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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4850
COMPARATIVE STUDY OF SBS AND EVA POLYMER MODIFIED BITUMEN
Vaishali Gupta1, Tarushi singh1, Abhishek Verma2, Amit Kumar2, Ashish Choudhary2, Hardik
Anand2
1 Assistant Professor, Department of Civil Engineering,
Dr. Akhilesh Das Gupta Institute of Technology Management, Shastri Park, New Delhi-110053
2 UG Students (Civil Engineering), Department of Civil Engineering,
Dr. Akhilesh Das Gupta Institute of Technology and Management,
Affiliated to IP University, Shastri Park, New Delhi-110053
----------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - Polymer modified bitumen is to provideextralife
to pavement, roads and construction designs. The polymer
that is added is to modify the propertiesofbitumenarestyrene
butadiene styrene (SBS) andEthylenevinylacetate(EVA) both
of these polymers acts as a binder modificationagent. Theaim
of this study to find those economical ways through which we
can alter properties of bitumen to make it much more durable
as well as resilient to the temperature changes that occurs in
the external environment. In this study we have used to use
SBS and EVA polymer at different percentages to modify the
properties of bitumen and comparetheeconomical factorthat
is associated with both these polymers to modify the
properties of bitumen through various type of testing.
Key Words: Styrene butadiene Styrene, Ethyl Vinyl Acetate,
Binder Modification agent, Economical Factor
1. INTRODUCTION
Bitumen is a by-product of the fractional distillationofcrude
oil. It has a unique combination of excellent water-proofing
and adhesive propertieswhichhavebeenused effectivelyfor
more than 5000 years.
It is widely used in roofing, road and pavement applications.
However, it is brittle in cold environments and softens
readily in warm environments. One of the many methods
employed to toughen bitumen is to blend it with polymers,
either virgin or scrap, toproducePolymermodifiedbitumen.
2. LITERATURE REVIEW
In the last thirty years many researchers and development
chemists have experimented with modified bitumen mainly
for industrial uses, adding asbestos, special filler, mineral
fibers and rubber. Their studies are concluded below: -
 Panda and Mazumdar (2016): Studied the
stability value using 80/100 penetration grade
bitumen and Ethylene Vinyl Acetate (EVA)
copolymer. The study that there was an increase in
stability value in case of polymer modified bitumen.
Stability value was high as 14kN in case of polymer
modified bitumen. Tensile strength was also
increased and stripping properties were improved.
 Sharma et al. (2014): studied using 60/70
penetration grade bitumen. Here waste
plastic/polymer was used as modifiers. The waste
plastic/polymer was added on the aggregatebefore
mixing Optimum Binder Content (OBC) in dry
process at 150-160o C temperature. This type of
mixing increases the bonding between aggregates
coated with plastic/polymer which increases the
strength of the bituminous concrete mixes.
 Gupta and Veeraragavan (2013): experimented
using 60/70penetrationgradebitumenandStyrene
Butadiene Styrene(SBS)modifiedbinder.Heretests
were conducted by marshal stability test. The test
results showed thatstrength parametersliketensile
strength, Marshall stability values of SBS modified
mixes were higher than 21% to 25% than that of
conventional mixes. Fatigue life of SBS modified
binder mix was 2.1% to 2.4% higher than the
conventional mix.
 Kanchan Gowthami and P Gopal (2017): studied
the effects of use of a naturally & locally available
fibre called SISAL fibre as an addictive in BC. In this
study, it was found that OBC for BC turned out to be
5% & addition of SISAL fibre improve the mix
properties like Marshall stability & tensile strength
of bitumen.
 Praveen Kumar et al. (2013): Performed tests
using EVA with 60/70 grade bitumen & found that
EVA modified bitumen gives higher softening point
as well as higher viscosity
 Sakunthala and Kumara (2014): studied the
feasibility of using PMB in making pavements and
recommended that the highway sector in Sri Lanka
should move to perform fundamental tests rather
than empirical methods.
