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CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana


                 Life Cycle Assessment of Float Glass Sunshades vs. Fiber-
                               Reinforced Plastic Sunshades
                                                                                                        Prepared for: Kreysler & Associates
                                                                                        Veronica Chau, Kyle Pineo, Milciades Reyes Gonzalez, Roberto Santana


Abstract

Background: This report presents the results of a life cycle analysis (LCA) comparing two
sunshades for                                                      The two options compared are:
a fiber reinforced plastic (FRP) panel fabricated by Kreysler and Associates (K&A) in Napa, CA,
and a float glass (FG) panel manufactured by Schott in Hamburg, Germany.

Results: Of all the impact categories available, the following were weighed more heavily:
energy resources, greenhouse gas emissions, ozone layer, carcinogens, and solid waste. The life
cycle assessment showed that the FRP sunshade panels were lower in energy resources,
greenhouse gas emissions, ozone layer, and carcinogens. The FRP panels did not perform well in
the solid waste category, because there was no viable end of life recycling FRP option. The
majority of impact for both systems was in the raw material and production phases. For the float
glass system, the fabrication of steel had the largest impact in carcinogens and solid waste, yet
could be recycled. For the FRP, the resin had the highest impact for every category except solid
waste. However, the solid waste was counterbalanced by pollution minimization.

Conclusions: In almost every impact assessment category (except solid waste), the FRP
sunshade is more environmentally sustainable and cost effective. The recommendation is for
Kreysler & Associates to pursue building the sunshades using their FRP method.

Introduction

Fiber-reinforced plastic (FRP) is made of a polymer matrix reinforced with fibers. The first FRP
applications took place in the Second World War1, and production at commercial scale started in
the late 1950s. Currently, FRP is widely use in aerospace, automotive, marine, and construction
industries. The key advantages of FRP over other materials are weight and economic savings.
However, the use of FRP has come into question because fibers and plastics cannot be easily
separated, making FRP impossible to recycle.

Our project sponsor Kreysler & Associates (K&A), a Napa Valley company founded in 1982, is
interested in understanding the differences in environmental impact for a sunshade panel made of
FRP and another one made of float glass (FG). For this purpose, we conducted a comprehensive
life cycle analysis of both options. In this paper, we assess the environmental impact of FRP and
Float Glass from cradle to gate. With the help of SimaPro, a LCA simulation software, we
modeled the environmental impact caused by raw materials, production, transportation,

	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  
1	
  Erhard,                                              Gunter. Designing with plastics. Bruhl, Germany. 2006	
  


	
                                                                                                                                                                                                                                 1	
  
CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana

construction, and end of life of both FRP and float glass. We also included a life cycle cost
analysis before we present our final conclusions and recommendations.

Float Glass2 and RFP Process3

The production of float glass panels follows an industry standard procedure by first combining
sand, soda ash, dolomite, limestone, and cullet into a mixing batch. The batch materials are fed
into the furnace around 1600°C, followed by floating a continuous ribbon of molten glass along
the surface of molten tin bath. Irregularities are melted out here to ensure flat and parallel
surfaces in the glass. The glass is annealed and gradually cooled to around 200°C to prevent
splitting and breaking during the cutting process. The glass is cut, shipped, and installed onto the
building using a crane4 and bolted with steel. The lifespan per panel is estimated at 50 years. At
its end of life, the glass panels can be disposed of via recycling or landfill.

The production of FRP panels utilizes vacuum infusion by first spraying on the gel coat to give
the model color, followed by applying the glass fiber on top. The balsa core is placed on top of
the glass fiber, followed by the steel to be embedded and the inner layer of glass fiber. A rubber
bag is placed around the mold and sealed with a silicon rubber sheet. The vacuum is placed over
the construct, compressing it with atmospheric pressure, and the resin is let in permeating the
molding with glass fiber in it through feeder hoses. The entire molding is then cured, packaged,
and shipped off to the construction site, where a crane will lift the panels into the building. Steel
is bolted down every two feet. Each panel, like the glass is projected to have a 50-year lifespan;
at the end of which, it is unbolted and disposed of in the landfill.

Exhibit A shows the process life cycle of both FG and FRP.

Life Cycle Cost Analysis

In our life cycle cost estimate we assumed that the lifetime of the material is 50 years. We
considered separately the panel cost, steel support cost, use phase cost, and end of life cost
associated with the disposal of FRP and float glass. For panel costs, we obtained a dollar per
square foot cost estimate from K&A for both FRP and glass options. FRP is slightly more
expensive than glass ($36.7 versus $30 per sq. ft.), but it requires considerably less steel and
labor than the glass installation. The cost of steel for FRP (including labor) was provided by
K&A ($8 per sq. ft.). For float glass, we used market5 prices for steel. Savings in steel support
are derived from the weight advantage that FRP has over float glass. The difference in weights
translates into much lighter structural support needs for FRP.

