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Organic Chemistry
Basic Nomenclature and Structures
Hopefully this slideshow will help
O-chem students with some visuals
of structures.
Line Structure Abbreviation Structural formula Name Class of
compound
none
C
C
C
C
H
H
H
H
H
H H
H
but-1-ene alkene
RH
CH
H
H
C
H
H
C
H
H
C
H
H
H
butane
alkane
none
C
C
C
C
H
H
H
H
H
H
H
H
(2E)-but-2-ene
alkene
none
C C C CH
H
H H
H
H
but-1-yne alkyne
CH
H
H
C
H
H
C
H
H
C
H
H
H
none
C C C CH
H
H H
H
H
but-2-yne alkyne
OH
ROH
C C C C O
H
H
H
H
H
H
H
H
H
H
butan-1-ol
alcohol
OH
ROH
C C C
C
OH
H
H
H
H
H
H
H
H
H
butan-2-ol alcohol
Line Structure Abbreviation Structural formula Name Class of
compound
O
R(C=O)H
C C C C
O
H
H
H
H
H
H
H
H
butanal aldehyde
O
R(C=O)R’
C C C
C
O
H
H
H
H
H
H
H
H
butan-2-one Ketone
(with 2
different
alkyl groups)
NH2
RNH2
C C C C NH
H
H H
H
H
H
H
H
H
H
butan-1-amine amine
NH2
RNH2
C C C
C
NH
H
H H
H
H
HH
H
H
H
butan-2-amine amine
Line Structure Abbreviation Structural formula Name Class of
compound
Cl
RX
C C C C Cl
H
H
H
H
H
H
H
H
H
1-chlorobutane Alkyl halide
Br
RX
C C C C
BrH
H
H
H
H
H H
H
H
2-bromobutane Alkyl halide
OH
O
RCO2H
RCOOH
R(C=O)OH
C C C
O
O
C
H
H
H
H
H
H
H
H butanoic acid Carboxylic
acid
O
ROR’
C C C O
C
CH
H
H H
H
H
H
H
H
H
H
H
butyl methyl
ether
Ether (with 2
different
alkyl groups)
Line Structure Abbreviation Structural formula Name Class of
compound
O
ROR
C
C
O
C
C
H
H
H
H
H H
H
H
H
H
diethyl ether Ether (with
one
type of
alkyl group)
Cl
O
R(C=O)X
C C C
Cl
O
C
H
H
H
H
H
H
H
butanoyl
chloride
Acyl halide
CH3
O
NH2
R(C=O)NH2
C C C C
O
N
H
H
H
H
H
H
H
H
H
butanamide Amide
Line Structure Abbreviation Structural formula Name Class of
compound
O
O
Na
R(C=O)OM
(M indicates
a metal)
C C C
O
O
C
Na
H
H
H
H
H
H
H sodium
butanoate
Carboxylate
salt
O
O O
R(C=O)O(C=O)R
C
C
O
O
C
O
C
H
H
H
H
H
H
acetic
anhydride
Anhydride
SH
RSH
C C C C SH
H
H H
H
H
H
H
H
H
butane-1-thiol Thio alcohol
mercaptan
S
S
RSSR
S
S C
C
H
H
H
H
H
H
dimethyl
disulfide
Disulfide
Ar
C
C
C
C
C
C
H
H
H
H
H
H
benzene Aromatic
OH ArOH
PhOH
(Ph indicates
phenyl)
C
C
C
C
C
C
OH
H
H
H
H
H
phenol A phenol, an
aromatic
alcohol
O
OH
Ar(C=O)OH
ArCO2H
ArCOOH
Ph(C=O)OH
PhCO2H
PhCOOH
C
C
C
C
C
C
C
O
O
H
H
H
H
H
H
benzoic acid A benzoic acid
(an aromatic
carboxylic
acid)
NH2 ArNH2
PhNH2
C
C
C
C
C
C
N
H
H
H
H
H
H
H
aniline An aniline
(an aromatic
amine)
O Ar(C=O)H
Ph(C=O)H
C
C
C
C
C
C
C
O
H
H
H
H
H
H benzaldehyde A
benzaldehyde,
an aromatic
aldehyde
ArMe
PhMe
(Me indicates
methyl, -CH3)
C
C
C
C
C
C
C
H
H
H
H
H
H
H
H methylbenzene A toluene, a
methyl-
benzene
Line Structure Abbreviation Structural formula Name Class of
compound

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Presentation6 orgchem

  • 2. Hopefully this slideshow will help O-chem students with some visuals of structures.