 Mohammed Sadique and K.A Patil (2014):
studied the performance of EVA modified bitumen
with respect to the bitumen modified by waste low
density polyethylene (LDPE) & it is found that the
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4851
waste plastic could be better alternative to use for
modification of bitumen.
 Sawant P.A and Kulkarni S.S(2014):
experimented using 60/70 gradebitumen withEVA
polymer and crumb rubber to find solutions on
potholes and crack formations & found that the
addition of EVA & crumb rubber obtained from
waste tyres increases the stiffness and improves
temperature susceptibility of bitumen.
The primary objective of polymer modified bitumen is to
provide extra life to pavement, roads and construction
designs. The polymer that is added is styrene butadiene
styrene (SBS) and Ethylene vinyl acetate (EVA)bothofthese
acts as a binder modification agent and the qualities
exhibited by these polymers are:
Higher rigidity, resistance to deformations, Increased
resistance to cracks and stripping, Better water resistance
properties, High durability.
3. MATERIALS REQUIRED
 BASE BITUMEN- Bitumen (grade80/100)isusedto
perform multiple test on bitumen.
 Aggregate – Aggregates used for the Marshall
stability test according to the calibration chart
available with the machinery to perform the
Marshall stability test.
 Ethylene Vinyl Acetate (EVA) - Ethylene vinyl
acetate (EVA) is the copolymerof ethyleneandvinyl
acetate. Which exhibits low temperature toughness
and water proofing properties. The chemical
structure of the EVA is
Fig-1: EVA
 Styrene butadiene styrene (SBS) - Styrene
butadiene styrene is a copolymer of polystyrene as
well as of polybutadiene provides increase in
stiffness as well as great temperaturesusceptibility.
The chemical structure of SBS is
Fig-2: SBS
4. EXPERIMENTATIONS
 The behaviour of Bitumen (grade 80/100) is
studied by varying the percentage of SBS and EVA
polymer (2 ,4,6 & 8 %) then we performed these
tests on the bitumen sample -
 Penetration Test
 Softening Point Test
 Ductility Test
 Marshall Stability Test
3. RESULTS AND DISCUSSIONS
 The effect of polymers are studied through various
experimentations on the bitumen sample.
 The graph in the figure no. 1 shows the penetration
value decreases that shows increase in stiffness.
 The graph in the figure no. 2 shows the softening
point of bitumen increases with the increase in the
polymer content.
 The graph in the figure no. 3 shows ductility value
of bitumen is improved in comparison to
conventional bitumen.
 The graph shows that the optimum content of
bitumen is found at 6 percent for both EVA and SBS
polymer.
PENETRATION TEST RESULTS
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4852
SOFTENING POINT RESULTS
41.9
43
53
65
75
41.9
45.6
57
69
78
0
20
40
60
80
100
0 2 4 6 8 10
SOFTENINGPOINT(°C)
ADDITIVE CONTENT (%)
EVA SBS
DUCTILITY TEST RESULTS
MARSHALL STABILITY VALUES(KN)
%Bitumen
in the
sample
4.5 5 5.5
Polymer
modified
bitumen
2% SBS 4.472 5.092 4.316
2% EVA 4.056 4.446 3.691
4% SBS 4.316 5.340 3.145
4% EVA 3.925 4.498 3.405
6% SBS 5.340 7.694 4.316
6% EVA 4.836 5.436 3.925
8% SBS 2.885 4.758 4.186
8% EVA 3.535 4.212 3.405
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4853
FLOW VALUE RESULTS
%Bitumen
in the
sample
4.5 5 5.5
Polymer
modified
bitumen
2% SBS 4.5 5.7 6.2
2% EVA 4.3 5.7 5.8
4% SBS 7.5 8.1 10.1
4% EVA 5 6.5 7
6% SBS 7.3 7.9 8.9
6% EVA 6.6 6.9 7.5
8% SBS 5.9 6.7 7.5
8% EVA 5.6 6.4 6.9
3
5
7
9
3 4 5 6
FLOWVALUE(mm)
% BITUMEN
2% PMB
SBS EVA STANDARD BITUMEN
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4854
4. CONCLUSIONS
 The Sample of EVA and SBS at 2,4,6,8 % with
respect to the bitumen, showed only little variation
in the readings of Ductility, softening point and
penetration test.
