Pipeline Design for Isothermal, Laminar Flow of Non-Newtonian Fluids
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 RHEOLOGICAL BEHAVIOR OF PURELY VISCOUS
NON-NEWTONIAN FLUIDS
4.1 Experimental Characterization
4.2 Rheological Models
5 PRESSURE DROP-FLOW RATE RELATIONSHIPS
BASED DIRECTLY ON EXPERIMENTAL DATA
5.1 Use of Shear Stress – Shear Rate Data
5.2 Tubular Viscometer Data
6 PRESSURE DROP – FLOW RATE RELATIONSHIPS BASED ON RHEOLOGICAL MODELS
7 LOSSES IN PIPE FITTINGS
7.1 Entrances Losses
7.2 Expansion Effects
7.3 Contraction Losses
7.4 Valves
7.5 Bends
8 EFFECT OF WALL SLIP
9 VELOCITY PROFILES
9.1 Velocity Profile from Experimental Flow-Curve
9.2 Velocity Profile from Rheological Model
9.3 Residence Time Distribution
10 CHECKS ON THE VALIDITY OF THE
DESIGN PROCEDURES
10.1 Rheological Behavior
10.2 Validity of Experimental Data
10.2 Check on Laminar Flow
11 NOMENCLATURE
12 REFERENCES
FIGURES
1 FLOW CURVES FOR PURELY VISCOUS FLUIDS
2 PLOTS OF D∆P/4L VERSUS 32Q/ɳD3 FOR PURELY VISCOUS FLUIDS
3 LOG-LOG PLOT OF t VERSUS ý
4 FLOW CURVE FOR A BINGHAM PLASTIC
5 LOG-LOG PLOT FOR A GENERALIZED BINGHAM
PLASTIC
6 CORRELATION OF ENTRANCE LOSS
7 CORRELATION OF EXPANSION LOSS
8 EFFECT OF “WALL SLIP” ON VELOCITY PROFILE
9 D∆P/4L VERSUS Q/ɳR3 WITH WALL SLIP
10 EVALUATION OFUs WITH Ʈw
11 VARIATION OF Us WITH Ʈw
12 PLOT OF D∆P/4L VERSUS 8 (ū- Us)/D FOR
CONDITIONS OF WALL SLIP
13 CUMULATIVE RESIDENCE TIME DISTRIBUTION
TO POWER LAW FLUIDS
14 EFFECTS OF TUBE LENGTH AND DIAMETER ON
RELATIONSHIP BETWEEN D∆P/4L AND 32Q/ɳD3
Thermal Design Margins for Heat Exchangers
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 TERMINOLOGY
5 REASONS FOR SPECIFYING A DESIGN MARGIN
5.1 Instantaneous Rates
5.2 Future Uprating
5.3 Plant Upsets
5.4 Process Control
5.5 Uncertainties in Properties
5.6 Uncertainties in Design Methods
5.7 Fouling
6 COMBINATION OF DESIGN MARGINS
7 CRITICAL AND NON-CRITICAL DUTIES
7.1 General
7.2 Penalties of Over-design
8 OPTIMIZATION OF EXCHANGER DUTY
9 WAYS OF PROVIDING DESIGN MARGINS
9.1 The Provision of Excess Surface
9.2 Decreasing the Design Temperature Difference
9.3 Increasing the Design Process Throughput
9.4 Increasing the Design Fouling Resistance
9.5 Reducing the Design Process Outlet Temperature Approach
9.6 Adjusting the Physical Properties
10 ACCURACY OF THE DESIGN METHODS FOR SHELL AND TUBE EXCHANGERS
10.1 Pressure Drop
10.2 Heat Transfer
11 SUGGESTED DESIGN MARGINS
11.1 No Phase Change Duties
11.2 Condensers
11.3 Boilers
12 EFFECT OF UNDER- OR OVER-SURFACE ON PERFORMANCE
FIGURES
1 EFFECT OF LENGTH ON EXCHANGER DUTY COUNTERCURRENT FLOW, C* = 1.0
2 EFFECT OF NUMBER OF TUBES ON EXCHANGER PERFORMANCE COUNTERCURRENT FLOW, C* = 1.0, ALL RESISTANCE IN TUBES
3 EFFECT OF TUBE LENGTH ON NUMBER OF TUBES, AREA AND PRESSURE DROP
1. The document discusses procedures for calculating pressure safety valve (PSV) sizes for various scenarios that could lead to overpressure. It covers scenarios like closed outlets, external fires, control valve failures, hydraulic expansion, heat exchanger tube ruptures, and power or cooling failures.
2. Calculation methods include enthalpy balances for fractionating columns and the use of relief equations specified in codes like API 521. Worst cases are chosen from all possible scenarios to determine the required PSV size.
3. Key scenarios discussed in detail include closed outlets on vessels, external fires, failures of automatic controls, hydraulic expansion, heat exchanger tube ruptures, total and partial power failures, reflux losses,
Juan Pablo Hernández presented information on control valve sizing for compressible fluids. Control valves are used to meet process conditions and product quality specifications. Three methods for sizing control valves were compared: hand made calculations, Fisher software, and Aspen Hysys simulation. All three methods produced similar results for the example case of sizing a control valve for superheated steam. However, the Fisher software was identified as the preferred method due to providing reliable sizing in less time compared to hand calculations.
CENTRIFUGAL COMPRESSOR SETTLE OUT CONDITIONS TUTORIALVijay Sarathy
Centrifugal Compressors are a preferred choice in gas transportation industry, mainly due to their ability to cater to varying loads. In the event of a compressor shutdown as a planned event, i.e., normal shutdown (NSD), the anti-surge valve is opened to recycle gas from the discharge back to the suction (thereby moving the operating point away from the surge line) and the compressor is tripped via the driver (electric motor or Gas turbine / Steam Turbine). In the case of an unplanned event, i.e., emergency shutdown such as power failure, the compressor trips first followed by the anti-surge valve opening. In doing so, the gas content in the suction side & discharge side mix.
Therefore, settle out conditions is explained as the equilibrium pressure and temperature reached in the compressor piping and equipment volume following a compressor shutdown
Safety is the most important factor in designing a process system. Some undesired conditions might happen leading to damage in a system. Control systems might be installed to prevent such conditions, but a second safety device is also needed. One kind of safety device which is commonly used in the processing industry is the relief valve. A relief valve is a type of valve to control or limit the pressure in a system by allowing the pressurised fluid to flow out from the system.
Excel sheet Download Link: https://www.scribd.com/document/385945712/PSV-Sizing-Tool-API-Based-Calc-Sheets
PSV Sizing for Blocked Liquid Discharge Condition
PSV Sizing for Blocked Gas Discharge Condition
PSV Sizing for Fire Case of Liquid Filled Vessel
PSV Sizing for Control Valve Fail Open Case
Relief Valve Sizing for Thermal Expansion
Restriction Orifice Sizing for Gas Flow
Restriction Orifice Sizing for Liquid Flow
Single Phase Flow Line Sizing Tool
Gas Control Valve Sizing Tool
Thermal Design Margins for Heat Exchangers
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 TERMINOLOGY
5 REASONS FOR SPECIFYING A DESIGN MARGIN
5.1 Instantaneous Rates
5.2 Future Uprating
5.3 Plant Upsets
5.4 Process Control
5.5 Uncertainties in Properties
5.6 Uncertainties in Design Methods
5.7 Fouling
6 COMBINATION OF DESIGN MARGINS
7 CRITICAL AND NON-CRITICAL DUTIES
7.1 General
7.2 Penalties of Over-design
8 OPTIMIZATION OF EXCHANGER DUTY
9 WAYS OF PROVIDING DESIGN MARGINS
9.1 The Provision of Excess Surface
9.2 Decreasing the Design Temperature Difference
9.3 Increasing the Design Process Throughput
9.4 Increasing the Design Fouling Resistance
9.5 Reducing the Design Process Outlet Temperature Approach
9.6 Adjusting the Physical Properties
10 ACCURACY OF THE DESIGN METHODS FOR SHELL AND TUBE EXCHANGERS
10.1 Pressure Drop
10.2 Heat Transfer
11 SUGGESTED DESIGN MARGINS
11.1 No Phase Change Duties
11.2 Condensers
11.3 Boilers
12 EFFECT OF UNDER- OR OVER-SURFACE ON PERFORMANCE
FIGURES
1 EFFECT OF LENGTH ON EXCHANGER DUTY COUNTERCURRENT FLOW, C* = 1.0
2 EFFECT OF NUMBER OF TUBES ON EXCHANGER PERFORMANCE COUNTERCURRENT FLOW, C* = 1.0, ALL RESISTANCE IN TUBES
3 EFFECT OF TUBE LENGTH ON NUMBER OF TUBES, AREA AND PRESSURE DROP
1. The document discusses procedures for calculating pressure safety valve (PSV) sizes for various scenarios that could lead to overpressure. It covers scenarios like closed outlets, external fires, control valve failures, hydraulic expansion, heat exchanger tube ruptures, and power or cooling failures.
2. Calculation methods include enthalpy balances for fractionating columns and the use of relief equations specified in codes like API 521. Worst cases are chosen from all possible scenarios to determine the required PSV size.
3. Key scenarios discussed in detail include closed outlets on vessels, external fires, failures of automatic controls, hydraulic expansion, heat exchanger tube ruptures, total and partial power failures, reflux losses,
Juan Pablo Hernández presented information on control valve sizing for compressible fluids. Control valves are used to meet process conditions and product quality specifications. Three methods for sizing control valves were compared: hand made calculations, Fisher software, and Aspen Hysys simulation. All three methods produced similar results for the example case of sizing a control valve for superheated steam. However, the Fisher software was identified as the preferred method due to providing reliable sizing in less time compared to hand calculations.
CENTRIFUGAL COMPRESSOR SETTLE OUT CONDITIONS TUTORIALVijay Sarathy
Centrifugal Compressors are a preferred choice in gas transportation industry, mainly due to their ability to cater to varying loads. In the event of a compressor shutdown as a planned event, i.e., normal shutdown (NSD), the anti-surge valve is opened to recycle gas from the discharge back to the suction (thereby moving the operating point away from the surge line) and the compressor is tripped via the driver (electric motor or Gas turbine / Steam Turbine). In the case of an unplanned event, i.e., emergency shutdown such as power failure, the compressor trips first followed by the anti-surge valve opening. In doing so, the gas content in the suction side & discharge side mix.
Therefore, settle out conditions is explained as the equilibrium pressure and temperature reached in the compressor piping and equipment volume following a compressor shutdown
Safety is the most important factor in designing a process system. Some undesired conditions might happen leading to damage in a system. Control systems might be installed to prevent such conditions, but a second safety device is also needed. One kind of safety device which is commonly used in the processing industry is the relief valve. A relief valve is a type of valve to control or limit the pressure in a system by allowing the pressurised fluid to flow out from the system.
Excel sheet Download Link: https://www.scribd.com/document/385945712/PSV-Sizing-Tool-API-Based-Calc-Sheets
PSV Sizing for Blocked Liquid Discharge Condition
PSV Sizing for Blocked Gas Discharge Condition
PSV Sizing for Fire Case of Liquid Filled Vessel
PSV Sizing for Control Valve Fail Open Case
Relief Valve Sizing for Thermal Expansion
Restriction Orifice Sizing for Gas Flow
Restriction Orifice Sizing for Liquid Flow
Single Phase Flow Line Sizing Tool
Gas Control Valve Sizing Tool
The document summarizes the basics of pressure relief devices, including why they are required, common components, classification and types. It provides examples of relief scenarios and causes of overpressure. The key steps in relief device sizing calculations are outlined. An example calculation is shown for checking the adequacy of installed relief devices for a reactor system during an emergency relief scenario involving an external fire.
This document discusses overpressure scenarios and required relief rates for process equipment. It identifies key data needed for the analysis such as P&IDs and equipment specifications. Common overpressure scenarios are described such as fires, control valve failures, thermal expansion, and utility failures. Industry guidelines for analyzing these scenarios are presented. Methods for determining applicable scenarios, calculating relief rates, and addressing special cases like gas blowby are outlined. The document stresses being conservative in initial analysis and reviewing all relevant guidelines.
Heating and Cooling of Batch Processes
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
3.1 units
4 STATEMENT OF THE PROBLEM
5 DEVELOPMENT OF THE METHOD
5.1 Assumptions
5.2 Basic Equations
6 APPLICATION OF THE METHOD
6.1 Determining the Behavior of an Existing System
6.2 Specifying the Heat Transfer Duty for a New System
APPENDICES
A DERIVATION OF THE EQUATIONS
B WORKED EXAMPLES
FIGURES
1 CASES CONSIDERED
This document discusses separator design and sizing. It describes different separator configurations including horizontal and vertical separators. It also discusses the use of demisters to remove liquid mist. The document outlines how to size separators using parameters like flow rates, pressures, temperatures and physical properties. It presents methods for sizing separators using computer simulations, hand calculations and industry standards. Sample calculations are shown for various separator cases with and without demisters. Design specifications like diameter, length and L/D ratios are compared between the different methods. The summary reiterates the key steps and outcomes of separator sizing.
The Design and Layout of Vertical Thermosyphon ReboilersGerard B. Hawkins
The Design and Layout of Vertical Thermosyphon Reboilers
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 THE DESIGN PROBLEM
5 COMPUTER PROGRAMS
6 GENERAL CONSIDERATIONS
6.1 Heating Medium Temperature
6.2 Fouling Resistance
7 DESIGN PARAMETERS
7.1 Overall Arrangement and Specifications
7.2 Geometry Elements
8 ANALYSIS OF COMMERCIALLY AVAILABLE
PROGRAM RESULTS
8.1 Main Results
8.2 Supplementary Results
8.3 Error Analysis
8.4 Adjustments to Design
9 OPERATING RANGE
10 CONTROL
10.1 Control of Condensing Heating Medium Pressure
10.2 Control of The Condensate Level
10.3 Control of Sensible Fluid Flow Rate
11 LAYOUT
11.1 Factors Influencing Design
11.2 A Standard Layout
12 BIBLIOGRAPHY
Pressure Safety Valve Sizing - API 520/521/526Vijay Sarathy
No chemical process facility is immune to the risk of overpressure to avoid dictating the necessity for overpressure protection. For every situation that demands safe containment of process gas, it becomes an obligation for engineers to equally provide pressure relieving and flaring provisions wherever necessary. The levels of protection are hierarchical, starting with designing an inherently safe process to avoid overpressure followed by providing alarms for operators to intervene and Emergency Shutdown provisions through ESD and SIL rated instrumentation. Beyond these design and instrument based protection measures, the philosophy of containment and abatement steps such as pressure relieving devices, flares, physical dikes and Emergency Response Services is employed
Basics of two phase flow (gas-liquid) line sizingVikram Sharma
This document discusses two-phase flow line sizing for liquid-gas flows in piping systems. It describes the different flow regimes that can occur using Baker's flow regime map. The key steps outlined are: 1) determining the flow regime based on fluid properties and flow rates, 2) calculating pressure drops for the liquid and gas phases separately using correlations, 3) using a multiplier to determine the two-phase pressure drop based on the flow regime, and 4) summing pressure drops from friction, elevation changes, and fittings to obtain the total pressure drop. Care must be taken to size each pipe segment separately as properties and regimes can change along the line.
This document outlines a continuing education course on overpressure protection and relief system design. The course contents include an introduction to relief systems, applicable codes and standards, the work process for relief system design, relief device terminology, and causes of overpressure and determining relief loads. The presentation provides information on different types of relief devices, relief system discharge configurations, references and codes, and the multi-step design process and required design data. Key relief device terminology is also defined.
This document summarizes API STD 521 Part-I, which provides guidance on overpressure protection for refinery equipment. It discusses overpressure causes and protection philosophies. It also lists the minimum recommended contents for relief system designs and flare header calculations. These include analyzing overpressure causes, operating conditions, relief device sizing, and documentation of simulation inputs and outputs. Various overpressure causes are outlined, such as closed outlets, absorbent or cooling failures, accumulation of non-condensables, abnormal heat input, explosions, and depressurizing. Protection measures against these causes like relief valves, rupture disks, and explosion prevention are also mentioned.
Definition and selection of design temperature and pressure prg.gg.gen.0001Efemena Doroh
This document provides guidelines for determining the design temperature and pressure of equipment and piping for oil and chemical plants. It defines key terms like operating temperature, design temperature, minimum metal temperature, and design pressure. It outlines general criteria for setting design temperature, such as adding 30°C to the maximum operating temperature below 343°C. It also provides special considerations and guidelines for various equipment types. Minimum design metal temperature should be set to avoid material brittleness at low temperatures and pressures.
