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8/8/2020
1
Effect of Air
Pollution
• Green House Effect
• Global Warming
• Acid Rain
• Ozone Layer Depletion
• Photochemical Smog
Green House Effect
• The Greenhouse shield that keeps our
planet warm enough to sustain life ……….
• But now is becoming a heat trap
threatening to disrupt the global
environment.
• Thin layer of certain gases - 25km up-
acts like glass letting heat through but
stoppping enough radiation back in to
warm our world.
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• The heat trap provided by
atmospheric CO2 probably help to
create the conditions necessary for
the evolution of life and greening of
the earth
• Compare to moderately warm
planets, Mars, with too little CO2 in
its atmosphere is frozen cold and
Venus with to much dry…
• But now the expansion of human activity
in industry and agriculture is changing the
fundamental environmental system
making the “GREENHOUSE” layer denser,
keeping in more heat.
• CO2 is the chief single culprit – other 39
known gases
• The atmospheric content of CO2 has
increased by 25% in last 100 Years
• Raise the planet temperature between 1.5
– 4.5 oC
• Sea level around 12cm.
Green House Effect
• “The process of warming of earth surface
due to blanketing of CO2 in the
atmosphere is called as “GREEN HOUSE
EFFECT”
• The phenomena due to which the earth
retains heat is called as GREENHOUSE
EFFECT.
• The main green house gases
– CO2
– Methane
– Chloro floro carbon
– NO2
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• CO2 is confined exclusively to the
troposphere, its higher concentration
may act as serious pollutant.
• Under normal condition the temp. at
the surface of the earth is
maintained by the energy balance of
the sunrays that strike the planet
and heat that is radiated back into
space.
• Solar energy in the form of light
radiation has wavelengths in the
range of 0.2 to 4 µm.
• It will loss some energy after striking
the earth and will be converted to
heat energy of longer wavelengths.
• The wavelength of this terrestrial
reradiation, from earth to
atmosphere is more..(4-100 µm).
• E = hv = hc/λ
• As Energy Wavelength
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• CO2 has radiation absorbance band in the
range of 12-18 µm wavelength.
• Thus CO2 is present in the atmosphere, it
allows the incoming solar radiation to pass
through but does not allow the reradiation
from the earth to space to pass through.
• This is the origin of the term GREEN
HOUSE EFFECT.
• Due to the presence of the CO2 layer in the
atmosphere it causes much heating effect
on the earth atmosphere
• Due to greenhouse effect the earth
atmosphere rises every year the world wide
concentration of CO2 is increasing at a rate
of 0.75 ppm & temp is rising at the rate of
0.05 0C every year
• Nearly 100 years ago CO2 275ppm
• Today 350ppm
• By 2035 & 2040 450ppm
Imagine the earth’s temperature
then??????
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Greenhouse gases
• Greenhouse gases covered by the
Kyoto Protocol are:
CO2 Carbon dioxide
CH4 Methane
N2O Nitrous Oxide
SF6 Sulphur hexafluoride
PFCs Perfluorocarbones
HFCs Hydrofluorocarbons
The greenhouse gases
Greenhouse Gas
Emissions
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• Combustion of fossil fuels?
– coal-burning power plants,
– automobile exhausts,
– factory smokestacks,
– other waste vents of the human environment
– contribute 22 billion tons of carbon dioxide and
other greenhouse gases each year
• Animal agriculture, manure, natural gas,
rice paddies, landfills, coal, and other
anthropogenic sources contribute about
450 million tons of methane each year
• Atmospheric concentrations of CO2 and
CH4 have increased by 31% and 149%
respectively above pre-industrial levels
since 1750
Effect of Greenhouse gases
Effect of Greenhouse gases
• According to WHO, mosquitoes may
have longer lives and breeds in
larger nos. hence spreads MALARIA.
• Warmer & Humid condition enhance
growth of bacteria & moulds.
• CO2 is also expected to influence
intensely the process of depletion of
OZONE layer
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• The temperature of the atmosphere
is increasing day by day
• the glaciers, polar ice caps melts,
resulting in flooding of many low
laying areas
• The climate changes from one region
to another region with global CO2
increases day by day
• increasing the sea level
• At a higher the CO2 undergoes
photochemical reacting producing
CO, Which is more poisonous
Global Warming
• An increase in the average temperature
of the Earth’s atmosphere and oceans
• Global temperature on both land and
sea increased by 0.6 ± 0.2 °C over the
past century
• Volume of atmospheric carbon dioxide
increased from 280 parts per million in
1800 to 367 in 2000, a 31% increase
over 200 years
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Our Changing Climate
• Global mean surface temperatures have
increased 0.5-1.0°F since the late 19th
century
• The snow cover in the Northern
Hemisphere and floating ice in the Arctic
Ocean have decreased
• Sea level has risen 4-8 inches over the
past century
• Global surface temp. could rise 1- 4.5°F
(0.6-2.5°C) in the next fifty years, and
2.2-10°F (1.4-5.8°C) in the next century
What causes it?
• Human Impacts- Atmospheric greenhouse gases trap
some of the outgoing energy, retaining heat
• Natural Impacts- Change in sun’s energy output
Volcanoes Water Vapor Clouds
Greenhouse Gases -
• CO2 Methane Nitrous oxide Fluorinated compounds
• Since industrial revolution, atmospheric
concentrations of carbon dioxide increased 30%,
methane more than doubled, nitrous oxide risen by
15%.
• These increases have enhanced the heat-trapping
capability of the earth’s atmosphere
• Combustion of fossil fuels, coal-burning power plants,
automobile exhausts, factory smokestacks, other waste
vents of the human environment contribute 22 billion
tons of carbon dioxide and other greenhouse gases each
year
• Animal agriculture, manure, natural gas, rice paddies,
landfills, coal, and other anthropogenic sources
contribute about 450 million tons of methane each year
• Atmospheric concentrations of CO2 and CH4 have
increased by 31% and 149% respectively above pre-
industrial levels since 1750
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Greenhouse Gas Emissions
• Power Plants
40% of carbon dioxide emissions stem from the
burning of fossil fuels for the purpose of electricity
generation
• Cars
20% of carbon dioxide emissions comes from the
burning of gasoline in internal-combustion engines of
cars and light trucks with poor gas mileage contribute
the most to global warming
• Trucks
Another 13% of carbon dioxide emissions come from
trucks used mostly for commercial purposes
• Airplanes
Aviation causes 3.5 percent of global warming, and
the figure could rise to 15 percent by 2050
• Carbon Dioxide from Building structure account
for about 12% of carbon dioxide emissions
Methane
• Methane is more than 20 times as effective as CO2 at
trapping heat in the atmosphere 2004 Levels of
atmospheric methane have risen 145% in the last 100
years
• Derived from sources such as rice paddies, bovine
flatulence, bacteria in bogs and fossil fuel production.
