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LINSEED OIL
BY
Dr. Jitendra Patel
Associate Professor
AIPS, Hyderabad, India.
Synonyms
1. Flax seed,
2. Alsi (Hindi).
Biological Source
• Linseed is the dried, ripe seed of Linum
usitatissimum Linn. Linseed oil is obtained by
expression of linseeds, belonging to family
Linaceae.
Geographical Source
• Linseed is cultivated in many sub-tropical
countries such as South America, India,
United States, Canada, England, Russia,
Greece, Italy, Spain, and Algeria.
Collection
• Linseed in an erect annual herb, 60–120 cm
high with sky-blue flowers, and a globular
capsule.
• The plant is cultivated for its seeds and fibre
(flax).
• A moderate rainfall is best suited for its
growth.
• It grows in almost all types of soils where
sufficient moisture is available, but thrives
best in heavy soils with high moisture
retaining capacity.
• As a mixed crop it is sown either on the
margins of fields or in rows alternating with
the other crop.
• Nitrogenous fertilizers yield better crop.
• The crop is harvested in February and March
before the capsules are dried.
• Plants are cut close to the ground, dried in the
field, and threshed to separate seeds.
Morphology of Seeds
• The seeds are oval, flattened,
elongated, 4–6 mm long, and 2–3 mm
wide. Testa is glossy, smooth, reddish-
brown with minutely pitted surface.
• Seeds are rounded at one end. The
other end is obliquely pointed where
the hilum and micropyle are present
in a slight depression.
• Raphe is present along one edge.
Endosperm is narrow and encircles
the embryo.
• It consists of two thick flattened,
plano-convex cotyledons, and a
radicle.
• The seeds art odourless but possess
an oily and mucilaginous taste.
Preparation
• The dried seeds are crushed in rollers, moistened and
heated to 80–90°C in steam to soften the seed tissues.
• They are then pressed through hot hydraulic press at a
high pressure.
• The oil so obtained is treated with alkali to separate
free fatty acids and bleached with fuller’s earth or
charcoal.
• On cooling the oil waxy substances are removed.
Linseed oil is a yellowish liquid, with a peculiar odour
and bland taste.
• On exposure to air it gradually thickens, becomes
darker and acquires a more pronounced odour and
taste.
• On drying it forms a hard varnish. It has a high iodine
value (~170) which indicates the presence of excess
amount of glycerides of unsaturated fatty acids.
• The oil is slightly soluble in alcohol, miscible with
chloroform, ether, petroleum ether, carbon disulphide,
and terpentine oil.
• It has density 0.925–0.935, viscosity 1.47, congealing
point ~20°C, saponification number 187–195,
refractive index 1.47–1.48, and unsaponifiable matters
not over 1.5%.
• A water-soluble resinous matter with antioxidant
properties has been isolated from the oil.
Chemical constituents
• Linseed contains fixed oil (30–40%), mucilage (6–10%), protein (25%)
(linin and colinin), small amount of enzyme lipase, and linamarin which
is a cyanogenetic glycoside.
• The carbohydrates present are sucrose, raffinose, cellulose, and
mucilage. Linamarin is a glucose either of acetone cyanohydrin and is
identical to phaseolunatin.
• Unripe seeds contain starch which is converted to mucilage on ripening
the seeds. The mucilage can be fractionated into a neutral fraction a
remified, arabinoxylan composed of D-xylose, L-arabinose, D-glucose
and D-galactose; and an acidic fraction mainly com posed of L-
rhamnose and D-galactose.
• Mucilage swells with water and forms red colour with ruthenium red.
Linamarin on hydrolysis yields acetone, hydrocyanic acid, and glucose.
• The other constituents are phytin, lecithin, wax, resin, pigments, malic
acid, cyanogenic glycosides linustatin neolinustatin, and
secoisolariciresinol and phenylpropanoid glucoside linusitamarin.
• On hydrolysis Linseed oil produces unsaturated acids like linolenic acid
(30–50%), linoleic acid (23–24%), oleic acid (10–18%) together with
saturated acids-myristic, stearic, and palmitic (5–11%).
Uses
• Linseed is used as demulcent and in form of poultices
for gouty and rheumatic swellings.
• Internally it is used for gonorrhoea and irritation of
the genito-urinary system.
• Linseed oil has emollient, expectorant, diuretic,
demulcent, and laxative properties and is utilized
externally in lotions and liniments.
• Nonstaining iodine ointment soap, linoleum, greases,
polishes, polymers, varnishes, paints, putty, oil cloths,
printing inks, artificial rubber, tracing cloth, tanning
and enamelling leather, etc. are also prepared from
Linseed oil.
• The mucilaginous infusion is used internally as a
demulcent in colds, coughs, bronchial affections,
inflammation of the urinary tract, gonorrhoea, and
diarrhoea.
