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FACULTY OF ENGINEERING
INTERNATIONAL UNIVERSITY OF IMAM KHOMEINI QAZVIN
STRUCTURES, PROCESSING &
APPLICATIONS OF BARITE
By : Ali mehri
Supervisor : Dr. Karimi
Content
■ Introduction
■ Sources
■ Minerals
■ Processing methods
■ Applications
■ Holder countries
■ References
2
Introduction[1][2][3]
■ Found in the 17th century near Bologna in Italy.
■ Barite was named from the Greek word barus which means heavy.
■ It also named barytine, barytite, Heavy Spar, tiff.
■ It was used for the production of barium hydroxide for sugar
refining, and as a white pigment for textiles, paper, and paint.
3
Sources[2][3]
■ As a vein filling and as a gangue mineral in silver, copper, nickel ores.
■ In lead-zinc veins in limestones.
■ In hot spring deposits.
■ often associated with the minerals Anglesite and Celestine.
■ With Hematite ore.
■ Hydrothermal and evaporation environments.
■ Rarely in basalts.
■ It has also been identified in meteorites.
4
Barite[3][4]
 Chemical Formula BaSO4
 Color Colorless , white , yellow ,
orange , red , pink , purple, brown, blue,
gray, and black
 Streak White
 Specific Gravity 4.3 - 4.6
 Hardness 3 - 3.5
 Crystal System Orthorhombic
Luster Vitreous to pearly
 Solubility insoluble
 Melting point 1580 C
5
Witherite[4][5]
 Chemical Formula BaCO3
 Color White, cream, grayish-white,
pale yellow, pale green
 Streak White
 Specific Gravity 4.3 - 4.6
 Hardness 3 - 3.5
 Crystal System Orthorhombic
 Luster Vitreous
 Solubility insoluble
 Melting point 811 C
6
Processing method[6]
Dry type Wet type
7
Cone/jaw
crusher
Ball mill
Shaking
table
Dryer
Jig
Washing
Cone/jaw
crusher
Ball millJig/flotation
Applications[2][7]
weighting agent for drilling
fluids(BaSO4)
Advantages:
■ Increase mud density up to
21 lb/gal (2.5 g/cm3 )
■ Control formation pressure
■ Stabilize the borehole
8
Applications[8]
As a filler in paints(BaSO4)
■ Blanc Fixe :
Blanc Fixe is an advanced filler
for Paint & Coatings
Advantages:
Easy dispersion, excellent
gloss, pigment spacing
effects
9
Information
Average particle size : 0.7 µm
Oil index : 14 g/100g
Lightness L* : 99 %
Blanc fixe[9]
■ industrial grade barite production has
the grade of 97 %.
■ The barite grading over 98% is created
chemically in a laboratory named by
blanc fixe.
■ VIM barite is naturally occurring to as
high as 99.26% BaSO4. VIM barite
requires NO CHEMICALS to produce.
10
Applications[3]
As a coating for hot cathodes
(BaO)
Material
Operating
temperature
Emission
efficacy
Specific
emission
Tungsten 2500 K 5 mA/W 500 mA/cm2
Thoriated
tungsten
2000 K 100 mA/W 5 A/cm2
Oxide
coated
1000 K 500 mA/W 10 A/cm2
Barium
aluminate
1300 K 400 mA/W 4 A/cm2
11
Applications[10]
Brin process (BaO)
■ Brin process is a now obsolete
industrial scale production
process for oxygen.
■ In this process barium oxide
reacts at 500–600 °C with air
to form barium peroxide which
decomposes at above 800 °C
by releasing oxygen.
12
2Ba + O2 → 2BaO
BaCO3 → BaO + CO2
Applications[8]
Barium carbonate(BaCO3)
■ coarse powder is used for
the production of crystal
glass.
■ Granular form is used for
the production of special
glasses.
■ Fine powder is specially
developed for usage in
ceramics.
■ standard powder is used in 13
Applications[8]
Barium Chloride(BaO)
■ Barium Chloride Dihydrate
is used in waste water
treatment, the production of
PVC stabilizers and oil
lubricants.
14
World production[11]
15
Holder countries[12]
16
References
1. Beniamino Barbieri, 2010, A Short History of Fluorescence.
2. Dr. Kamar Shah Ariffin, 2002, baryte.
3. https://en.wikipedia.org/ Asarelah, 20 August 2016
4. http://www.minerals.net/ 2 September 2016
5. http://www.chemicalland21.com/ 2 September 2016
6. http://www.ngdir.ir/2 September 2016
7. Pal skalle, 2011, Drilling fluid engineering, page 15
8. http://www.solvay.com/3 September 2016
9. Steven R. Livingston, 2012 , Voyageur Industrial Minerals Ltd
10.William B. Jensen, 2009, The Origin of the Brin Process for the
Manufacture of Oxygen
11.www.indmin.com, 3 September 2016
12.http://www.indexmundi.com, 3 September 2016
17