 The Flow value of SBS modified bitumen sample at
5.4 % unexpectedly increased, in Marshall Stability
Test.
 The Optimum value of Marshall Stability is found to
be at 6 percent for both EVA and SBS.
 As the cost of EVA polymer is 160 Rs/kg with
respect to the SBS polymer which costs at the rate
of 220 Rs/KG according to the Indian market, we
found out that EVA polymer is way more
economical than SBS polymer to enhance the
properties of bitumen .
 This study also reveals that the polymer modified
bitumen offer better engineering properties there
by increasing the durability of the road to a certain
extent and their usage will also serve as a means of
managing the waste menace properly.
REFERENCES
 IRC SP: 53(2002). “Guidelines on Use of
Polymer and Rubber Modified BitumeninRoad
Construction”, Indian Road Congress, New
Delhi.
 IS 1203 (1978). “Methods for Testing Tar and
BituminousMaterials,Penetrationtest”,Bureau
of Indian Standards, New Delhi.
 IS 1205 (1978). “Methods for Testing Tar and
Bituminous Materials, Softening Point Test”,
Bureau of Indian Standards, New Delhi.
 IS 1208 (1978). “Methods for Testing Tar and
Bituminous Materials,DuctilityTest”,Bureauof
Indian Standards, New Delhi.
 M. Murphy, M. O’ Mahony, C. Lycett and I.
Jamison, “Bitumen Modified with Recycled
Polymers”, Material and Structures, vol. 36, pp.
438-444. 2003.
 Sinan Hınıslıoglu, Emine Agar, “Use of Waste
High Density Polyethylene as BitumenModifier
in Asphalt Concrete Mix” Materials Letters 58,
pp 267– 271. 2004.
 Esmaeil Ahmadinia , Majid Zargar, Mohamed
Rehan Karim, Mahrez Abdelaziz, Payam
Shafigh, “Using Waste Plastic Bottles as
Additive for Stone Mastic Asphalt” Materials
and Design 32 , pp 4844–4849. 2011.
 M. Naskar, T. K. Chaki and K.S Reddy, “Effect of
Waste Plastic as Modifier on Thermal Stability
and Degradation Kinetics of Bitumen/Waste
Plastics Blend” Thermochimica Acta 509, pp
128–134. 2010.
 Parveen Kumar, H.C. Mehndiratta,K.Lakshman
Singh, “Rheological PropertiesofCrumbRubber
Modified Bitumen-A Lab Study”, Journal of
Scientific and Industrial Research, vol.68, pp.
812-816.2009.
 ASTM D 2872 (2004), “Standard Test Method
for Effect of Heat and Air on a Moving Film of
Asphalt (Rolling Thin-Film Oven Test)”
 ASTM D 4402. (2006). “Standard Test Method
for Viscosity Determination of Asphalt at
Elevated Temperatures Using a Rotational
Viscometer”.
 Gonzalez, O., Muno, M. and Santama, A. (2004).
“Rheology and Stability of Bitumen-EVA
Blends”, European Polymer Journal, Elsevier
Science Ltd, 40, 2365-2372.