Thank You

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LINSEED OIL- Flax seed.

  • 1. LINSEED OIL BY Dr. Jitendra Patel Associate Professor AIPS, Hyderabad, India.
  • 2.
  • 4. Biological Source • Linseed is the dried, ripe seed of Linum usitatissimum Linn. Linseed oil is obtained by expression of linseeds, belonging to family Linaceae.
  • 5. Geographical Source • Linseed is cultivated in many sub-tropical countries such as South America, India, United States, Canada, England, Russia, Greece, Italy, Spain, and Algeria.
  • 6. Collection • Linseed in an erect annual herb, 60–120 cm high with sky-blue flowers, and a globular capsule. • The plant is cultivated for its seeds and fibre (flax). • A moderate rainfall is best suited for its growth. • It grows in almost all types of soils where sufficient moisture is available, but thrives best in heavy soils with high moisture retaining capacity. • As a mixed crop it is sown either on the margins of fields or in rows alternating with the other crop. • Nitrogenous fertilizers yield better crop. • The crop is harvested in February and March before the capsules are dried. • Plants are cut close to the ground, dried in the field, and threshed to separate seeds.
  • 7. Morphology of Seeds • The seeds are oval, flattened, elongated, 4–6 mm long, and 2–3 mm wide. Testa is glossy, smooth, reddish- brown with minutely pitted surface. • Seeds are rounded at one end. The other end is obliquely pointed where the hilum and micropyle are present in a slight depression. • Raphe is present along one edge. Endosperm is narrow and encircles the embryo. • It consists of two thick flattened, plano-convex cotyledons, and a radicle. • The seeds art odourless but possess an oily and mucilaginous taste.
  • 8. Preparation • The dried seeds are crushed in rollers, moistened and heated to 80–90°C in steam to soften the seed tissues. • They are then pressed through hot hydraulic press at a high pressure. • The oil so obtained is treated with alkali to separate free fatty acids and bleached with fuller’s earth or charcoal. • On cooling the oil waxy substances are removed. Linseed oil is a yellowish liquid, with a peculiar odour and bland taste. • On exposure to air it gradually thickens, becomes darker and acquires a more pronounced odour and taste. • On drying it forms a hard varnish. It has a high iodine value (~170) which indicates the presence of excess amount of glycerides of unsaturated fatty acids. • The oil is slightly soluble in alcohol, miscible with chloroform, ether, petroleum ether, carbon disulphide, and terpentine oil. • It has density 0.925–0.935, viscosity 1.47, congealing point ~20°C, saponification number 187–195, refractive index 1.47–1.48, and unsaponifiable matters not over 1.5%. • A water-soluble resinous matter with antioxidant properties has been isolated from the oil.
  • 9. Chemical constituents • Linseed contains fixed oil (30–40%), mucilage (6–10%), protein (25%) (linin and colinin), small amount of enzyme lipase, and linamarin which is a cyanogenetic glycoside. • The carbohydrates present are sucrose, raffinose, cellulose, and mucilage. Linamarin is a glucose either of acetone cyanohydrin and is identical to phaseolunatin. • Unripe seeds contain starch which is converted to mucilage on ripening the seeds. The mucilage can be fractionated into a neutral fraction a remified, arabinoxylan composed of D-xylose, L-arabinose, D-glucose and D-galactose; and an acidic fraction mainly com posed of L- rhamnose and D-galactose. • Mucilage swells with water and forms red colour with ruthenium red. Linamarin on hydrolysis yields acetone, hydrocyanic acid, and glucose. • The other constituents are phytin, lecithin, wax, resin, pigments, malic acid, cyanogenic glycosides linustatin neolinustatin, and secoisolariciresinol and phenylpropanoid glucoside linusitamarin. • On hydrolysis Linseed oil produces unsaturated acids like linolenic acid (30–50%), linoleic acid (23–24%), oleic acid (10–18%) together with saturated acids-myristic, stearic, and palmitic (5–11%).
  • 10. Uses • Linseed is used as demulcent and in form of poultices for gouty and rheumatic swellings. • Internally it is used for gonorrhoea and irritation of the genito-urinary system. • Linseed oil has emollient, expectorant, diuretic, demulcent, and laxative properties and is utilized externally in lotions and liniments. • Nonstaining iodine ointment soap, linoleum, greases, polishes, polymers, varnishes, paints, putty, oil cloths, printing inks, artificial rubber, tracing cloth, tanning and enamelling leather, etc. are also prepared from Linseed oil. • The mucilaginous infusion is used internally as a demulcent in colds, coughs, bronchial affections, inflammation of the urinary tract, gonorrhoea, and diarrhoea.