• In flooded fields, anaerobic conditions develop and
the organic matter in the soil decomposes
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Nitrous oxide
• Naturally produced by oceans and
rainforests , man-made sources-nylon and
nitric acid production, the use of fertilizers
in agriculture, cars with catalytic converters
and the burning of organic matter
• Deforestation
Responsible for 25% of all carbon
emissions entering the atmosphere by the
burning and cutting of about 34 million
acres of trees each year .
Effects of Global
Warming
Negative Effects
• Rising Sea Level
• Change of precipitation and local climate
conditions;
• acid rain
• Alteration of forests and crop yields
• Expansions of deserts into existing rangelands
• More intense rainstorms
• Destabilization of Ocean currents
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Positive Effects
• Can stimulate plant growth in places where
CO2 and temperature are the limiting factors
(preventing photorespiration which can destroy
existing sugars).
• Melting Arctic ice may open the Northwest
Passage in summer, which would cut 5,000
nautical miles from shipping routes between
Europe and Asia
What Can be Done:
Alternatives
• Solar Energies
• Wind Power
• Biomass
• Geothermal
• Hybrid
• Fuel Cell
• Battery-Electric
Hybrid Fuel Cell Battery-Electric
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Kyoto Protocol
• 1997, Kyoto, Japan developed countries
agreed to specific targets for cutting their
emissions of greenhouse gases
• Industrialized countries committed to an
overall reduction of emissions of greenhouse
gases to 5.2% below 1990 levels for the period
2008 - 2012
Ozone Layer Depletion
Introduction
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• The layer of life-protecting ozone found at
the top of the stratosphere.
• A brief history of the discovery of the
ozone 'hole' is included.
• The general concepts found in this section
include the following:
• Concentrations of stratospheric ozone
represent a balance, established over
eons, between creative and destructive
forces and this balance, or dynamic
equilibrium, has been changed by human
activity.
• Ozone is formed in the earth's
stratosphere and is critical to life on earth
as we know it.
• There is compelling scientific evidence that
ozone is destroyed in the stratosphere and
that some human-released chemicals are
speeding up the breakdown of ozone in
the atmosphere.
• CFCs, a human-developed compound, are
particularly destructive to the breakdown
of ozone in the atmosphere.
• Ultraviolet radiation is present in natural
outdoor light and can be blocked or
filtered by various substances.
Historical Perspective
• The ozone 'hole', it is really not a hole but
rather a thinning of the ozone layer in the
stratosphere.
• We will use the term 'hole' in reference to the
seasonal thinning of the ozone layer.
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• The appearance of a hole in the earth's
ozone layer over Antarctica, first detected in
1976.
• 1974: Rowland & Molina theorize CFCs
destroy stratospheric ozone molecules
• 1975: University of Michigan / Harvard
papers predict that CFCs deplete Earth’s
ozone layer
• 1985: Ozone holes found over Antarctic
• 1988: Ozone layer thinning over North Pole
• 1993: Thinning over mid-latitudes of the
Northern Hemisphere
• 1997: Low values of total ozone occur in
Arctic as well as Antarctic
Antarctic Ozone Hole
Progression
1979 1986 1991
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Earth’s Atmosphere
CH4 itself is an important greenhouse gas, and links
climate with air pollution via its influence on tropospheric
ozone
Ozone Layer Depleting
Chemicals
• chlorofluorocarbons (CFCs)
– Freon-11, Trichlorofluromethane (CCl3F)
– Freon-12, Dichlorofluromethane (CCl2F)
– Freon-22, CHClF2CClF2
– Freon-114, CClF2CClF2
– Freon-115, CClF2CF3
• carbon tetrachloride (CCl4)
• methyl chloroform (CH3CCl3)
• hydrochloric acid (HCl)
• methyl chloride (CH3Cl)
• methyl bromide(CH3Br)
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• Freon 11: A/C, Refregeration,
Cleaning Foams, aerosols etc…
• Freon 22: aerosol-propellants
• Freon 13: Refrigeration
• Freon 114:aerosol, refregeration,
cleaning foams etc.
• CF2BrCl: used in Fire extingushers
Ozone Layer Depleting Chemicals:
CFCs
• CFCs are inert, non reactive,
nontoxic, nonflammable.
• Human-made CFCs used in:
- refrigeration
- air conditioning
- foam blowing
- cleaning electronic components
- solvents
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•Ozone is a triatomic form of oxygen
(O3) found in Earth’s upper and
lower atmosphere.
•The ozone layer, situated in the
stratosphere about 15 to 30 km above
the earth's surface.
•Ozone protects living organisms by
absorbing harmful ultraviolet
radiation (UVB) from the sun.
•The ozone layer is being destroyed
by CFCs and other substances.
• Ozone depletion progressing
globally except in the tropical zone.
The ozone layer
www.epcc.pref.osaka.jp/apec/ eng/earth/ozone_layer_depletion/susumu.html
Source: NASA
• Meteorological
mechanism
– Movement of air from
one place to another in
the upper stratosphere
– Cold temperature in
the upper atmosphere
causes nitric acid to
freeze into crystals
forming wispy pink
clouds
– Forms a vortex of
tightly twisted winds
thus forming a hole in
the upper atmosphere
Hole Formation Based on Two
different mechanisms:
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Chemical
Mechanism
• Different chemicals are responsible for the destruction of the
ozone layer
• Topping the list :
– chlorofluorocarbons (CFC’s)
– man-made, non-toxic and inert in the troposphere
– In the stratosphere are photolysed, releasing reactive chlorine
atoms that catalytically destroy ozone
• CFCl3 hv/ sunlight CFCl2 + Cl
• CFCl2 hv/ sunlight CFCl + Cl
• CF2Cl2 hv/ sunlight CF2Cl + Cl
• CClF2 hv/ sunlight CClFC + Cl
A combination of low temperatures and
elevated chlorine and bromine concentrations
are responsible for the destruction of ozone in
the upper stratosphere thus forming a “hole”.
(Kerr, 1987) www.met.sjsu.edu/~cordero/ education/education.htm
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Stratospheric Ozone and Ultraviolet Radiation (UVR)
• Ultra-violet radiation (UVR) high energy electromagnetic wave emitted from the
sun. It is made up of wavelengths ranging from 100nm to 400nm.