The use phase cost associated with both materials is considered to be zero for purposes of the
study because very little maintenance is required in the regular used of the panel. Bearing any
catastrophic damage like high intensity earthquakes this assumption should hold true. For the end
of life calculations, we assumed a discount rate of 4%, which is slightly above inflation. Since
	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  
2
  Source: http://www.pfg.co.za/all-about-glass.aspx
3
  Source: Kreysler & Associates	
  
4
  Building is 4 stories with the assumption of 12 feet per story
5
  Source: http://www.meps.co.uk/World%20Carbon%20Price.htm


	
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CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana

FRP cannot be recycled, we used average tipping fees for California6. Prices for recycled glass
and steel were taken from secondary material pricing rates7. As shown in Exhibit B, the FRP
option is 50% less expensive than float glass.

LCA Methods and Functional Unit

For this model we took into account various aspects of the process of fabrication of the fiber
reinforced polymer panel and the float glass option. To obtain the results of the impacts we used
a process-based LCA analysis; for this we used the software SimaPro and the “Eco-Indicator 95”
protocol. The assumptions that were made for this analysis are related to various aspects like
transportation distances, processes used and materials taken into account. The use phase was not
taken into account in our analysis because the impacts are negligible and similar to both
sunshades.

Our functional unit is a 40’ x 10’ panel for the two options; our assumptions and differences
between these two options are described below.

Impact Assessment Results by Phase: Material Production - Assumptions

Materials
The materials used for the production of the FRP panels are:
   1. Glass Fiber provided by Owens Corning. M5 Chopped Strand Mat for Hand-Lay Up. A
       waste factor of 3% was used for glass fiber, as well as for the resin.
   2. Unsaturated Polyester Resin, provided by Ashland Chemical. HETRON FR620T-20. A
       waste factor of 3% was used.
   3. Balsa Wood provided by BALTEK. BALTEK® SB STRUCTURAL END-GRAIN
       BALSA.
   4. Gelcoat provided by Valspar. WHITE BASE – STANDARD VOC.
   5. Steel, for structural purposes. Steel type Fe 360 I as considered in SimaPro.
For the float glass panels, the following materials were considered:
   1. Float Glass coated EHS.
   2. Steel type Fe 360 I. For structural and framing purposes.
Weight distribution for each material
For RFP panel the distribution is as follow:
                     Raw Material                                                                                                                                                                                                          Weight (kg)   % of total
                                                                                                                                                          Glass Fiber                                                                        456.89        49.5%
                                                                                                                                                        Polyester Resin                                                                      219.31        23.7%
                                                                                                                                                        Structural Steel                                                                     128.81        13.9%
                                                                                                                                                          Balsa Wood                                                                         118.79        12.9%
                                                                                                                                                             Total                                                                           923.79
	
  


	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  
6
        Source: http://tinyurl.com/6nbcefv
7
        Source: https://www.cmg.net/recyclingmarkets/smp/smpsample.html	
  


	
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CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana

For Float glass panels:
                     Raw Material                           Weight (kg)   % of total
                        Float glass                           2362.00       78.3%
                      Structural Steel                         653.73       21.7%
                           Total                              3015.73

Exhibit C was used to help determine total weight of the FRP panel.

Impact Assessment Results by Phase: Material Production – Results

As mentioned previously we used SimaPro and the protocol Ecoindicator 95 to obtain the results
in our analyses of both options. Please refer to Exhibit D for the table showing the quantitative
impact and the charts show the percentage of the total impact that each material is causing. And
for the results of the float glass panel please refer to Exhibit E, for the same information.

As seen on those exhibits, the float glass option accounts for most impacts in most of the
categories. On the other hand, the FRP panel accounts for most of the solid waste and this is due
to the production of glass fiber and balsa wood. At the same time, the unsaturated polyester resin
has the greatest impact in all categories, except solid waste. But, when these are compared to the
float glass option is still less.

As for the carcinogens category, float glass panel has an impactful footprint due to the large
amount of steel required to support the panel.

Impact Assessment Results by Phase: Transportation and Construction – Assumptions

The FRP panels are made in the Kreysler and Associates fabrication plant in Napa and all raw
materials were brought there, processed and shipped to their final location          as panels
ready to be installed for a distance of   km. On the other hand, it was assumed that Schott, a
glass company in Hamburg, fabricated the float glass panels in Germany. These glass panels
were assumed to be transported 6400 km by a transoceanic freight ship from Hamburg to New
York and then carried 4650 km by diesel powered freight rail from NY to San Francisco, and
finally transported 69.5 km by truck from San Francisco to the final location in        .

Impact Assessment Results by Phase: Transportation and Construction – Results

Exhibit F shows the relative environmental and construction impacts for float glass, and Exhibit
G shows the relative environmental impacts for FRP. For FG, rail transport contributed the
largest relative impact. For FRP, transportation of materials to the plant had the largest
environmental impact. The magnitudes of the FRP environmental impacts were smaller than the
FG impacts because the FRP panel was about one-third the weight of a FG panel and its
transportation distance was assumed to be much less. Both zinc coating for FG and vacuum
infusion for FRP had minimal environmental impacts.

A schematic (not to scale) of the FRP system, Exhibit H, is located in the exhibit section.




