% by volume 
of diesel (900ml), Blend B15 was obtained by 
mixing 15% by volume of CNSL (150 ml) with 
85% by volume of diesel (850 ml), Blend B20 
was obtained by mixing 20% by volume of CNSL 
(200 ml) with 80% by volume of diesel (800 ml), 
BlendRatio 
Specific 
Gravity 
Dynamic 
ViscosityCen 
tipoises 
Flash pointoC 
Fire PointoC 
pH 
Calorific 
Value KJ/Kg 
Diesel 0.85 4.450 96 117 8-9 450 
5% 0.90 
0 
4.560 120 135 6.6 436 
70 
10% 0.90 
8 
5.619 118 128 6.6 420 
58 
15% 0.91 
2 
5.643 105 122 6.5 420 
00 
20% 0.92 
0 
6.550 103 118 6.4 439 
76 
25% 0.93 
6 
7.786 101 113 6.4 428 
24 
100% 1.02 
4 
116.6 
6 
- - 5.6 379 
69
International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 
E-ISSN: 2321-9637 
127 
Blends BDEB5 and BDEB10 were obtained by 
mixing 5% (50 ml) and 10% (100 ml) by volume 
of ethanol, with 95% (950 ml) and 90% (900 ml) 
by volume of blend B15 respectively. 
6. ENGINE SPECIFICATIONS 
MAKE: KIRLOSKAR 
CAPACITY: 3.7kw 
COMPRESSION RATIO: 16.5:1 
CYLINDER BORE: 80mm 
STROKE: 110mm 
CYLINDER CAPACITY: 553cc 
COOLING: water cooled 
LOADING: Eddy Current Dynamometer 
MAKE: Power MAG 
SPEED: 1500RPM 
EXCITATION VOLTAGE: 80V 
7. RESULT ANALYSIS AND DISCUSSION 
On the basis of experiments carried out so far tables 
have been made for the performance characteristics 
for each of the blends tested on the diesel engine. 
Using these tables graphs have been plotted to give a 
better idea of each blend is in comparison to 
conventional diesel. The engine is run at a speed of 
1500RPM and is loaded using an Eddy Current 
Dynamometer. 
8. ENGINE PERFORMANCE TEST 
PERFORMANCE TABLES: 
The time required to consume 10cc of the fuel for 
different blends at different loads is measured along 
with the exhaust gas temperature and air flow rate. 
Table 2. Performance Characteristics – DIESEL 
Sl No Torque 
(N-M) 
Time To 
Consume 
10 CC 
(Secs) 
Exhaust Gas 
Temperature 
(0C) 
Table 3. Performance Characteristics – B10 
Table 4 Performance Characteristics – B15 
Table 5 Performance Characteristics – B20 
Air Flow 
Rate 
(m3/Hr) 
1 0 95.28 174 14.1 
2 5 70.34 238 13.8 
3 10 54.35 314 13.8 
4 15 43.44 394 13.8 
5 20 34.25 499 13.8 
Sl No Torque 
(N-M) 
Time To 
Consume 10 
CC (Secs) 
Exhaust Gas 
Temperature 
(0C) 
Air Flow 
Rate 
(m3/Hr) 
1 0 102.41 174 14.1 
2 5 73.81 232 13.8 
3 10 55.16 305 13.8 
4 15 42.90 395 13.8 
5 20 35.94 498 13.4 
Sl 
No 
Torque 
(N-M) 
Time To 
Consume 10 
CC (Secs) 
Exhaust Gas 
Temperature 
(0C) 
Air Flow 
Rate 
(m3/Hr) 
1 0 98.41 178 13.8 
2 5 74.03 232 13.8 
3 10 55.25 310 13.8 
4 15 44.50 379 13.8 
5 20 35.01 490 13.4 
Sl No Torque 
(N-M) 
Time To 
Consume 
10 CC 
(Secs) 
Exhaust Gas 
Temperature 
(0C) 
Air 
Flow 
Rate 
(m3/Hr) 
1 0 93.87 172 14.1 
2 5 70.06 238 13.8 
3 10 55.41 304 13.8 
4 15 43.94 391 13.8 
5 20 34.82 519 13.4
International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 
E-ISSN: 2321-9637 
128 
Table 6 Performance Characteristics – BDEB5 
Table 7 Performance Characteristics – BDEB10 
9. PERFORMANCE GRAPHS 
On the basis of experiments, calculated the 
performance parameters of the engine with various 
blends of the fuel and compare it with that of 
conventional diesel. The following parameters have 
been taken, such as Brake thermal efficiency, 
Indicated thermal efficiency, Brake specific fuel 
consumption, indicated specific fuel consumption 
and Mechanical Efficicncy. The following blends 
B10, B15, B20, BDEB5, BDEB10 are used for 
engine performance characterization. Along the X-axis 
we have the load which is varied using an Eddy 
current dynamometer in steps of 5 N-m, from 0N-m 
to 20N-m.Along the Y-Axis we have indicated and 
brake thermal efficiency, indicated and brake specific 
fuel consumption (measured in Kg/KW-hr) and 
mechanical efficiency. The Kirloskar diesel engine is 
run at a constant speed of 1500RPM. 