• UV radiation includes UV-A, the least dangerous form of UV radiation, with a
wavelength range between 315nm to 400nm, UV-B with a wavelength range
between 280nm to 315nm, and UV-C which is the most dangerous between 100nm
to 280nm. UV-C is unable to reach Earth’s surface due to stratospheric ozone’s
ability to absorb it. (Last, 2006)
Good & Bad Effects of Sunlight
Too much ultra-violet light can
result in:
• Skin cancer
• Eye damage such as cataracts
• Immune system damage
• Reduction in phytoplankton
• Damage to the DNA in various life-forms
– this has been as observed in Antarctic ice-fish that lack
pigments to shield them from the ultra-violet light
(they've never needed them before)
• Possibly other things too that we don't know about
at the moment
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• The impact of a depleted ozone layer on
human depends mainly on theire reaction
to UV-B rays.
• Every 1% loss in Ozone leads to 2%
increase in disease
• Increase the incidence of cataracts &
photocaratitis.
• Make the blood vessels carry more blood
making the skin hot, swollen or red and
cause sun burn
• It causes leukemia
• Crop yields, especially tea, cabbage and
soybean reduced.
Effects of UV radiation on biological organisms
• DNA damage ………………………….. Maximum effect on small and single cell
organisms
• Impaired growth and photosynthesis ...poor crop yields
• Phytoplankton: ………………………...Reduced uptake of CO2
…………………………………………..mortality
…………………………………………..Impaired reproductive capacity
• Nitrogen-fixing soil bacteria…………. Reduced, damaged
• Human health effects:
Suppressed immune system……………..Enhanced susceptibility to infection
…………………………………………..Increase risk of Cancer
Dermatology (skin)……………………...Sunburn
…………….………………………….....Loss of skin elasticity (Premature aging)
…………….…………………………… Photosensitivity
Neoplasia (cancer)……………………....Melanocytic (malignant melanoma)
…………….………………………….....Squamous cell skin – cancer
…………….……………………………Basal skin – cancer
Still questionable if causes lip cancer or cancer of
the salivary glands
Oculur (Eye)….…………………….......Cataract
…………….…………………………....Pterygium
(last, 1993)
UV-B Effects on
Human Effects
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Effects on Human Health
• Over exposure may:
– Increase risk of non-
melanoma and malignant
melanoma skin cancer
– Higher risks of malignant
melanoma from severe
sunburns – especially in
childhood
– Risk of malignant
melanoma has increased
10%
– Risk of nonmalignant
melanoma has increased
26%
malignant
Non-malignant
www.ldeo.columbia.edu/.../ lectures/ozone_health/
Over Exposure
– Suppress immune system
– Accelerate aging of skin due high exposure
– Cause an outbreak of rash in fair skinned
people due to photo allergy – can be severe
dermis.multimedica.de/.../ en/13007/image.htm
Skin Protection
• Protect the skin against the solar
radiation using skin creams with Sun
Protective Factor
– The greater the numerical value of the
SPF the greater the protection
• Use lip balm with SPF
• Cover up
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www.ldeo.columbia.edu/.../ lectures/ozone_health
cornea is encountered first
then the lens
vitreous humor
• Increases the risk of
cataracts
– Induces type of protein
that provokes cleaving
(splitting) in the lens
– Leading cause of
blindness
– The prevalence of
cataract after age 30 is
doubling each decade
• Causes apterygial
– A wedge-shaped growth
over the central cornea
Over Exposure to UV-B….
Manifestations of…
Cataracts
Pterygium
Cancer
brought on
by over
exposure to
UV-B
Protection
• Sunglasses with 100% UV
block
• Wrap around sunglasses
• Eye protection for children
• Hats
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What Is Being Done to Counter the
Effects of Ozone Depletion?
• Montreal Protocol– panel of experts was
formed to investigate substances responsible for
hole formation
– Established policies that prevent future use of
certain types of chemicals
– Stipulated that the production and consumption of
compounds contributing towards depletion of ozone
in the stratosphere were to be phased out by the
year 2000 (2005 for methylchloroform)
Control of Ozone Depletion
• More than 80% of Ozone layer depletion may
be attributed to the large scale release of
CFCs in to atmosphere. Hence CFCs must be
controlled.
• US has recently developed Bioact FC-7, a
successful alternative for Freon-12.
• US scientist have developed bacteria that can
eat the main chemicals threatening to Ozone
layer
• The satellite Research Institute of Frankfort,
Germany has developed a method to use
hydrogen as propellant in aerosol sprays
which is best alternative to CFC / Butane.
• The Montreal Protocol on Substances That
Deplete the Ozone Layer is an international treaty
designed to protect the ozone layer by phasing
out the production of a number of substances
believed to be responsible for ozone depletion.
The treaty entered into force on January 1, 1989.
• Due to its widespread adoption and
implementation it has been hailed as an example
of exceptional international cooperation
• "Perhaps the single most successful international
agreement to date...".
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The Environmental Protection Agency (EPA)
• Responsible for enforcing the Montreal
Protocol within the U.S.
– The EPA has several programs in place;
• Regulating and enforcing on-road car and truck air-
conditioning systems
• Regulating most air-conditioning and refrigeration
appliances
• Technician certification
• Service equipment
Signs of Recovery???
There have been some signs of recovery
– 1997 satellite showed a decline of several known ozone-
depleting gases
– Satellite images show some slowing down of ozone loss
However….
www.coolantarctica.com/. ../ozone_hole.htm
Recovery is slow
Antarctica - Dec. 2005
Images of Antarctica Taken Indicate A Slow
Recovery
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• Montreal Protocol has led to reductions in
the emissions of CFCs, atmospheric
concentrations of the most significant
compounds have been declining. These
substances are being gradually removed
from the atmosphere.
• By 2015, the Antarctic ozone hole would
have reduced by only 1 million km² out of
25
• Complete recovery of the Antarctic
ozone layer will not occur until the
year 2050 or later.
• A detectable recovery will not occur
until around 2024, with ozone levels
recovering to 1980 levels by around
2068.
Efforts Need to Be Continued
• Create reliable models
– To gain a better understanding of the effects ozone
depletion has on organisms living within different
ecosystems
• Enforcement of Montreal Protocol
– To reduce concentrations of chemicals responsible for
ozone depletion
• Monitoring chemicals being emitted
• Gain a better overall understanding on just how
ozone depletion is affecting our planet
...
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An invisible threat
Contents
• Definition
• Causes
• Formation
• Affected Areas
• Effects
• Preventive Measures
What is acid deposition?
Often called acid rain
SO2 and NOx in the atmosphere
interacts to produce acidic
chemicals that can travel long
distances before falling to
earth.
Coal power plants are huge
source.
Secondary Pollutant
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Acidic Review
“Normal”
precipitation is
slightly acidic.
Acidity Review
What ever happened to acid
rain?
• In the 1980’s, acid rain received a lot
of media attention.