	
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CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana

Impact Assessment Results by Phase: End of Life - Assumptions

The total life of both FG and FRP were assumed to be 50 years. Because there is no viable
recycling option for FRP8, it was assumed that FRP system goes directly to landfill. The FG
panel system was assumed to be 100% recycled.

Impact Assessment Results by Phase: End of Life – Results

No end of life analysis was performed because FRP has no practical recycling options. We can
qualitatively infer that the FRP end of life impact is higher than the FG impact because of the
glass recycling process.

Total Impact Assessment


                                                            Impact Category                                                                                                                                                        Total (FG) Total (FRP) Difference % Difference
                                        Acidification (kg SO2)                                                                                                                                                                      24.958       10.00390      14.954     149
                                       Carcinogens (kg B(a)P)                                                                                                                                                                      0.000582      0.000179     0.000402    224
                                     Energy resources (MJ LHV)                                                                                                                                                                     62421.049     37412.100   25008.948   66.8
                                      Eutrophication (kg PO4)                                                                                                                                                                        2.742         1.429        1.312    91.8
                                       Greenhouse (kg CO2)                                                                                                                                                                         4057.697      2144.518     1913.179   89.2
                                        Heavy metals (kg Pb)                                                                                                                                                                        0.0346        0.0178       0.0167    93.8
                                      Ozone layer (kg CFC11)                                                                                                                                                                       0.000663      0.000392     0.000270   68.9
                                       Pesticides (kg act.sub)                                                                                                                                                                         0             0            0        0
                                          Solid Waste (kg)                                                                                                                                                                           7.047        28.469       -21.422   -75.2
                                      Summer smog (kg C2H4)                                                                                                                                                                          1.535         1.414        0.120     8.5
                                       Winter smog (kg SPM)                                                                                                                                                                         13.228         6.508        6.719     103

Taking into account all the aforementioned processes, assumptions, and results, the FRP panel
performed much better environmentally and financially compared to the FG panels. In every
impact category (except for solid waste), the FRP panel at minimum 66.8% environmentally
better than the FG (except for summer smog and solid waste, which performed at 8.5% and -
75.2%, respectively). Of the four major categories in our LCA, energy resources, greenhouse gas
emissions, ozone layer, carcinogens, and solid waste, carcinogens were decreased by 224%.

Put into perspective, a reduction of approximately 2,000 kg of CO2 is equivalent to driving one
30-mpg car almost 12,000 miles in one year. Saving 25,000 MJ per panel, on the other hand, is
equivalent to burning 1 metric ton of coal9.

A sensitivity analysis was performed to better compare the environmental impacts of FG and
FRP by taking out FG’s transoceanic and rail transports. The float glass was then assumed to
travel the exact distance the FRP was (both assumed to originate from K&A) to             .
Exhibit I shows a spider graph of all impact categories in percentages of the two panels with all
transportation included. Exhibit J shows the same spider graph but with transoceanic and rail
transport excluded. Still, the FRP panels performed better.

	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  
8
        Source: http://mntap.umn.edu/fiber/resources/report12-04.pdf
9	
  Source:    Professor Anthony Kovscek, Stanford.	
  


	
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CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana



Combining the materials, processes, and transportation environmental impacts into one, Exhibit
K and Exhibit L (FG and FRP respectively), structural steel and float glass account for the
majority of the environmental impacts over transportation. For the FRP the polyester resin and
structural steel account for most of the environmental impacts.

Conclusion and Recommendations
	
  
The FRP panel performed more favorably in terms of environmental sustainably and financially.
With reductions per panel in the majority of the impact categories by over 60%, total weight by
44%, and total cost by 53%, we recommend that Kreysler & Associates further communications
with the computer company to install FRP sunshades over float glass sunshades.

To further improve the environmental practicality of FRP sunshades, recommendations that
Kreysler & Associates should consider is the end-of-life recycling of the panels once they are no
longer being used. Even though FRP recycling is still in its infancy, K&A should be aware of
new technology that could help the FRP panel perform better at end-of-life. Drawing from the
environmental impacts of the FRP resin, and in general, it is always advisable that Kreysler &
Associates be on the lookout for alternative materials that can perform just as well as FRP (and
the resin), but with even less environmental impacts.	
  




	
                                                  6	
  
CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana

                              Exhibit	
  A:	
  FG	
  and	
  FRP	
  Process	
  Flow	
  




                                                                                                	
  
                                                          	
  
                               Exhibit	
  B:	
  Life	
  Cycle	
  Cost	
  Analysis	
  




                                                                                         	
  


	
                                                      7	
  
CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana

                           Exhibit	
  C:	
  Raw	
  Material	
  Densities	
  for	
  FRP	
  




                                                                                                                              	
  
                                                         	
  
                             Exhibit	
  D:	
  FRP	
  Environmental	
  Impacts	
  

                  FRP,	
  Materials	
  Environmental	
  Impacts	
  
       1.2	
  

          1	
  

       0.8	
  

       0.6	
  
                                                                                             Balsa	
  Wood	
  
       0.4	
                                                                                 Structural	
  Steel	
  
                                                                                             Polyester	
  Resin	
  
       0.2	
  
                                                                                             Glass	
  Fiber	
  
          0	
  




                                                                                                                       	
  