Brake Thermal Efficiency: all blends vs diesel 
FIGURE 1 Brake Thermal Efficiency: all blends vs 
diesel 
Indicated Thermal Efficiency: all blends vs diesel 
FIGURE 2 Indicated Thermal Efficiency: all blends 
vs diesel 
INFERENCE (Brake And Indicated Thermal 
Efficiency) 
The variation of Brake and Indicated thermal 
efficiencies with respect to load for different blends 
of CNSL oil are as shown in the graphs presented 
above. In all cases, both brake and indicated thermal 
efficiencies have the tendency to increase with 
increase in applied load. This is due to the reduction 
in heat loss and increase in power developed with 
increase in load. The thermal efficiencies of all 
blends of CNSL oil is lower than that of neat diesel. 
This is due to poor mixture formation as a result of 
low volatility, higher viscosity and higher density of 
CNSL oil. The Brake and Indicated thermal 
Sl No Torque 
(N-M) 
Time To 
Consume 
10 CC 
(Secs) 
Exhaust Gas 
Temperature 
(0C) 
Air 
Flow 
Rate 
(m3/Hr) 
1 0 78 208 14.1 
2 5 62.57 264 14.1 
3 10 52.22 335 13.8 
4 15 41.66 408 13.4 
5 20 33.56 506 13.4 
Sl No Torque 
(N-M) 
Time To 
Consume 
10 CC 
(Secs) 
Exhaust Gas 
Temperature 
(0C) 
Air 
Flow 
Rate 
(m3/Hr) 
1 0 92.81 169 14.1 
2 5 70.59 236 13.8 
3 10 51.9 325 13.4 
4 15 41.85 408 13.1 
5 20 31 538 13.1
International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 
E-ISSN: 2321-9637 
129 
efficiencies of B10 blend is higher compared to other 
blends namely B15, B20, for the reason that more the 
blend results in higher viscosity of fuel, poor 
atomization and hence poor combustion. The two 
BDEB (5%  10%) blends are seen to have the 
lowest thermal efficiencies (both brake and 
indicated), blend BDEB10 being lower of the two. 
This is because the addition of ethanol to the B15 
blend reduces the thermal efficiency of the blend due 
to the presence of oxygen and low heat content of 
ethanol. 
SPECIFIC FUEL CONSUMPTION 
Brake Sp Fuel Consumption: all blends vs diesel 
FIGURE 3 Brake Sp Fuel Consumption: all blends vs 
diesel 
Indicated Sp Fuel Consumption: all blends vs diesel 
FIGURE 3 Brake Sp Fuel Consumption: all blends vs 
diesel 
INFERENCE (Brake and Indicated specific fuel 
consumption) 
The variations of Brake and Indicated specific 
fuel consumption with load for different fuels is as 
shown in the graphs presented earlier. The specific 
fuel consumption of CNSL oil is higher than that of 
diesel for all loads. This is caused due to the effect of 
higher viscosity and poor mixture formation of CNSL 
oil. For all the blends tested, it is seen that specific 
fuel consumptions (both brake and indicated) are 
found to decrease with an increase in the load. This is 
because more blended fuel is used to produce same 
power as compared to diesel. Hence the mixture 
formation is very poor if we increase the amount of 
CNSL oil with diesel. However from the graph, it is 
seen that the blend B20 blend gives lesser brake and 
indicated fuel consumptions when compared to all 
other blends. This may have resulted due to failure to 
run the engine with the B20 blend for a sufficient 
period of time before loading the engine.With 
increase in blend percentage, the calorific value of 
fuel decreases. Hence, the specific fuel consumption 
of the higher percentage of blends must increase 
when compared to that of diesel.It is also clearly seen 
from the graphs that the two BDEB blends (5%  
10%) offer the highest specific fuel consumption 
values, BDEB 10 being the higher of the two. The 
reason being, the addition of ethanol to the blend 
increases the oxygen content resulting in faster
International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 
E-ISSN: 2321-9637 
130 
combustion and hence, higher rate of fuel 
consumption. 