• Although we don’t hear about acid
rain as much these days, it is still a
problem that deserves our attention.
• Fortunately, acid rain is a problem
that we can all help to solve.
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Definition of Acid Rain
• Precipitation that has a pH of less than that of
natural rainwater (which is about 5.6 due to
dissolved carbon dioxide).
• It is formed when sulphur dioxides and
nitrogen oxides, as gases or fine particles in
the atmosphere, combine with water vapour
and precipitate as sulphuric acid or nitric acid
in rain, snow, or fog.
Causes of Acid Rain
• Natural Sources
– Emissions from volcanoes and from biological
processes that occur on the land, in wetlands, and
in the oceans contribute acid-producing gases to
the atmosphere
– Effects of acidic deposits have been detected in
glacial ice thousands of years old in remote parts
of the globe
Causes of Acid Rain
• The principal cause of acid rain is from human
sources
– Industrial factories, power-generating plants and
vehicles
– Sulphur dioxide and oxides of nitrogen are
released during the fuel burning process (i.e.
combustion)
MSN Encarta
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Formation of Acid Rain
Formation of Acid Rain
• When water vapour condeses, or as the rain
falls, they dissolve gases in the water to form
sulphuric acid (H2SO4) and nitric acid (HNO3).
• While the air in cleaned of the pollutants in
this way, it also causes precipitation to become
acidic, forming acid rain
Reactions
• 2SO2 + O2 +2H2O 2H2SO4
• 4NO2 + 2H2O + O2 4HNO3
• HCl + H2O  HCl (aq)
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Formation of Acid Rain
Wind
Transformation
to sulfuric acid
(H2SO4) and nitric
acid (HNO3)
Windborne ammonia gas
and some soil particles partially
neutralize acids and form dry
sulfate and nitrate salts
Dry acid deposition
(sulfur dioxide gas
and particles of
sulfate and nitrate salts)
Lakes in deep
soil high in
limestone
are buffered
Lakes in shallow soil
low in limestone
become acidic
Wet acid deposition
(droplets of H2SO4 and
HNO3 dissolved in rain
and snow)
Nitric oxide (NO)
Sulfur dioxide
(SO2) and NO
Where do Sulfur Dioxide &
Nitrogen Oxide Particles
Come From?
• Sulfur dioxide and
nitrogen dioxide
particles are emitted
from utility plants,
especially coal-fed
electric plants
• Automobiles also emit
acid rain causing
pollution
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• Now a days, acid rain with pH<4.5
are common in many developed
countries.
Effects of Acid Rain
• Harmful to aquatic life
– Increased acidity in water bodies
– Stops eggs of certain organisms (e.g. fish) to stop
hatching
• Changes population ratios
• Affects the ecosystem
Effects of Acid Rain
• Harmful to vegetation
– Increased acidity in soil
– Leaches nutrients from soil, slowing plant growth
– Leaches toxins from soil, poisoning plants
– Creates brown spots in leaves of trees, impeding
photosynthesis
– Allows organisms to infect through broken leaves
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Effects of Acid Rain
MSN Encarta
Effects of Acid Rain
• Accelerates weathering in metal
and stone structures
– Eg. Parthenon in Athens,
Greece; Taj Mahal in Agra,
India
http://www.lauraknauth.com/photos/france/thinker.jpg
MSN Encarta
Effects of Acid Rain
• Affects human health
– Respiratory problems, asthma, dry coughs,
headaches and throat irritations
– Leaching of toxins from the soil by acid rain can
be absorbed by plants and animals. When
consumed, these toxins affect humans severely.
– Brain damage, kidney problems, and Alzheimer's
disease has been linked to people eating "toxic"
animals/plants.
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Preventive Measures
• Reduce amount of sulphur dioxide and oxides of
nitrogen released into the atmosphere
– Use less energy (hence less fuel burnt)
– Use cleaner fuels
– Remove oxides of sulphur and oxides of nitrogen
before releasing
• Flue gas desulphurization
• Catalytic Converters
Preventive Measures
• Use cleaner fuels
– Coal that contains less sulphur
– "Washing" the coal to reduce sulphur content
– Natural Gas
What else needs to be
done about Acid Rain ?
• In 1990, an amendment to the Clean Air Act called
for reductions in sulfur emissions
• This proved to be less effective than hoped, as acid
rain still persists today
• This is largely due to 2 reasons:
1) reductions in sulfur emissions were not great
enough and
2) there were no reductions in nitrogen emissions
which are also implicated in forming acid rain
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• The New England Governors and eastern
Canadian Premieres were working together on
a solution
• An International Acid Rain Steering
Committee was formed and is currently
discussing joint action to further reduce sulfur
emissions by 50% and reduce nitrogen
emissions by 30% by the year 2010
Can We Do Anything
About Acid Rain?
• YES! We can all take small actions to help
solve the problem
• We can help by:
-using our cars less
-conserving electricity
-choosing electricity providers that emit lower
amounts of air pollution emissions
• Use other sources of electricity (i.e. nuclear
power, hydro-electricity, wind energy,
geothermal energy, and solar energy)
– Issue of cost
http://upload.wikimedia.org/wikipedia/commons/4/4e/Nuclear_Power_Plant_Cattenom.jpg
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Photochemical Smog
Photochemical Smog
 Brown-air smog
 Photochemical
reaction
 Photochemical
oxidants
Fig. 20-5 p. 440
What is photochemical
smog?
Secondary Pollutant
VOCs + NOx + heat + Sunlight = Ground
Level
Ozone (O3)
Complex series of
chemical reactions
SMOG (smoke + fog)
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What is photochemical smog?
All modern cities have smog,
but it is more common in
hot, sunny, warm climates
with a lot of motor vehicle
traffic.
What time of year do you
think it is most common?
• Los Angeles
• Denver
• Mexico City
• Houston
• Beijing China
Los Angeles
Mexico City
Exceeded ozone levels
300 days a year often by
400%
What is photochemical
smog?
Industrial Smog: a
mixture of SO2,
droplets of sulfuric
acid and suspended
PM from burning coal
and oil.
More of a problem
today in developing
counties.
Coal burning HUGE
issue.