This document discusses pressure relief systems, which are critical in the chemical process industries to safely handle overpressurization. It describes causes of overpressurization, types of safety valves and rupture disks used for relief, and components of open and closed pressure relief systems. Open systems vent non-hazardous gases to the atmosphere, while closed systems route flammable gases through flare headers and knockout drums to be burned in a flare stack. The document provides example calculations for sizing relief valves, piping, and other components to ensure systems can safely relieve pressure without resealing valves.
Gas Compression Stages – Process Design & OptimizationVijay Sarathy
The following tutorial demonstrates how to estimate the required number of compression stages and optimize the individual pressure ratio in a multistage centrifugal compression system.
This document summarizes the key steps in designing liquid pipelines according to API 14E standards. It discusses important considerations like ensuring velocity is below 15 feet per second to avoid erosion and pressure drop is below 1 psi per 100 feet. The document then provides an example calculation for sizing a water pipeline using schedule 40 and 80 steel pipes. It determines that an 8-inch schedule 40 pipe meets both velocity and pressure drop requirements and has the lowest annual operating costs.
Troubleshooting in Distillation Columns
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 FLOW DIAGRAM FOR TROUBLESHOOTING
5 GENERAL APPRAISAL OF PROBLEM
5.1 Is the Problem Real?
5.2 What Is the Magnitude of the Problem?
5.3 Is it the Column or the Associated Equipment which is Causing the Problem?
6 PROBLEMS IN THE COLUMN
6.1 Capacity Problems
6.2 Efficiency Problems
7 PROBLEMS OUTSIDE THE COLUMN
7.1 Effect of Other Units on Column Performance
7.2 Column Control System
7.3 Improper Operating Conditions
7.4 Auxiliary Equipment
8 USEFUL BACKGROUND READING
9 BIBLIOGRAPHY
FIGURES
1 FLOW DIAGRAM FOR TROUBLESHOOTING
2 DETERMINATION OF COLUMN CAPACITY
This document provides guidelines for selecting, sizing, and specifying relief devices such as pressure relief valves and rupture disks. It discusses general criteria for relief device selection, mechanical design considerations, and specific selection criteria for different services. It also covers relief device calculations, requisitioning, specifications, identification, protection, packaging, and documentation. The guidelines are based on standards from ASME, API, and ISO, and are intended to help achieve maximum technical and economic benefit from standardization when designing oil, gas, chemical, and other processing facilities.
Control of Continuous Distillation Columns
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 GENERAL DESCRIPTION OF A DISTILLATION COLUMN
5 REGULATORY CONTROL
5.1 Composition Control
5.2 Mass Balance Control
5.3 Design of Feedback Control Systems
5.4 Pressure and Condensation Control
5.5 Reboiler Control
6 DISTURBANCE COMPENSATION
6.1 Feed-forward Control
6.2 Cascade Control
6.3 Internal Reflux Control
7 CONSTRAINT CONTROL
7.1 Override Controls
7.2 Flooding
7.3 Limiting Control
8 MORE ADVANCED TOPICS
8.1 Temperature Position Control
8.2 Inferential Measurement
8.1 Floating Pressure Control
8.2 Model Based Predictive Control
8.1 Control of Side-streams
8.2 Extractive/Azeotropic Systems
9 REFERENCES
TABLES
1 SYMPTOMS OF IMBALANCE AND THE REGULATORY VARIABLES
2 PRACTICAL LINKAGES BETWEEN CONTROL
(P, R, B, C) AND REGULATION VARIABLES
(h, r, d, b, c, v)
3 COMPOSITION REGULATION
4 COMPOSITION REGULATION - VERY SMALL FLOWS
Sizing of relief valves for supercritical fluidsAlexis Torreele
The document provides an overview of Jacobs, an engineering company, and discusses their approach to sizing relief valves for supercritical fluids. It then presents a case study example of calculating the relief requirements for a vessel containing methane undergoing an external fire. The key steps involve: (1) gathering process data; (2) determining heat input from the fire; (3) calculating fluid properties as temperature increases; (4) determining mass and volume relief rates; (5) calculating choked flow rates; and (6) sizing the required relief valve orifice. The example demonstrates that relief of supercritical fluids can involve complex two-phase flow that requires specialized modeling approaches.
Centrifugal Compressors
SECTION ONE - ANTI-SURGE PROTECTION AND THROUGHPUT REGULATION
0 INTRODUCTION
1 SCOPE
2 MACHINE CHARACTERISTICS
2.1 Characteristics of a Single Compressor Stage
2.2 Characteristic of a Multiple Stage Having More
Than One Impeller
2.3 Use of Compressor Characteristics in Throughput
Regulation Schemes
3 MECHANISM AND EFFECTS OF SURGE
3.1 Basic Flow Instabilities
3.2 Occurrence of Surge
3.3 Intensity of Surge
3.4 Effects of Surge
3.5 Avoidance of Surge
3.6 Recovery from Surge
4 CONTROL SCHEMES INCLUDING SURGE PROTECTION
4.1 Output Control
4.2 Surge Protection
4.3 Surge Detection and Recovery
5 DYNAMIC CONSIDERATIONS
5.1 Interaction
5.2 Speed of Response of Antisurge Control System
6 SYSTEM EQUIPMENT SPECIFICATIONS
6.1 The Antisurge Control Valve
6.2 Non-return Valve
6.3 Pressure and flow measurement
6.4 Signal transmission
6.5 Controllers
7 TESTING
7.1 Determination of the Surge Line
7.2 Records
8 INLET GUIDE VANE UNITS
8.1 Application
8.2 Effect on Power Consumption of the Compressor
8.3 Effect of Gas Conditions, Properties and Contaminants
8.4 Aerodynamic Considerations
8.5 Control System Linearity
8.6 Actuator Specification
8.7 Avoidance of Surge
8.8 Features of Link Mechanisms
8.9 Limit Stops and Shear Links
APPENDICES
A LIST OF SYMBOLS AND PREFERRED UNITS
B WORKED EXAMPLE 1 COMPRESSOR WITH VARIABLE INLET PRESSURE AND VARIABLE GAS COMPOSITION
C WORKED EXAMPLE 2 A CONSTANT SPEED ~ STAGE COMPRESSOR WITH INTER-COOLING
D WORKED EXAMPLE 3 DYNAMIC RESPONSE OF THE ANTISURGE PROTECTION SYSTEM FOR A SERVICE AIR COMPRESSOR RUNNING AT CONSTANT SPEED
E EXAMPLE OF INLET GUIDE VANE REGULATION
FIGURES
2.1 TYPICAL COMPRESSOR STAGE CHARACTERISTIC PLOTTED WITH FLOW AT DISCHARGE CONDITIONS
2.2 TYPICAL COMPRESSOR STAGE CHARACTERISTIC PLOTTED WITH FLOW AT INLET CONDITIONS
2.3 PERFORMANCE CHARACTERISTICS OF A COMPRESSOR STAGE AT VARYING SPEEDS
2.4 SYSTEM WORKING POINT DEFINED BY INTERSECTION OF PROCESS AND COMPRESSOR CHARACTERISTICS
2.5 DISCHARGE THROTTLE REGULATION
2.6 BYPASS REGULATION
2.7 INLET THROTTLE REGULATION
2.8 INLET GUIDE VANE REGULATION
2.9 VARIABLE SPEED REGULATION
3.1 GAS PULSATION LEVELS FOR A CENTRIFUGAL COMPRESSOR
3.2 REPRESENTATION OF CYCLIC FLOW DURING SURGE OF LONG PERIOD
3.3 TYPICAL WAVEFORM OF DISCHARGE PRESSURE DURING SURGE
3.4 MULTIPLE SURGE LINE FOR A MULTISTAGE CENTRIFUGAL COMPRESSOR
3.5 TYPICAL MULTIPLE SURGE LINES FOR SINGLE STAGE AXIAL-FLOW COMPRESSOR
4.1 GENERAL SCHEMATIC FOR COMPRESSORS OPERATING IN PARALLEL TO FEED MULTIPLE USER PLANTS
4.2 ILLUSTRATION OF SAFETY MARGIN BETWEEN SURGE POINT AND SURGE PROTECTION POINT AT WHICH ANTISURGE SYSTEM IS ACTIVATED
4.3 ANTISURGE SYSTEM FOR COMPRESSOR WITH FLAT PERFO ..........
Pipeline Design for Isothermal, Turbulent Flow of Non-Newtonian FluidsGerard B. Hawkins
Pipeline Design for Isothermal, Turbulent Flow of Non-Newtonian Fluids
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 DESCRIPTION OF ANOMALOUS EFFECTS
4.1 Wall Slip
4.2 Drag Reduction in Polymeric Materials
4.3 Transition Delay by Polymeric Materials
4.4 Drag Reduction in Suspensions
5 DESIGN PROCEDURE FOR PRESSURE DROP
IN TURBULENT PIPE FLOW IN THE ABSENCE
OF DRAG REDUCTION
5.1 Pressure Drop in the Absence of Wall Slip and
Drag Reduction
5.2 Wall Slip
5.3 Pipe Roughness
5.4 Pipe Fittings
6 DESIGN PROCEDURE FOR DRAG REDUCING
POLYMERIC MATERIALS
6.1 General
6.2 Transition Delay
6.3 Pipe Roughness
6.4 Pipe Fittings
7 DESIGN PROCEDURE FOR DRAG REDUCING
FIBRE SUSPENSIONS
8 BIBLIOGRAPHY
9 NOMENCLATURE
FIGURES
1 DRAG REDUCTION PHENOMENA
2 TRANSITION DELAY PHENOMENA
3 PROCEDURE FOR THE CALCULATION OF
PRESSURE DROP IN TURBULENT NON-NEWTONIAN
PIPE FLOW
4 TYPICAL RELATIONSHIP FOR Ψ VERSUS ʋ*
Turbulent Heat Transfer to Non Newtonian Fluids in Circular TubesGerard B. Hawkins
Turbulent Heat Transfer to Non Newtonian Fluids in Circular Tubes
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 THE INTEGRATION OF THE ENERGY EQUATION
5 THE EDDY VISCOSITY FOR NON-NEWTONIAN AND DRAG REDUCING FLUIDS
6 THE CALCULATION OF HEAT TRANSFER
COEFFICIENTS FOR NON-NEWTONIAN AND DRAG
REDUCING FLUIDS IN TURBULENT PIPE FLOW
6.1 General
6.2 Drag Reducing Fibre Suspensions
6.3 Transition Delay
7 NOMENCLATURE
8 BIBLIOGRAPHY
The document summarizes the basics of pressure relief devices, including why they are required, common components, classification and types. It provides examples of relief scenarios and causes of overpressure. The key steps in relief device sizing calculations are outlined. An example calculation is shown for checking the adequacy of installed relief devices for a reactor system during an emergency relief scenario involving an external fire.
This document discusses overpressure scenarios and required relief rates for process equipment. It identifies key data needed for the analysis such as P&IDs and equipment specifications. Common overpressure scenarios are described such as fires, control valve failures, thermal expansion, and utility failures. Industry guidelines for analyzing these scenarios are presented. Methods for determining applicable scenarios, calculating relief rates, and addressing special cases like gas blowby are outlined. The document stresses being conservative in initial analysis and reviewing all relevant guidelines.
Heating and Cooling of Batch Processes
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
3.1 units
4 STATEMENT OF THE PROBLEM
5 DEVELOPMENT OF THE METHOD
5.1 Assumptions
5.2 Basic Equations
6 APPLICATION OF THE METHOD
6.1 Determining the Behavior of an Existing System
6.2 Specifying the Heat Transfer Duty for a New System
APPENDICES
A DERIVATION OF THE EQUATIONS
B WORKED EXAMPLES
FIGURES
1 CASES CONSIDERED
This document discusses separator design and sizing. It describes different separator configurations including horizontal and vertical separators. It also discusses the use of demisters to remove liquid mist. The document outlines how to size separators using parameters like flow rates, pressures, temperatures and physical properties. It presents methods for sizing separators using computer simulations, hand calculations and industry standards. Sample calculations are shown for various separator cases with and without demisters. Design specifications like diameter, length and L/D ratios are compared between the different methods. The summary reiterates the key steps and outcomes of separator sizing.
The Design and Layout of Vertical Thermosyphon ReboilersGerard B. Hawkins
The Design and Layout of Vertical Thermosyphon Reboilers
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 THE DESIGN PROBLEM
5 COMPUTER PROGRAMS
6 GENERAL CONSIDERATIONS
6.1 Heating Medium Temperature
6.2 Fouling Resistance
7 DESIGN PARAMETERS
7.1 Overall Arrangement and Specifications
7.2 Geometry Elements
8 ANALYSIS OF COMMERCIALLY AVAILABLE
PROGRAM RESULTS
8.1 Main Results
8.2 Supplementary Results
8.3 Error Analysis
8.4 Adjustments to Design
9 OPERATING RANGE
10 CONTROL
10.1 Control of Condensing Heating Medium Pressure
10.2 Control of The Condensate Level
10.3 Control of Sensible Fluid Flow Rate
11 LAYOUT
11.1 Factors Influencing Design
11.2 A Standard Layout
12 BIBLIOGRAPHY
Pressure Safety Valve Sizing - API 520/521/526Vijay Sarathy
No chemical process facility is immune to the risk of overpressure to avoid dictating the necessity for overpressure protection. For every situation that demands safe containment of process gas, it becomes an obligation for engineers to equally provide pressure relieving and flaring provisions wherever necessary. The levels of protection are hierarchical, starting with designing an inherently safe process to avoid overpressure followed by providing alarms for operators to intervene and Emergency Shutdown provisions through ESD and SIL rated instrumentation. Beyond these design and instrument based protection measures, the philosophy of containment and abatement steps such as pressure relieving devices, flares, physical dikes and Emergency Response Services is employed
Basics of two phase flow (gas-liquid) line sizingVikram Sharma
This document discusses two-phase flow line sizing for liquid-gas flows in piping systems. It describes the different flow regimes that can occur using Baker's flow regime map. The key steps outlined are: 1) determining the flow regime based on fluid properties and flow rates, 2) calculating pressure drops for the liquid and gas phases separately using correlations, 3) using a multiplier to determine the two-phase pressure drop based on the flow regime, and 4) summing pressure drops from friction, elevation changes, and fittings to obtain the total pressure drop. Care must be taken to size each pipe segment separately as properties and regimes can change along the line.
This document outlines a continuing education course on overpressure protection and relief system design. The course contents include an introduction to relief systems, applicable codes and standards, the work process for relief system design, relief device terminology, and causes of overpressure and determining relief loads. The presentation provides information on different types of relief devices, relief system discharge configurations, references and codes, and the multi-step design process and required design data. Key relief device terminology is also defined.
This document summarizes API STD 521 Part-I, which provides guidance on overpressure protection for refinery equipment. It discusses overpressure causes and protection philosophies. It also lists the minimum recommended contents for relief system designs and flare header calculations. These include analyzing overpressure causes, operating conditions, relief device sizing, and documentation of simulation inputs and outputs. Various overpressure causes are outlined, such as closed outlets, absorbent or cooling failures, accumulation of non-condensables, abnormal heat input, explosions, and depressurizing. Protection measures against these causes like relief valves, rupture disks, and explosion prevention are also mentioned.
Definition and selection of design temperature and pressure prg.gg.gen.0001Efemena Doroh
This document provides guidelines for determining the design temperature and pressure of equipment and piping for oil and chemical plants. It defines key terms like operating temperature, design temperature, minimum metal temperature, and design pressure. It outlines general criteria for setting design temperature, such as adding 30°C to the maximum operating temperature below 343°C. It also provides special considerations and guidelines for various equipment types. Minimum design metal temperature should be set to avoid material brittleness at low temperatures and pressures.
This document discusses pressure relief systems, which are critical in the chemical process industries to safely handle overpressurization. It describes causes of overpressurization, types of safety valves and rupture disks used for relief, and components of open and closed pressure relief systems. Open systems vent non-hazardous gases to the atmosphere, while closed systems route flammable gases through flare headers and knockout drums to be burned in a flare stack. The document provides example calculations for sizing relief valves, piping, and other components to ensure systems can safely relieve pressure without resealing valves.
Gas Compression Stages – Process Design & OptimizationVijay Sarathy
The following tutorial demonstrates how to estimate the required number of compression stages and optimize the individual pressure ratio in a multistage centrifugal compression system.
This document summarizes the key steps in designing liquid pipelines according to API 14E standards. It discusses important considerations like ensuring velocity is below 15 feet per second to avoid erosion and pressure drop is below 1 psi per 100 feet. The document then provides an example calculation for sizing a water pipeline using schedule 40 and 80 steel pipes. It determines that an 8-inch schedule 40 pipe meets both velocity and pressure drop requirements and has the lowest annual operating costs.