MECHANICAL EFFICIENCY 
Mechanical Efficiency: all blends vs diesel 
10. CONCLUSION 
Several engine performance tests have been 
carried out on a variety of blends of CNSL  CNSL 
with ethanol. The conclusion at this stage of research 
can be summarized as under: 
The use of blends of CNSL and diesel as a fuel 
reduces the overall diesel consumption and hence 
dependency on diesel. Among the blends tested 
against diesel (B10, B15, B20), the blend 
B15( 15%CNSL and 85% Diesel) proved to be 
superior, displaying better engine performance 
characteristics, in comparison with diesel and the 
other blends (Figures 1, 2, 3, 4, 5). Testing of 25% 
CNSL and above, with diesel cannot be carried out, 
due to “Engine Cranking”, resulting from the high 
viscosity of the blend. Hence pre-heating may be 
required to counter this problem. Addition of Ethanol 
to any fuel helps in completing the fuel combustion 
process in the engine. Of the two biodiesel ethanol 
blends (BDEB5 and BDEB10) tested, BDEB 5 
proved to be the better blend displaying better engine 
performance (Figures 4.1 – 4.10) at the maximum 
tested load. However, these two blends have 
displayed inferior engine performance when 
compared against the original B15 blend used. 
Future progress in the current research work can 
be elaborated as under: 
The above tests can be conducted for different 
biodiesels derived from different species. Fuel 
optimization by different method of 
transesterfication. Long hour durability tests can be 
conducted on the diesel engine. Further studies, on 
future bio diesel-diesel blends as fuels, may be 
carried out in order to reduce the viscosity as well as 
improve the engine performance and exhaust 
characteristics by changing different parameters. The 
computational fluid dynamics (CFD) simulations can 
be carried out to examine the fluid flow, air-fuel 
mixing formation; combustion process, carbon 
monoxide emission distribution as well as NO 
emission formation occurred inside engine cylinder 
by burning of these biodiesel blending derived from 
biofuels. 
REFERENCES 
[1] Mustafa Balat , Havva Balat (2008) “A critical 
review of bio-diesel as a vehicular fuel” Energy 
Conversion and Management 49, Page 2727– 
2741. 
[2] Gerhard Knothe, Jon Van Gerpen, Jürgen Krahl 
(2005) “The Biodiesel Handbook” AOCS Press 
Champaign, Illinois. 
[3] Report of the committee on development of bio-fuel, 
(2003) Planning Commission India. 
[4] Fangrui Maa, Milford A. Hannab, (1999) 
“Biodiesel production: a review” Bioresource 
Technology 70, Page 1-15. 
[5] Ulf Schuchardta, Ricardo Serchelia, Rogério 
Matheus Vargas (1998) “Transesterification of 
Vegetable Oils: a Review” , J. Braz. Chem. Soc., 
Vol. 9, No. 1, Page 199-210. 
[6] S.P. Singh, Dipti Singh, (2010) “Biodiesel 
production through the use of different sources 
and characterization of oils and their esters as 
the substitute of diesel: A review Renewable and 
Sustainable Energy Reviews 
[7] M.Mathiyazhagan, A.Ganapathi, B. Jaganath, N. 
Renganayaki, And N. Sasireka (2011) 
“Production of biodiesel from non-edible plant 
oils having high FFA content”, International 
Journal of Chemical and Environmental 
Engineering, Vol. 2, No.2. 
[8] M. Canakci, J. Van Gerpen (2001) “Biodiesel 
production from oils and fats with high free fatty 
acids” American Society of Agricultural 
Engineers ISSN, Vol. 44(6), Page 1429–1436. 