                                                          	
  


	
                                                       8	
  
CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana



                      FRP,	
  Processes	
  Environmental	
  Impacts	
  
        0.5	
  
       0.45	
                                                                Wood	
  Cutting	
  and	
  preparation	
  
        0.4	
  
       0.35	
  
        0.3	
  
                                                                             Transportation	
  of	
  materials	
  to	
  
       0.25	
  
                                                                             plant	
  
        0.2	
  
       0.15	
  
                                                                             Vacuum	
  Infusion	
  process	
  for	
  
        0.1	
  
                                                                             making	
  panels	
  
       0.05	
  
          0	
  
                                                                             Transportation	
  from	
  plant	
  to	
  
                                                                             site	
  




                                                                                                                                   	
  
                                                                	
  
                            Exhibit	
  E:	
  Float	
  Glass	
  Environmental	
  Impacts	
  

                      FG,	
  Materials	
  Environmental	
  Impacts	
  
           1.2	
  

              1	
  

          0.8	
  
                                                                                                  Structural	
  Steel	
  
          0.6	
  

           0.4	
  

           0.2	
                                                                                  Float	
  Glass	
  
              0	
  




                                                                                                                            	
  
                                                           	
  
                                                           	
  




	
                                                        9	
  
CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana



                                   FG,	
  Processes	
  Environmental	
  Impacts	
  
                  0.7	
  

                  0.6	
  

                  0.5	
  

                  0.4	
  

                  0.3	
                                                                    Transportation	
  by	
  truck	
  
                                                                                           Transportation	
  by	
  rail	
  
                  0.2	
  
                                                                                           Transportation	
  transoceanic	
  
                  0.1	
                                                                    Zinc	
  Coating	
  

                      0	
  




                                                                                                                                        	
  
                                                                         	
  
                              Exhibit	
  F:	
  Float	
  Glass	
  Environmental	
  and	
  Construction	
  Impacts	
  

                              FG,	
  Transporta0on	
  Environmental	
  Impacts	
  
                 0.7	
  
                 0.6	
  
                 0.5	
  
                 0.4	
  
       (%)	
  




                 0.3	
                                                                               Transporta3on	
  by	
  truck	
  

                 0.2	
                                                                               Transporta3on	
  by	
  rail	
  

                 0.1	
                                                                               Transporta3on	
  transoceanic	
  
                                                                                                     Zinc	
  Coa3ng	
  
                    0	
  




                                                                                                                                               	
  
                                                                         	
  




	
                                                                     10	
  
CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana

                           Exhibit	
  G:	
  FRP	
  Environmental	
  and	
  Construction	
  Impacts	
  

                          FRP,	
  Transporta0on	
  Environmental	
  Impacts	
  
                0.5	
  
               0.45	
                                                                 Wood	
  CuAng	
  and	
  prepara3on	
  
                0.4	
  
               0.35	
  
                0.3	
                                                                 Transporta3on	
  of	
  materials	
  to	
  
       %	
  




               0.25	
                                                                 plant	
  
                0.2	
  
               0.15	
                                                                 Vacuum	
  Infusion	
  process	
  for	
  
                0.1	
                                                                 making	
  panels	
  
               0.05	
  
                  0	
                                                                 Transporta3on	
  from	
  plant	
  to	
  site	
  




                                                                                                                                         	
  
                                                               	
  
                                                               	
  
                                        Exhibit	
  H:	
  Schematic	
  of	
  FRP	
  System	
  




                                                                                                                                                	
  




                                                                                                                                                	
  




	
                                                              11	
  
CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana

                Exhibit	
  I:	
  Comparative	
  Environmental	
  Impact	
  with	
  Transport	
  


                                                 Greenhouse	
  
                                               100%	
  
                         Solid	
  waste	
                                    Ozone	
  layer	
  
                                                80%	
  
                                                60%	
  
        Energy	
  resources	
                   40%	
                                   AcidiQication	
  
                                                20%	
  
                                                 0%	
                                             Percentage	
  FRP	
  
           Winter	
  smog	
                                                               Eutrophication	
  
                                                                                                  Percentage	
  FG	
  


               Summer	
  smog	
                                                    Heavy	
  metals	
  

                                   Pesticides	
                Carcinogens	
  



                                                                                                                                            	
  
                                                      	
  
              Exhibit	
  J:	
  Comparative	
  Environmental	
  Impact	
  without	
  Transport	
  



                                                     Greenhouse	
  
                                                    90%	
  
                          Solid	
  waste	
          80%	
                         Ozone	
  layer	
  
                                                    70%	
  
                                                    60%	
  
                                                    50%	
  
        Energy	
  resources	
                       40%	
                                     AcidiQication	
  
                                                    30%	
  
                                                    20%	
  
                                                    10%	
                                                           FRP	
  
                                                     0%	
  
           Winter	
  smog	
                                                                                     Float	
  Glass	
  
                                                                                                  Eutrophication	
  



                Summer	
  smog	
                                                         Heavy	
  metals	
  

                                     Pesticides	
                 Carcinogens	
  




                                                                                                                                     	
  