Troubleshooting in Distillation Columns
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 FLOW DIAGRAM FOR TROUBLESHOOTING
5 GENERAL APPRAISAL OF PROBLEM
5.1 Is the Problem Real?
5.2 What Is the Magnitude of the Problem?
5.3 Is it the Column or the Associated Equipment which is Causing the Problem?
6 PROBLEMS IN THE COLUMN
6.1 Capacity Problems
6.2 Efficiency Problems
7 PROBLEMS OUTSIDE THE COLUMN
7.1 Effect of Other Units on Column Performance
7.2 Column Control System
7.3 Improper Operating Conditions
7.4 Auxiliary Equipment
8 USEFUL BACKGROUND READING
9 BIBLIOGRAPHY
FIGURES
1 FLOW DIAGRAM FOR TROUBLESHOOTING
2 DETERMINATION OF COLUMN CAPACITY
This document provides guidelines for selecting, sizing, and specifying relief devices such as pressure relief valves and rupture disks. It discusses general criteria for relief device selection, mechanical design considerations, and specific selection criteria for different services. It also covers relief device calculations, requisitioning, specifications, identification, protection, packaging, and documentation. The guidelines are based on standards from ASME, API, and ISO, and are intended to help achieve maximum technical and economic benefit from standardization when designing oil, gas, chemical, and other processing facilities.
Control of Continuous Distillation Columns
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 GENERAL DESCRIPTION OF A DISTILLATION COLUMN
5 REGULATORY CONTROL
5.1 Composition Control
5.2 Mass Balance Control
5.3 Design of Feedback Control Systems
5.4 Pressure and Condensation Control
5.5 Reboiler Control
6 DISTURBANCE COMPENSATION
6.1 Feed-forward Control
6.2 Cascade Control
6.3 Internal Reflux Control
7 CONSTRAINT CONTROL
7.1 Override Controls
7.2 Flooding
7.3 Limiting Control
8 MORE ADVANCED TOPICS
8.1 Temperature Position Control
8.2 Inferential Measurement
8.1 Floating Pressure Control
8.2 Model Based Predictive Control
8.1 Control of Side-streams
8.2 Extractive/Azeotropic Systems
9 REFERENCES
TABLES
1 SYMPTOMS OF IMBALANCE AND THE REGULATORY VARIABLES
2 PRACTICAL LINKAGES BETWEEN CONTROL
(P, R, B, C) AND REGULATION VARIABLES
(h, r, d, b, c, v)
3 COMPOSITION REGULATION
4 COMPOSITION REGULATION - VERY SMALL FLOWS
Sizing of relief valves for supercritical fluidsAlexis Torreele
The document provides an overview of Jacobs, an engineering company, and discusses their approach to sizing relief valves for supercritical fluids. It then presents a case study example of calculating the relief requirements for a vessel containing methane undergoing an external fire. The key steps involve: (1) gathering process data; (2) determining heat input from the fire; (3) calculating fluid properties as temperature increases; (4) determining mass and volume relief rates; (5) calculating choked flow rates; and (6) sizing the required relief valve orifice. The example demonstrates that relief of supercritical fluids can involve complex two-phase flow that requires specialized modeling approaches.
Centrifugal Compressors
SECTION ONE - ANTI-SURGE PROTECTION AND THROUGHPUT REGULATION
0 INTRODUCTION
1 SCOPE
2 MACHINE CHARACTERISTICS
2.1 Characteristics of a Single Compressor Stage
2.2 Characteristic of a Multiple Stage Having More
Than One Impeller
2.3 Use of Compressor Characteristics in Throughput
Regulation Schemes
3 MECHANISM AND EFFECTS OF SURGE
3.1 Basic Flow Instabilities
3.2 Occurrence of Surge
3.3 Intensity of Surge
3.4 Effects of Surge
3.5 Avoidance of Surge
3.6 Recovery from Surge
4 CONTROL SCHEMES INCLUDING SURGE PROTECTION
4.1 Output Control
4.2 Surge Protection
4.3 Surge Detection and Recovery
5 DYNAMIC CONSIDERATIONS
5.1 Interaction
5.2 Speed of Response of Antisurge Control System
6 SYSTEM EQUIPMENT SPECIFICATIONS
6.1 The Antisurge Control Valve
6.2 Non-return Valve
6.3 Pressure and flow measurement
6.4 Signal transmission
6.5 Controllers
7 TESTING
7.1 Determination of the Surge Line
7.2 Records
8 INLET GUIDE VANE UNITS
8.1 Application
8.2 Effect on Power Consumption of the Compressor
8.3 Effect of Gas Conditions, Properties and Contaminants
8.4 Aerodynamic Considerations
8.5 Control System Linearity
8.6 Actuator Specification
8.7 Avoidance of Surge
8.8 Features of Link Mechanisms
8.9 Limit Stops and Shear Links
APPENDICES
A LIST OF SYMBOLS AND PREFERRED UNITS
B WORKED EXAMPLE 1 COMPRESSOR WITH VARIABLE INLET PRESSURE AND VARIABLE GAS COMPOSITION
C WORKED EXAMPLE 2 A CONSTANT SPEED ~ STAGE COMPRESSOR WITH INTER-COOLING
D WORKED EXAMPLE 3 DYNAMIC RESPONSE OF THE ANTISURGE PROTECTION SYSTEM FOR A SERVICE AIR COMPRESSOR RUNNING AT CONSTANT SPEED
E EXAMPLE OF INLET GUIDE VANE REGULATION
FIGURES
2.1 TYPICAL COMPRESSOR STAGE CHARACTERISTIC PLOTTED WITH FLOW AT DISCHARGE CONDITIONS
2.2 TYPICAL COMPRESSOR STAGE CHARACTERISTIC PLOTTED WITH FLOW AT INLET CONDITIONS
2.3 PERFORMANCE CHARACTERISTICS OF A COMPRESSOR STAGE AT VARYING SPEEDS
2.4 SYSTEM WORKING POINT DEFINED BY INTERSECTION OF PROCESS AND COMPRESSOR CHARACTERISTICS
2.5 DISCHARGE THROTTLE REGULATION
2.6 BYPASS REGULATION
2.7 INLET THROTTLE REGULATION
2.8 INLET GUIDE VANE REGULATION
2.9 VARIABLE SPEED REGULATION
3.1 GAS PULSATION LEVELS FOR A CENTRIFUGAL COMPRESSOR
3.2 REPRESENTATION OF CYCLIC FLOW DURING SURGE OF LONG PERIOD
3.3 TYPICAL WAVEFORM OF DISCHARGE PRESSURE DURING SURGE
3.4 MULTIPLE SURGE LINE FOR A MULTISTAGE CENTRIFUGAL COMPRESSOR
3.5 TYPICAL MULTIPLE SURGE LINES FOR SINGLE STAGE AXIAL-FLOW COMPRESSOR
4.1 GENERAL SCHEMATIC FOR COMPRESSORS OPERATING IN PARALLEL TO FEED MULTIPLE USER PLANTS
4.2 ILLUSTRATION OF SAFETY MARGIN BETWEEN SURGE POINT AND SURGE PROTECTION POINT AT WHICH ANTISURGE SYSTEM IS ACTIVATED
4.3 ANTISURGE SYSTEM FOR COMPRESSOR WITH FLAT PERFO ..........
Pipeline Design for Isothermal, Turbulent Flow of Non-Newtonian FluidsGerard B. Hawkins
Pipeline Design for Isothermal, Turbulent Flow of Non-Newtonian Fluids
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 DESCRIPTION OF ANOMALOUS EFFECTS
4.1 Wall Slip
4.2 Drag Reduction in Polymeric Materials
4.3 Transition Delay by Polymeric Materials
4.4 Drag Reduction in Suspensions
5 DESIGN PROCEDURE FOR PRESSURE DROP
IN TURBULENT PIPE FLOW IN THE ABSENCE
OF DRAG REDUCTION
5.1 Pressure Drop in the Absence of Wall Slip and
Drag Reduction
5.2 Wall Slip
5.3 Pipe Roughness
5.4 Pipe Fittings
6 DESIGN PROCEDURE FOR DRAG REDUCING
POLYMERIC MATERIALS
6.1 General
6.2 Transition Delay
6.3 Pipe Roughness
6.4 Pipe Fittings
7 DESIGN PROCEDURE FOR DRAG REDUCING
FIBRE SUSPENSIONS
8 BIBLIOGRAPHY
9 NOMENCLATURE
FIGURES
1 DRAG REDUCTION PHENOMENA
2 TRANSITION DELAY PHENOMENA
3 PROCEDURE FOR THE CALCULATION OF
PRESSURE DROP IN TURBULENT NON-NEWTONIAN
PIPE FLOW
4 TYPICAL RELATIONSHIP FOR Ψ VERSUS ʋ*
Turbulent Heat Transfer to Non Newtonian Fluids in Circular TubesGerard B. Hawkins
Turbulent Heat Transfer to Non Newtonian Fluids in Circular Tubes
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 THE INTEGRATION OF THE ENERGY EQUATION
5 THE EDDY VISCOSITY FOR NON-NEWTONIAN AND DRAG REDUCING FLUIDS
6 THE CALCULATION OF HEAT TRANSFER
COEFFICIENTS FOR NON-NEWTONIAN AND DRAG
REDUCING FLUIDS IN TURBULENT PIPE FLOW
6.1 General
6.2 Drag Reducing Fibre Suspensions
6.3 Transition Delay
7 NOMENCLATURE
8 BIBLIOGRAPHY
Physical Properties for Heat Exchanger Design
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 COMPONENT PROPERTIES
4.1 General
4.2 Use of Component Properties for Mixtures
5 INPUT OF MIXTURE CURVES
5.1 General
5.2 Generation of the Mixture Curves
5.3 Selection of Temperature Points
5.4 Extrapolation
6 IMMISCIBLE CONDENSATES
FIGURES
1 TEMPERATURE POINTS SELECTED FOR EQUAL ENTHALPY CHANGE
2 TEMPERATURE POINTS SELECTED FOR GOOD
FIT TO CURVE
How to use the GBHE Reactor Technology Guides
0 INTRODUCTION / PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 BACKGROUND
5 THE DECISION TREE
6 GBHE REACTION ENGINEERING
7 GENERAL ASPECTS OF REACTOR TECHNOLOGY
7.1 Criteria of Reactor Performance
7.2 Factors of Economic Importance
7.3 Physicochemical Mechanisms
8 GENERAL GUIDE TO SELECTION OF REACTOR TYPE AND OPERATION
8.1 Choice of Reactor Type
8.2 Reaction Mechanism and Kinetics
8.3 Thermodynamics
8.4 Other Factors
9 GENERAL REFERENCES AND SOURCES OF
INFORMATION
APPENDICES
A RELATIONSHIP BEWTEEN DEFINED TERMS
FIGURES
1 DECISION TREE
2 RELATIVE YIELDS OF B FOR BATCH (OR PLUG FLOW) AND CST REACTORS
3 REACTOR SURVEY FORM
Gas-Solid-Liquid Mixing Systems
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 SELECTION OF EQUIPMENT
5 THREE-PHASE MASS TRANSFER WITH CHEMICAL REACTION
6 STIRRED VESSEL DESIGN
6.1 Agitator Design
6.2 Design for Solids Suspension
6.3 Vessel Design
6.4 Gas-Liquid Mass Transfer Coefficient and Surface Area
7 THREE-PHASE FLUIDIZED BEDS
7.1 Gas and Liquid Hold-Up
7.2 Calculation Procedure
7.3 Bubble Size
7.4 Mass Transfer
7.5 Heat Transfer
7.6 Elutriation
8 SLURRY REACTORS
8.1 Gas Rate
8.2 Mass Transfer
9 NOMENCLATURE
10 BIBLIOGRAPHY
Fouling Resistances for Cooling Water
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 GENERAL
5 COOLING WATER FOULING
6 CHROMATE SYSTEMS
6.1 General
6.2 Constraints
6.3 Requirements
6.4 Fouling resistances
7 NON-CHROMATE SYSTEMS
7.1 General
7.2 Requirements and Constraints
7.3 Fouling resistances
8 UNTREATED COOLING WATER
9 MATERIALS OTHER THAN MILD STEEL
APPENDICES
A FOULING RESISTANCES FOR COOLING WATER
B FOULING FILM THICKNESS
How to Use the GBHE Mixing Guides
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 THE MIXING GUIDES
4.1 Mixing Guides
4.2 GBHE Mixing and Agitation Manual
5 DEVICE SELECTION
6 MIXING QUESTIONNAIRE
6.1 What is being mixed?
6.2 Why is it being mixed?
6.3 How is it to be mixed?
6.4 Is Heat Transfer Important?
6.5 Is Mixing Time Important?
6.6 Is Inventory Important?
6.7 Is Subsequent Phase Separation Important?
6.8 What Quantities?
6.9 What are the Selection Criteria?
6.10 What Data are required?
7 BASICS
7.1 Bulk Movement
7.2 Shear and Elongation
7.3 Turbulent Diffusion
7.4 Molecular Diffusion
7.5 Mixing Mechanisms
APPENDICES
A ROTATING MIXING DEVICES
B MIXING DEVICES WITHOUT MOVING PARTS
Shortcut Methods of Distillation Design
0 INTRODUCTION/PURPOSE
1 SCOPE
2 ESTIMATIONOF PLATEAGE AND REFLUX
REQUIREMENTS
2.1 Generalized Procedure for Nmin and Rmin
2.2 Equation based Procedure for Nmin and Rmin
3 PREDICTION OF OVERALL PLATE EFFICIENCY
4 SIZING OF MAIN PLANT ITEMS
4.1 Column Diameter
4.2 Surface Area of Condensers and Reboilers
FIGURES
1 NON-IDEAL EQUILIBRIUM CURVE
2 AT A GLANCE CHART BASED ON FENSKE,
UNDERWOOD
3 PLATE EFFICIENCY CORRELATION OF O’CONNEL
Design and Rating of Packed Distillation Columns
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 DESIGN PHILOSOPHY
5 PERFORMANCE GUARANTEES
6 DESCRIPTION OF PACKED COLUMN INTERNALS
7. DESIGN CALCULATIONS
7.1 Selection of Packing Size
7.2 Rough Design
7.3 Detailed Design and Rating
8 LIQUID DISTRIBUTION AND REDISTRIBUTION
8.1 Basic Concepts
8.2 Pour Point Density
8.3 Peripheral Irrigation - the Wall Zone
8.4 Distributor Levelness
8.5 Maximum Bed Height and Liquid Redistribution
9 PRACTICAL ASPECTS OF PACKED COLUMN DESIGN
9.1 Packing
9.2 Support Grid
9.3 Liquid Collector
9.4 Liquid Distributor or Redistributor
9.5 Packing Hold-down Grid
9.6 Reflux or Feed Pipe
9.7 Reboil Return Pipe
9.8 Liquid Draw-offs
9.9 Vapor Draw-offs
10 BIBLIOGRAPHY
APPENDICES
A DEFINITIONS
A.1 INTRODUCTION
A.2 MECHANICAL DEFINITIONS
A.3 PERFORMANCE DEFINITIONS
B PACKING HYDRAULICS - THE NORTON METHOD
TABLES
1 PACKING FACTORS FOR THE MORE COMMON
RANDOM PACKINGS
This document is a guide created by the Oil & Gas Accountability Project (OGAP) to help landowners understand oil and gas development processes and impacts. It outlines the typical stages of development including exploration, field organization, production, and site abandonment. It also describes common extraction methods like seismic testing, drilling, fracturing and discusses associated environmental and community issues. The guide aims to inform landowners of their rights and responsibilities regarding mineral leases and development on their property.
Sachin Gupta has over 7 years of experience as an offshore and onshore pipeline engineer. He has worked on projects in India and the United Arab Emirates involving major clients such as ONGC, MRPL, and Saudi Aramco. Gupta has experience with the full life cycle of pipeline systems including conceptual design, detailed design review, installation engineering, and integrity management. Notable projects he has worked on include the SARB 3 Field Development Project in Abu Dhabi and the MHNRD Phase-3 Pipeline Project in India. Gupta holds a B.Tech in Mechanical Engineering from IIT BHU and is pursuing an MBA in Oil and Gas Management.
This document provides technical data and material specifications for the 37 km pipeline system of the Ogabiri Gas Gathering Project in Nigeria. It includes dimensions, quantities, anti-corrosion coatings, and results from pipeline simulations. The pipeline will connect five flow stations and facilities to transport gas to the Nigerian Gas Company's pipeline network. It discusses the project background, scope of work, and acknowledgements. It also provides illustrations of the pipeline routing and network simulations.
