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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 11 Issue: 01 | Jan 2024 www.irjet.net p-ISSN: 2395-0072
© 2024, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 543
PM10 CONCENTRATION CHANGES AS A RESULT OF WIDESPRING
PRECIPITATION IN AGRA
Kalpana Singh*, Dr. Randhir Singh Indolia,
Department of Physics, Dr. Bhimrao Ambedkar University, Agra (U.P), India
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - - From 2021 to 2022, research was conducted at the Sanjay Place site to examine the impact of widespread
precipitation on the decrease in PM₁ₒ concentration. There was a discernible variation in the concentrations of PM₁ₒ particles
before and after. There was a noticeable change in the average PM₁ₒ concentration and less PM₁ₒ in the air during periods of
precipitation compared to those without. The average PM₁₀ concentration was 101.1µg/m³ and 184.8µg/m³ with and without
precipitation. Over the July–September period, the intensity of moderate to light rain was found to have the biggest effect on the
decrease in PM₁ₒ concentration. The results showed that the accumulation of aerosol concentration was preventedbycontinuous
low intensity rain episodes and that the amount and duration of precipitation have an effect on how
Key Words: PM₁ₒ, Atmospheric purification, Precipitation, Meteorological condition
1.INTRODUCTION
At the expense of other elements of the natural environment, below-cloud scavenging serves as a key process that enablesthe
removal of pollutants from the ground level zone and plays a crucial part in the maintenance of excellent air quality [1]. As a
result, it is a crucial step in maintaining the equilibrium between the entrance and outflow of aerosol particles [2]. All
mechanisms that cause rain, snow, fog, and ice to wash off particle matter are considered to be a part of wet below-cloud
scavenging. According to [3], below-cloud scavenging appears to be more significant than in-cloud scavenging from the
perspective of human well-being and the quality of the ground-level zone. This claim is supported by the observation that the
particulate matter that poses an immediate threat to human health is primarily released asa resultofbelow-cloudscavenging,
with the major mechanism involved being the collision of solidparticles with raindrops [4].The wetaerosol washout processis
inherently complicated because it is influenced by a variety of external phenomena,suchasdropsize,particlesize distribution,
water chemical composition, rainfall intensity, ambient temperature, as well as the chemical and physical characteristics of
drops and aerosol [5]. The bulk particle number, bulk particle mass, or size-resolved particle number and mass concentration
can all be used to establish the aerosol scavenging coefficient [6]. Experimental research into below-cloudpurificationcarried
out under real-world circumstances focuses on several aspects of this process. The processes are studied both on a complex
scale, which includes details of the effectiveness of solid particle removal by specific types of precipitation, and on a specific
scale, which can include the effectiveness of scavenging of different types of particulate particles by specific types of
precipitation [7]. Transport from outside the area is the primary source of air pollution in addition to local accumulation.
Clearly, there is a great deal of uncertainty around the method by which contaminants are removed byprecipitation [8,9].This
paper's main goal is to analyze the variability of wet deposition, which istheprocess of removingcoarseparticles,in relationto
the length, intensity, and location of precipitation [10].
2.EXPERIMENTAL
2.1. Study Area.
At the Sanjay Place site in Agra city, PM₁₀ aerosol samples and rainwater samples were taken simultaneously. India's Agra isa
major city. With the Thar Desert of Rajasthan enclosing two-thirds of its outer limits (SE, W, and NW), it is located in the north
central area of India (27.18 N 78.02 E). Agra has 1.6 million people, according to the Census (2011). The summer months in
Agra are hot and dry, with daily average temperatures ranging from 21.9 to 48 degrees Celsius, and from 4.2 to 31.7 degrees
Celsius in the winter. Agra receives about 736.6 mm of rainfall each year.
2.2. Description of sampling site
The study was conducted in Sanjay place site of Agra city from October 2021 to September 2022. Map of sampling site and
surroundings are shown in Fig.1. The main causes of air pollution were nearby commercial activity, industrial emissions, and
emissions from vehicles. These sources have a significant impact on the site, depending on seasonal variations in wind and
direction. Sanjay place is one of the most polluted areas in Agra city.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 11 Issue: 01 | Jan 2024 www.irjet.net p-ISSN: 2395-0072
© 2024, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 544
Fig.1 Map showing study area at Agra city.
2.3. Sample collection
PM₁₀ samples were collected by low volume sampler. Three sets of samples were collected before rain, during rain and after
rain each at site. The rainfall data was collected by using rain gauge instrument through bottleandfunnel method. Theamount
of rain was measured for calculation of rain intensity. The site is free from any obstacles. The PM₁₀ instrument shown in fig.2
and Rain gauge instrument shown in fig.3.
