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J na i Go le
 a d     nza z-Lord
Q: What is matter?

   Ma r isa
     tte   nythingthat
   o c ie s a ea ha
    c up s p c nd s
          ms
           as
what is meant by a
state?

"s te m a "p ic l
  ta " e ns hys a
s te - s m thingtha
 ta ” o e          t
yo c n s ea /o fe l
   u a e nd r e

m in s te o m tte o
  a ta s f a r r
p s - s lid liq a
 ha e o , uid nd
gs
 a

s s nc o c ng sits
 ub ta e nly ha e
p s , no itss ture
 ha e t      truc
Properties of states or phases of
matter
Or
     W t ism tte m d upo
      ha    a r ae      f?
Huh?
Brownian motion                  Wha s
                                  this
                                      t’
                                      ?
Ab ut 2 0ye rsa o aBritis
   o 0 a g,               h
b ta t b thena eo Ro e
 o nis y        m f b rt
Bro n, w slo kinga s m
    w a o           t o e
p lle g insthro h his
 o n ra         ug
m ro c p a re lis d tha the
  ic s o e nd a e        t y
w rem vinga o Furthe
  e    o      b ut.     r
inve tig tio s w d tha isw s
    s a n ho e        t    a
thew te m le ule tha w re
     a r o c s t e
b tingthep lle g insa o
 uffe         o n ra     b ut!

Thisra o m tio o p rtic s
      nd m o n f a le
w nt o to b kno n a Brownian
 e n       e w s
motion.
Importance of Brownian motion
 Ma r ism d
    tte     ae
  up o p rtic s
      f a le
  in c ns nt,
      o ta
  ra o m tio
    nd m o n
Further investigation led to
              Kinetic
             Mo c r
                le ula
              The ry
                  o
Kinetic Molecular Theory (KMT)
 Kine Ene y = m vinge rg
       tic   rg    o      ne y
 All m tte m d o p rtic s(m le ule , io o a m )
        a r a e f a le o c s ns r to s
 P rtic sin c ns nt m tio tova
   a le       o ta    o n      ryingd g e
                                      e re s
 All p rtic sha kine e rg to va
       a le ve        tic ne y     ryingd g e
                                          e re s
 Thed g eo m tio isd p nd nt o thee rg o the
        e re f o n e e e n               ne y f
  p rtic s
   a le
 Thee rg o thep rtic sd te ine thes teo m tte
        ne y f     a le e rm s           ta f a r
Key Assumptions of KMT
                         Thevo eo c ie b the
                               lum c up d y
Thefirs 2p intsa n’
       t o       re t     m le ule isd tothes a ein
                            o c s ue             pc
 s tly true–s
  tric         hhh!
                          b tw e them le ule a no the
                           e en        o c s nd t
                          m le ule the s lve .
                            o c s me s
                         Noe rg islo t w n them le ule
                               ne y    s he          o c s
                          c llid w e c o r o thew lls
                           o e ith a h the r           a
                          o the c nta r.
                           f ir o ine
                         Sta o m tte isd p nd nt o b th
                             te f a r      ee e n o
                          thekine e rg o them le ule
                                 tic ne y f        o c s
                          a w ll a thea c
                           s e s       ttra tivefo e
                                                  rc s
                          b tw e m le ule .
                           e en o c s
Ho d e KMT e la s lid , liq s
  w os      xp in o s uid
         a gss
          nd a e ?
Ho d e KMT e la w w g t fro
  w os        xp in ho e e m
      s lid to liq to g s
       o          uid  a?
Phase changes
                n
             aio
              t




                                                      Me
           im




                                            Fre
                           t n
                          aio




                                                        ltin
        ul
       sb




                                               ei
                                                zn
                       lim




                                                            g
     De




                                                  g
                    Sub




                                  Boiling

                                 C nd ns tio
                                  o e a n
What are heating/cooling curves?
Heating Curve                    Cooling Curve
 Gra hic l re re e tio o
     p a p s nta n f              Gra hic l re re e tio o
                                      p a p s nta n f
    w t ha p nsw n as s nc
      ha p e      he   ub ta e       w t ha p nsw n as s nc
                                       ha p e       he   ub ta e
    ishe te upo r tim
        a d     ve   e               isc o do r tim
                                        o le ve      e
   Y-a –Te p ra
       xis    m e ture              Y-a –Te p ra
                                         xis    m e ture
   X-a –Tim
       xis     e                    X-a –Tim
                                         xis     e
   Sho sm ltinga b iling
        w e       nd o              Sho sc nd ns tio a
                                         w o e a n nd
    p ints
     o                               fre zingp ints
                                        e     o
   Sho s3p s s
        w    ha e                   Sho s3p s s
                                         w    ha e
Heating curves