                                                                      	
  




	
                                                                12	
  
CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana

                                  Exhibit	
  K:	
  FG	
  Total	
  Combined	
  
       100%	
  

        90%	
  

        80%	
  

        70%	
  

        60%	
  
                                                                                      Transport:	
  truck	
  
        50%	
  
                                                                                      Transport:	
  rail	
  
        40%	
  
                                                                                      Transport:	
  transoceanic	
  
        30%	
                                                                         Zinc	
  Coating	
  
        20%	
                                                                         Structural	
  Steel	
  
        10%	
                                                                         Float	
  Glass	
  

          0%	
  




                                                                                                                         	
  
                                                          	
  
                                 Exhibit	
  L:	
  FRP	
  Total	
  Combined	
  
       100%	
  

        90%	
  
                                                                            Wood	
  Cutting	
  and	
  preparation	
  
        80%	
  

        70%	
                                                               Transport:	
  materials	
  to	
  plant	
  

        60%	
  
                                                                            Vacuum	
  Infusion:	
  making	
  
        50%	
                                                               panels	
  
                                                                            Transport:	
  plant	
  to	
  site	
  
        40%	
  

        30%	
                                                               Balsa	
  Wood	
  
        20%	
  
                                                                            Structural	
  Steel	
  
        10%	
  

          0%	
                                                              Polyester	
  Resin	
  

                                                                            Glass	
  Fiber	
  




	
                                                   13	
  
CEE 226: Life Cycle Assessment of Complex Systems
Chau, Pineo, Reyes Gonzalez, Santana

                                             References

1. Ali S.M., Lepech, M., Basbagill, J.P. PROBABILISTIC DEVELOPMENT OF A LIFE
   CYCLE INVENTORY (LCI) DATASET FOR PULTRUDED FIBER REINFORCED
   POLYMER (FRP) COMPOSITES. Stanford University. Stanford.


2. Bartholomew, Kyle. "Fiberglass Reinforced Pastics Recycling." (2004).


3. Erhard, Gunter. Designing with plastics. Bruhl, Germany. 2006

4. Kreysler, Bill. Kreysler & Associates. American Canyon, CA.


5. Kovscek, Anthony. “Energy Scale (Joules)”. Stanford.


6. "Secondary Materials Pricing.com - Sample Prices." Web.
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7. "Tipping Fees." California Tipping Fees. Web. 09 Dec. 2011. <http://tinyurl.com/6nbcefv>.


8. World Carbon Steel Prices. Web. <http://www.pfg.co.za/all-about-glass.aspx>.




	
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Kreysler & Associates LCA for RFP Sunshades

