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Industrial Waste TreatmentIndustrial Waste Treatment
Introduction
Industrial (including agro-industrial)
wastewaters have very varied
compositions depending on the type of
industry and materials processed.industry and materials processed.
Some of these wastewaters can be
organically very strong, easily
biodegradable, largely inorganic, or
potentially inhibitory.
This means TSS, BOD5 and COD values
may be in the tens of thousands mg/lit.
Unlike sewage, pH values well beyond
the range of 6–9 are also frequently
encountered.
Such wastewaters may also be associated
with high concentrations of dissolved
metal salts.metal salts.
The flow pattern of industrial wastewater
streams can be very different from that of
domestic sewage.
Since the flow of industrial
wastewater would be influenced
by the nature of the operations
within a factory rather than the
usual activities encountered in theusual activities encountered in the
domestic setting.
A significant factor influencing the
flow pattern would be the shift nature
of work at factories.
These shifts may be 8 h or 12 h shifts
and there can be up to three shifts per
day.
wastewater characteristics within awastewater characteristics within a
factory can also vary with time because
it may practice batch manufacturing, or
it may practice slug discharges
(Accidental discharges) on top of its
usual discharges.
Apart from these events which occur on
a regular basis, there would be
spillages and dumping which may
occur within the factory infrequently
but can have very adverse impacts on
the performance of the wastewaterthe performance of the wastewater
treatment plant.
Industrial wastewater
characteristics which would require
consideration include the
following:
(i) biodegradability;
(ii) strength;(ii) strength;
(ii) volumes;
(iv) variations and;
(v) special characteristics which may lead
to operational difficulties.
1. Biodegradability
For an industrial wastewater to be
successfully treated by biological means it
should have quantities of organics
requiring removal and these (and any other
constituents present in the wastewater)constituents present in the wastewater)
should not inhibit the biological process.
The quantity of organics in a wastewater
is indicated by the wastewater’s BOD5
and COD (dichromate) values.
2. Strength
Industrial wastewaters often have organic
strengths which are very much higher than
those encountered in sewage.
Agro-industrial wastewaters are among those
which may have very high organic strengths.
E.g.- sugar-molases, distillery-spentwashE.g.- sugar-molases, distillery-spentwash
Typically the biological processes address
the dissolved and colloidal organic
components in a wastewater since the
particulate can be easily removed using
physical treatment options.
3.Volumes
It can be a common misconception that
industrial wastewater treatment plants
handle volumes which are smaller.
While this may be so when compared with
sewage flows received by sewage treatmentsewage flows received by sewage treatment
plants serving metropolitan areas, not all
sewage treatment plants serve large
communities and not all industrial
wastewater flows are small.
The range of industrial wastewater
volumes to be treated can be very
large, not only from one industry
to the next but also from factoryto the next but also from factory
to factory within an industry ,
than sewage flows.
4.Variations
The study of wastewater characteristics
show that the wastewaters generated by
different factories vary even within the
same industry group.same industry group.
This is so for every parameter indicated
and particularly so in the case of the
volumes of wastewater discharged.
In part the variation would have been
the result of different quantities of
materials processed at different
locations but even in terms of unit
quantity of materials processed there
are still variations and this is due toare still variations and this is due to
differences in housekeeping
practices therein.
5.Special Characteristics
Industrial wastewaters may have certain
characteristics, the effect of which may
not be apparent from the sort of
wastewater data usually provided.wastewater data usually provided.
These may, however, have significant
adverse impact on the equipment or unit
process performance, and aesthetics of a
wastewater treatment plant.
Heavy metals
Sources of Industrial wastewater
In most industries, wastewater
effluents result from the following
water uses:
1. Sanitary wastewater (from washing,1. Sanitary wastewater (from washing,
drinking, etc.);
2. Cooling (from disposing of excess heat
to the environment);
3. Process wastewater (including both
water used for making and washing
Products and for removal and
transport of waste and by-products);
and
4. Cleaning (including wastewater4. Cleaning (including wastewater
from cleaning and maintenance of
ndustrial areas).