  • 3. Line Structure Abbreviation Structural formula Name Class of compound none C C C C H H H H H H H H but-1-ene alkene RH CH H H C H H C H H C H H H butane alkane none C C C C H H H H H H H H (2E)-but-2-ene alkene none C C C CH H H H H H but-1-yne alkyne CH H H C H H C H H C H H H
  • 4. none C C C CH H H H H H but-2-yne alkyne OH ROH C C C C O H H H H H H H H H H butan-1-ol alcohol OH ROH C C C C OH H H H H H H H H H butan-2-ol alcohol Line Structure Abbreviation Structural formula Name Class of compound
  • 5. O R(C=O)H C C C C O H H H H H H H H butanal aldehyde O R(C=O)R’ C C C C O H H H H H H H H butan-2-one Ketone (with 2 different alkyl groups) NH2 RNH2 C C C C NH H H H H H H H H H H butan-1-amine amine NH2 RNH2 C C C C NH H H H H H HH H H H butan-2-amine amine Line Structure Abbreviation Structural formula Name Class of compound
  • 6. Cl RX C C C C Cl H H H H H H H H H 1-chlorobutane Alkyl halide Br RX C C C C BrH H H H H H H H H 2-bromobutane Alkyl halide OH O RCO2H RCOOH R(C=O)OH C C C O O C H H H H H H H H butanoic acid Carboxylic acid O ROR’ C C C O C CH H H H H H H H H H H H butyl methyl ether Ether (with 2 different alkyl groups) Line Structure Abbreviation Structural formula Name Class of compound
  • 7. O ROR C C O C C H H H H H H H H H H diethyl ether Ether (with one type of alkyl group) Cl O R(C=O)X C C C Cl O C H H H H H H H butanoyl chloride Acyl halide CH3 O NH2 R(C=O)NH2 C C C C O N H H H H H H H H H butanamide Amide Line Structure Abbreviation Structural formula Name Class of compound
  • 8. O O Na R(C=O)OM (M indicates a metal) C C C O O C Na H H H H H H H sodium butanoate Carboxylate salt O O O R(C=O)O(C=O)R C C O O C O C H H H H H H acetic anhydride Anhydride SH RSH C C C C SH H H H H H H H H H butane-1-thiol Thio alcohol mercaptan S S RSSR S S C C H H H H H H dimethyl disulfide Disulfide
  • 9. Ar C C C C C C H H H H H H benzene Aromatic OH ArOH PhOH (Ph indicates phenyl) C C C C C C OH H H H H H phenol A phenol, an aromatic alcohol O OH Ar(C=O)OH ArCO2H ArCOOH Ph(C=O)OH PhCO2H PhCOOH C C C C C C C O O H H H H H H benzoic acid A benzoic acid (an aromatic carboxylic acid) NH2 ArNH2 PhNH2 C C C C C C N H H H H H H H aniline An aniline (an aromatic amine)
  • 10. O Ar(C=O)H Ph(C=O)H C C C C C C C O H H H H H H benzaldehyde A benzaldehyde, an aromatic aldehyde ArMe PhMe (Me indicates methyl, -CH3) C C C C C C C H H H H H H H H methylbenzene A toluene, a methyl- benzene Line Structure Abbreviation Structural formula Name Class of compound