This document discusses components and valves used in pipelines for chemical and pharmaceutical industries. It describes the advantages of using borosilicate glass for these components, including resistance to corrosion and chemicals, transparency for monitoring processes, and suitability for vacuum use. It then provides specifications for various pipe sections, fittings, valves, bends, and crosses made of borosilicate glass and PTFE. Dimensions and part numbers are listed for each item.
This document presents the design of an optimized water pipeline to transport water between two reservoirs located 415 km apart with a change in elevation from 300m to 500m. The optimized design uses a twinned 0.9m diameter pipe for the first 384 km to reduce head losses, and a single 0.9m pipe for the remaining distance. This design, with 7 pumps rather than 8, lowers total costs by $3.2 million compared to the initial single pipeline design. The optimized solution meets all design requirements to deliver 1m3/s of water while minimizing expenditures.
The document describes OPIMsoft's OFFPIPE Assistant Toolbox software for offshore pipeline S-lay design. It allows users to build detailed laybarge and stinger models, run finite element analyses to optimize pipeline bending radius and tension for minimum stress, and output optimized parameters, analysis results and charts. The toolbox includes modules for model building, analysis, parameter optimization, converting stress-strain curves and simulating wave spectra. It aims to improve on traditional manual S-lay design methods.
Solomon Brown (University College London) - Material Considerations in CO2 Pipeline Design: Practical Issues and Ongoing Work - UKCCSRC Cranfield Biannual 21-22 April 2015
TEMPERATURE MEASUREMENT:
RESISTANCE ELEMENTS AND THERMOCOUPLES
SPECIFICATION OF FUNCTION
DESCRIPTION OF FLUID
NORMAL OPERATING TEMPERATURE
REQUIRED TEMPERATURE RANGE
ALARM SETTINGS
TRIP SETTINGS
FLUID VELOCITY
REYNOLDS NUMBER
LINE SIZE
LINE REFERENCE
EQUIPMENT REFERENCE
NOZZLE SIZE
MINIMUM DESIGN PRESSURE
CORRESPONDING TEMPERATURE
MAXIMUM DESIGN PRESSURE
CORRESPONDING TEMPERATURE
GBH Enterprises provides guidelines for managing pressure systems, pressure relief streams, protective devices, and pressure vessels. The document outlines responsibilities for design review, registration, and periodic inspection to ensure safety. It also references national regulations and standards that must be followed.
Reactor Modeling Tools - An Overview
CONTENTS
1 SCOPE
2 OPTIONS IN REACTOR MODELING
2.1 General
2.2 Level of Complexity of Model
2.3 Mode of Operation of Model
2.4 Deterministic versus Empirical Modeling
2.5 Platforms for Model
2.6 Steady State versus Dynamic Model
2.7 Dimensions Modeled in Reactor
2.8 Scale of Modeling for Multiphase Reactors
2.9 Writing and Using the Model
APPENDICES
A CHARACTERISTICS OF DIFFERENT REACTOR MODELS
B NEEDS FOR MODELING AT DIFFERENT SCALES IN
HETEROGENEOUS CATALYTIC REACTORS
C REACTOR MODELS EMPLOYED WITHIN GBHE
DOCUMENTS REFERRED TO IN THIS PROCESS ENGINEERING GUIDE
"SEDIMENTATION"
INTRODUCTION - THE PHENOMENON OF SEDIMENTATION
Sedimentation is the physical process whereby solid particles, of greater density than their suspending medium, will tend to separate into regions of higher concentration under the influence of gravity. As a solids/liquids separation technique it therefore possesses the great advantage of utilizing a natural, and therefore costless, driving force. This section of the suspension processing Guide is Intended to provide an Introduction to the science of the subject, and the means to judge where and how best to exploit sedimentation as a separation (or other processing) technique.
As a scientific discipline the subject of sedimentation is vast with perspectives ranging from the field of chemical engineering through to theoretical physics being covered In the literature [1-11]. Good reviews of the subject, with a bias towards the engineering aspects, have been written by Fitch and Koz [12, 13]. A short summary of some of the more relevant contributions from the literature is also provided in GBHE-SPG-PEG-302 “Basic Principles & Test Methods”, of the Suspensions Processing Guides.
.
The sedimentation process is traditionally divided into ..."
Overflows and Gravity Drainage Systems
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 OUTLINE OF THE PROBLEM
5 DESIGNING FOR FLOODED FLOW
6 DESIGNING NON-FLOODED PIPELINES
6.1 Vertical Pipework
6.2 From the Side of a Vessel
6.3 Established (uniform) Flow in Near-horizontal Pipes
6.4 Non-uniform Flow
7 NON-FLOODED FLOW IN COMPLEX SYSTEMS
8 ENTRAINING FLOW
9 SIMPLE TANK OVERFLOWS
9.1 Venting of the Tank
10 BIBLIOGRAPHY
11 NOMENCLATURE
TABLE
1 GEOMETRICAL FUNCTIONS OF PART-FULL PIPES
FIGURES
1 TYPICAL SEQUENCE OF SURGING FLOW
2 DESIGNING FOR FLOODED FLOW
3 CAPACITY OF SLOPING PIPELINES
4 OVERFLOW FROM SIDE OF VESSEL
5 METHODS OF AVOIDING LARGE CIRCULAR SIDE
OVERFLOWS
6 CAPACITY OF A GENTLY SLOPING PIPE AS A FUNCTION OF LIQUID DEPTH
7 COMPLEX PIPE SYSTEMS
8 REMOVAL OF ENTRAINED GASES
Large Water Pumps
CONTENTS
1 SCOPE
SECTION ONE: INTEGRATION OF PUMPS INTO THE PROCESS
2 PROPERTIES OF FLUID
2.1 Cooling Water
2.2 Brine
2.3 Estuary Water
2.4 Harbor Water
2.5 Oil-field water
3 CALCULATION OF DUTY
4 CHOICE OF TYPE AND NUMBER OF PUMPS
4.1 Type of Pump
4.2 Points to Consider
4.3 Number of Pumps
5 RECOMMENDED LINE DIAGRAM
5.1 Check List for Each Pump
6 RECOMMENDED LAYOUT
SECTION TWO: CONSTRUCTION FEATURES
7 HORIZONTAL, AXIALLY SPLIT CASING PUMPS
7.1 Pressure Casing
7.2 Bolting
7.3 Flanges and Connections
7.4 Rotating Elements
7.5 Wear Rings
7.6 Running Clearances
7.7 Mechanical Seals
7.8 Packed Glands
7.9 Bearings and Bearing Housings
7.10 Lubrication
7.11 Couplings
7.12 Guards
7.13 Baseplates
7.14 Flywheels
8 VERTICAL PUMPS
8.1 General
8.2 Pressure Casing
8.3 Bolting
8.4 Flanges and Connections
8.5 Rotating Element
8.6 Packed Glands
8.7 Bearings and Bearing Housings
8.8 Pump Head
8.9 Column Pipes
8.10 Line Shaft and Couplings
8.11 Reverse Rotation
8.12 Gearboxes
9 MATERIALS
9.1 Castings
9.2 Casings
9.3 Impellers
9.4 Shafts
9.5 Shaft Sleeves
9.6 Bolts and Nuts
10 DRIVERS
10.1 Electric Motor Drives
11 BIBLIOGRAPHY
APPENDICES:
A COOLING WATER - EUROPEAN SITE
B TIDAL RIVER ESTUARY
C FLYWHEEL INERTIA FOR PRESSURE SURGE ABATEMENT
D RESIN COATING OF CASINGS FOR WATER PUMPS
E AREA RATIO METHOD
F NOTES ON PUMP IMPELLERS CASTINGS
G LIMIT ON SHAFT DIAMETER FOR HORIZONTAL PUMPS HAVING
ONE DOUBLE-ENTRY IMPELLER SUPPORTED BETWEEN BEARINGS
H FORCES AND BENDING MOMENTS ON RISING MAIN ASSEMBLY
I POWER COSTS
J PUTATIVE COST COMPARISON SHEET
K TECHNICAL COMPARISON SHEETS
FIGURES
2.1 VAPOR TEMPERATURE CURVES
2.2 DENSITY TEMPERATURE CURVES
3.1 TYPICAL HEAD OF PUMPS
3.2 TOTAL HEAD OF VERTICAL IMMERSED PUMP
3.3 TYPICAL TIDAL RIVER ESTUARY LEVELS
3.5 SUBMERGENCE LIMITS
4.1 TYPES OF PUMP
4.2 GUIDE TO PUMP TYPE AND SPEED
5.1 TYPICAL LINE DIAGRAM
6 GUIDE TO SUCTION PIPEWORK DESIGN
7 CASING AND IMPELLER DETAILS
8.1 DRY WELL AND WET WELL PUMP INSTALLATIONS
8.2 BELLMOUTH DIMENSIONS FOR VERTICAL INTAKES
8.3 MAXIMUM SPACING BETWEEN SHAFT GUIDE BUSHING
8.4 LINE SHAFT COUPLING
9 TYPICAL VOLUTE CASING
10 TYPICAL CASE WEAR RINGS
11 SEAL AREA
TABLES
1 LIQUID PROPERTIES SODIUM CHLORIDE (25% W/W)
2 LIQUID PROPERTIES SODIUM CHLORIDE (20% W/W)
3 LIQUID PROPERTIES SODIUM CHLORIDE (16.25% W/W)
4 LIQUID PROPERTIES SODIUM CHLORIDE (15% W/W)
5 LIQUID PROPERTIES SODIUM CHLORIDE (10% W/W)
6 LIQUID PROPERTIES SODIUM CHLORIDE (5% W/W)
7 GUIDE TO PUMP TYPE AND SPEED
8 RECOMMENDED CAST MATERIALS FOR USE IN THE PUMP INDUSTRY
GRAPHS
1 GUIDE TO ROTOR INERTIA
2 LIMITS BETWEEN BEARINGS
DOCUMENTS REFERRED TO IN THIS ENGINEERING DEPARTMENT DESIGN GUIDE
Hydrogen Compressors
Engineering Design Guide
1 SCOPE
2 PHYSICAL ROPERTIES
2.1 Data for Pure Hydrogen
2.2 Influence of Impurities
3 MATERIALS OF CONSTRUCTION
3.1 Hydrogen from Electrolytic Cells
3.2 Pure Hydrogen
4 DESIGN
4.1 Pulsation
4.2 Bypass
5 TESTING OR COMMISSIONING RECIPROCATING COMPRESSORS
6 LUBRICATION
7 LAYOUT
8 REFERENCES
FIGURES
1 MOLLIER CHART - HYDROGEN
2 COMPRESSIBILITY CHART
3 NELSON DIAGRAM
4 WATER CONTENT IN HYDROGEN FOR OIL-LUBRICATED COMPRESSORS AS GRAMM/M2 SWEPT CYLINDER AREA
Filtration
0 INTRODUCTION
1 The Theory Underlying Filtration Processes
1.1 The Mechanism of Simple Filtration Systems
1.1.2 Cake Filtration
1.1.3 Complete Blocking
1.1.4 Standard Blocking
1.1.5 Intermediate Blocking
1.2 Cake Filtration – Models and Mechanisms
1.2.1 Classical Theory for the Permeability of Porous Cakes and Beds
1.2.2 The Rate of Filtration through a Compressible Cake – The Standard Filtration Equation
1.2.3 The Compression or Consolidation of Filter Cakes – Ultimate degree of dewatering
1.2.4 The Rate of Consolidation
1.2.5 Useful Semi-Empirical Relations for Constant Pressure and Constant Rate Cake Filtration
1.2.6 Constant Pressure Filtration
1.2.7 Constant Rate Filtration
1.2.8 Multiphase Theory of Filtration
1.3 Crossflow Filtration
2 The Range and Selection of Filtration Equipment Technology
2.1 Scale
2.2 Solids Recovery, Liquids Clarification or Feed stream Concentration
2.3 Rate of Sedimentation
2.4 Rate of Cake Formation and Drainage
2.5 Batch vs Continuous Operation
2.6 Solids Loading
2.7 Further Processing
2.8 Aseptic or “Hygienic” Operation
2.9 Miscellaneous
2.10 Shear versus Compressional Deformation
2.11 Pressure versus Vacuum
3 Suspension Conditioning Prior to Filtration
3.1 Simple Filtration Aids
3.2 Mechanical Treatments
4 Post-Filtration Treatments and Further Downstream Processing
4.1 Washing
4.1.1 Air-Blowing
4.1.2 Drying
5 Testing and Characterization of Suspensions
5.1 Introduction – Suspension
5.2 Properties relevant to Filtration Performance
5.2.1 Pre-Filtration Properties of Suspension
5.2.2 Properties of Filter Cake
5.2.3 Laboratory Scale Filtration Rigs
5.3 Means of Monitoring Flocculant Dosage
5.4 Filter Cake Testing
5.4.1 Strength Testing (See also piston press described earlier)
5.4.2 Cake Permeability or Resistance
5.4.3 Rate of Cake Formation
6 Examples of the Application of the Forgoing Principles
6.1 Dewatering of Calcium Carbonate Slurries
6.2 Dewatering of Organic Products – Procion Dyestuffs
6.3 Filtration of Biological Systems – Harvesting a Filamentous Organism
References
Tables
Figures
Introduction to Pressure Surge in Liquid Systems
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 CAUSES OF PRESSURE SURGE
4.1 Start-up
5 CONSEQUENCES OF PRESSURE SURGES
6 PRELIMINARY CALCULATIONS
6.1 Estimation of the Sonic Velocity
6.2 Pipeline Period
7 CALCULATION OF PEAK PRESSURES
7.1 Rigid Liquid Column Theory
7.2 Sudden Changes in Flowrate
7.3 Moderately Rapid Changes in Flowrate
7.4 Reflections and Attenuations
7.5 Vapor Cavity Formation
7.6 Complex Piping Systems
8 FORCES ON PIPE SUPPORTS.
9 METHODS OF REDUCING THE EFFECTS OF
PRESSURE SURGE
9.1 Flowrate
9.2 Pipe Diameter
9.3 Valve Selection and Operation
9.4 Pump Start-up/Shut-down
9.5 Surge Tanks and Accumulators
9.6 Vacuum Breakers
9.7 Changes to Equipment
10 DETAILED ANALYSIS
10.1 Data Requirements
10.2 Interpretation of Results
11 GUIDELINES FOR CALCULATIONS
12 EXAMPLES OF PRESSURE SURGE INCIDENTS
12.1 Caustic Soda Pipeline Movement
12.2 Ammonia Pipe Movement
12.3 Propylene Reactor Start-up
12.4 Cooling Water Failure
12.5 Dry Riser Fire Sprinkler Systems
12.6 Cast Iron Fire Main Pressurization
Estimation of Pressure Drop in Pipe Systems
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
3.1 units
4 SOURCES OF DATA
5 BASIC CONCEPTS
5.1 Equation for Pressure Change in a Flowing
Fluid
5.2 Static and Stagnation Pressures
5.3 Sonic Flow
6 INCOMPRESSIBLE FLOW IN PIPES OF CONSTANT
CROSS-SECTION
6.1 Straight Circular Pipes
6.2 Ducts of Non-circular Cross-section
6.3 Coils
6.4 General Equation for Incompressible Flow
in Pipes of Constant Cross-section
7 COMPRESSIBLE FLOW IN PIPES OF CONSTANT
CROSS-SECTION
7.1 Isothermal Flow
7.2 Adiabatic Flow
7.3 Estimation of Pressure Drop for Adiabatic
Flow in Pipes of Constant Cross-section
7.4 Ratio of Isothermal to Adiabatic Pressure Drop
8 FLOW IN PIPE FITTINGS
8.1 Incompressible Flow
8.2 Compressible Flow
9 FLOW IN BENDS
9.1 Incompressible Flow in Bends
9.2 Compressible Flow in Bends
10 CHANGES IN CROSS-SECTIONAL AREA
9.1 Incompressible Flow
9.2 Compressible Flow
11 ORIFICES, NOZZLES AND VENTURIS
11.1 Incompressible Flow through an Orifice
11.2 Compressible Flow through an Orifice or Nozzle
11.3 Venturi Choke Tubes
12 VALVES
12.1 General
12.2 Incompressible Flow in Valves
12.2 Compressible Flow in Valves
13 COMBINING AND DIVIDING FLOW
9.1 Incompressible Flow
9.2 Compressible Flow
14 COMPUTER PROGRAMS FOR FLUID FLOW
15 NOMENCLATURE
16 REFERENCES
APPENDICES
A BASIC THERMODYNAMICS
B COMPRESSIBLE FLOW THROUGH ORIFICES
C THE ‘TWO-K’ METHOD FOR FITTING PRESSURE LOSS
Batch Distillation
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 BACKGROUND TO THE DESIGN
4.1 General
4.2 Choice of batch/continuous operation
4.3 Boiling point curve and cut policy
4.4 Method of design
4.5 Scope of calculations required for design
5 SIMPLE BATCH DISTILLATION
6 FRACTIONAL BATCH DISTILLATION
6.1 General
6.2 Approximate methods
6.3 Rigorous design - use of a computer model
6.4 Other factors influencing the design
6.4.1 Occupation
6.4.2 Choice of Batch Rectification or Stripping
6.4.3 Batch size
6.4.4 Initial estimate of cut policy
6.4.5 Liquid Holdup
6.4.6 Total reflux operation and heating-up time
6.4.7 Column operating pressure
6.5 Optimum Design of the Batch Still
6.6 Special design problems
7 GENERAL ASPECTS OF EQUIPMENT DESIGN
7.1 Kettle reboilers
7.2 Column Internals
7.3 Condensers and reflux split boxes
8 PROCESS CONTROL AND INSTRUMENTATION IN
BATCH DISTILLATION
9 MECHANICAL DESIGN FEATURES
10 BIBLIOGRAPHY
APPENDICES
A McCABE - THIELE METHOD - TYPICAL EXAMPLE
Interpretation and Correlation of Viscometric Data
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 NON-NEWTONIAN FLUID BEHAVIOR
4.1 Introduction
4.2 Classification of Non-Newtonian Fluids
4.3 Caution
5 VISCOMETER MEASUREMENTS FOR
TIME-INDEPENDENT FLUIDS
5.1 Concentric Cylinder Viscometers
5.2 Cone and Plate Viscometers
5.3 Parallel Plate Viscometer
5.4 Tube or Capillary Viscometer
5.5 Checks for Consistency of Data and Interpretation
5.6 Estimate of Process Shear Rate
6 MODEL FITTING TO FLOW CURVES
6.1 Power Law
6.2 Bingham Plastic
6.3 Direct use of Numerical Data
6.4 Rheological Models Involving Temperature Dependence
7 CHARACTERIZATION OF TIME-DEPENDENT LIQUIDS
7.1 Sample Loading
7.2 Tests at Constant Shear Rate
7.3 Dynamic Response Measurement
7.4 Changes in Shear Rate
7.4 Concluding Remarks
8 TECHNIQUES FOR CHARACTERIZATION OF
VISCOELASTIC LIQUIDS
8.1 Stress Relaxation
8.2 Oscillatory Shear Measurements
8.3 Normal Force Measurement
8.4 Elongational Viscosity Measurement
9 NOMENCLATURE
10 BIBLIOGRAPHY
APPENDICES
A EQUATIONS FOR VISCOMETERS
A.1 EQUATIONS FOR CONCENTRIC CYLINDER
VISCOMETERS
A.2 EQUATIONS FOR CONE AND PLATE VISCOMETERS
A.3 EQUATIONS FOR PARALLEL PLATE VISCOMETER
A.4 EQUATIONS FOR TUBE OR CAPILLARY VISCOMETER
This document provides guidance on designing pipelines for turbulent flow of non-Newtonian fluids. It describes anomalous effects like wall slip and drag reduction that can occur. The guidance covers design procedures for calculating pressure drop in turbulent pipe flow without and with drag reduction from polymeric materials or fiber suspensions. Key steps include determining transition delay and accounting for pipe roughness and fittings. The intended audience is process engineers at GBH Enterprises.
Laminar Heat Transfer to Non Newtonian Fluids in Circular TubesGerard B. Hawkins
Laminar Heat Transfer to Non Newtonian Fluids in Circular Tubes
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 APPLICABILITY AND LIMITATIONS
4.1 Applicability
4.2 Limitations
5 THEORETICAL BACKGROUND
6 PRESENTATION OF RESULTS
7 PRESENTATION OF RESULTS
8 USE OF “The VAULT”
8.1 Limitations of “The VAULT”
9 NOMENCLATURE
10 BIBLIOGRAPHY
This document provides guidance on residence time distribution (RTD) data for process engineers. It discusses:
1) How RTD data measures mixing in reactors and can be used to model reactor performance.
2) Examples of how RTD data can model reactors for first and second order reactions, and the differences between micro and macromixing models.
3) Techniques for measuring RTD using radioactive tracers and modeling results based on the measured curves.
Solid Catalyzed Reactions
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 GENERAL BACKGROUND
4.1 General Considerations
5 SOLID CATALYZED GAS REACTIONS
5.1 Reaction Kinetics
5.2 Tests for Transport Limitations
5.3 Building a Reaction Kinetic Equation
6 INTRAPARTICLE
6.1 Types of Pore System
6.2 The Catalyst Effectiveness Factor
6.3 The Measurement of Effective Diffusivity
7 ENHANCEMENT OF INTRAPARTICLE
8 NOMENCLATURE
8.1 Dimensionless Parameters
8.2 Greek Letters
8.3 Subscripts
9 BIBLIOGRAPHY
9.1 Further Reading
APPENDICES
A LANGMUIR - HINSHELWOOD KINETICS
FIGURES
1 EFFECTIVE RATE CONSTANT
2 ITERATIVE APPROACH TO REACTOR MODEL
DEVELOPMENT
3 COMMON LABORATORY MICROREACTORS (FLOW TYPE)
4 THE BERTY REACTOR
5 STEPS IN BUILDING A REACTION RATE EQUATION
6 A CENTRAL-COMPOSITE DESIGN FOR TWO FACTORS
7 FIRST ORDER ISOTHERMAL IRREVERSIBLE
REACTION WITHIN A CATALYST SPHERE
8 INTEGRAL YIELD vs CONVERSION SHOWING EFFECT OF PELLET DIFFUSION
9 PREDICTED AND EXPERIMENTAL EFFECTIVENESS FACTORS
10 STRUCTURAL PERMEABILITY vs PRESSURE PARAMETER Z FOR BI-MODAL SUPPORTS
11 EFFECTIVENESS FACTOR vs THIELE MODULUS AND INTRAPARTICLE PECLET NUMBER
12 RELATIVE INCREASE IN CATALYST PERFORMANCE
Distillation Sequences, Complex Columns and Heat IntegrationGerard B. Hawkins
Distillation Sequences, Complex Columns and Heat Integration
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 SEQUENCING OF SIMPLE COLUMNS
4.1 Sidestream Columns
4.2 Multi-Feed Columns
5 SIMPLE COLUMN SEQUENCING AND HEAT
INTEGRATION INTERACTIONS
5.1 Energy Quantity and Quality
5.2 Heat Integration within the Total Flowsheet
6 COMPLEX COLUMN ARRANGEMENTS
6.1 Indirect Sequence with Vapor Link
6.2 Sidestream Systems
6.3 Pre-Fractionator Systems
7 COMPLEX COLUMNS AND HEAT INTEGRATION
INTERACTIONS
FIGURES
1 DIRECT AND INDIRECT SEQUENCES
2 A SINGLE SIDESTREAM COLUMN REPLACING 2
SIMPLE COLUMNS
3 A TYPICAL MULTI-FEED COLUMN
4 TYPICAL GRAND COMPOSITION CURVE
5 TYPICAL INDIRECT SEQUENCE WITH VAPOUR LINK
6 SIDESTREAM STRIPPER AND SIDESTREAM
RECTIFIER
7 SIMPLEST PRE-FRACTIONATOR SYSTEM
8 SIMPLEST PRE-FRACTIONATOR SYSTEM
9 PETLYUK COLUMN
Shell and Tube Heat Exchangers Using Cooling Water
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
3.1 HTFS
3.2 TEMA
4 CHECKLIST
5 QUALITY OF COOLING WATER
6 COOLING WATER ON SHELL SIDE OR TUBE SIDE
7 COOLING WATER ON THE SHELL SIDE
7.1 Baffle Spacing
7.2 Impingement Plates
7.3 Horizontal or Vertical Shell Orientation
7.4 Baffle Cut Orientation
7.5 Sludge Blowdown
7.6 Removable Bundles
8 FOULING RESISTANCES AND LIMITING TEMPERATURES
9 PRESSURE DROP
9.1 Pressure Drop Restrictions
9.2 Fouling and Pressure Drop
9.3 Elevation of a Heat Exchanger in the Plant
10 MATERIALS OF CONSTRUCTION
11 WATER VELOCITY
11.1 Low Water Velocity
11.1.1 Tube Side Water Flow
11.1.2 Shell Side Water Flow
11.2 High Water Velocity
12 ECONOMICS
13 DIRECTION OF WATER FLOW
14 VENTS AND DRAINS
15 CONTROL
15.1 Operating Variables
15.2 Heat Load Control
15.2.1 General
15.2.2 Heat load control by varying cooling water flow
15.3 Orifice Plates
16 MAINTENANCE
The Preliminary Choice of Fan or Compressor
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 METHOD FOR PRELIMINARY SELECTION
OF COMPRESSOR
5 PROCESS DATA SHEET
5.1 Essential Data for the Completion of a
Process Data Sheet
5.2 Gas Properties
5.3 Discharge Requirements
6 PRELIMINARY CHOICE OF FAN AND
COMPRESSOR TYPE
6.1 Essential Data for Preliminary Selection
7 FAN AND COMPRESSOR APPLICATIONS
7.1 Fans
7.2 Centrifugal Compressors
7.3 Axial Compressors
7.4 Reciprocating Compressors
7.5 Screw Compressors
7.6 Positive Displacement Blowers
7.7 Sliding Vane Compressors
7.8 Liquid Ring Compressors
8 PROVISION OF INSTALLED SPARES
9 PRELIMINARY ESTIMATE OF COSTS
VLE Data - Selection and Use
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 DIAGRAMMATIC REPRESENTATION OF IDEAL
AND NON-IDEAL SYSTEMS
4.1 Ideal Mixtures
4.2 Non-Ideal Mixtures
5 REVIEW OF VLE MODELS
5.1 Ideal Behavior in Both Phases
5.2 Liquid Phase Non-Idealities
5.3 High Pressure Systems
5.4 Special Models
6 SETTING UP A VLE MODEL
6.1 Define Problem
6.2 Select Data
6.3 Select Correlation(s)
6.4 Produce Model
7 AVOIDING PITFALLS
7.1 Experimental Data is Better than Estimates
7.2 Check Validity of Fitted Model
7.3 Check Limitations of Estimation Methods
7.4 Know Your System
7.5 Appreciate Errors and Effects
7.6 If in Doubt – Ask
8 A CASE STUDY
8.1 The Problem
8.2 The System
8.3 Data Available
8.4 Selected Correlation
8.5 Simulation
8.6 Selection of Model
9 RECOMMENDED READING
10 VLE EXPERTS IN GBHE
APPENDICES
A USE OF EXTENDED ANTOINE EQUATION
B USE OF WILSON EQUATION
C USEFUL METHODS OF ESTIMATING
D EQUATIONS OF STATE FOR VLE CALCULATIONS
TABLES
1 SUMMARY OF VLE METHODS
2 LIST OF USEFUL REFERENCES
FIGURES
1 VAPOR-LIQUID EQUILIBRIUM - IDEAL SOLUTION
BEHAVIOR
2 VAPOR-LIQUID EQUILIBRIUM - A GENERALISED
Y-X DIAGRAM
3 VAPOR-LIQUID EQUILIBRIUM - MINIMUM BOILING
AZEOTROPE
4 VAPOR-LIQUID EQUILIBRIUM - MAXIMUM BOILING
AZEOTROPE
5 VAPOR-LIQUID EQUILIBRIUM - MINIMUM BOILING
AZEOTROPE -TWO LIQUID PHASES
6 SENSITIVITY TO ERROR IN VLE DATA (BASED ON FENSKE EQUATION)
7(a) FITTING WILSON 'A' VALUES TO VLE DATA - CASE A
7(b) FITTING WILSON 'A' VALUES TO VLE DATA - CASE B
7(c) FITTING WILSON 'A' VALUES TO VLE DATA - CASE C
SYNOPSIS
The principles underlying centrifugal separation of particulate species are briefly considered, and the main types of separator available are noted. The procedures available for scale-up from laboratory or semi-technical data are then discussed in detail with particular reference to perhaps the most important class of machine for fine particle processing: the disc-nozzle centrifuge.
Starting with the basic concepts behind their design, discussion follows to explain the factors which may limit centrifuge performance. It is shown how a few simple; laboratory scale tests can give a valuable insight into the design and operation of full-scale industrial machines.
Similar to Pipeline Design for Isothermal, Laminar Flow of Non-Newtonian Fluids (20)
Pressure Relief Systems Vol 2
Causes of Relief Situations
This Volume 2 is a guide to the qualitative identification of common causes of overpressure in process equipment. It cannot be exhaustive; the process engineer and relief systems team should look for any credible situation in addition to those given in this Part which could lead to a need for pressure relief (a relief situation).
This document provides guidelines for engineering design of pressure relief systems. It discusses key principles such as identifying potential overpressure and underpressure causes, sizing relief systems to prevent hazards, and safely disposing of relieved materials. The guidelines cover statutory requirements, recommended design procedures, and documentation standards. The overall goal is to preserve equipment integrity and prevent failure from over or under pressure during all process phases.
GAS DISPERSION - A Definitive Guide to Accidental Releases of Heavy GasesGerard B. Hawkins
GAS DISPERSION - A Definitive Guide to Accidental Releases of Heavy Gases
This Process Safety Guide has been written with the aim of assisting process engineers, hazard analysts and environmental advisers in carrying out gas dispersion calculations. The Guide aims to provide assistance by:
• Improving awareness of the range of dispersion models available within GBHE, and providing guidance in choosing the most appropriate model for a particular application.
• Providing guidance to ensure that source terms and other model inputs are correctly specified, and the models are used within their range of applicability.
• Providing guidance to deal with particular topics in gas dispersion such as dense gas dispersion, complex terrain, and modeling the chemistry of oxides of nitrogen.
• Providing general background on air quality and dispersion modeling issues such as meteorology and air quality standards.
• Providing example calculations for real practical problems.
SCOPE
The gas dispersion guide contains the following Parts:
1 Fundamentals of meteorology.
2 Overview of air quality standards.
3 Comparison between different air quality models.
4 Designing a stack.
5 Dense gas dispersion.
6 Calculation of source terms.
7 Building wake effects.
8 Overview of the chemistry of the oxides of nitrogen.
9 Overview of the ADMS complex terrain module.
10 Overview of the ADMS deposition module.
11 ADMS examples.
12 Modeling odorous releases.
13 Bibliography of useful gas dispersion books and reports.
14 Glossary of gas dispersion modeling terms.
Appendix A : Modeling Wind Generation of Particulates.
APPENDIX B TABLE OF PROPERTY VALUES FOR SPECIFIC CHEMICALS
101 Things That Can Go Wrong on a Primary Reformer - Best Practices GuideGerard B. Hawkins
This document discusses common problems that can occur in primary reformers and associated equipment. It identifies issues that can lead to plant shutdowns or efficiency losses, grouping them under catalysts, tubes, furnace boxes, burners, flue gas ducts, headers, and refractories. Some examples discussed include carbon formation, tube overheating, flame impingement, leaks in air preheaters, combustion air maldistribution, and damage to coffins. The document provides an overview of these issues to improve plant reliability over its lifespan.