  • 1. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana Life Cycle Assessment of Float Glass Sunshades vs. Fiber- Reinforced Plastic Sunshades Prepared for: Kreysler & Associates Veronica Chau, Kyle Pineo, Milciades Reyes Gonzalez, Roberto Santana Abstract Background: This report presents the results of a life cycle analysis (LCA) comparing two sunshades for The two options compared are: a fiber reinforced plastic (FRP) panel fabricated by Kreysler and Associates (K&A) in Napa, CA, and a float glass (FG) panel manufactured by Schott in Hamburg, Germany. Results: Of all the impact categories available, the following were weighed more heavily: energy resources, greenhouse gas emissions, ozone layer, carcinogens, and solid waste. The life cycle assessment showed that the FRP sunshade panels were lower in energy resources, greenhouse gas emissions, ozone layer, and carcinogens. The FRP panels did not perform well in the solid waste category, because there was no viable end of life recycling FRP option. The majority of impact for both systems was in the raw material and production phases. For the float glass system, the fabrication of steel had the largest impact in carcinogens and solid waste, yet could be recycled. For the FRP, the resin had the highest impact for every category except solid waste. However, the solid waste was counterbalanced by pollution minimization. Conclusions: In almost every impact assessment category (except solid waste), the FRP sunshade is more environmentally sustainable and cost effective. The recommendation is for Kreysler & Associates to pursue building the sunshades using their FRP method. Introduction Fiber-reinforced plastic (FRP) is made of a polymer matrix reinforced with fibers. The first FRP applications took place in the Second World War1, and production at commercial scale started in the late 1950s. Currently, FRP is widely use in aerospace, automotive, marine, and construction industries. The key advantages of FRP over other materials are weight and economic savings. However, the use of FRP has come into question because fibers and plastics cannot be easily separated, making FRP impossible to recycle. Our project sponsor Kreysler & Associates (K&A), a Napa Valley company founded in 1982, is interested in understanding the differences in environmental impact for a sunshade panel made of FRP and another one made of float glass (FG). For this purpose, we conducted a comprehensive life cycle analysis of both options. In this paper, we assess the environmental impact of FRP and Float Glass from cradle to gate. With the help of SimaPro, a LCA simulation software, we modeled the environmental impact caused by raw materials, production, transportation,                                                                                                                 1  Erhard, Gunter. Designing with plastics. Bruhl, Germany. 2006     1  
  • 2. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana construction, and end of life of both FRP and float glass. We also included a life cycle cost analysis before we present our final conclusions and recommendations. Float Glass2 and RFP Process3 The production of float glass panels follows an industry standard procedure by first combining sand, soda ash, dolomite, limestone, and cullet into a mixing batch. The batch materials are fed into the furnace around 1600°C, followed by floating a continuous ribbon of molten glass along the surface of molten tin bath. Irregularities are melted out here to ensure flat and parallel surfaces in the glass. The glass is annealed and gradually cooled to around 200°C to prevent splitting and breaking during the cutting process. The glass is cut, shipped, and installed onto the building using a crane4 and bolted with steel. The lifespan per panel is estimated at 50 years. At its end of life, the glass panels can be disposed of via recycling or landfill. The production of FRP panels utilizes vacuum infusion by first spraying on the gel coat to give the model color, followed by applying the glass fiber on top. The balsa core is placed on top of the glass fiber, followed by the steel to be embedded and the inner layer of glass fiber. A rubber bag is placed around the mold and sealed with a silicon rubber sheet. The vacuum is placed over the construct, compressing it with atmospheric pressure, and the resin is let in permeating the molding with glass fiber in it through feeder hoses. The entire molding is then cured, packaged, and shipped off to the construction site, where a crane will lift the panels into the building. Steel is bolted down every two feet. Each panel, like the glass is projected to have a 50-year lifespan; at the end of which, it is unbolted and disposed of in the landfill. Exhibit A shows the process life cycle of both FG and FRP. Life Cycle Cost Analysis In our life cycle cost estimate we assumed that the lifetime of the material is 50 years. We considered separately the panel cost, steel support cost, use phase cost, and end of life cost associated with the disposal of FRP and float glass. For panel costs, we obtained a dollar per square foot cost estimate from K&A for both FRP and glass options. FRP is slightly more expensive than glass ($36.7 versus $30 per sq. ft.), but it requires considerably less steel and labor than the glass installation. The cost of steel for FRP (including labor) was provided by K&A ($8 per sq. ft.). For float glass, we used market5 prices for steel. Savings in steel support are derived from the weight advantage that FRP has over float glass. The difference in weights translates into much lighter structural support needs for FRP. The use phase cost associated with both materials is considered to be zero for purposes of the study because very little maintenance is required in the regular used of the panel. Bearing any catastrophic damage like high intensity earthquakes this assumption should hold true. For the end of life calculations, we assumed a discount rate of 4%, which is slightly above inflation. Since                                                                                                                 2 Source: http://www.pfg.co.za/all-about-glass.aspx 3 Source: Kreysler & Associates   4 Building is 4 stories with the assumption of 12 feet per story 5 Source: http://www.meps.co.uk/World%20Carbon%20Price.htm   2  
