Remote Procedure Call (RPC) and Remote Method Invocation (RMI) allow processes to execute procedures or methods remotely. RPC uses client and server stubs to marshal and unmarshal parameters and results as messages are passed between client and server. RMI is similar but uses object-oriented programming and passes objects rather than data structures. Both provide abstraction and enable distributed applications but RMI has lower overhead and is easier to program. Middleware like RPC, RMI, message queues, and MPI support various types of communication between distributed processes.