Industrial effluents
Whereas the nature domestic
wastewater is relatively constant, the
extreme diversity of industrial
effluents calls for an individual
investigation for each type ofinvestigation for each type of
industry and often entails the use of
specific treatment processes.
Therefore, a thorough understanding
of the production processes and the
system organization is fundamental.
1- General manufacturing effluents:
Most processes give rise to polluting
effluents resulting from the contact
of water with gases, liquids or
solids. The effluents are eithersolids. The effluents are either
continuous or intermittent.
They even might only be produced
several months a year.
Usually if production is regular,
pollution flows are known.
However, for industries working in
specific campaigns (synthetic
chemistry, pharmaceutical and
parachemical industries), it is moreparachemical industries), it is more
difficult to analyze the effluents as they
are always changing.
2- Specific effluents:
Some effluents are likely to be separated
either for specific treatment after which
they are recovered, or to be kept in a
storage tank ready to be reinjected at astorage tank ready to be reinjected at a
weighted flow rate into the treatment
line.
Such as, pickling and electroplating
baths; spent caustic soda.
3- General service effluents:
These effluents may include
wastewater (canteens, etc.), water
used for heating (boiler blow down;
pent resin regenerates) etc.pent resin regenerates) etc.
4- Intermittent effluents:
These must not be forgotten; they
may occur from accidental leaks
of Products during handling or
storage, from floor wash waterstorage, from floor wash water
and from polluted water, of
which storm water may also give
rise to a hydraulic overload.
For the correct design of an industrial effluent
treatment plant, the following parameters
must be carefully established
- types of production, capacities and
cycles, raw materials used,cycles, raw materials used,
- composition of the make-up water
used by the industrial plant,
- possibility of separating effluents
and/or recycling them,
- daily volume of effluents per type,
- average and maximum hourly flows
(duration and frequency by, type),
- average and maximum pollution flow
(frequency and duration)
- per type of waste and for the specific
type of pollution coming from the
industry under consideration.
Objective questions
1. The flow of industrial wastewater would
be influenced by
____________________________.
2. The major factor influencing the flow
pattern is the ________________of work atpattern is the ________________of work at
factories.
Theory questions
Q1. Discuss components of industrial
wastewater flow

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L 3 quality and quantity of industrial wastes

  • 2. Introduction Industrial (including agro-industrial) wastewaters have very varied compositions depending on the type of industry and materials processed.industry and materials processed. Some of these wastewaters can be organically very strong, easily biodegradable, largely inorganic, or potentially inhibitory. This means TSS, BOD5 and COD values may be in the tens of thousands mg/lit.
  • 3. Unlike sewage, pH values well beyond the range of 6–9 are also frequently encountered. Such wastewaters may also be associated with high concentrations of dissolved metal salts.metal salts. The flow pattern of industrial wastewater streams can be very different from that of domestic sewage.
  • 4. Since the flow of industrial wastewater would be influenced by the nature of the operations within a factory rather than the usual activities encountered in theusual activities encountered in the domestic setting.
  • 5. A significant factor influencing the flow pattern would be the shift nature of work at factories. These shifts may be 8 h or 12 h shifts and there can be up to three shifts per day. wastewater characteristics within awastewater characteristics within a factory can also vary with time because it may practice batch manufacturing, or it may practice slug discharges (Accidental discharges) on top of its usual discharges.
  • 6. Apart from these events which occur on a regular basis, there would be spillages and dumping which may occur within the factory infrequently but can have very adverse impacts on the performance of the wastewaterthe performance of the wastewater treatment plant.
  • 7. Industrial wastewater characteristics which would require consideration include the following: (i) biodegradability; (ii) strength;(ii) strength; (ii) volumes; (iv) variations and; (v) special characteristics which may lead to operational difficulties.
  • 8. 1. Biodegradability For an industrial wastewater to be successfully treated by biological means it should have quantities of organics requiring removal and these (and any other constituents present in the wastewater)constituents present in the wastewater) should not inhibit the biological process. The quantity of organics in a wastewater is indicated by the wastewater’s BOD5 and COD (dichromate) values.