Fig.2. PM₁₀ Low Volume sampler Fig.3. Rain gauge
3. RESULT AND DISCUSSION
3.1. Statistical description
Table.1 provides a summary of the statistical information thatwasexaminedduringthe2021–2022yearexperiment,including
information on the chosen air pollution (PM₁₀), meteorological variables, and precipitation.Rainfall intensity(light,moderate,
heavy) plays a crucial role in the removal of PM₁₀ from the troposphere.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 11 Issue: 01 | Jan 2024 www.irjet.net p-ISSN: 2395-0072
© 2024, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 545
Table 1. PM₁₀ and meteorological parameters characterization
Precipitation
samples
Descriptive
statistics
PM₁ₒ T (°C) RH (%) WS WD
11 samples avg 135 26.3 70.2 2.19 169.3
min 51 11 30.5 1.04 94
max 281.3 36 82 3.52 267
med 144.6 26 74 2.58 141
Note: T- temperature, RH- relative humidity, WS- wind speed,WD-winddirection,Avg.-average,Med.-median,Min-minimum,
Max-maximum, precipitation samples.
During large-scale rain events in the cold and warm seasons, the average air temperature was around 19.8°C and 31.8°C
respectively. The warm season is characterized by higher relative humidity and lower wind speed than cold season.
3.2. PM₁ₒ concentration with and without precipitation
In the case of rainfalls, PM₁₀ concentrations were lower than during the non-precipitation period, and between 101.1 and
184.8, there was a discernible difference in average PM₁₀ concentration. The patternofhourlyPM₁₀concentration variationof
precipitation and non-precipitation was quite similar to each other. Quantitatively, the reduction effect of precipitation
scavenging in the warm period was higher than in the cold period. The hourly PM₁₀ concentration in thecoldperiodincreased
due to a relatively more substantial direct effect of vehicle emissions despite the rainfall. The meteorological parameters also
effect the concentration of PM₁₀ during warm and cold periods.
Fig. 4 PM₁₀ hourly variations of precipitation and non-precipitation in the cold period.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 11 Issue: 01 | Jan 2024 www.irjet.net p-ISSN: 2395-0072
© 2024, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 546
Fig. 5 PM₁₀ hourly variations of precipitation and non-precipitation in the warm period.
At the Sanjay place site, A comparison was made between the hourly PM₁₀ concentration during periods of rainfall and no
precipitation to ascertain the purifying impact of precipitation.
4.CONCLUSION
After 6 hours of continuous rain with low to moderate intensity, the warm season had the greatest PM₁₀ concentration
reduction. The most frequent duration of rainfall was an hour, and low intensity precipitation predominated. The PM₁₀
concentration measured in the cold and warm periods showed a substantial difference as a result of the differing emission
sources and weather conditions. In places with poor air quality, the immediatepurificationeffect broughton bytheoccurrence
of moist deposition is reduced to a minimum. Scavenging efficiency greatly depends on the structure of the precipitation.
ACKNOWLEDGEMENT
Thanks to the Central Pollution Control Board for providing the environmental monitoring data.
REFERENCES
[1] Goncalves FL, et al., “Modelling and measurements of below cloud scavenging processes in the highly industrialisedregion
of Cubatao-Brazil”. Atmos Environ. (2000).
[2] Chate DM. Rao P, et al., “Scavenging of aerosols and their chemical species by rain”. Atmos Environ. (2003).
[3] Bae SY et al., “Development and evaluation of an expression for polydisperse particle scavenging coefficient for the below-
cloud scavenging as a function of rain intensity using the moment method”. Aerosol Sci. (2006).
[4] Kim J-E et al., “Factors influencing atmospheric wet deposition of trace elements in rural korea”. Amos Res. (2012).
[5] Zhao H, et al., “solution of wet removal of aerosols by precipitation”. Atmos Environ. (2006).
[6] Andronache C, et al., “A Scavenging of ultrafine particles rainfall ata boreal site:observationandmodel estimations”. Atmos
Chem Phys. (2006).
[7] Kreidenweis SM, et al., “Modification of aerosol mass and size distribution due to aqueous-phase SO2 oxidation in clouds:
Comparison of several models”. J Geophys Res. (2003).
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 11 Issue: 01 | Jan 2024 www.irjet.net p-ISSN: 2395-0072
© 2024, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 547
[8] L. Zhang, et al., “Numerical studies of aerosol scavenging by low-level, warm stratiform clouds and precipitation,”
Atmospheric Environment, vol. (2004).
[9] K. F. Li, et al., “Analysis on precipitation scavenging on PM10 and PM2.5 in central and south of Beijing-Tianjin-hebei
region,” Journal of Arid Land Resources and Environment, (2019).
[10] Zhang X, et al., “Aerosol characteristics includingfumigation effectunder weak precipitationoverthesoutheasterncoastof
China”. J Atmos. Phy. (2012).