El impacto en el rendimiento del catalizador por envenenamiento y ensuciamien...Gerard B. Hawkins
El documento describe los procesos de refinería y catalizadores, así como los efectos del envenenamiento y ensuciamiento en el rendimiento de los catalizadores. El envenenamiento reduce la actividad de los catalizadores al bloquear los sitios activos o modificar la química de la superficie, lo que afecta la actividad y selectividad. Los niveles bajos de contaminantes tienen un mayor impacto en catalizadores con menor área de superficie. El envenenamiento también puede causar cambios estructurales en el catalizador y permitir
Theory of Carbon Formation in Steam Reforming
Contents
1 Introduction
2 Underpinning Theory
2.1 Conceptualization
2.2 Reforming Reactions
2.3 Carbon Formation Chemistry
2.3.1 Natural Gas
2.3.2 Carbon Formation for Naphtha Feeds
2.3.3 Carbon Gasification
2.4 Heat Transfer
3 Causes
3.1 Effects of Carbon Formation
3.2 Types of Carbon
4 What are the Effects of Carbon Formation?
4.1 Why does Carbon Formation Get Worse?
4.1.1 So what is the Next Step?
4.2 Consequences of Carbon Formation
4.3 Why does Carbon Form where it does?
4.3.1 Effect on Process Gas Temperature
4.4 Why does Carbon Formation Propagate Down the Tube?
4.4.1 Effect on Radiation on the Fluegas Side
4.5 Why does Carbon Formation propagate Up the Tube?
5 How do we Prevent Carbon Formation
5.1 The Role of Potash
5.2 Inclusion of Pre-reformer
5.3 Primary Reformer Catalyst Parameters
5.3.1 Activity
5.3.2 Heat Transfer
5.3.3 Increased Steam to Carbon Ratio
6 Steam Out
6.1 Why does increasing the Steam to Carbon Ratio Not Work?
6.2 Why does reducing the Feed Rate not help?
6.3 Fundamental Principles of Steam Outs
TABLES
1 Heat Transfer Coefficients in a Typical Reformer
2 Typical Catalyst Loading Options
FIGURES
1 Hot Bands
2 Conceptual Pellet
3 Naphtha Carbon Formation
4 Heat Transfer within an Reformer
5 Types of Carbon Formation
6 Effect of Carbon on Nickel Crystallites
7 Absorption of Heat
8 Comparison of "Base Case" v Carbon Forming Tube
9 Carbon Formation Vicious Circle
10 Temperature Profiles
11 Carbon Pinch Point
12 Carbon Formation
13 Effect on Process Gas Temperature
14 How does Carbon Propagate into an Unaffected Zone?
15 Movement of the Carbon Forming Region
16 Effect of Hot Bands on Radiative Heat Transfer
17 Effect of Potash on Carbon Formation
18 Application of a Pre-reformer
19 Effect of Activity on Carbon Formation
Adiabatic Reactor Analysis for Methanol Synthesis Plant Note Book Series: P...Gerard B. Hawkins
The document discusses adiabatic reactor analysis for methanol synthesis from syngas. It provides the reaction kinetics and calculates conversion, temperature, and reactor volume needed at different conversions. Energy and mass balances are used to derive relationships between conversion, temperature and reaction rate. Data is generated to plot conversion versus volumetric flow rate for reactor sizing. The plot indicates a continuous stirred tank reactor (CSTR) could achieve 85% conversion before switching to a plug flow reactor (PFR) for higher conversion with less volume.
STEAMING PROCEDURE FOR VULCAN STEAM REFORMING CATALYSTSGerard B. Hawkins
The document discusses procedures for steaming Vulcan steam reforming catalysts to recover from sulfur poisoning and carbon formation incidents. It describes maintaining steam flow at 30-40% of design levels and an outlet temperature above 780°C. Gas samples should be taken hourly to monitor CO2, CH4, H2S and SO2. Steaming is complete when CO2 levels stabilize over 2-3 samples after increasing the temperature. The process typically takes 12-24 hours to complete and closely monitors pressure drop and tube conditions. After steaming, the catalyst requires reduction before restarting hydrocarbon feed.
Calculation of an Ammonia Plant Energy Consumption: Gerard B. Hawkins
Calculation of an Ammonia Plant Energy Consumption:
Case Study: #06023300
Plant Note Book Series: PNBS-0602
CONTENTS
0 SCOPE
1 CALCULATION OF NATURAL GAS PROCESS FEED CONSUMPTION
2 CALCULATION OF NATURAL GAS PROCESS FUEL CONSUMPTION
3 CALCULATION OF NATURAL GAS CONSUMPTION FOR PILOT BURNERS OF FLARES
4 CALCULATION OF DEMIN. WATER FROM DEMIN. UNIT
5 CALCULATION OF DEMIN. WATER TO PACKAGE BOILERS
6 CALCULATION OF MP STEAM EXPORT
7 CALCULATION OF LP STEAM IMPORT
8 DETERMINATION OF ELECTRIC POWER CONSUMPTION
9 DETERMINATION OF THE TOTAL ENERGY CONSUMPTION OF THE AMMONIA PLANT ISBL
10 ADJUSTMENT OF ELECTRIC POWER CONSUMPTION FOR TEST RUN CONDITIONS
11 CALCULATION OF AMMONIA SHARE IN MP STEAM CONSUMPTION IN UTILITIES
12 CALCULATION OF AMMONIA SHARE IN ELECTRIC POWER CONSUMPTION IN UTILITIES
13 DETERMINATION OF THE TOTAL ENERGY CONSUMPTION OF THE AMMONIA PLANT OSBL
14 DETERMINATION OF THE TOTAL ENERGY CONSUMPTION OF THE AMMONIA PLANT
Ammonia Plant Technology
Pre-Commissioning Best Practices
GBHE-APT-0102
PICKLING & PASSIVATION
CONTENTS
1 PURPOSE OF THE WORK
2 CHEMICAL CONCEPT
3 TECHNICAL CONCEPT
4 WASTES & SAFETY CONCEPT
5 TARGET RESULTS
6 THE GENERAL CLEANING SEQUENCE MANAGEMENT
6.6.1 Pre-cleaning or “Physical Cleaning
6.6.2 Pre-rinsing
6.6.3 Chemical Cleaning
6.6.4 Critical Factors in Cleaning Success
6.6.5 Rinsing
6.6.6 Inspection and Re-Cleaning, if Necessary
7 Systems to be treated by Pickling/Passivation
Ammonia Plant Technology
Pre-Commissioning Best Practices
Piping and Vessels Flushing and Cleaning Procedure
CONTENTS
1 Scope
2 Aim/purpose
3 Responsibilities
4 Procedure
4.1 Main cleaning methods
4.1.1 Mechanical cleaning
4.1.2 Cleaning with air
4.1.3 Cleaning with steam (for steam networks only)
4.1.4 Cleaning with water
4.2 Choice of the cleaning method
4.3 Cleaning preparation
4.4 Protection of the devices included in the network
4.5 Protection of devices in the vicinity of the network
4.6 Water flushing procedure
4.6.1 Specific problems of water flushing
4.6.2 Preparation for water flushing
4.6.3 Performing a water flush
4.6.4 Cleanliness criteria
4.7 Air blowing procedure
4.7.1 Specific problems of air blowing
4.7.2 Preparation for air blowing
4.7.3 Performing air blowing
4.7.4 Cleanliness checks
4.8 Steam blowing procedure
4.8.1 Specific problems of steam blowing
4.8.2 Preparation for steam blowing
4.8.3 Performing steam blowing
4.8.4 Cleanliness checks
4.9 Chemical cleaning procedure
4.9.1 Specific problems of cleaning with a chemical solution
4.9.2 Preparation for chemical cleaning
4.9.3 Performing a chemical cleaning
4.9.4 Cleanliness criteria
4.10 Re-assembly - general guideline
4.11 Preservation of flushed piping
DESIGN OF VENT GAS COLLECTION AND DESTRUCTION SYSTEMS Gerard B. Hawkins
DESIGN OF VENT GAS COLLECTION AND DESTRUCTION SYSTEMS
CONTENTS
1 INTRODUCTION
1.1 Purpose
1.2 Scope of this Guide
1.3 Use of the Guide
2 ENVIRONMENTAL ISSUES
2.1 Principal Concerns
2.2 Mechanisms for Ozone Formation
2.3 Photochemical Ozone Creation Potential
2.4 Health and Environmental Effects
2.5 Air Quality Standards for Ground Level Concentrations of Ozone, Targets for Reduction of VOC Discharges and Statutory Discharge Limits
3 VENTS REDUCTION PHILOSOPHY
3.1 Reduction at Source
3.2 End-of-pipe Treatment
4 METHODOLOGY FOR COLLECTION & ASSESSMENT OF PROCESS FLOW DATA
4.1 General
4.2 Identification of Vent Sources
4.3 Characterization of Vents
4.4 Quantification of Process Vent Flows
4.5 Component Flammability Data Collection
4.6 Identification of Operating Scenarios
4.7 Quantification of Flammability Characteristics for Combined Vents
4.8 Identification, Quantification and Assessment of Possibility of Air Ingress Routes
4.9 Tabulation of Data
4.10 Hazard Study and Risk Assessment
4.11 Note on Aqueous / Organic Wastes
4.12 Complexity of Systems
4.13 Summary
5 SAFE DESIGN OF VENT COLLECTION HEADER SYSTEMS
5.1 General
5.2 Process Design of Vent Headers
5.3 Liquid in Vent Headers
5.4 Materials of Construction
5.5 Static Electricity Hazard
5.6 Diversion Systems
5.7 Snuffing Systems
6 SAFE DESIGN OF THERMAL OXIDISERS
6.1 Introduction
6.2 Design Basis
6.3 Types of High Temperature Thermal Oxidizer
6.4 Refractories
6.5 Flue Gas Treatment
6.6 Control and Safety Systems
6.7 Project Program
6.8 Commissioning
6.9 Operational and Maintenance Management
APPENDICES
A GLOSSARY
B FLAMMABILITY
C EXAMPLE PROFORMA
D REFERENCES
DOCUMENTS REFERRED TO IN THIS PROCESS GUIDE
TABLE
1 PHOTOCHEMICAL OZONE CREATION POTENTIAL REFERENCED
TO ETHYLENE AS UNITY
FIGURES
1 SCHEMATIC OF TYPICAL VENT COLLECTION AND THERMAL OXIDIZER SYSTEM
2 TYPICAL KNOCK-OUT POT WITH LUTED DRAIN
3 SCHEMATIC OF DIVERSION SYSTEM
4 CONVENTIONAL VERTICAL THERMAL OXIDIZER
5 CONVENTIONAL OXIDIZER WITH INTEGRAL WATER SPARGER
6 THERMAL OXIDIZER WITH STAGED AIR INJECTION
7 DOWN-FIRED UNIT WITH WATER BATH QUENCH
8 FLAMELESS THERMAL OXIDATION UNIT
9 THERMAL OXIDIZER WITH REGENERATIVE HEAT RECOVERY
10 TYPICAL PROJECT PROGRAM
11 TYPICAL FLAMMABILITY DIAGRAM
12 EFFECT OF DILUTION WITH AIR
13 EFFECT OF DILUTION WITH AIR ON 100 Rm³ OF FLAMMABLE GAS
PRACTICAL GUIDE ON THE SELECTION OF PROCESS TECHNOLOGY FOR THE TREATMENT OF A...Gerard B. Hawkins
PRACTICAL GUIDE ON THE SELECTION OF PROCESS TECHNOLOGY FOR THE TREATMENT OF AQUEOUS ORGANIC EFFLUENT STREAMS
CONTENTS
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
3.1 IPU
3.2 AOS
3.3 BODs
3.4 COD
3.5 TOC
3.6 Toxicity
3.7 Refractory Organics/Hard COD
3.8 Heavy Metals
3.9 EA
3.10 Biological Treatment Terms
3.11 BATNEEC
3.12 BPEO
3.13 EQS/LV
3.14 IPC
3.15 VOC
3.16 F/M Ratio
3.17 MLSS
3.18 MLVSS
4 DESIGN/ECONOMIC GUIDELINES
5 EUROPEAN LEGISLATION
5.1 General
5.2 Integrated Pollution Control (IPC)
5.3 Best Available Techniques Not Entailing Excessive Costs (BATNEEC)
5.4 Best Practicable Environmental Option (BPEO)
5.5 Environmental Quality Standards(EQS)
6 IPU EXIT CONCENTRATION
7 SITE/LOCAL REQUIREMENTS
8 PROCESS SELECTION PROCEDURE
8.1 Waste Minimization Techniques (WMT)
8.2 AOS Stream Definition
8.3 Technical Check List
8.4 Preliminary Selection of Suitable Technologies
8.5 Process Sequences
8.6 Economic Evaluation
8.7 Process Selection
APPENDICES
A DIRECTIVE 76/464/EEC - LIST 1
B DIRECTIVE 76/464/EEC - LIST 2
C THE EUROPEAN COMMISSION PRIORITY CANDIDATE LIST
D THE UK RED LIST
E CURRENT VALUES FOR EUROPEAN COMMUNITY ENVIRONMENTAL QUALITY STANDARDS AND CORRESPONDING LIMIT VALUES
F ESTABLISHED TECHNOLOGIES
G EMERGING TECHNOLOGY
H PROPRIETARY/LESS COMMON TECHNOLOGIES
J COMPARATIVE COST DATA
PRACTICAL GUIDE ON THE REDUCTION OF DISCHARGES TO ATMOSPHERE OF VOLATILE ORGA...Gerard B. Hawkins
PRACTICAL GUIDE ON THE REDUCTION OF DISCHARGES TO ATMOSPHERE OF VOLATILE ORGANIC COMPOUNDS (VOCs)
FOREWORD
CONTENTS
1 INTRODUCTION
2 THE NEED FOR VOC CONTROL
3 CONTROL AT SOURCE
3.1 Choice or Solvent
3.2 Venting Arrangements
3.3 Nitrogen Blanketing
3.4 Pump Versus Pneumatic Transfer
3.5 Batch Charging
3.6 Reduction of Volumetric Flow
3.7 Stock Tank Design
4 DISCHARGE MEASUREMENT
4.1 By Inference or Calculation
4.2 Flow Monitoring Equipment
4.3 Analytical Instruments
4.4 Vent Emissions Database
5 ABATEMENT TECHNOLOGY
5.1 Available Options
5.2 Selection of Preferred Option
5.3 Condensation
5.4 Adsorption
5.5 Absorption
5.6 Thermal Incineration
5.7 Catalytic Oxidation
5.8 Biological Filtration
5.9 Combinations of Process technologies
5.10 Processes Under Development
6 GLOSSARY OF TERMS
7 REFERENCES
Appendix 1. Photochemical Ozone Creation Potentials
Appendix 2. Examples of Adsorption Preliminary Calculations
Appendix 3. Example of Thermal Incineration Heat and Mass Balance
Appendix 4. Cost Correlations
Getting the Most Out of Your Refinery Hydrogen PlantGerard B. Hawkins
Getting the Most Out of Your Refinery Hydrogen Plant
Contents
Summary
1 Introduction
2 "On-purpose" Hydrogen Production
3 Operational Aspects
4 Uprating Options on the Steam Reformer
4.1 Steam Reforming Catalysts and Tube Metallurgy
4.2 Oxygen-blown Secondary Reformer
4.3 Pre-reforming
4.4 Post-reforming
5 Downstream Units
6 Summary of Uprating Options
7 Conclusions
EMERGENCY ISOLATION OF CHEMICAL PLANTS
CONTENTS
1 Introduction
2 When should Emergency Isolation Valves be Installed
3 Emergency Isolation Valves and Associated Equipment
3.1 Installations on existing plant
3.2 Actuators
3.3 Power to close or power to open
3.4 The need for testing
3.5 Hand operated Emergency Valves
3.6 The need to stop pumps in an emergency
3.7 Location of Operating Buttons
3.8 Use of control valves for Isolation
4 Detection of Leaks and Fires
5 Precautions during Maintenance
6 Training Operators to use Emergency Isolation Valves
7 Emergency Isolation when no remotely operated valve is available
References
Glossary
Appendix I Some Fires or Serious Escapes of Flammable Gases or Liquids that could have been controlled by Emergency Isolation Valves
Appendix II Some typical Installations
Amine Gas Treating Unit - Best Practices - Troubleshooting Guide Gerard B. Hawkins
Amine Gas Treating Unit Best Practices - Troubleshooting Guide for H2S/CO2 Amine Systems
Contents
Process Capabilities for gas treating process
Typical Amine Treating
Typical Amine System Improvements
Primary Equipment Overview
Inlet Gas Knockout
Absorber
Three Phase Flash Tank
Lean/Rich Heat Exchanger
Regenerator
Filtration
Amine Reclaimer
Operating Difficulties Overview
Foaming
Failure to Meet Gas Specification
Solvent Losses
Corrosion
Typical Amine System Improvements
Degradation of Amines and Alkanolamines during Sour Gas Treating
APPENDIX
Best Practices - Troubleshooting Guide
20 Comprehensive Checklist of Designing and Developing a WebsitePixlogix Infotech
Dive into the world of Website Designing and Developing with Pixlogix! Looking to create a stunning online presence? Look no further! Our comprehensive checklist covers everything you need to know to craft a website that stands out. From user-friendly design to seamless functionality, we've got you covered. Don't miss out on this invaluable resource! Check out our checklist now at Pixlogix and start your journey towards a captivating online presence today.
Sudheer Mechineni, Head of Application Frameworks, Standard Chartered Bank
Discover how Standard Chartered Bank harnessed the power of Neo4j to transform complex data access challenges into a dynamic, scalable graph database solution. This keynote will cover their journey from initial adoption to deploying a fully automated, enterprise-grade causal cluster, highlighting key strategies for modelling organisational changes and ensuring robust disaster recovery. Learn how these innovations have not only enhanced Standard Chartered Bank’s data infrastructure but also positioned them as pioneers in the banking sector’s adoption of graph technology.
Essentials of Automations: The Art of Triggers and Actions in FMESafe Software
In this second installment of our Essentials of Automations webinar series, we’ll explore the landscape of triggers and actions, guiding you through the nuances of authoring and adapting workspaces for seamless automations. Gain an understanding of the full spectrum of triggers and actions available in FME, empowering you to enhance your workspaces for efficient automation.