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Presentation3

  • 1. FACULTY OF ENGINEERING INTERNATIONAL UNIVERSITY OF IMAM KHOMEINI QAZVIN STRUCTURES, PROCESSING & APPLICATIONS OF BARITE By : Ali mehri Supervisor : Dr. Karimi
  • 2. Content ■ Introduction ■ Sources ■ Minerals ■ Processing methods ■ Applications ■ Holder countries ■ References 2
  • 3. Introduction[1][2][3] ■ Found in the 17th century near Bologna in Italy. ■ Barite was named from the Greek word barus which means heavy. ■ It also named barytine, barytite, Heavy Spar, tiff. ■ It was used for the production of barium hydroxide for sugar refining, and as a white pigment for textiles, paper, and paint. 3
  • 4. Sources[2][3] ■ As a vein filling and as a gangue mineral in silver, copper, nickel ores. ■ In lead-zinc veins in limestones. ■ In hot spring deposits. ■ often associated with the minerals Anglesite and Celestine. ■ With Hematite ore. ■ Hydrothermal and evaporation environments. ■ Rarely in basalts. ■ It has also been identified in meteorites. 4
  • 5. Barite[3][4]  Chemical Formula BaSO4  Color Colorless , white , yellow , orange , red , pink , purple, brown, blue, gray, and black  Streak White  Specific Gravity 4.3 - 4.6  Hardness 3 - 3.5  Crystal System Orthorhombic Luster Vitreous to pearly  Solubility insoluble  Melting point 1580 C 5
  • 6. Witherite[4][5]  Chemical Formula BaCO3  Color White, cream, grayish-white, pale yellow, pale green  Streak White  Specific Gravity 4.3 - 4.6  Hardness 3 - 3.5  Crystal System Orthorhombic  Luster Vitreous  Solubility insoluble  Melting point 811 C 6
  • 7. Processing method[6] Dry type Wet type 7 Cone/jaw crusher Ball mill Shaking table Dryer Jig Washing Cone/jaw crusher Ball millJig/flotation
  • 8. Applications[2][7] weighting agent for drilling fluids(BaSO4) Advantages: ■ Increase mud density up to 21 lb/gal (2.5 g/cm3 ) ■ Control formation pressure ■ Stabilize the borehole 8
  • 9. Applications[8] As a filler in paints(BaSO4) ■ Blanc Fixe : Blanc Fixe is an advanced filler for Paint & Coatings Advantages: Easy dispersion, excellent gloss, pigment spacing effects 9 Information Average particle size : 0.7 µm Oil index : 14 g/100g Lightness L* : 99 %
  • 10. Blanc fixe[9] ■ industrial grade barite production has the grade of 97 %. ■ The barite grading over 98% is created chemically in a laboratory named by blanc fixe. ■ VIM barite is naturally occurring to as high as 99.26% BaSO4. VIM barite requires NO CHEMICALS to produce. 10
  • 11. Applications[3] As a coating for hot cathodes (BaO) Material Operating temperature Emission efficacy Specific emission Tungsten 2500 K 5 mA/W 500 mA/cm2 Thoriated tungsten 2000 K 100 mA/W 5 A/cm2 Oxide coated 1000 K 500 mA/W 10 A/cm2 Barium aluminate 1300 K 400 mA/W 4 A/cm2 11
  • 12. Applications[10] Brin process (BaO) ■ Brin process is a now obsolete industrial scale production process for oxygen. ■ In this process barium oxide reacts at 500–600 °C with air to form barium peroxide which decomposes at above 800 °C by releasing oxygen. 12 2Ba + O2 → 2BaO BaCO3 → BaO + CO2
  • 13. Applications[8] Barium carbonate(BaCO3) ■ coarse powder is used for the production of crystal glass. ■ Granular form is used for the production of special glasses. ■ Fine powder is specially developed for usage in ceramics. ■ standard powder is used in 13
  • 14. Applications[8] Barium Chloride(BaO) ■ Barium Chloride Dihydrate is used in waste water treatment, the production of PVC stabilizers and oil lubricants. 14
  • 17. References 1. Beniamino Barbieri, 2010, A Short History of Fluorescence. 2. Dr. Kamar Shah Ariffin, 2002, baryte. 3. https://en.wikipedia.org/ Asarelah, 20 August 2016 4. http://www.minerals.net/ 2 September 2016 5. http://www.chemicalland21.com/ 2 September 2016 6. http://www.ngdir.ir/2 September 2016 7. Pal skalle, 2011, Drilling fluid engineering, page 15 8. http://www.solvay.com/3 September 2016 9. Steven R. Livingston, 2012 , Voyageur Industrial Minerals Ltd 10.William B. Jensen, 2009, The Origin of the Brin Process for the Manufacture of Oxygen 11.www.indmin.com, 3 September 2016 12.http://www.indexmundi.com, 3 September 2016 17

Editor's Notes

  1. Limestones = سنگ آهک
  2. Luster Vitreous = درخشش زجاجیه
  3. bentonite clay (gel) with additives such as barium sulfate (barite), calcium carbonate (chalk) or hematite. Quartz/feldspar/calcite/pyrite/smectite/illite/chlorite/kaolinite
  4. Easy dispersion, excellent gloss, pigment spacing effects =رنگدانه فاصله پراکندگی آسان، براق عالی، اثرات
  5. Barium carbonate coarse powder is used for the production of display glass, crystal glass and other special glass, glazes, frits and enamels. granular
  6. Barium Chloride is the inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like other barium salts, it is toxic and imparts a yellow-green coloration to a flame. It is also hygroscopic. As an inexpensive, soluble salt of barium, Barium Chloride finds wide application in the laboratory. It is commonly used as a test for sulfate ion. In industry, Barium Chloride is mainly used in the purification of brine solution in caustic chlorine plants and also in the manufacture of heat treatment salts, case hardening of steel, in the manufacture of pigments, and in the manufacture of other barium salts. Barium Chloride is also used in fireworks to give a bright green color. However, its toxicity limits its applicability.