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PM10 CONCENTRATION CHANGES AS A RESULT OF WIDESPRING PRECIPITATION IN AGRA

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 11 Issue: 01 | Jan 2024 www.irjet.net p-ISSN: 2395-0072 © 2024, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 543 PM10 CONCENTRATION CHANGES AS A RESULT OF WIDESPRING PRECIPITATION IN AGRA Kalpana Singh*, Dr. Randhir Singh Indolia, Department of Physics, Dr. Bhimrao Ambedkar University, Agra (U.P), India ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - - From 2021 to 2022, research was conducted at the Sanjay Place site to examine the impact of widespread precipitation on the decrease in PM₁ₒ concentration. There was a discernible variation in the concentrations of PM₁ₒ particles before and after. There was a noticeable change in the average PM₁ₒ concentration and less PM₁ₒ in the air during periods of precipitation compared to those without. The average PM₁₀ concentration was 101.1µg/m³ and 184.8µg/m³ with and without precipitation. Over the July–September period, the intensity of moderate to light rain was found to have the biggest effect on the decrease in PM₁ₒ concentration. The results showed that the accumulation of aerosol concentration was preventedbycontinuous low intensity rain episodes and that the amount and duration of precipitation have an effect on how Key Words: PM₁ₒ, Atmospheric purification, Precipitation, Meteorological condition 1.INTRODUCTION At the expense of other elements of the natural environment, below-cloud scavenging serves as a key process that enablesthe removal of pollutants from the ground level zone and plays a crucial part in the maintenance of excellent air quality [1]. As a result, it is a crucial step in maintaining the equilibrium between the entrance and outflow of aerosol particles [2]. All mechanisms that cause rain, snow, fog, and ice to wash off particle matter are considered to be a part of wet below-cloud scavenging. According to [3], below-cloud scavenging appears to be more significant than in-cloud scavenging from the perspective of human well-being and the quality of the ground-level zone. This claim is supported by the observation that the particulate matter that poses an immediate threat to human health is primarily released asa resultofbelow-cloudscavenging, with the major mechanism involved being the collision of solidparticles with raindrops [4].The wetaerosol washout processis inherently complicated because it is influenced by a variety of external phenomena,suchasdropsize,particlesize distribution, water chemical composition, rainfall intensity, ambient temperature, as well as the chemical and physical characteristics of drops and aerosol [5]. The bulk particle number, bulk particle mass, or size-resolved particle number and mass concentration can all be used to establish the aerosol scavenging coefficient [6]. Experimental research into below-cloudpurificationcarried out under real-world circumstances focuses on several aspects of this process. The processes are studied both on a complex scale, which includes details of the effectiveness of solid particle removal by specific types of precipitation, and on a specific scale, which can include the effectiveness of scavenging of different types of particulate particles by specific types of precipitation [7]. Transport from outside the area is the primary source of air pollution in addition to local accumulation. Clearly, there is a great deal of uncertainty around the method by which contaminants are removed byprecipitation [8,9].This paper's main goal is to analyze the variability of wet deposition, which istheprocess of removingcoarseparticles,in relationto the length, intensity, and location of precipitation [10]. 2.EXPERIMENTAL 2.1. Study Area. At the Sanjay Place site in Agra city, PM₁₀ aerosol samples and rainwater samples were taken simultaneously. India's Agra isa major city. With the Thar Desert of Rajasthan enclosing two-thirds of its outer limits (SE, W, and NW), it is located in the north central area of India (27.18 N 78.02 E). Agra has 1.6 million people, according to the Census (2011). The summer months in Agra are hot and dry, with daily average temperatures ranging from 21.9 to 48 degrees Celsius, and from 4.2 to 31.7 degrees Celsius in the winter. Agra receives about 736.6 mm of rainfall each year. 2.2. Description of sampling site The study was conducted in Sanjay place site of Agra city from October 2021 to September 2022. Map of sampling site and surroundings are shown in Fig.1. The main causes of air pollution were nearby commercial activity, industrial emissions, and emissions from vehicles. These sources have a significant impact on the site, depending on seasonal variations in wind and direction. Sanjay place is one of the most polluted areas in Agra city.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 11 Issue: 01 | Jan 2024 www.irjet.net p-ISSN: 2395-0072 © 2024, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 544 Fig.1 Map showing study area at Agra city. 2.3. Sample collection PM₁₀ samples were collected by low volume sampler. Three sets of samples were collected before rain, during rain and after rain each at site. The rainfall data was collected by using rain gauge instrument through bottleandfunnel method. Theamount of rain was measured for calculation of rain intensity. The site is free from any obstacles. The PM₁₀ instrument shown in fig.2 and Rain gauge instrument shown in fig.3. Fig.2. PM₁₀ Low Volume sampler Fig.3. Rain gauge 3. RESULT AND DISCUSSION 3.1. Statistical description Table.1 provides a summary of the statistical information thatwasexaminedduringthe2021–2022yearexperiment,including information on the chosen air pollution (PM₁₀), meteorological variables, and precipitation.Rainfall intensity(light,moderate, heavy) plays a crucial role in the removal of PM₁₀ from the troposphere.