[9] Gerhard Knothe (2005) “Dependence of biodiesel 
fuel properties on the structure of fatty acid alkyl 
esters” Fuel Processing Technology 86, Page 
1059– 1070. 
[10] P.K.Gupta, Rakesh Kumar, B.S.Panesar, and 
V.K.Thapar (2007) “Parametric Studies on Bio-diesel 
prepared from Rice Bran Oil” Agricultural 
Engineering International: the CIGR Ejournal. 
Manuscript EE06 007, Vol. IX.
International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 
E-ISSN: 2321-9637 
131 
[11] Janahiraman Krishnakumar, V. S. Karuppannan 
Venkatachalapathy, Sellappan Elancheliyan 
(2008) “Technical aspects of biodiesel production 
from vegetable oils”, Thermal Science, Vol. 12 
No. 2, Page 159-169. 
[12]Young-Cheol Bak, Joo-Hong Choi, Sung-Bae 
Kim, Dong-Weon Kang (1996) “Production of 
bio-diesel fuels by transesterification of rice bran 
oil”, Korean J. of Chem. Eng., Vol.13(3), Page 
242-245. 
[13] Lin Lin , Dong Ying, Sumpun Chaitep , 
Saritporn Vittayapadung (2008) “Biodiesel 
production from crude rice bran oil and properties 
as fuel” Applied Energy, Page 681–688. 
[14] Rambabu Kantipudi, Appa Rao.B.V, Hari 
Babu.N, Satyanarayana.CH (2010) “ Studies on 
Di diesel engine fueled with rice bran methyl ester 
injection and ethanol carburetion”, International 
Journal Of Applied Engineering Research, 
Dindigul Volume 1 No1, Page 206-221.

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Analysis of diesel engine performance using Cashew Nut Shell Liquid biodiesel blends

  • 1. International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 E-ISSN: 2321-9637 Performance characteristics Analysis of Diesel Engine Using Biodiesel derived from Cashew Nut Shell Liquid 125 (CNSL) As a Alternative Fuel Mr. Rajeesh.S1, Dr. S V Prakash2 & Mr. Girish V Kulkarni3 Department of Mechanical Engineering, M S Ramaiah Institute of Technology, Bangalore 1, 2, 3 Email: s.rajeesh@gmail.com 1, yagprash@hotmail.com 2, gvkulkarni@gmail.com 3 Abstract: The world is confronted with the twin crises of fossil fuel depletion and environmental degradation. The indiscriminate extraction and consumption of fossil fuels have led to a reduction in petroleum reserves. Petroleum based fuels are obtained from limited reserves. These finite reserves are highly concentrated in certain regions of the world. Therefore, those countries not having these resources are facing a foreign exchange crisis, mainly due to the import of crude petroleum oil. Hence it is necessary to look for alternative fuels, which can be produced from resources available within the country. Although vegetative oils can be used as fuel for diesel engines, their high viscosities, low volatilities and poor cold flow properties have prompted investigations of its various derivatives. The present paper investigates the use of the Cashew Nut Shell Liquid (CNSL) Biodiesel As a Alternative Fuel through experimental analysis of engine performance. All these are carried out on a of a compression ignition engine fuelled with various blends of biodiesel. The research by experimentation of these biodiesel fuels in an IC Engine offers a range of edible and non edible oils apart from methyl esters as substitute for the diesel fuel and promotes future possibilities of Biodiesel as an alternative fuels for transportation sector. In this study, biodiesel derived from CNSL blended with diesel has been chosen for testing and analysis. Several engine performance tests have been carried out and initial results have been tabulated. The experiments disclose that the use of blends of CNSL and diesel as a fuel reduces the overall diesel consumption and hence dependency on diesel. Among the blends tested against diesel (B10, B15, B20),the blend B15( 15%CNSL and 85% Diesel) proved to be superior, displaying better engine performance characteristics, in comparison with diesel and the other blends. Keyword: Cashew Nut Shell Liquid (CNSL), blend of ethanol with biofuels, Engine Performance Characteristics . 