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Health Impacts of Smog
Smog Impacts:
• Breathing Problems
• Coughing, Eye
Irritation
• Aggravates asthma,
heart problems
• Speeds up aging of
lung tissue
• Damage plants
• Reduce Visibility
Factors Influencing Smog
Formation
Smog Levels Are
Influenced By:
• Local climate
• Topography
• Population Density
• No. of industry
• Transportation
Factors Influencing Smog
Formation
Factors Can Increase
Smog:
1) Tall urban buildings
slow air exchange
2) Hills or Mountains do
the same
3) High temperatures
4) Atmospheric
Circulation towards
poles
8/8/2020
38
Factors Influencing Smog
Formation
Natural Factors Can
Reduce Smog:
1) Rain or snow can
“wash wash” air
2) Winds can push
pollutants elsewhere”
air
3) Salty Sea Spray can
also “

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3. global effect of air pollution

  • 1. 8/8/2020 1 Effect of Air Pollution • Green House Effect • Global Warming • Acid Rain • Ozone Layer Depletion • Photochemical Smog Green House Effect • The Greenhouse shield that keeps our planet warm enough to sustain life ………. • But now is becoming a heat trap threatening to disrupt the global environment. • Thin layer of certain gases - 25km up- acts like glass letting heat through but stoppping enough radiation back in to warm our world.
  • 2. 8/8/2020 2 • The heat trap provided by atmospheric CO2 probably help to create the conditions necessary for the evolution of life and greening of the earth • Compare to moderately warm planets, Mars, with too little CO2 in its atmosphere is frozen cold and Venus with to much dry… • But now the expansion of human activity in industry and agriculture is changing the fundamental environmental system making the “GREENHOUSE” layer denser, keeping in more heat. • CO2 is the chief single culprit – other 39 known gases • The atmospheric content of CO2 has increased by 25% in last 100 Years • Raise the planet temperature between 1.5 – 4.5 oC • Sea level around 12cm. Green House Effect • “The process of warming of earth surface due to blanketing of CO2 in the atmosphere is called as “GREEN HOUSE EFFECT” • The phenomena due to which the earth retains heat is called as GREENHOUSE EFFECT. • The main green house gases – CO2 – Methane – Chloro floro carbon – NO2
  • 3. 8/8/2020 3 • CO2 is confined exclusively to the troposphere, its higher concentration may act as serious pollutant. • Under normal condition the temp. at the surface of the earth is maintained by the energy balance of the sunrays that strike the planet and heat that is radiated back into space. • Solar energy in the form of light radiation has wavelengths in the range of 0.2 to 4 µm. • It will loss some energy after striking the earth and will be converted to heat energy of longer wavelengths. • The wavelength of this terrestrial reradiation, from earth to atmosphere is more..(4-100 µm). • E = hv = hc/λ • As Energy Wavelength
  • 4. 8/8/2020 4 • CO2 has radiation absorbance band in the range of 12-18 µm wavelength. • Thus CO2 is present in the atmosphere, it allows the incoming solar radiation to pass through but does not allow the reradiation from the earth to space to pass through. • This is the origin of the term GREEN HOUSE EFFECT. • Due to the presence of the CO2 layer in the atmosphere it causes much heating effect on the earth atmosphere • Due to greenhouse effect the earth atmosphere rises every year the world wide concentration of CO2 is increasing at a rate of 0.75 ppm & temp is rising at the rate of 0.05 0C every year • Nearly 100 years ago CO2 275ppm • Today 350ppm • By 2035 & 2040 450ppm Imagine the earth’s temperature then??????
  • 5. 8/8/2020 5 Greenhouse gases • Greenhouse gases covered by the Kyoto Protocol are: CO2 Carbon dioxide CH4 Methane N2O Nitrous Oxide SF6 Sulphur hexafluoride PFCs Perfluorocarbones HFCs Hydrofluorocarbons The greenhouse gases Greenhouse Gas Emissions
  • 6. 8/8/2020 6 • Combustion of fossil fuels? – coal-burning power plants, – automobile exhausts, – factory smokestacks, – other waste vents of the human environment – contribute 22 billion tons of carbon dioxide and other greenhouse gases each year • Animal agriculture, manure, natural gas, rice paddies, landfills, coal, and other anthropogenic sources contribute about 450 million tons of methane each year • Atmospheric concentrations of CO2 and CH4 have increased by 31% and 149% respectively above pre-industrial levels since 1750 Effect of Greenhouse gases Effect of Greenhouse gases • According to WHO, mosquitoes may have longer lives and breeds in larger nos. hence spreads MALARIA. • Warmer & Humid condition enhance growth of bacteria & moulds. • CO2 is also expected to influence intensely the process of depletion of OZONE layer
  • 7. 8/8/2020 7 • The temperature of the atmosphere is increasing day by day • the glaciers, polar ice caps melts, resulting in flooding of many low laying areas • The climate changes from one region to another region with global CO2 increases day by day • increasing the sea level • At a higher the CO2 undergoes photochemical reacting producing CO, Which is more poisonous Global Warming • An increase in the average temperature of the Earth’s atmosphere and oceans • Global temperature on both land and sea increased by 0.6 ± 0.2 °C over the past century • Volume of atmospheric carbon dioxide increased from 280 parts per million in 1800 to 367 in 2000, a 31% increase over 200 years
  • 8. 8/8/2020 8 Our Changing Climate • Global mean surface temperatures have increased 0.5-1.0°F since the late 19th century • The snow cover in the Northern Hemisphere and floating ice in the Arctic Ocean have decreased • Sea level has risen 4-8 inches over the past century • Global surface temp. could rise 1- 4.5°F (0.6-2.5°C) in the next fifty years, and 2.2-10°F (1.4-5.8°C) in the next century What causes it? • Human Impacts- Atmospheric greenhouse gases trap some of the outgoing energy, retaining heat • Natural Impacts- Change in sun’s energy output Volcanoes Water Vapor Clouds Greenhouse Gases - • CO2 Methane Nitrous oxide Fluorinated compounds • Since industrial revolution, atmospheric concentrations of carbon dioxide increased 30%, methane more than doubled, nitrous oxide risen by 15%. • These increases have enhanced the heat-trapping capability of the earth’s atmosphere • Combustion of fossil fuels, coal-burning power plants, automobile exhausts, factory smokestacks, other waste vents of the human environment contribute 22 billion tons of carbon dioxide and other greenhouse gases each year • Animal agriculture, manure, natural gas, rice paddies, landfills, coal, and other anthropogenic sources contribute about 450 million tons of methane each year • Atmospheric concentrations of CO2 and CH4 have increased by 31% and 149% respectively above pre- industrial levels since 1750