  • 3. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana FRP cannot be recycled, we used average tipping fees for California6. Prices for recycled glass and steel were taken from secondary material pricing rates7. As shown in Exhibit B, the FRP option is 50% less expensive than float glass. LCA Methods and Functional Unit For this model we took into account various aspects of the process of fabrication of the fiber reinforced polymer panel and the float glass option. To obtain the results of the impacts we used a process-based LCA analysis; for this we used the software SimaPro and the “Eco-Indicator 95” protocol. The assumptions that were made for this analysis are related to various aspects like transportation distances, processes used and materials taken into account. The use phase was not taken into account in our analysis because the impacts are negligible and similar to both sunshades. Our functional unit is a 40’ x 10’ panel for the two options; our assumptions and differences between these two options are described below. Impact Assessment Results by Phase: Material Production - Assumptions Materials The materials used for the production of the FRP panels are: 1. Glass Fiber provided by Owens Corning. M5 Chopped Strand Mat for Hand-Lay Up. A waste factor of 3% was used for glass fiber, as well as for the resin. 2. Unsaturated Polyester Resin, provided by Ashland Chemical. HETRON FR620T-20. A waste factor of 3% was used. 3. Balsa Wood provided by BALTEK. BALTEK® SB STRUCTURAL END-GRAIN BALSA. 4. Gelcoat provided by Valspar. WHITE BASE – STANDARD VOC. 5. Steel, for structural purposes. Steel type Fe 360 I as considered in SimaPro. For the float glass panels, the following materials were considered: 1. Float Glass coated EHS. 2. Steel type Fe 360 I. For structural and framing purposes. Weight distribution for each material For RFP panel the distribution is as follow: Raw Material Weight (kg) % of total Glass Fiber 456.89 49.5% Polyester Resin 219.31 23.7% Structural Steel 128.81 13.9% Balsa Wood 118.79 12.9% Total 923.79                                                                                                                   6 Source: http://tinyurl.com/6nbcefv 7 Source: https://www.cmg.net/recyclingmarkets/smp/smpsample.html     3  
  • 4. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana For Float glass panels: Raw Material Weight (kg) % of total Float glass 2362.00 78.3% Structural Steel 653.73 21.7% Total 3015.73 Exhibit C was used to help determine total weight of the FRP panel. Impact Assessment Results by Phase: Material Production – Results As mentioned previously we used SimaPro and the protocol Ecoindicator 95 to obtain the results in our analyses of both options. Please refer to Exhibit D for the table showing the quantitative impact and the charts show the percentage of the total impact that each material is causing. And for the results of the float glass panel please refer to Exhibit E, for the same information. As seen on those exhibits, the float glass option accounts for most impacts in most of the categories. On the other hand, the FRP panel accounts for most of the solid waste and this is due to the production of glass fiber and balsa wood. At the same time, the unsaturated polyester resin has the greatest impact in all categories, except solid waste. But, when these are compared to the float glass option is still less. As for the carcinogens category, float glass panel has an impactful footprint due to the large amount of steel required to support the panel. Impact Assessment Results by Phase: Transportation and Construction – Assumptions The FRP panels are made in the Kreysler and Associates fabrication plant in Napa and all raw materials were brought there, processed and shipped to their final location as panels ready to be installed for a distance of km. On the other hand, it was assumed that Schott, a glass company in Hamburg, fabricated the float glass panels in Germany. These glass panels were assumed to be transported 6400 km by a transoceanic freight ship from Hamburg to New York and then carried 4650 km by diesel powered freight rail from NY to San Francisco, and finally transported 69.5 km by truck from San Francisco to the final location in . Impact Assessment Results by Phase: Transportation and Construction – Results Exhibit F shows the relative environmental and construction impacts for float glass, and Exhibit G shows the relative environmental impacts for FRP. For FG, rail transport contributed the largest relative impact. For FRP, transportation of materials to the plant had the largest environmental impact. The magnitudes of the FRP environmental impacts were smaller than the FG impacts because the FRP panel was about one-third the weight of a FG panel and its transportation distance was assumed to be much less. Both zinc coating for FG and vacuum infusion for FRP had minimal environmental impacts. A schematic (not to scale) of the FRP system, Exhibit H, is located in the exhibit section.   4  
  • 5. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana Impact Assessment Results by Phase: End of Life - Assumptions The total life of both FG and FRP were assumed to be 50 years. Because there is no viable recycling option for FRP8, it was assumed that FRP system goes directly to landfill. The FG panel system was assumed to be 100% recycled. Impact Assessment Results by Phase: End of Life – Results No end of life analysis was performed because FRP has no practical recycling options. We can qualitatively infer that the FRP end of life impact is higher than the FG impact because of the glass recycling process. Total Impact Assessment Impact Category Total (FG) Total (FRP) Difference % Difference Acidification (kg SO2) 24.958 10.00390 14.954 149 Carcinogens (kg B(a)P) 0.000582 0.000179 0.000402 224 Energy resources (MJ LHV) 62421.049 37412.100 25008.948 66.8 Eutrophication (kg PO4) 2.742 1.429 1.312 91.8 Greenhouse (kg CO2) 4057.697 2144.518 1913.179 89.2 Heavy metals (kg Pb) 0.0346 0.0178 0.0167 93.8 Ozone layer (kg CFC11) 0.000663 0.000392 0.000270 68.9 Pesticides (kg act.sub) 0 0 0 0 Solid Waste (kg) 7.047 28.469 -21.422 -75.2 Summer smog (kg C2H4) 1.535 1.414 0.120 8.5 Winter smog (kg SPM) 13.228 6.508 6.719 103 Taking into account all the aforementioned processes, assumptions, and results, the FRP panel performed much better environmentally and financially compared to the FG panels. In every impact category (except for solid waste), the FRP panel at minimum 66.8% environmentally better than the FG (except for summer smog and solid waste, which performed at 8.5% and - 75.2%, respectively). Of the four major categories in our LCA, energy resources, greenhouse gas emissions, ozone layer, carcinogens, and solid waste, carcinogens were decreased by 224%. Put into perspective, a reduction of approximately 2,000 kg of CO2 is equivalent to driving one 30-mpg car almost 12,000 miles in one year. Saving 25,000 MJ per panel, on the other hand, is equivalent to burning 1 metric ton of coal9. A sensitivity analysis was performed to better compare the environmental impacts of FG and FRP by taking out FG’s transoceanic and rail transports. The float glass was then assumed to travel the exact distance the FRP was (both assumed to originate from K&A) to . Exhibit I shows a spider graph of all impact categories in percentages of the two panels with all transportation included. Exhibit J shows the same spider graph but with transoceanic and rail transport excluded. Still, the FRP panels performed better.                                                                                                                 