1. INTRODUCTION TO BIODIESEL The predicted shortage of fossil fuel has encouraged the search for substitutes for petroleum derivatives. This search has resulted in an alternative fuel called "biodiesel". Bio-diesel is an alternative to petroleum-based fuels derived from vegetable oils, animal fats, and used waste cooking oil including triglycerides. Since the petroleum crises in 1970s, the rapidly increasing prices and uncertainties concerning petroleum availability, a growing concern of the environment and the effect of greenhouse gases during the last decades, has revived more and more interests in the use of biodiesel as a substitute of fossil fuels [1]. Bio-diesel production is a very modern and technological area for researchers due to the relevance that it is winning everyday because of the increase in the petroleum prices and the environmental advantages biodiesel offers over diesel. Accordingly, many researchers around the world have dealt with these issues and in many cases devised unique solutions. Countless legislative and regulatory efforts around the world have helped pave the way toward the widespread application of the concept [2]. 2. BIODIESEL The major components of vegetable oils and animal fats are triacylglycerols (TAG; often also called triglycerides). Chemically, TAG are esters of fatty acids (FA) with glycerol (1,2,3-propanetriol; glycerol is often also called glycerine). The TAG of vegetable oils and animal fats typically contain several different FA. Thus, different FA can be attached to one glycerol backbone. The different FA that are contained in the TAG comprise the FA profile (or FA composition) of the vegetable oil or animal fat. Because different FA have different physical and chemical properties, the FA profile is probably the most important parameter influencing
  • 2. International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 E-ISSN: 2321-9637 126 the corresponding properties of a vegetable oil or animal fat. [2]. 3. HISTORY OF BIODIESEL The use of vegetable oils as alternative fuels has been around for one hundred years when the inventor of the diesel engine Rudolph Diesel first tested peanut oil, in his compression-ignition engine. In the 1930s and 1940s vegetable oils were used as diesel fuels from time to time, but usually only in emergency situations. In 1940 first trials with vegetable oil methyl and ethyl esters were carried out in France and, at the same time, scientists in Belgium were using palm oil ethyl ester as a fuel for buses. Not much was done until the late 1970s and early 1980s, when concerns about high petroleum prices motivated extensive experimentation with fats and oils as alternative fuels. Bio-diesel (mono alkyl esters) started to be widely produced in the early 1990s and since then production has been increasing steadily. In the European Union (EU), bio-diesel began to be promoted in the 1980s as a means to prevent the decline of rural areas while 3 responding to increasing levels of energy demand. However, it only began to be widely developed in the second half of the 1990s [1]. Objectives: The objectives of the study are: To evaluate the performance analysis of compression ignition engine fuelled with different blends of biodiesel extracted from methyl esters. To compare optimized biodiesel and diesel performance and emission characteristics. Use of the Cashew Nut Shell Liquid (CNSL) Biodiesel and Cashew Nut Shell Liquid (CNSL) blended with ethanol As a Alternative Fuel for transportation sector. 4. PROPERTIES OF THE SAMPLES TESTED Table 1 Properties of Samples Tested Review of Related Literature: A lot of work has been done on Performance Analysis of Diesel Engine Using Cashew Nut Shell Liquid (CNSL) Biodiesel. Limited amount of work is done on the Performance Analysis of Diesel Engine Using Cashew Nut Shell Liquid (CNSL) blended with ethanol as a Alternative Fuel. In India, the high content of glycerin and free fatty acid in CSNL prevents their use in biodiesel preparation. But through fuel production process optimization (by blending of ethanol), CSNL oils are affordable for biodiesel production. Cost associated with biodiesel is reduced due to the low cost of the CSNL oils (approximately Rs 25 per liter). Research Methodology: To meet the main aim and the specific objectives of the study a quantitative research methodology study along with a comprehensive literature review were employed. A lot of work has been done on transesterification of edible Non edible oils. Limited amount of work is done on Cashew Nut Shell Liquid (CNSL). Limited amount of work has been done on the engine performance analysis fuelled with biodiesel derived from CNSL and CNSL mixed with ethonal. 