  • 9. 8/8/2020 9 Greenhouse Gas Emissions • Power Plants 40% of carbon dioxide emissions stem from the burning of fossil fuels for the purpose of electricity generation • Cars 20% of carbon dioxide emissions comes from the burning of gasoline in internal-combustion engines of cars and light trucks with poor gas mileage contribute the most to global warming • Trucks Another 13% of carbon dioxide emissions come from trucks used mostly for commercial purposes • Airplanes Aviation causes 3.5 percent of global warming, and the figure could rise to 15 percent by 2050 • Carbon Dioxide from Building structure account for about 12% of carbon dioxide emissions Methane • Methane is more than 20 times as effective as CO2 at trapping heat in the atmosphere 2004 Levels of atmospheric methane have risen 145% in the last 100 years • Derived from sources such as rice paddies, bovine flatulence, bacteria in bogs and fossil fuel production. • In flooded fields, anaerobic conditions develop and the organic matter in the soil decomposes
  • 10. 8/8/2020 10 Nitrous oxide • Naturally produced by oceans and rainforests , man-made sources-nylon and nitric acid production, the use of fertilizers in agriculture, cars with catalytic converters and the burning of organic matter • Deforestation Responsible for 25% of all carbon emissions entering the atmosphere by the burning and cutting of about 34 million acres of trees each year . Effects of Global Warming Negative Effects • Rising Sea Level • Change of precipitation and local climate conditions; • acid rain • Alteration of forests and crop yields • Expansions of deserts into existing rangelands • More intense rainstorms • Destabilization of Ocean currents
  • 11. 8/8/2020 11 Positive Effects • Can stimulate plant growth in places where CO2 and temperature are the limiting factors (preventing photorespiration which can destroy existing sugars). • Melting Arctic ice may open the Northwest Passage in summer, which would cut 5,000 nautical miles from shipping routes between Europe and Asia What Can be Done: Alternatives • Solar Energies • Wind Power • Biomass • Geothermal • Hybrid • Fuel Cell • Battery-Electric Hybrid Fuel Cell Battery-Electric
  • 12. 8/8/2020 12 Kyoto Protocol • 1997, Kyoto, Japan developed countries agreed to specific targets for cutting their emissions of greenhouse gases • Industrialized countries committed to an overall reduction of emissions of greenhouse gases to 5.2% below 1990 levels for the period 2008 - 2012 Ozone Layer Depletion Introduction
  • 13. 8/8/2020 13 • The layer of life-protecting ozone found at the top of the stratosphere. • A brief history of the discovery of the ozone 'hole' is included. • The general concepts found in this section include the following: • Concentrations of stratospheric ozone represent a balance, established over eons, between creative and destructive forces and this balance, or dynamic equilibrium, has been changed by human activity. • Ozone is formed in the earth's stratosphere and is critical to life on earth as we know it. • There is compelling scientific evidence that ozone is destroyed in the stratosphere and that some human-released chemicals are speeding up the breakdown of ozone in the atmosphere. • CFCs, a human-developed compound, are particularly destructive to the breakdown of ozone in the atmosphere. • Ultraviolet radiation is present in natural outdoor light and can be blocked or filtered by various substances. Historical Perspective • The ozone 'hole', it is really not a hole but rather a thinning of the ozone layer in the stratosphere. • We will use the term 'hole' in reference to the seasonal thinning of the ozone layer.
  • 14. 8/8/2020 14 • The appearance of a hole in the earth's ozone layer over Antarctica, first detected in 1976. • 1974: Rowland & Molina theorize CFCs destroy stratospheric ozone molecules • 1975: University of Michigan / Harvard papers predict that CFCs deplete Earth’s ozone layer • 1985: Ozone holes found over Antarctic • 1988: Ozone layer thinning over North Pole • 1993: Thinning over mid-latitudes of the Northern Hemisphere • 1997: Low values of total ozone occur in Arctic as well as Antarctic Antarctic Ozone Hole Progression 1979 1986 1991
  • 15. 8/8/2020 15 Earth’s Atmosphere CH4 itself is an important greenhouse gas, and links climate with air pollution via its influence on tropospheric ozone Ozone Layer Depleting Chemicals • chlorofluorocarbons (CFCs) – Freon-11, Trichlorofluromethane (CCl3F) – Freon-12, Dichlorofluromethane (CCl2F) – Freon-22, CHClF2CClF2 – Freon-114, CClF2CClF2 – Freon-115, CClF2CF3 • carbon tetrachloride (CCl4) • methyl chloroform (CH3CCl3) • hydrochloric acid (HCl) • methyl chloride (CH3Cl) • methyl bromide(CH3Br)
  • 16. 8/8/2020 16 • Freon 11: A/C, Refregeration, Cleaning Foams, aerosols etc… • Freon 22: aerosol-propellants • Freon 13: Refrigeration • Freon 114:aerosol, refregeration, cleaning foams etc. • CF2BrCl: used in Fire extingushers Ozone Layer Depleting Chemicals: CFCs • CFCs are inert, non reactive, nontoxic, nonflammable. • Human-made CFCs used in: - refrigeration - air conditioning - foam blowing - cleaning electronic components - solvents
  • 17. 8/8/2020 17 •Ozone is a triatomic form of oxygen (O3) found in Earth’s upper and lower atmosphere. •The ozone layer, situated in the stratosphere about 15 to 30 km above the earth's surface. •Ozone protects living organisms by absorbing harmful ultraviolet radiation (UVB) from the sun. •The ozone layer is being destroyed by CFCs and other substances. • Ozone depletion progressing globally except in the tropical zone. The ozone layer www.epcc.pref.osaka.jp/apec/ eng/earth/ozone_layer_depletion/susumu.html Source: NASA • Meteorological mechanism – Movement of air from one place to another in the upper stratosphere – Cold temperature in the upper atmosphere causes nitric acid to freeze into crystals forming wispy pink clouds – Forms a vortex of tightly twisted winds thus forming a hole in the upper atmosphere Hole Formation Based on Two different mechanisms:
  • 18. 8/8/2020 18 Chemical Mechanism • Different chemicals are responsible for the destruction of the ozone layer • Topping the list : – chlorofluorocarbons (CFC’s) – man-made, non-toxic and inert in the troposphere – In the stratosphere are photolysed, releasing reactive chlorine atoms that catalytically destroy ozone • CFCl3 hv/ sunlight CFCl2 + Cl • CFCl2 hv/ sunlight CFCl + Cl • CF2Cl2 hv/ sunlight CF2Cl + Cl • CClF2 hv/ sunlight CClFC + Cl A combination of low temperatures and elevated chlorine and bromine concentrations are responsible for the destruction of ozone in the upper stratosphere thus forming a “hole”. (Kerr, 1987) www.met.sjsu.edu/~cordero/ education/education.htm
  • 19. 8/8/2020 19 Stratospheric Ozone and Ultraviolet Radiation (UVR) • Ultra-violet radiation (UVR) high energy electromagnetic wave emitted from the sun. It is made up of wavelengths ranging from 100nm to 400nm. • UV radiation includes UV-A, the least dangerous form of UV radiation, with a wavelength range between 315nm to 400nm, UV-B with a wavelength range between 280nm to 315nm, and UV-C which is the most dangerous between 100nm to 280nm. UV-C is unable to reach Earth’s surface due to stratospheric ozone’s ability to absorb it. (Last, 2006) Good & Bad Effects of Sunlight Too much ultra-violet light can result in: • Skin cancer • Eye damage such as cataracts • Immune system damage • Reduction in phytoplankton • Damage to the DNA in various life-forms – this has been as observed in Antarctic ice-fish that lack pigments to shield them from the ultra-violet light (they've never needed them before) • Possibly other things too that we don't know about at the moment