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 11 Issue: 01 | Jan 2024 www.irjet.net p-ISSN: 2395-0072 © 2024, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 545 Table 1. PM₁₀ and meteorological parameters characterization Precipitation samples Descriptive statistics PM₁ₒ T (°C) RH (%) WS WD 11 samples avg 135 26.3 70.2 2.19 169.3 min 51 11 30.5 1.04 94 max 281.3 36 82 3.52 267 med 144.6 26 74 2.58 141 Note: T- temperature, RH- relative humidity, WS- wind speed,WD-winddirection,Avg.-average,Med.-median,Min-minimum, Max-maximum, precipitation samples. During large-scale rain events in the cold and warm seasons, the average air temperature was around 19.8°C and 31.8°C respectively. The warm season is characterized by higher relative humidity and lower wind speed than cold season. 3.2. PM₁ₒ concentration with and without precipitation In the case of rainfalls, PM₁₀ concentrations were lower than during the non-precipitation period, and between 101.1 and 184.8, there was a discernible difference in average PM₁₀ concentration. The patternofhourlyPM₁₀concentration variationof precipitation and non-precipitation was quite similar to each other. Quantitatively, the reduction effect of precipitation scavenging in the warm period was higher than in the cold period. The hourly PM₁₀ concentration in thecoldperiodincreased due to a relatively more substantial direct effect of vehicle emissions despite the rainfall. The meteorological parameters also effect the concentration of PM₁₀ during warm and cold periods. Fig. 4 PM₁₀ hourly variations of precipitation and non-precipitation in the cold period.
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 11 Issue: 01 | Jan 2024 www.irjet.net p-ISSN: 2395-0072 © 2024, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 546 Fig. 5 PM₁₀ hourly variations of precipitation and non-precipitation in the warm period. At the Sanjay place site, A comparison was made between the hourly PM₁₀ concentration during periods of rainfall and no precipitation to ascertain the purifying impact of precipitation. 4.CONCLUSION After 6 hours of continuous rain with low to moderate intensity, the warm season had the greatest PM₁₀ concentration reduction. The most frequent duration of rainfall was an hour, and low intensity precipitation predominated. The PM₁₀ concentration measured in the cold and warm periods showed a substantial difference as a result of the differing emission sources and weather conditions. In places with poor air quality, the immediatepurificationeffect broughton bytheoccurrence of moist deposition is reduced to a minimum. Scavenging efficiency greatly depends on the structure of the precipitation. ACKNOWLEDGEMENT Thanks to the Central Pollution Control Board for providing the environmental monitoring data. REFERENCES [1] Goncalves FL, et al., “Modelling and measurements of below cloud scavenging processes in the highly industrialisedregion of Cubatao-Brazil”. Atmos Environ. (2000). [2] Chate DM. Rao P, et al., “Scavenging of aerosols and their chemical species by rain”. Atmos Environ. (2003). [3] Bae SY et al., “Development and evaluation of an expression for polydisperse particle scavenging coefficient for the below- cloud scavenging as a function of rain intensity using the moment method”. Aerosol Sci. (2006). [4] Kim J-E et al., “Factors influencing atmospheric wet deposition of trace elements in rural korea”. Amos Res. (2012). [5] Zhao H, et al., “solution of wet removal of aerosols by precipitation”. Atmos Environ. (2006). [6] Andronache C, et al., “A Scavenging of ultrafine particles rainfall ata boreal site:observationandmodel estimations”. Atmos Chem Phys. (2006). [7] Kreidenweis SM, et al., “Modification of aerosol mass and size distribution due to aqueous-phase SO2 oxidation in clouds: Comparison of several models”. J Geophys Res. (2003).
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 11 Issue: 01 | Jan 2024 www.irjet.net p-ISSN: 2395-0072 © 2024, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 547 [8] L. Zhang, et al., “Numerical studies of aerosol scavenging by low-level, warm stratiform clouds and precipitation,” Atmospheric Environment, vol. (2004). [9] K. F. Li, et al., “Analysis on precipitation scavenging on PM10 and PM2.5 in central and south of Beijing-Tianjin-hebei region,” Journal of Arid Land Resources and Environment, (2019). [10] Zhang X, et al., “Aerosol characteristics includingfumigation effectunder weak precipitationoverthesoutheasterncoastof China”. J Atmos. Phy. (2012).