We’ll kick things off by showcasing the most commonly used event-based triggers, introducing you to various automation workflows like manual triggers, schedules, directory watchers, and more. Plus, see how these elements play out in real scenarios.
Whether you’re tweaking your current setup or building from the ground up, this session will arm you with the tools and insights needed to transform your FME usage into a powerhouse of productivity. Join us to discover effective strategies that simplify complex processes, enhancing your productivity and transforming your data management practices with FME. Let’s turn complexity into clarity and make your workspaces work wonders!
Maruthi Prithivirajan, Head of ASEAN & IN Solution Architecture, Neo4j
Get an inside look at the latest Neo4j innovations that enable relationship-driven intelligence at scale. Learn more about the newest cloud integrations and product enhancements that make Neo4j an essential choice for developers building apps with interconnected data and generative AI.
Encryption in Microsoft 365 - ExpertsLive Netherlands 2024Albert Hoitingh
In this session I delve into the encryption technology used in Microsoft 365 and Microsoft Purview. Including the concepts of Customer Key and Double Key Encryption.
GraphSummit Singapore | The Future of Agility: Supercharging Digital Transfor...Neo4j
Leonard Jayamohan, Partner & Generative AI Lead, Deloitte
This keynote will reveal how Deloitte leverages Neo4j’s graph power for groundbreaking digital twin solutions, achieving a staggering 100x performance boost. Discover the essential role knowledge graphs play in successful generative AI implementations. Plus, get an exclusive look at an innovative Neo4j + Generative AI solution Deloitte is developing in-house.
Building RAG with self-deployed Milvus vector database and Snowpark Container...Zilliz
This talk will give hands-on advice on building RAG applications with an open-source Milvus database deployed as a docker container. We will also introduce the integration of Milvus with Snowpark Container Services.
Unlocking Productivity: Leveraging the Potential of Copilot in Microsoft 365, a presentation by Christoforos Vlachos, Senior Solutions Manager – Modern Workplace, Uni Systems
Threats to mobile devices are more prevalent and increasing in scope and complexity. Users of mobile devices desire to take full advantage of the features
available on those devices, but many of the features provide convenience and capability but sacrifice security. This best practices guide outlines steps the users can take to better protect personal devices and information.
Introducing Milvus Lite: Easy-to-Install, Easy-to-Use vector database for you...Zilliz
Join us to introduce Milvus Lite, a vector database that can run on notebooks and laptops, share the same API with Milvus, and integrate with every popular GenAI framework. This webinar is perfect for developers seeking easy-to-use, well-integrated vector databases for their GenAI apps.
In the rapidly evolving landscape of technologies, XML continues to play a vital role in structuring, storing, and transporting data across diverse systems. The recent advancements in artificial intelligence (AI) present new methodologies for enhancing XML development workflows, introducing efficiency, automation, and intelligent capabilities. This presentation will outline the scope and perspective of utilizing AI in XML development. The potential benefits and the possible pitfalls will be highlighted, providing a balanced view of the subject.
We will explore the capabilities of AI in understanding XML markup languages and autonomously creating structured XML content. Additionally, we will examine the capacity of AI to enrich plain text with appropriate XML markup. Practical examples and methodological guidelines will be provided to elucidate how AI can be effectively prompted to interpret and generate accurate XML markup.
Further emphasis will be placed on the role of AI in developing XSLT, or schemas such as XSD and Schematron. We will address the techniques and strategies adopted to create prompts for generating code, explaining code, or refactoring the code, and the results achieved.
The discussion will extend to how AI can be used to transform XML content. In particular, the focus will be on the use of AI XPath extension functions in XSLT, Schematron, Schematron Quick Fixes, or for XML content refactoring.
The presentation aims to deliver a comprehensive overview of AI usage in XML development, providing attendees with the necessary knowledge to make informed decisions. Whether you’re at the early stages of adopting AI or considering integrating it in advanced XML development, this presentation will cover all levels of expertise.
By highlighting the potential advantages and challenges of integrating AI with XML development tools and languages, the presentation seeks to inspire thoughtful conversation around the future of XML development. We’ll not only delve into the technical aspects of AI-powered XML development but also discuss practical implications and possible future directions.
Removing Uninteresting Bytes in Software FuzzingAftab Hussain
Imagine a world where software fuzzing, the process of mutating bytes in test seeds to uncover hidden and erroneous program behaviors, becomes faster and more effective. A lot depends on the initial seeds, which can significantly dictate the trajectory of a fuzzing campaign, particularly in terms of how long it takes to uncover interesting behaviour in your code. We introduce DIAR, a technique designed to speedup fuzzing campaigns by pinpointing and eliminating those uninteresting bytes in the seeds. Picture this: instead of wasting valuable resources on meaningless mutations in large, bloated seeds, DIAR removes the unnecessary bytes, streamlining the entire process.
In this work, we equipped AFL, a popular fuzzer, with DIAR and examined two critical Linux libraries -- Libxml's xmllint, a tool for parsing xml documents, and Binutil's readelf, an essential debugging and security analysis command-line tool used to display detailed information about ELF (Executable and Linkable Format). Our preliminary results show that AFL+DIAR does not only discover new paths more quickly but also achieves higher coverage overall. This work thus showcases how starting with lean and optimized seeds can lead to faster, more comprehensive fuzzing campaigns -- and DIAR helps you find such seeds.
- These are slides of the talk given at IEEE International Conference on Software Testing Verification and Validation Workshop, ICSTW 2022.
In his public lecture, Christian Timmerer provides insights into the fascinating history of video streaming, starting from its humble beginnings before YouTube to the groundbreaking technologies that now dominate platforms like Netflix and ORF ON. Timmerer also presents provocative contributions of his own that have significantly influenced the industry. He concludes by looking at future challenges and invites the audience to join in a discussion.
Full-RAG: A modern architecture for hyper-personalizationZilliz
Mike Del Balso, CEO & Co-Founder at Tecton, presents "Full RAG," a novel approach to AI recommendation systems, aiming to push beyond the limitations of traditional models through a deep integration of contextual insights and real-time data, leveraging the Retrieval-Augmented Generation architecture. This talk will outline Full RAG's potential to significantly enhance personalization, address engineering challenges such as data management and model training, and introduce data enrichment with reranking as a key solution. Attendees will gain crucial insights into the importance of hyperpersonalization in AI, the capabilities of Full RAG for advanced personalization, and strategies for managing complex data integrations for deploying cutting-edge AI solutions.
Observability Concepts EVERY Developer Should Know -- DeveloperWeek Europe.pdfPaige Cruz
Monitoring and observability aren’t traditionally found in software curriculums and many of us cobble this knowledge together from whatever vendor or ecosystem we were first introduced to and whatever is a part of your current company’s observability stack.
While the dev and ops silo continues to crumble….many organizations still relegate monitoring & observability as the purview of ops, infra and SRE teams. This is a mistake - achieving a highly observable system requires collaboration up and down the stack.
I, a former op, would like to extend an invitation to all application developers to join the observability party will share these foundational concepts to build on:
Observability Concepts EVERY Developer Should Know -- DeveloperWeek Europe.pdf
Pipeline Design for Isothermal, Laminar Flow of Non-Newtonian Fluids
1. GBH Enterprises, Ltd.
Process Engineering Guide:
GBHE-PEG-FLO-303
Pipeline Design for Isothermal,
Laminar Flow of Non-Newtonian
Fluids
Information contained in this publication or as otherwise supplied to Users is
believed to be accurate and correct at time of going to press, and is given in
good faith, but it is for the User to satisfy itself of the suitability of the information
for its own particular purpose. GBHE gives no warranty as to the fitness of this
information for any particular purpose and any implied warranty or condition
(statutory or otherwise) is excluded except to the extent that exclusion is
prevented by law. GBHE accepts no liability resulting from reliance on this
information. Freedom under Patent, Copyright and Designs cannot be assumed.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
2. Process Engineering Guide:
Pipeline Design for Isothermal,
Laminar Flow of Non-Newtonian
Fluids
CONTENTS
SECTION
0
INTRODUCTION/PURPOSE
3
1
SCOPE
3
2
FIELD OF APPLICATION
3
3
DEFINITIONS
3
4
RHEOLOGICAL BEHAVIOR OF PURELY VISCOUS
NON-NEWTONIAN FLUIDS
3
4.1
4.2
Experimental Characterization
Rheological Models
4
5
5
PRESSURE DROP-FLOW RATE RELATIONSHIPS
BASED DIRECTLY ON EXPERIMENTAL DATA
7
5.1
5.2
Use of Shear Stress – Shear Rate Data
Tubular Viscometer Data
7
9
6
PRESSURE DROP – FLOW RATE RELATIONSHIPS
BASED ON RHEOLOGICAL MODELS
10
7
LOSSES IN PIPE FITTINGS
11
7.1
7.2
7.3
7.4
7.5
Entrances Losses
Expansion Effects
Contraction Losses
Valves
Bends
12
13
14
14
14
8
EFFECT OF WALL SLIP
14
9
VELOCITY PROFILES
17
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
3. 9.1
9.2
9.3
10
Velocity Profile from Experimental Flow-Curve
Velocity Profile from Rheological Model
Residence Time Distribution
CHECKS ON THE VALIDITY OF THE
DESIGN PROCEDURES
18
18
18
20
10.1
10.2
10.2
Rheological Behavior
Validity of Experimental Data
Check on Laminar Flow
20
21
21
11
NOMENCLATURE
22
12
REFERENCES
23
FIGURES
1
FLOW CURVES FOR PURELY VISCOUS FLUIDS
4
2
PLOTS OF D∆P/4L VERSUS 32Q/ɳD3 FOR PURELY
VISCOUS FLUIDS
4
3
LOG-LOG PLOT OF t VERSUS ý
5
4
FLOW CURVE FOR A BINGHAM PLASTIC
6
5
LOG-LOG PLOT FOR A GENERALIZED BINGHAM
PLASTIC
6
6
CORRELATION OF ENTRANCE LOSS
12
7
CORRELATION OF EXPANSION LOSS
14
8
EFFECT OF “WALL SLIP” ON VELOCITY PROFILE
15
9
D∆P/4L VERSUS Q/ɳR3 WITH WALL SLIP
15
10
EVALUATION OFUs WITH Ʈw
16
11
VARIATION OF Us WITH Ʈw
16
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
4. 12
PLOT OF D∆P/4L VERSUS 8 (ū- Us)/D FOR
CONDITIONS OF WALL SLIP
13
CUMULATIVE RESIDENCE TIME DISTRIBUTION
TO POWER LAW FLUIDS
14
17
20
EFFECTS OF TUBE LENGTH AND DIAMETER ON
RELATIONSHIP BETWEEN D∆P/4L AND 32Q/ɳD3
DOCUMENTS REFERRED TO IN THIS PROCESS
ENGINEERING GUIDE
20
24
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
5. 0
INTRODUCTION/PURPOSE
This Process Engineering Guide is one of a series of guides on non-Newtonian
flow prepared by GBH Enterprises.
1
SCOPE
This Guide presents the basis for the prediction of flow rate - pressure drop
relationships for the laminar flow of non-Newtonian fluid through circular pipes
and selected fittings under isothermal conditions. In addition, the prediction of
velocity profiles and hence residence time distributions are covered.
The Scope is subject to the following limitations:
(a)
the fluid is homogeneous and remains so under all conditions, i.e. if the
material is a suspension of solids, then the solids do not settle;
(b)
the fluid is purely viscous in behavior, i.e. it does not exhibit timedependency of a thixotropic or anti-thixotropic kind, nor is it viscoelastic.
This restricts the predictions to fluids the rheological properties of which
may be expressed in the form: shear rate is a function of shear stress;
(c)
the flow is laminar;
(d)
there is no slip at the wall. Advice on the procedure to be adopted if slip
does occur is given in Clause 8;
(e)
the flow occurs under isothermal conditions.
Two distinct cases will be considered:
(1)
prediction based on idealized rheological models which aim to
approximate the observed behavior, and
(2)
predictions based directly on experimental measurements of the
rheological properties.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
6. 2
FIELD OF APPLICATION
This Guide applies to the process engineering community in GBH Enterprises
worldwide.
3
DEFINITIONS
For the purposes of this Guide no specific definitions apply.
4
RHEOLOGICAL BEHAVIOR OF PURELY VISCOUS
NON-NEWTONIAN FLUIDS
For a more general description of rheological behavior consult GBHE-PEG-FLO302. This Clause defines the terms used in this Guide.
4.1
Experimental Characterization
4.1.1 Shear stress - shear rate data from rotational viscometers
Many experimental techniques may be used (see Refs. 1, 2 & 3) to characterize
purely viscous fluids in rotational instruments. In these, the fluid is subjected to
simple shear e.g. between coaxial cylinders or between a shallow cone and a flat
plate. In each case the objective is to establish the relationship under simple
steady shearing conditions between the shear stress (f), and the shear rate (y).
When this relationship is shown graphically, the result is known as the 'flow
curve' for the material. Some typical examples are given in Figure 1 and others
may be found elsewhere (see Ref. 3)
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
7. FIGURE 1
FLOW CURVES FOR PURELY VISCOUS FLUIDS
4.1.2 Flow rate-pressure drop data from tubular viscometers
In the case of tubular viscometers the relationship between pressure drop and
flow rate is determined experimentally. The data are normally presented
3
graphically by plotting 32Q/ɳD (which is related to shear rate) against
DΔ.P/4L (which is the wall shear stress). Typical examples are shown in Figure
2 for various types of fluid (see Clause 11 for nomenclature).
FIGURE 2 PLOTS OF DΔ.P/4L VERSUS 32Q/nD3 FOR PURELY VISCOUS
FLUIDS
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
8. In this form, the data may be used directly for pipeline design using a scale-up
procedure (see Ref. 2). Alternatively, the data can be processed (see Ref. 2) to
yield the basic relationship between shear stress and shear rate, i.e. the
experimental flow curve, as in the case of rotational viscometers considered
above.
4.2
Rheological Models
A large number of empirical models have been proposed which aim to
approximate the observed rheological behavior of real fluids and details of these
can be found elsewhere.
However, many of these are of little value for engineering design purposes and it
is usually adequate to consider only a limited number. These are discussed
below.
4.2.1 The power-law model
This gives the following relationship between the stress (t) and the shear rate (ẏ):
where K is the 'consistency index' and ɳ is the 'power·law index'. This model can
describe both shear thinning behavior (ɳ < 1) and shear thickening behavior
(ɳ > 1).
If a real fluid approximates to power· law behavior then a logarithmic plot of t
against ẏ gives a straight line from which ɳ may be obtained from the slope, and
K from the intercept.
Very often the data do not give a linear logarithmic plot over the full range of
shear rate. Even so, the model can still be useful if the conditions of shear rate or
stress in the engineering situation under consideration are within the linear
region. A typical example is given in Figure 3.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
9. 4.2.2 The Bingham plastic model
This describes fluids which exhibit a Yield stress, ty, i.e.:
where µρ is the 'plastic viscosity'. These parameters can easily be determined
from the flow curve, as Indicated in Figure 4.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
10. 4.2.3 The generalized Bingham-plastic model
This combines the characteristics of the previous two models viz:
For a given fluid, t ẏ can be found from the flow curve as for a simple Bingham
plastic fluid. The remaining parameters, ɳ and K, may then be determined from
the slope of a logarithmic plot of t . t ẏ against ẏ as illustrated in Figure 5.
Equation (3) is clearly the most versatile model, since the other two are special
cases of it. This is the model which will be mainly used in this Guide.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
11. FIGURE 5
5
LOG-LOG PLOT FOR A GENERALISED BINGHAM PLASTIC
PRESSURE DROP-FLOW RATE RELATIONSHIPS BASED DIRECTLY
ON EXPERIMENTAL DATA
Design methods are given for two cases: using shear stress and shear rate data
and using unprocessed data from tubular viscometers.
5.1
Use of Shear Stress - Shear Rate Data
For a purely viscous non-Newtonian fluid in laminar flow in a tube assuming there
is no slip at the wall it may be shown that:
where f(t) is the function which defines the rheological behavior of the fluid i.e.:
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
12. It therefore gives the relationship between Q, D and ΔP/L.
The general procedure to be followed is first to approximate the experimental
flow curve Equation (5) by a polynomial and to evaluate Equation (4) by
numerical integration.
Note:
It is necessary to include the low shear rate region where data are often sparse.
In practice this is does not lead to serious errors.
A number of cases of practical interest will be considered separately.