  • 20. 8/8/2020 20 • The impact of a depleted ozone layer on human depends mainly on theire reaction to UV-B rays. • Every 1% loss in Ozone leads to 2% increase in disease • Increase the incidence of cataracts & photocaratitis. • Make the blood vessels carry more blood making the skin hot, swollen or red and cause sun burn • It causes leukemia • Crop yields, especially tea, cabbage and soybean reduced. Effects of UV radiation on biological organisms • DNA damage ………………………….. Maximum effect on small and single cell organisms • Impaired growth and photosynthesis ...poor crop yields • Phytoplankton: ………………………...Reduced uptake of CO2 …………………………………………..mortality …………………………………………..Impaired reproductive capacity • Nitrogen-fixing soil bacteria…………. Reduced, damaged • Human health effects: Suppressed immune system……………..Enhanced susceptibility to infection …………………………………………..Increase risk of Cancer Dermatology (skin)……………………...Sunburn …………….………………………….....Loss of skin elasticity (Premature aging) …………….…………………………… Photosensitivity Neoplasia (cancer)……………………....Melanocytic (malignant melanoma) …………….………………………….....Squamous cell skin – cancer …………….……………………………Basal skin – cancer Still questionable if causes lip cancer or cancer of the salivary glands Oculur (Eye)….…………………….......Cataract …………….…………………………....Pterygium (last, 1993) UV-B Effects on Human Effects
  • 21. 8/8/2020 21 Effects on Human Health • Over exposure may: – Increase risk of non- melanoma and malignant melanoma skin cancer – Higher risks of malignant melanoma from severe sunburns – especially in childhood – Risk of malignant melanoma has increased 10% – Risk of nonmalignant melanoma has increased 26% malignant Non-malignant www.ldeo.columbia.edu/.../ lectures/ozone_health/ Over Exposure – Suppress immune system – Accelerate aging of skin due high exposure – Cause an outbreak of rash in fair skinned people due to photo allergy – can be severe dermis.multimedica.de/.../ en/13007/image.htm Skin Protection • Protect the skin against the solar radiation using skin creams with Sun Protective Factor – The greater the numerical value of the SPF the greater the protection • Use lip balm with SPF • Cover up
  • 22. 8/8/2020 22 www.ldeo.columbia.edu/.../ lectures/ozone_health cornea is encountered first then the lens vitreous humor • Increases the risk of cataracts – Induces type of protein that provokes cleaving (splitting) in the lens – Leading cause of blindness – The prevalence of cataract after age 30 is doubling each decade • Causes apterygial – A wedge-shaped growth over the central cornea Over Exposure to UV-B…. Manifestations of… Cataracts Pterygium Cancer brought on by over exposure to UV-B Protection • Sunglasses with 100% UV block • Wrap around sunglasses • Eye protection for children • Hats
  • 23. 8/8/2020 23 What Is Being Done to Counter the Effects of Ozone Depletion? • Montreal Protocol– panel of experts was formed to investigate substances responsible for hole formation – Established policies that prevent future use of certain types of chemicals – Stipulated that the production and consumption of compounds contributing towards depletion of ozone in the stratosphere were to be phased out by the year 2000 (2005 for methylchloroform) Control of Ozone Depletion • More than 80% of Ozone layer depletion may be attributed to the large scale release of CFCs in to atmosphere. Hence CFCs must be controlled. • US has recently developed Bioact FC-7, a successful alternative for Freon-12. • US scientist have developed bacteria that can eat the main chemicals threatening to Ozone layer • The satellite Research Institute of Frankfort, Germany has developed a method to use hydrogen as propellant in aerosol sprays which is best alternative to CFC / Butane. • The Montreal Protocol on Substances That Deplete the Ozone Layer is an international treaty designed to protect the ozone layer by phasing out the production of a number of substances believed to be responsible for ozone depletion. The treaty entered into force on January 1, 1989. • Due to its widespread adoption and implementation it has been hailed as an example of exceptional international cooperation • "Perhaps the single most successful international agreement to date...".
  • 24. 8/8/2020 24 The Environmental Protection Agency (EPA) • Responsible for enforcing the Montreal Protocol within the U.S. – The EPA has several programs in place; • Regulating and enforcing on-road car and truck air- conditioning systems • Regulating most air-conditioning and refrigeration appliances • Technician certification • Service equipment Signs of Recovery??? There have been some signs of recovery – 1997 satellite showed a decline of several known ozone- depleting gases – Satellite images show some slowing down of ozone loss However…. www.coolantarctica.com/. ../ozone_hole.htm Recovery is slow Antarctica - Dec. 2005 Images of Antarctica Taken Indicate A Slow Recovery
  • 25. 8/8/2020 25 • Montreal Protocol has led to reductions in the emissions of CFCs, atmospheric concentrations of the most significant compounds have been declining. These substances are being gradually removed from the atmosphere. • By 2015, the Antarctic ozone hole would have reduced by only 1 million km² out of 25 • Complete recovery of the Antarctic ozone layer will not occur until the year 2050 or later. • A detectable recovery will not occur until around 2024, with ozone levels recovering to 1980 levels by around 2068. Efforts Need to Be Continued • Create reliable models – To gain a better understanding of the effects ozone depletion has on organisms living within different ecosystems • Enforcement of Montreal Protocol – To reduce concentrations of chemicals responsible for ozone depletion • Monitoring chemicals being emitted • Gain a better overall understanding on just how ozone depletion is affecting our planet ...
  • 26. 8/8/2020 26 An invisible threat Contents • Definition • Causes • Formation • Affected Areas • Effects • Preventive Measures What is acid deposition? Often called acid rain SO2 and NOx in the atmosphere interacts to produce acidic chemicals that can travel long distances before falling to earth. Coal power plants are huge source. Secondary Pollutant
  • 27. 8/8/2020 27 Acidic Review “Normal” precipitation is slightly acidic. Acidity Review What ever happened to acid rain? • In the 1980’s, acid rain received a lot of media attention. • Although we don’t hear about acid rain as much these days, it is still a problem that deserves our attention. • Fortunately, acid rain is a problem that we can all help to solve.