5. BIODIESEL PREPRATION METHODOLOGY Biodiesel preparation · Cashew Nut Shell Liquid (CNSL) was blended with diesel in three different proportions creating three different blends of one litre each. · All blends were made using a magnetic stirrer in which the different percentages by volume of CNSL and diesel were stirred continuously for 7-8 hours and then allowed to stand for at least 3-4 hours to ensure no separation of the constituents occurred. · Blend B10 was obtained by mixing 10% by volume of CNSL (100 ml) with 90% by volume of diesel (900ml), Blend B15 was obtained by mixing 15% by volume of CNSL (150 ml) with 85% by volume of diesel (850 ml), Blend B20 was obtained by mixing 20% by volume of CNSL (200 ml) with 80% by volume of diesel (800 ml), BlendRatio Specific Gravity Dynamic ViscosityCen tipoises Flash pointoC Fire PointoC pH Calorific Value KJ/Kg Diesel 0.85 4.450 96 117 8-9 450 5% 0.90 0 4.560 120 135 6.6 436 70 10% 0.90 8 5.619 118 128 6.6 420 58 15% 0.91 2 5.643 105 122 6.5 420 00 20% 0.92 0 6.550 103 118 6.4 439 76 25% 0.93 6 7.786 101 113 6.4 428 24 100% 1.02 4 116.6 6 - - 5.6 379 69
  • 3. International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 E-ISSN: 2321-9637 127 Blends BDEB5 and BDEB10 were obtained by mixing 5% (50 ml) and 10% (100 ml) by volume of ethanol, with 95% (950 ml) and 90% (900 ml) by volume of blend B15 respectively. 6. ENGINE SPECIFICATIONS MAKE: KIRLOSKAR CAPACITY: 3.7kw COMPRESSION RATIO: 16.5:1 CYLINDER BORE: 80mm STROKE: 110mm CYLINDER CAPACITY: 553cc COOLING: water cooled LOADING: Eddy Current Dynamometer MAKE: Power MAG SPEED: 1500RPM EXCITATION VOLTAGE: 80V 7. RESULT ANALYSIS AND DISCUSSION On the basis of experiments carried out so far tables have been made for the performance characteristics for each of the blends tested on the diesel engine. Using these tables graphs have been plotted to give a better idea of each blend is in comparison to conventional diesel. The engine is run at a speed of 1500RPM and is loaded using an Eddy Current Dynamometer. 8. ENGINE PERFORMANCE TEST PERFORMANCE TABLES: The time required to consume 10cc of the fuel for different blends at different loads is measured along with the exhaust gas temperature and air flow rate. Table 2. Performance Characteristics – DIESEL Sl No Torque (N-M) Time To Consume 10 CC (Secs) Exhaust Gas Temperature (0C) Table 3. Performance Characteristics – B10 Table 4 Performance Characteristics – B15 Table 5 Performance Characteristics – B20 Air Flow Rate (m3/Hr) 1 0 95.28 174 14.1 2 5 70.34 238 13.8 3 10 54.35 314 13.8 4 15 43.44 394 13.8 5 20 34.25 499 13.8 Sl No Torque (N-M) Time To Consume 10 CC (Secs) Exhaust Gas Temperature (0C) Air Flow Rate (m3/Hr) 1 0 102.41 174 14.1 2 5 73.81 232 13.8 3 10 55.16 305 13.8 4 15 42.90 395 13.8 5 20 35.94 498 13.4 Sl No Torque (N-M) Time To Consume 10 CC (Secs) Exhaust Gas Temperature (0C) Air Flow Rate (m3/Hr) 1 0 98.41 178 13.8 2 5 74.03 232 13.8 3 10 55.25 310 13.8 4 15 44.50 379 13.8 5 20 35.01 490 13.4 Sl No Torque (N-M) Time To Consume 10 CC (Secs) Exhaust Gas Temperature (0C) Air Flow Rate (m3/Hr) 1 0 93.87 172 14.1 2 5 70.06 238 13.8 3 10 55.41 304 13.8 4 15 43.94 391 13.8 5 20 34.82 519 13.4
  • 4. International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 E-ISSN: 2321-9637 128 Table 6 Performance Characteristics – BDEB5 Table 7 Performance Characteristics – BDEB10 9. PERFORMANCE GRAPHS On the basis of experiments, calculated the performance parameters of the engine with various blends of the fuel and compare it with that of conventional diesel. The following parameters have been taken, such as Brake thermal efficiency, Indicated thermal efficiency, Brake specific fuel consumption, indicated specific fuel consumption and Mechanical Efficicncy. The following blends B10, B15, B20, BDEB5, BDEB10 are used for engine performance characterization. Along the X-axis we have the load which is varied using an Eddy current dynamometer in steps of 5 N-m, from 0N-m to 20N-m.Along the Y-Axis we have indicated and brake thermal