  • 9. 2. Strength Industrial wastewaters often have organic strengths which are very much higher than those encountered in sewage. Agro-industrial wastewaters are among those which may have very high organic strengths. E.g.- sugar-molases, distillery-spentwashE.g.- sugar-molases, distillery-spentwash Typically the biological processes address the dissolved and colloidal organic components in a wastewater since the particulate can be easily removed using physical treatment options.
  • 10. 3.Volumes It can be a common misconception that industrial wastewater treatment plants handle volumes which are smaller. While this may be so when compared with sewage flows received by sewage treatmentsewage flows received by sewage treatment plants serving metropolitan areas, not all sewage treatment plants serve large communities and not all industrial wastewater flows are small.
  • 11. The range of industrial wastewater volumes to be treated can be very large, not only from one industry to the next but also from factoryto the next but also from factory to factory within an industry , than sewage flows.
  • 12. 4.Variations The study of wastewater characteristics show that the wastewaters generated by different factories vary even within the same industry group.same industry group. This is so for every parameter indicated and particularly so in the case of the volumes of wastewater discharged.
  • 13. In part the variation would have been the result of different quantities of materials processed at different locations but even in terms of unit quantity of materials processed there are still variations and this is due toare still variations and this is due to differences in housekeeping practices therein.
  • 14. 5.Special Characteristics Industrial wastewaters may have certain characteristics, the effect of which may not be apparent from the sort of wastewater data usually provided.wastewater data usually provided. These may, however, have significant adverse impact on the equipment or unit process performance, and aesthetics of a wastewater treatment plant.
  • 16. Sources of Industrial wastewater In most industries, wastewater effluents result from the following water uses: 1. Sanitary wastewater (from washing,1. Sanitary wastewater (from washing, drinking, etc.); 2. Cooling (from disposing of excess heat to the environment);
  • 17. 3. Process wastewater (including both water used for making and washing Products and for removal and transport of waste and by-products); and 4. Cleaning (including wastewater4. Cleaning (including wastewater from cleaning and maintenance of ndustrial areas).
  • 18. Industrial effluents Whereas the nature domestic wastewater is relatively constant, the extreme diversity of industrial effluents calls for an individual investigation for each type ofinvestigation for each type of industry and often entails the use of specific treatment processes. Therefore, a thorough understanding of the production processes and the system organization is fundamental.
  • 19.
  • 20. 1- General manufacturing effluents: Most processes give rise to polluting effluents resulting from the contact of water with gases, liquids or solids. The effluents are eithersolids. The effluents are either continuous or intermittent. They even might only be produced several months a year.
  • 21. Usually if production is regular, pollution flows are known. However, for industries working in specific campaigns (synthetic chemistry, pharmaceutical and parachemical industries), it is moreparachemical industries), it is more difficult to analyze the effluents as they are always changing.
  • 22. 2- Specific effluents: Some effluents are likely to be separated either for specific treatment after which they are recovered, or to be kept in a storage tank ready to be reinjected at astorage tank ready to be reinjected at a weighted flow rate into the treatment line. Such as, pickling and electroplating baths; spent caustic soda.
  • 23. 3- General service effluents: These effluents may include wastewater (canteens, etc.), water used for heating (boiler blow down; pent resin regenerates) etc.pent resin regenerates) etc.
  • 24. 4- Intermittent effluents: These must not be forgotten; they may occur from accidental leaks of Products during handling or storage, from floor wash waterstorage, from floor wash water and from polluted water, of which storm water may also give rise to a hydraulic overload.
  • 25. For the correct design of an industrial effluent treatment plant, the following parameters must be carefully established - types of production, capacities and cycles, raw materials used,cycles, raw materials used, - composition of the make-up water used by the industrial plant, - possibility of separating effluents and/or recycling them,
  • 26. - daily volume of effluents per type, - average and maximum hourly flows (duration and frequency by, type), - average and maximum pollution flow (frequency and duration) - per type of waste and for the specific type of pollution coming from the industry under consideration.
  • 27. Objective questions 1. The flow of industrial wastewater would be influenced by ____________________________. 2. The major factor influencing the flow pattern is the ________________of work atpattern is the ________________of work at factories.
  • 28. Theory questions Q1. Discuss components of industrial wastewater flow