  • 28. 8/8/2020 28 Definition of Acid Rain • Precipitation that has a pH of less than that of natural rainwater (which is about 5.6 due to dissolved carbon dioxide). • It is formed when sulphur dioxides and nitrogen oxides, as gases or fine particles in the atmosphere, combine with water vapour and precipitate as sulphuric acid or nitric acid in rain, snow, or fog. Causes of Acid Rain • Natural Sources – Emissions from volcanoes and from biological processes that occur on the land, in wetlands, and in the oceans contribute acid-producing gases to the atmosphere – Effects of acidic deposits have been detected in glacial ice thousands of years old in remote parts of the globe Causes of Acid Rain • The principal cause of acid rain is from human sources – Industrial factories, power-generating plants and vehicles – Sulphur dioxide and oxides of nitrogen are released during the fuel burning process (i.e. combustion) MSN Encarta
  • 29. 8/8/2020 29 Formation of Acid Rain Formation of Acid Rain • When water vapour condeses, or as the rain falls, they dissolve gases in the water to form sulphuric acid (H2SO4) and nitric acid (HNO3). • While the air in cleaned of the pollutants in this way, it also causes precipitation to become acidic, forming acid rain Reactions • 2SO2 + O2 +2H2O 2H2SO4 • 4NO2 + 2H2O + O2 4HNO3 • HCl + H2O  HCl (aq)
  • 30. 8/8/2020 30 Formation of Acid Rain Wind Transformation to sulfuric acid (H2SO4) and nitric acid (HNO3) Windborne ammonia gas and some soil particles partially neutralize acids and form dry sulfate and nitrate salts Dry acid deposition (sulfur dioxide gas and particles of sulfate and nitrate salts) Lakes in deep soil high in limestone are buffered Lakes in shallow soil low in limestone become acidic Wet acid deposition (droplets of H2SO4 and HNO3 dissolved in rain and snow) Nitric oxide (NO) Sulfur dioxide (SO2) and NO Where do Sulfur Dioxide & Nitrogen Oxide Particles Come From? • Sulfur dioxide and nitrogen dioxide particles are emitted from utility plants, especially coal-fed electric plants • Automobiles also emit acid rain causing pollution
  • 31. 8/8/2020 31 • Now a days, acid rain with pH<4.5 are common in many developed countries. Effects of Acid Rain • Harmful to aquatic life – Increased acidity in water bodies – Stops eggs of certain organisms (e.g. fish) to stop hatching • Changes population ratios • Affects the ecosystem Effects of Acid Rain • Harmful to vegetation – Increased acidity in soil – Leaches nutrients from soil, slowing plant growth – Leaches toxins from soil, poisoning plants – Creates brown spots in leaves of trees, impeding photosynthesis – Allows organisms to infect through broken leaves
  • 32. 8/8/2020 32 Effects of Acid Rain MSN Encarta Effects of Acid Rain • Accelerates weathering in metal and stone structures – Eg. Parthenon in Athens, Greece; Taj Mahal in Agra, India http://www.lauraknauth.com/photos/france/thinker.jpg MSN Encarta Effects of Acid Rain • Affects human health – Respiratory problems, asthma, dry coughs, headaches and throat irritations – Leaching of toxins from the soil by acid rain can be absorbed by plants and animals. When consumed, these toxins affect humans severely. – Brain damage, kidney problems, and Alzheimer's disease has been linked to people eating "toxic" animals/plants.
  • 33. 8/8/2020 33 Preventive Measures • Reduce amount of sulphur dioxide and oxides of nitrogen released into the atmosphere – Use less energy (hence less fuel burnt) – Use cleaner fuels – Remove oxides of sulphur and oxides of nitrogen before releasing • Flue gas desulphurization • Catalytic Converters Preventive Measures • Use cleaner fuels – Coal that contains less sulphur – "Washing" the coal to reduce sulphur content – Natural Gas What else needs to be done about Acid Rain ? • In 1990, an amendment to the Clean Air Act called for reductions in sulfur emissions • This proved to be less effective than hoped, as acid rain still persists today • This is largely due to 2 reasons: 1) reductions in sulfur emissions were not great enough and 2) there were no reductions in nitrogen emissions which are also implicated in forming acid rain
  • 34. 8/8/2020 34 • The New England Governors and eastern Canadian Premieres were working together on a solution • An International Acid Rain Steering Committee was formed and is currently discussing joint action to further reduce sulfur emissions by 50% and reduce nitrogen emissions by 30% by the year 2010 Can We Do Anything About Acid Rain? • YES! We can all take small actions to help solve the problem • We can help by: -using our cars less -conserving electricity -choosing electricity providers that emit lower amounts of air pollution emissions • Use other sources of electricity (i.e. nuclear power, hydro-electricity, wind energy, geothermal energy, and solar energy) – Issue of cost http://upload.wikimedia.org/wikipedia/commons/4/4e/Nuclear_Power_Plant_Cattenom.jpg
  • 35. 8/8/2020 35 Photochemical Smog Photochemical Smog  Brown-air smog  Photochemical reaction  Photochemical oxidants Fig. 20-5 p. 440 What is photochemical smog? Secondary Pollutant VOCs + NOx + heat + Sunlight = Ground Level Ozone (O3) Complex series of chemical reactions SMOG (smoke + fog)
  • 36. 8/8/2020 36 What is photochemical smog? All modern cities have smog, but it is more common in hot, sunny, warm climates with a lot of motor vehicle traffic. What time of year do you think it is most common? • Los Angeles • Denver • Mexico City • Houston • Beijing China Los Angeles Mexico City Exceeded ozone levels 300 days a year often by 400% What is photochemical smog? Industrial Smog: a mixture of SO2, droplets of sulfuric acid and suspended PM from burning coal and oil. More of a problem today in developing counties. Coal burning HUGE issue.
  • 37. 8/8/2020 37 Health Impacts of Smog Smog Impacts: • Breathing Problems • Coughing, Eye Irritation • Aggravates asthma, heart problems • Speeds up aging of lung tissue • Damage plants • Reduce Visibility Factors Influencing Smog Formation Smog Levels Are Influenced By: • Local climate • Topography • Population Density • No. of industry • Transportation Factors Influencing Smog Formation Factors Can Increase Smog: 1) Tall urban buildings slow air exchange 2) Hills or Mountains do the same 3) High temperatures 4) Atmospheric Circulation towards poles
  • 38. 8/8/2020 38 Factors Influencing Smog Formation Natural Factors Can Reduce Smog: 1) Rain or snow can “wash wash” air 2) Winds can push pollutants elsewhere” air 3) Salty Sea Spray can also “