8 Source: http://mntap.umn.edu/fiber/resources/report12-04.pdf 9  Source: Professor Anthony Kovscek, Stanford.     5  
  • 6. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana Combining the materials, processes, and transportation environmental impacts into one, Exhibit K and Exhibit L (FG and FRP respectively), structural steel and float glass account for the majority of the environmental impacts over transportation. For the FRP the polyester resin and structural steel account for most of the environmental impacts. Conclusion and Recommendations   The FRP panel performed more favorably in terms of environmental sustainably and financially. With reductions per panel in the majority of the impact categories by over 60%, total weight by 44%, and total cost by 53%, we recommend that Kreysler & Associates further communications with the computer company to install FRP sunshades over float glass sunshades. To further improve the environmental practicality of FRP sunshades, recommendations that Kreysler & Associates should consider is the end-of-life recycling of the panels once they are no longer being used. Even though FRP recycling is still in its infancy, K&A should be aware of new technology that could help the FRP panel perform better at end-of-life. Drawing from the environmental impacts of the FRP resin, and in general, it is always advisable that Kreysler & Associates be on the lookout for alternative materials that can perform just as well as FRP (and the resin), but with even less environmental impacts.     6  
  • 7. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana Exhibit  A:  FG  and  FRP  Process  Flow       Exhibit  B:  Life  Cycle  Cost  Analysis       7  
  • 8. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana Exhibit  C:  Raw  Material  Densities  for  FRP       Exhibit  D:  FRP  Environmental  Impacts   FRP,  Materials  Environmental  Impacts   1.2   1   0.8   0.6   Balsa  Wood   0.4   Structural  Steel   Polyester  Resin   0.2   Glass  Fiber   0         8  
  • 9. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana FRP,  Processes  Environmental  Impacts   0.5   0.45   Wood  Cutting  and  preparation   0.4   0.35   0.3   Transportation  of  materials  to   0.25   plant   0.2   0.15   Vacuum  Infusion  process  for   0.1   making  panels   0.05   0   Transportation  from  plant  to   site       Exhibit  E:  Float  Glass  Environmental  Impacts   FG,  Materials  Environmental  Impacts   1.2   1   0.8   Structural  Steel   0.6   0.4   0.2   Float  Glass   0           9  
  • 10. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana FG,  Processes  Environmental  Impacts   0.7   0.6   0.5   0.4   0.3   Transportation  by  truck   Transportation  by  rail   0.2   Transportation  transoceanic   0.1   Zinc  Coating   0       Exhibit  F:  Float  Glass  Environmental  and  Construction  Impacts   FG,  Transporta0on  Environmental  Impacts   0.7   0.6   0.5   0.4   (%)   0.3   Transporta3on  by  truck   0.2   Transporta3on  by  rail   0.1   Transporta3on  transoceanic   Zinc  Coa3ng   0         10  
  • 11. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana Exhibit  G:  FRP  Environmental  and  Construction  Impacts   FRP,  Transporta0on  Environmental  Impacts   0.5   0.45   Wood  CuAng  and  prepara3on   0.4   0.35   0.3   Transporta3on  of  materials  to   %   0.25   plant   0.2   0.15   Vacuum  Infusion  process  for   0.1   making  panels   0.05   0   Transporta3on  from  plant  to  site         Exhibit  H:  Schematic  of  FRP  System         11  
  • 12. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana Exhibit  I:  Comparative  Environmental  Impact  with  Transport   Greenhouse   100%   Solid  waste   Ozone  layer   80%   60%   Energy  resources   40%   AcidiQication   20%   0%   Percentage  FRP   Winter  smog   Eutrophication   Percentage  FG   Summer  smog   Heavy  metals   Pesticides   Carcinogens       Exhibit  J:  Comparative  Environmental  Impact  without  Transport   Greenhouse   90%   Solid  waste   80%   Ozone  layer   70%   60%   50%   Energy  resources   40%   AcidiQication   30%   20%   10%   FRP   0%   Winter  smog   Float  Glass   Eutrophication   Summer  smog   Heavy  metals   Pesticides   Carcinogens         12  
  • 13. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana Exhibit  K:  FG  Total  Combined   100%   90%   80%   70%   60%   Transport:  truck   50%   Transport:  rail   40%   Transport:  transoceanic   30%   Zinc  Coating   20%   Structural  Steel   10%   Float  Glass   0%       Exhibit  L:  FRP  Total  Combined   100%   90%   Wood  Cutting  and  preparation   80%   70%   Transport:  materials  to  plant   60%   Vacuum  Infusion:  making   50%   panels   Transport:  plant  to  site   40%   30%   Balsa  Wood   20%   Structural  Steel   10%   0%   Polyester  Resin   Glass  Fiber     13  
  • 14. CEE 226: Life Cycle Assessment of Complex Systems Chau, Pineo, Reyes Gonzalez, Santana References 1. Ali S.M., Lepech, M., Basbagill, J.P. PROBABILISTIC DEVELOPMENT OF A LIFE CYCLE INVENTORY (LCI) DATASET FOR PULTRUDED FIBER REINFORCED POLYMER (FRP) COMPOSITES. Stanford University. Stanford. 2. Bartholomew, Kyle. "Fiberglass Reinforced Pastics Recycling." (2004). 3. Erhard, Gunter. Designing with plastics. Bruhl, Germany. 2006 4. Kreysler, Bill. Kreysler & Associates. American Canyon, CA. 5. Kovscek, Anthony. “Energy Scale (Joules)”. Stanford. 6. "Secondary Materials Pricing.com - Sample Prices." Web. <https://www.cmg.net/recyclingmarkets/smp/smpsample.html>. 7. "Tipping Fees." California Tipping Fees. Web. 09 Dec. 2011. <http://tinyurl.com/6nbcefv>. 8. World Carbon Steel Prices. Web. <http://www.pfg.co.za/all-about-glass.aspx>.   14