                                                         s
                                                       Ga
                                                             Ab ve m ltingp int,
                                                                o     e    o
                                        Liq to g s
                                           uid  a            g s isfo e
                                                              a      rm d
Bo iling
p int
 o
      m e ture




                                      Be e n m ltinga b ilingp ints
                                        tw e e       nd o     o ,
                               uid
    Te p ra




                            Liq



                                      s s nc re a liq
                                       ub ta e m ins uid

                   So toliq
                     lid   uid
Me lting
p int
 o                  Be wm ltingp int, s lid isfo e
                      lo e      o      o        rm d
             lid
           So




                                                             Time
Heating curve for water




                                                  am
                                               Ste
                                                       Ab ve 10 °C g s
                                                          o     0 , a
            At 10 °C w te turnsto
                 0 , a r            w te tos a
                                     a r    te m
10 ° C
  0                                                    (s a ) isfo e
                                                         te m     rm d
            s a
             te m



                                Be e n 0 C a 10 °C w te re a
                                    tw e °  nd 0 , a r m ins
                          tr
                         ae


    At 0 C s lidturning
        ° , o
                                liq uid
                        W




    c m le ly toliq
     o p te        uid
    p s
     ha e
             Ic tow te
               e     a r
 0 C
  °
               Be w0 C s lid (ic ) isfo e
                 lo ° , o       e      rm d                 Time
     I ce
Cooling curves
                           Ab vec nd ns tio
                              o o e a n
                  Ga
                    s      p int, g se ts
                            o      a xis .
                                                    C nd ns tio
                                                     o e a n
                        Ga toliq
                          s     uid                 p int
                                                     o
                                          Li
                                             qu
                  Be e n c nd ns tio
                    tw e o e a n               id
       m e ture




                  a fre zingp ints
                   nd e      o ,
                  s s nc re a liq
                   ub ta e m ins uid
     Te p ra




Fre zing
   e                                                    Liq to s lid
                                                           uid o
                                                                       So
p int
 o                                                                       lid
                                               Be wfre zingp int,
                                                  lo    e     o
                                               s lid isfo e
                                                o        rm d

                                                                       Time
Cooling curve for water
       St
         e        Ab vec nd ns tio
                     o o e a n
          am
                  p int, g se ts
                   o      a xis .
                                         C nd ns tio
                                          o e a n
                 Ste mto w te
                    a     a r            p int
                                          o
  10 ° C
    0
                                 W
                                  at
           Be e n c nd ns tio
              tw e o e a n          er
           a fre zingp ints
            nd e      o ,
           w te e ts
             a r xis
                                             W te toic
                                              a r     e
    0 C
     °                                                    Ice
Fre zing
   e
                                     Be wfre zingp int,
                                        lo   e    o
p int
 o
                                     ic isfo e
                                       e    rm d