5.1.1 Q from Δ.P/L and D
The steps are as follows:
(a)
Calculate the wall shear stress, tw directly from:
(b)
Evaluate the integral:
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
13. 5.1.2 ΔP from Q, D and L
In this case it is not possible to calculate ΔP explicitly and a trial and error
solution is necessary as follows:
(a)
In order to get a first estimate of the wall shear stress (from which ΔP/L
can be found) evaluate ẏw N, the wall shear rate for a Newtonian fluid at
the same flow rate. from:
(b)
Calculate tw N, the corresponding wall shear stress, from the polynomial
approximation for ẏ = f(t) at tw N ·
(c)
Set tw = (1 + ki) tw N where k is small, say 0.001.
(d)
Set i = 0 and find I(tw) by numerical integration from Equation (8).
(e)
Calculate Q from Equation (9).
(f)
If Q > Q desired set t = -1 etc. and iterate
or:
if Q < Q desired set t = +1 etc. and iterate to give the correct value for Q and
hence t w
(g)
From the correct value of, t
w
evaluate ΔP from:
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
14. 5.1.3 D from ΔP/L and Q
In this case it is difficult to find a reasonable first estimate for D but the following
method is proposed.
(a)
Calculate t / ẏ from the polynomial approximation to ẏ = f(t) at some
arbitrary value of ẏ (or t), say the midpoint of the experimental data, and
set this equal to an apparent viscosity, µa, i.e.:
(b)
Evaluate a first estimate of diameter, the diameter DN for a Newtonian fluid
of viscosity µa from:
(c)
Set D = (1 + Ki) DN where k is small.
(d)
Set i = 0 and evaluate tw = DΔP/4L.
(e)
Find I(tw) by numerical integration from Equation (8).
(f)
Calculate Q from Equation (9).
(g)
If Q > Q desired set i = -1 etc. and iterate
or
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
15. If Q < Q desired set i = + 1 etc. and iterate to give the value of D, which gives
the desired Q.
(h) Choose a standard diameter nearest to this value of D and repeat either
procedures 5.1 or 5.1.2.
5.2
Tubular Viscometer Data
It has been noted earlier in 4.1.2 (and it can be seen from Equations (4) and (6))
3
that for laminar flow of a purely viscous fluid through a tube 32Q/πD is function
only of the wall shear stress, DΔP/4L, and typical results are given graphically in
Figure 2. The methods proposed for pipeline design first involve a polynomial
approximation for the data, i.e.:
Note:
32Q/πD3 IS the wall shear rate for a Newtonian fluid. It is not so for a nonNewtonian fluid.
5.2.1 Q from ΔP/L and D
The steps are as follows:
(a)
Calculate DΔP/4L.
(b)
Evaluation 32Q/πD from polynomial Equation (14) and hence calculate
Q since D is known.
3
5.2.2 ΔP/L from Q and D
(a)
(c)
3
Calculate 32Q/πD
Evaluation DΔP/4L from polynomial Equation (14) and hence ΔP/L since
D is known.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
16. 5.2.3 D from ΔP/L and Q
Again the difficulty is to find a reasonable first estimate for D but we can proceed
In a manner similar to that adopted In 5.1.3.
(a) Find the ratio of:
from polynomial Equation (14) at a convenient value of 32Q/πD , say the
midpoint of the data.
3
(b)
Set this ratio equal to µa.
(b) Calculate the equivalent 'Newtonian diameter' DN, from Equation (13), i.e.:
(d)
Set D = (1 + ki) DN where k is small.
(e)
Calculate DΔP/4L and use this to calculate 32Q/πD from polynomial
Equation (14).
(f)
Calculate Q from 32Q/πD , compare this value of Q with the desired
value of Q and iterate on D to give the correct value of D, as in 5.1.3.
(g)
Choose a standard value of D near to the calculated value and repeat
either 5.2.1 or 5.2.2 as desired.
3
3
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
17. 6
PRESSURE DROP FLOW RATE RELATIONSHIPS BASED ON
RHEOLOGICAL MODELS
Since the generalized Bingham model, Equation (3), is the most versatile only
this will be considered. It can be shown (see Ref. 3) that by using this model in
conjunction with Equation (4) that:
This equation can be used to carry out pipeline design calculations if the three
rheological parameters, tẏ, ɳ and K have been determined. Again, three cases
are of interest.
6.1
Q from ΔP/L and D
The steps are as follows:
(a)
Calculate 'w from Equation (7).
(b)
Substitute 'w in Equation (15) to give Q directly.
6.2
ΔP/L from Q and D
In this case an iterative solution is necessary.
(a) Make a first estimate of the wall shear stress by assuming the fluid to be
Newtonian, i.e. by putting tẏ = 0 and ɳ = 1 in Equation (15). This gives:
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
18. (b)
Set tw = (1 + ki) tw N, etc.
(c)
Evaluate Q from Equation (15), compare this value of Q with the desired
value of Q and iterate on 'w to give the correct value of tw
(d) Evaluate Δ.P from tw using Ll.P = 4L , tw / D.
D from Δ.P/L and Q
6.3
Again an iterative solution is necessary.
(a) Make a first estimate of D by putting tw = 0 and ɳ = 1 in Equation (15)
which gives the 'Newtonian diameter', DN, as
(b)
Again set D = (1 + ki) DN where k is small.
(c)
Calculate tw = DΔP/4L and use this to calculate Q from Equation (15).
(d)
Compare this value of Q with the desired value of Q and iterate on D to
give the correct value of D as in 5.1.3 and 5.2.3.
(e)
Choose a standard value of D near to the calculated value and repeat
either 6.1 or 6.2 as desired.
7
LOSSES IN PIPE FITTINGS
These are not necessarily insignificant especially for relatively short pipes.
Whereas comprehensive data exist for a large range of fittings for low viscosity
Newtonian fluids in turbulent flow, the data for viscous Newtonian liquids and for
non-Newtonian fluids are very sparse. In general the losses for shear thinning
fluids could be expected to be less than for a Newtonian fluid with the same low
shear-rate viscosity. For shear thickening fluids this converse is likely and special
care is therefore necessary. Some of the more Important fittings will be
considered in turn.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
19. 7.1
Entrance Losses
The pressure drop in the entrance region of a pipe is greater than that for fully
developed flow in an equal length of pipe due to:
(a)
the conversion of pressure energy into kinetic energy;
(b)
excessive fluid friction due to the high velocity gradients near the wall.
7.1.1 Power law fluids
For a given length of pipe L from the entrance, the pressure drop ΔP for a power
law fluid in laminar flow may be written in the form:
and Nen is the excess mechanical energy loss due to the entrance, expressed as
a number of velocity heads, i.e. the excess head loss is:
where ū is the mean velocity in the pipe.
Experimental and theoretical results for Nen are available (see Refs. 4, 5 & 6)
and these are summarized in Figure 6.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
20. FIGURE 6
CORRELATION OF ENTRANCE LOSS
It is proposed that the value of Nen to be used in design is:
since this gives a slight conservative estimate. The range 0 < n < 2 covers most
fluids of commercial interest.
7.1.2 Fluids not obeying the power law
No theoretical studies have been found for fluids which do not approximate to
power law behavior. Experimental studies on a Bingham plastic slurry (see Ref.
6) indicated a value of Nen of 1.2, i.e. similar to that for Newtonian fluids. It is
therefore proposed that the fluid be represented as closely as possible by a
power law and the appropriate value of n used to determine N en .
7.2
Expansion Effects
Expansion losses can be predicted theoretically (see Refs. 2 & 3). For a power
law fluids the excess loss in an expansion from D1 to D2, expressed as a number
of velocity heads, is given by:
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
21. The excess head loss is given by:
where ū1 is the mean velocity in the pipe before the expansion.
Similar results could be found for other rheological models but since the loss is
small it is proposed that the closest power law approximation to any fluid be used
to evaluated N ex from Equation (20).
Equation (20) is plotted in Figure 7. Again it is seen that an empirical relationship:
gives a conservative estimate and it is proposed that this be used, which is
analogous to Equation (20) for entrance losses in place of Equation (21) for
expansion losses.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
22. FIGURE 7
7.3
CORRELATION OF EXPANSION LOSS
Contraction Losses
A theoretical analysis for contraction losses is not possible (because of the
unknown area and velocity profile in the vena contracta). However, the loss is
certainly going to be less than that for a sharp entrance and since the loss is
small it is proposed that Equation (19) be used again, I.e.:
7.4
Valves
Globe valves, even when open, have a large loss and it is recommended that
these should not be used with viscous non-Newtonian fluids. Gate valves are to
be preferred and when these are fully open It is proposed that the same
contraction as given in Equation (22) should again be used i.e.:
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
23. 7.5
Bends
No data have been found for losses in bends for non-Newtonian fluids. However,
for laminar flow. the losses should be small and it is proposed that they be
neglected.
8
EFFECT OF WALL SLIP
When thick solid/liquid suspensions or liquid/liquid emulsions are pumped
through tubes the dispersed phase adjacent to the wall, in some cases, migrates
towards the centre of the tube leaving a thin layer of continuous phase near the
wall. The 'plasma' layer is of relatively low viscosity and acts as a lubricant for the
central plug of homogeneous fluid. This wall effect is equivalent to a slip velocity
(11) at the wall as shown in Figure 8.
However, in the case of suspensions, there is no true slip as can sometimes be
observed when polymeric melts flow through smooth tubes. The effective slip
velocity is a function of wall shear stress and normally increases with wall shear
stress.
With such anomalous flow behavior near the wall the relationship between
Q/π R3 and RΔP/ 2L for a given fluid is no longer independent of the radius of
the tube. Instead a separate line will be obtained for each tube radius (with a
fixed length) as shown in Figure 9.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
24. FIGURE 8
EFFECT OF 'WALL SLIP' ON VELOCITY PROFILE
FIGURE 9
DΔP/4L VERSUS Q/πR3 WITH WALL SLIP
In place of Equation (4) we now have:
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
25. where ū g (tw,) is the effective wall slip velocity.
From data such as that shown in Figure 9 we could plot Q/πR against 1/R for a
given value of the wall shear stress, tw, This would give a straight line of slop us
as shown in Figure 10.
3
FIGURE 10 EVALUATION OF uS (tw,)
By repeating this procedure at different value of tw we could establish us as a
function of tw, for example as shown in Figure 11.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
26. FIGURE 11 VARIATION OF us WITH tw
Therefore, in place of Equation (14), viz.:
we can now establish from the experimental data the relationship:
Which is illustrated in Figure 12.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
27. FIGURE 12 PLOT OF DΔP/ 4L VERSUS 8(ū - us) / D FOR CONDITIONS OF
WALL SLIP
This is then used in the procedures described in 5.2 in place of Equation (14) for
pipeline design based on tubular viscometer data.
A similar method has to be employed to derive the true flow curve, i.e. ẏ = f(t)
from tubular viscometer data under conditions of wall slip.
9
VELOCITY PROFILES
For time-independent fluids we have that:
Hence:
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
28. I.e. if there is no wall slip.
Since r = Rṫ / tw we get the velocity profile in the form:
This can be evaluated numerically from rheological data or in terms of the
parameters of a rheological model.
If wall slip occurs the slip velocity has to be added to the value of u(r) to get the
total velocity.
9.1
Velocity Profile from Experimental Flow-Curve
The procedure in this case is:
(a)
express ẏ = f(ṫ) as a polynomial;
(b)
evaluate the integral in Equation (27) over a range of values of ṫ to give
u(r) for a given value of R and tw;
(c)
if wall slip occurs. add Us to u(r) for the corresponding value.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
29. 9.2
Velocity Profile from Rheological Model
Again only the generalized Bingham model, Equation (25), will be considered at
this is the most general. For this the velocity profile is given by:
where tr is the shear stress at radius r, i.e.,
From equation (28) u(r) can be evaluated directly if K, n, ṫẏ and ΔP/L are
known.
It should be noted that when n = 1, ṫẏ = 0 and K = µ this reduces to:
Which may be written:
i.e. the velocity profile for a Newtonian fluid.
If wall slip occurs us, has again to be added to u(r) to get the total velocity.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
30. 9.3
Residence Time Distribution
It is sometimes of Importance to know the distribution of residence times for
laminar flow through tubes. Examples are to be found in tubular reactors, the
displacement of material In multi-product lines or in the clearing of lines by
washing out.
For a pipe of length L the residence time, t, at radius r is given by:
and therefore the residence time of fluid elements will depend on their radial
position, the element at the centre line having the shortest residence time.
Let f(t) dt be the fraction of the total output, Q, which has been in the pipe for
times between t and t + dt. Then:
For a Newtonian fluid, with a velocity profile given by:
This leads to
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
31. Where ṫ is the mean residence time, given by:
Similarly, for a power-law fluid we have:
We can define the cumulative distribution function F(t) as the fraction of the
outflow which has residence times less than t, ie. F(t) is defined by:
where t(o) is the residence time of the central filament (which is the minimum).
For a Newtonian fluid this gives:
The function F(t) IS shown graphically for power law fluids in Figure 13.
In general, for any time-independent fluid f(t) and F(ṫ) can be found numerically
from the velocity profile derived in 9.1 and 9.2 by numerical integration.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
32. FIGURE 13 CUMULATIVE RESIDENCE TIME DISTRIBUTION TO POWER
LAW FLUIDS
10
CHECKS ON THE VALIDITY OF THE DESIGN PROCEDURES
10.1
Rheological Behavior
These design procedures are only valid for purely viscous fluids and any
significant time dependency or viscoelasticity could give rise to serious errors.
The well established methods of rheological characterization will allow such
behavior to be observed.
10.1.1
Time dependency
Rotational instruments in steady shear show a gradual decrease in torque at
constant speed for thixotropic fluids and a corresponding increase for antithixotropic (rheopectic) fluids. In tubular viscometers time-dependency can be
detected qualitatively since the relationship between Q/πR3 and RΔ.P/2L is not
independent of tube radius or length but is as shown in Figure 14. It should be
noted that the effect of increasing tube diameter for a fixed tube length for a
thixotropic fluid is similar to that observed with wall slip, as can be seen from
Figure 9 and 14. However, time-dependency and wall slip can be distinguished
by the fact that, with a fixed diameter but variable length, separate curves will still
be obtained with a thixotropic fluid but not with a time-independent fluid, which
only exhibits wall slip.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
33. FIGURE 14
10.1.2
EFFECTS OF TUBE LENGTH AND DIAMETER
ON RELATIONSHIP BETWEEN DΔP/4L AND 32Q/ΠD3
Viscoelasticity
Viscoelasticity is detected by dynamic experiments in rotational instruments.
These can be of the transient or frequency response kind.
Tubular viscometers can be used in a variety of modes, for example to observe
die-swell, the axial thrust produced by a free jet or the phenomenon of the
ductless syphon. Details can be found in the literature (Ref.7).
It should be noted that whereas viscoelastic effects will not have much influence
on pressure drop for steady flow in a uniform pipe, the losses in pipe fittings can
be greatly increased.
10.2
Validity of Experimental Data
It is important to check that the experimental data have been obtained over the
range of shear stress and/or shear rate which the fluid will experience in the fullscale pipeline. It is particularly important to note that for large pipelines data at
low shear rates may be required and the data should at least cover the range of
shear rates ẏw to ẏw/4.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
34. 10.3
Check on Laminar Flow
These design procedures apply only to laminar flow and it is necessary to check
that this restriction applies.
This can be done by calculating a Reynolds number.
where the effective viscosity µe is defined by:
The condition for laminar flow is then:
An alternative criterion is based on the velocity profile, where the condition for
laminar flow is (Ref. 8):
This reduces to the accepted condition that Re < 2000 for laminar flow.
The added complication of using this criterion is not considered necessary at this
stage.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
35. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
36. 12
REFERENCES
(1)
Van Wazer, J.R. et ai, 'Viscosity and Flow Measurement' Interscience
Publishers, 1963.
(2)
Wilkinson, WL, 'Non-Newtonian Flow and Heat Transfer' Wiley, 1967.
(3)
Skeliand, A.H.P., 'Non-Newtonian Flow and Heat Transfer' Wiley, 1967.
(4)
Lemmon, H.E., Phd Thesis, University of Utah, U.S.A. 1966.
(5)
Lanieve, H.L., MS Thesis, University of Tennessee, U.S.A.,1963.
(6)
Weltman, R.N., and Keller, T.A., Tech. Note 3889 (1957).
(7)
Walters, K., 'Rheometry', 1977.
(8)
Ryan, NW. and Johnson, M.M., A.I.Ch.E.J. 1959,5,433.
DOCUMENTS REFERRED TO IN THIS PROCESS ENGINEERING GUIDE
This Process Engineering Guide makes reference to the following documents:
ENGINEERING GUIDES
GBHE-PEG-FLO-302
Interpretation and Correlation of Viscometric Data
(referred to in Clause 2).
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
37. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com