efficiency, indicated and brake specific fuel consumption (measured in Kg/KW-hr) and mechanical efficiency. The Kirloskar diesel engine is run at a constant speed of 1500RPM. Brake Thermal Efficiency: all blends vs diesel FIGURE 1 Brake Thermal Efficiency: all blends vs diesel Indicated Thermal Efficiency: all blends vs diesel FIGURE 2 Indicated Thermal Efficiency: all blends vs diesel INFERENCE (Brake And Indicated Thermal Efficiency) The variation of Brake and Indicated thermal efficiencies with respect to load for different blends of CNSL oil are as shown in the graphs presented above. In all cases, both brake and indicated thermal efficiencies have the tendency to increase with increase in applied load. This is due to the reduction in heat loss and increase in power developed with increase in load. The thermal efficiencies of all blends of CNSL oil is lower than that of neat diesel. This is due to poor mixture formation as a result of low volatility, higher viscosity and higher density of CNSL oil. The Brake and Indicated thermal Sl No Torque (N-M) Time To Consume 10 CC (Secs) Exhaust Gas Temperature (0C) Air Flow Rate (m3/Hr) 1 0 78 208 14.1 2 5 62.57 264 14.1 3 10 52.22 335 13.8 4 15 41.66 408 13.4 5 20 33.56 506 13.4 Sl No Torque (N-M) Time To Consume 10 CC (Secs) Exhaust Gas Temperature (0C) Air Flow Rate (m3/Hr) 1 0 92.81 169 14.1 2 5 70.59 236 13.8 3 10 51.9 325 13.4 4 15 41.85 408 13.1 5 20 31 538 13.1
  • 5. International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 E-ISSN: 2321-9637 129 efficiencies of B10 blend is higher compared to other blends namely B15, B20, for the reason that more the blend results in higher viscosity of fuel, poor atomization and hence poor combustion. The two BDEB (5% 10%) blends are seen to have the lowest thermal efficiencies (both brake and indicated), blend BDEB10 being lower of the two. This is because the addition of ethanol to the B15 blend reduces the thermal efficiency of the blend due to the presence of oxygen and low heat content of ethanol. SPECIFIC FUEL CONSUMPTION Brake Sp Fuel Consumption: all blends vs diesel FIGURE 3 Brake Sp Fuel Consumption: all blends vs diesel Indicated Sp Fuel Consumption: all blends vs diesel FIGURE 3 Brake Sp Fuel Consumption: all blends vs diesel INFERENCE (Brake and Indicated specific fuel consumption) The variations of Brake and Indicated specific fuel consumption with load for different fuels is as shown in the graphs presented earlier. The specific fuel consumption of CNSL oil is higher than that of diesel for all loads. This is caused due to the effect of higher viscosity and poor mixture formation of CNSL oil. For all the blends tested, it is seen that specific fuel consumptions (both brake and indicated) are found to decrease with an increase in the load. This is because more blended fuel is used to produce same power as compared to diesel. Hence the mixture formation is very poor if we increase the amount of CNSL oil with diesel. However from the graph, it is seen that the blend B20 blend gives lesser brake and indicated fuel consumptions when compared to all other blends. This may have resulted due to failure to run the engine with the B20 blend for a sufficient period of time before loading the engine.With increase in blend percentage, the calorific value of fuel decreases. Hence, the specific fuel consumption of the higher percentage of blends must increase when compared to that of diesel.It is also clearly seen from the graphs that the two BDEB blends (5% 10%) offer the highest specific fuel consumption values, BDEB 10 being the higher of the two. The reason being, the addition of ethanol to the blend increases the oxygen content resulting in faster