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States Of Matter

  • 1. J na i Go le a d nza z-Lord
  • 2. Q: What is matter? Ma r isa tte nythingthat o c ie s a ea ha c up s p c nd s ms as
  • 3. what is meant by a state? "s te m a "p ic l ta " e ns hys a s te - s m thingtha ta ” o e t yo c n s ea /o fe l u a e nd r e m in s te o m tte o a ta s f a r r p s - s lid liq a ha e o , uid nd gs a s s nc o c ng sits ub ta e nly ha e p s , no itss ture ha e t truc
  • 4. Properties of states or phases of matter
  • 5. Or W t ism tte m d upo ha a r ae f?
  • 6. Huh? Brownian motion Wha s this t’ ? Ab ut 2 0ye rsa o aBritis o 0 a g, h b ta t b thena eo Ro e o nis y m f b rt Bro n, w slo kinga s m w a o t o e p lle g insthro h his o n ra ug m ro c p a re lis d tha the ic s o e nd a e t y w rem vinga o Furthe e o b ut. r inve tig tio s w d tha isw s s a n ho e t a thew te m le ule tha w re a r o c s t e b tingthep lle g insa o uffe o n ra b ut! Thisra o m tio o p rtic s nd m o n f a le w nt o to b kno n a Brownian e n e w s motion.
  • 7. Importance of Brownian motion Ma r ism d tte ae up o p rtic s f a le in c ns nt, o ta ra o m tio nd m o n
  • 8. Further investigation led to Kinetic Mo c r le ula The ry o
  • 9. Kinetic Molecular Theory (KMT)  Kine Ene y = m vinge rg tic rg o ne y  All m tte m d o p rtic s(m le ule , io o a m ) a r a e f a le o c s ns r to s  P rtic sin c ns nt m tio tova a le o ta o n ryingd g e e re s  All p rtic sha kine e rg to va a le ve tic ne y ryingd g e e re s  Thed g eo m tio isd p nd nt o thee rg o the e re f o n e e e n ne y f p rtic s a le  Thee rg o thep rtic sd te ine thes teo m tte ne y f a le e rm s ta f a r
  • 10. Key Assumptions of KMT  Thevo eo c ie b the lum c up d y Thefirs 2p intsa n’ t o re t m le ule isd tothes a ein o c s ue pc s tly true–s tric hhh! b tw e them le ule a no the e en o c s nd t m le ule the s lve . o c s me s  Noe rg islo t w n them le ule ne y s he o c s c llid w e c o r o thew lls o e ith a h the r a o the c nta r. f ir o ine  Sta o m tte isd p nd nt o b th te f a r ee e n o thekine e rg o them le ule tic ne y f o c s a w ll a thea c s e s ttra tivefo e rc s b tw e m le ule . e en o c s
  • 11. Ho d e KMT e la s lid , liq s w os xp in o s uid a gss nd a e ?
  • 12.
  • 13. Ho d e KMT e la w w g t fro w os xp in ho e e m s lid to liq to g s o uid a?
  • 14.
  • 15.
  • 16.
  • 17. Phase changes n aio t Me im Fre t n aio ltin ul sb ei zn lim g De g Sub Boiling C nd ns tio o e a n
  • 18.
  • 19. What are heating/cooling curves? Heating Curve Cooling Curve  Gra hic l re re e tio o p a p s nta n f  Gra hic l re re e tio o p a p s nta n f w t ha p nsw n as s nc ha p e he ub ta e w t ha p nsw n as s nc ha p e he ub ta e ishe te upo r tim a d ve e isc o do r tim o le ve e  Y-a –Te p ra xis m e ture  Y-a –Te p ra xis m e ture  X-a –Tim xis e  X-a –Tim xis e  Sho sm ltinga b iling w e nd o  Sho sc nd ns tio a w o e a n nd p ints o fre zingp ints e o  Sho s3p s s w ha e  Sho s3p s s w ha e
  • 20. Heating curves s Ga Ab ve m ltingp int, o e o Liq to g s uid a g s isfo e a rm d Bo iling p int o m e ture Be e n m ltinga b ilingp ints tw e e nd o o , uid Te p ra Liq s s nc re a liq ub ta e m ins uid So toliq lid uid Me lting p int o Be wm ltingp int, s lid isfo e lo e o o rm d lid So Time
  • 21. Heating curve for water am Ste Ab ve 10 °C g s o 0 , a At 10 °C w te turnsto 0 , a r w te tos a a r te m 10 ° C 0 (s a ) isfo e te m rm d s a te m Be e n 0 C a 10 °C w te re a tw e ° nd 0 , a r m ins tr ae At 0 C s lidturning ° , o liq uid W c m le ly toliq o p te uid p s ha e Ic tow te e a r 0 C ° Be w0 C s lid (ic ) isfo e lo ° , o e rm d Time I ce
  • 22. Cooling curves Ab vec nd ns tio o o e a n Ga s p int, g se ts o a xis . C nd ns tio o e a n Ga toliq s uid p int o Li qu Be e n c nd ns tio tw e o e a n id m e ture a fre zingp ints nd e o , s s nc re a liq ub ta e m ins uid Te p ra Fre zing e Liq to s lid uid o So p int o lid Be wfre zingp int, lo e o s lid isfo e o rm d Time
  • 23. Cooling curve for water St e Ab vec nd ns tio o o e a n am p int, g se ts o a xis . C nd ns tio o e a n Ste mto w te a a r p int o 10 ° C 0 W at Be e n c nd ns tio tw e o e a n er a fre zingp ints nd e o , w te e ts a r xis W te toic a r e 0 C ° Ice Fre zing e Be wfre zingp int, lo e o p int o ic isfo e e rm d