  • 6. International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 E-ISSN: 2321-9637 130 combustion and hence, higher rate of fuel consumption. MECHANICAL EFFICIENCY Mechanical Efficiency: all blends vs diesel 10. CONCLUSION Several engine performance tests have been carried out on a variety of blends of CNSL CNSL with ethanol. The conclusion at this stage of research can be summarized as under: The use of blends of CNSL and diesel as a fuel reduces the overall diesel consumption and hence dependency on diesel. Among the blends tested against diesel (B10, B15, B20), the blend B15( 15%CNSL and 85% Diesel) proved to be superior, displaying better engine performance characteristics, in comparison with diesel and the other blends (Figures 1, 2, 3, 4, 5). Testing of 25% CNSL and above, with diesel cannot be carried out, due to “Engine Cranking”, resulting from the high viscosity of the blend. Hence pre-heating may be required to counter this problem. Addition of Ethanol to any fuel helps in completing the fuel combustion process in the engine. Of the two biodiesel ethanol blends (BDEB5 and BDEB10) tested, BDEB 5 proved to be the better blend displaying better engine performance (Figures 4.1 – 4.10) at the maximum tested load. However, these two blends have displayed inferior engine performance when compared against the original B15 blend used. Future progress in the current research work can be elaborated as under: The above tests can be conducted for different biodiesels derived from different species. Fuel optimization by different method of transesterfication. Long hour durability tests can be conducted on the diesel engine. Further studies, on future bio diesel-diesel blends as fuels, may be carried out in order to reduce the viscosity as well as improve the engine performance and exhaust characteristics by changing different parameters. The computational fluid dynamics (CFD) simulations can be carried out to examine the fluid flow, air-fuel mixing formation; combustion process, carbon monoxide emission distribution as well as NO emission formation occurred inside engine cylinder by burning of these biodiesel blending derived from biofuels. REFERENCES [1] Mustafa Balat , Havva Balat (2008) “A critical review of bio-diesel as a vehicular fuel” Energy Conversion and Management 49, Page 2727– 2741. [2] Gerhard Knothe, Jon Van Gerpen, Jürgen Krahl (2005) “The Biodiesel Handbook” AOCS Press Champaign, Illinois. [3] Report of the committee on development of bio-fuel, (2003) Planning Commission India. [4] Fangrui Maa, Milford A. Hannab, (1999) “Biodiesel production: a review” Bioresource Technology 70, Page 1-15. [5] Ulf Schuchardta, Ricardo Serchelia, Rogério Matheus Vargas (1998) “Transesterification of Vegetable Oils: a Review” , J. Braz. Chem. Soc., Vol. 9, No. 1, Page 199-210. [6] S.P. Singh, Dipti Singh, (2010) “Biodiesel production through the use of different sources and characterization of oils and their esters as the substitute of diesel: A review Renewable and Sustainable Energy Reviews [7] M.Mathiyazhagan, A.Ganapathi, B. Jaganath, N. Renganayaki, And N. Sasireka (2011) “Production of biodiesel from non-edible plant oils having high FFA content”, International Journal of Chemical and Environmental Engineering, Vol. 2, No.2. [8] M. Canakci, J. Van Gerpen (2001) “Biodiesel production from oils and fats with high free fatty acids” American Society of Agricultural Engineers ISSN, Vol. 44(6), Page 1429–1436. [9] Gerhard Knothe (2005) “Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters” Fuel Processing Technology 86, Page 1059– 1070. [10] P.K.Gupta, Rakesh Kumar, B.S.Panesar, and V.K.Thapar (2007) “Parametric Studies on Bio-diesel prepared from Rice Bran Oil” Agricultural Engineering International: the CIGR Ejournal. Manuscript EE06 007, Vol. IX.
  • 7. International Journal of Research in Advent Technology, Vol.2, No.8, August 2014 E-ISSN: 2321-9637 131 [11] Janahiraman Krishnakumar, V. S. Karuppannan Venkatachalapathy, Sellappan Elancheliyan (2008) “Technical aspects of biodiesel production from vegetable oils”, Thermal Science, Vol. 12 No. 2, Page 159-169. [12]Young-Cheol Bak, Joo-Hong Choi, Sung-Bae Kim, Dong-Weon Kang (1996) “Production of bio-diesel fuels by transesterification of rice bran oil”, Korean J. of Chem. Eng., Vol.13(3), Page 242-245. [13] Lin Lin , Dong Ying, Sumpun Chaitep , Saritporn Vittayapadung (2008) “Biodiesel production from crude rice bran oil and properties as fuel” Applied Energy, Page 681–688. [14] Rambabu Kantipudi, Appa Rao.B.V, Hari Babu.N, Satyanarayana.CH (2010) “ Studies on Di diesel engine fueled with rice bran methyl ester injection and ethanol carburetion”, International Journal Of Applied Engineering Research, Dindigul Volume 1 No1, Page 206-221.