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IRJET- Comparative Study of SBS and EVA Polymer Modified Bitumen

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4850 COMPARATIVE STUDY OF SBS AND EVA POLYMER MODIFIED BITUMEN Vaishali Gupta1, Tarushi singh1, Abhishek Verma2, Amit Kumar2, Ashish Choudhary2, Hardik Anand2 1 Assistant Professor, Department of Civil Engineering, Dr. Akhilesh Das Gupta Institute of Technology Management, Shastri Park, New Delhi-110053 2 UG Students (Civil Engineering), Department of Civil Engineering, Dr. Akhilesh Das Gupta Institute of Technology and Management, Affiliated to IP University, Shastri Park, New Delhi-110053 ----------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - Polymer modified bitumen is to provideextralife to pavement, roads and construction designs. The polymer that is added is to modify the propertiesofbitumenarestyrene butadiene styrene (SBS) andEthylenevinylacetate(EVA) both of these polymers acts as a binder modificationagent. Theaim of this study to find those economical ways through which we can alter properties of bitumen to make it much more durable as well as resilient to the temperature changes that occurs in the external environment. In this study we have used to use SBS and EVA polymer at different percentages to modify the properties of bitumen and comparetheeconomical factorthat is associated with both these polymers to modify the properties of bitumen through various type of testing. Key Words: Styrene butadiene Styrene, Ethyl Vinyl Acetate, Binder Modification agent, Economical Factor 1. INTRODUCTION Bitumen is a by-product of the fractional distillationofcrude oil. It has a unique combination of excellent water-proofing and adhesive propertieswhichhavebeenused effectivelyfor more than 5000 years. It is widely used in roofing, road and pavement applications. However, it is brittle in cold environments and softens readily in warm environments. One of the many methods employed to toughen bitumen is to blend it with polymers, either virgin or scrap, toproducePolymermodifiedbitumen. 2. LITERATURE REVIEW In the last thirty years many researchers and development chemists have experimented with modified bitumen mainly for industrial uses, adding asbestos, special filler, mineral fibers and rubber. Their studies are concluded below: -  Panda and Mazumdar (2016): Studied the stability value using 80/100 penetration grade bitumen and Ethylene Vinyl Acetate (EVA) copolymer. The study that there was an increase in stability value in case of polymer modified bitumen. Stability value was high as 14kN in case of polymer modified bitumen. Tensile strength was also increased and stripping properties were improved.  Sharma et al. (2014): studied using 60/70 penetration grade bitumen. Here waste plastic/polymer was used as modifiers. The waste plastic/polymer was added on the aggregatebefore mixing Optimum Binder Content (OBC) in dry process at 150-160o C temperature. This type of mixing increases the bonding between aggregates coated with plastic/polymer which increases the strength of the bituminous concrete mixes.  Gupta and Veeraragavan (2013): experimented using 60/70penetrationgradebitumenandStyrene Butadiene Styrene(SBS)modifiedbinder.Heretests were conducted by marshal stability test. The test results showed thatstrength parametersliketensile strength, Marshall stability values of SBS modified mixes were higher than 21% to 25% than that of conventional mixes. Fatigue life of SBS modified binder mix was 2.1% to 2.4% higher than the conventional mix.  Kanchan Gowthami and P Gopal (2017): studied the effects of use of a naturally & locally available fibre called SISAL fibre as an addictive in BC. In this study, it was found that OBC for BC turned out to be 5% & addition of SISAL fibre improve the mix properties like Marshall stability & tensile strength of bitumen.  Praveen Kumar et al. (2013): Performed tests using EVA with 60/70 grade bitumen & found that EVA modified bitumen gives higher softening point as well as higher viscosity  Sakunthala and Kumara (2014): studied the feasibility of using PMB in making pavements and recommended that the highway sector in Sri Lanka should move to perform fundamental tests rather than empirical methods.  Mohammed Sadique and K.A Patil (2014): studied the performance of EVA modified bitumen with respect to the bitumen modified by waste low density polyethylene (LDPE) & it is found that the
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4851 waste plastic could be better alternative to use for modification of bitumen.  Sawant P.A and Kulkarni S.S(2014): experimented using 60/70 gradebitumen withEVA polymer and crumb rubber to find solutions on potholes and crack formations & found that the addition of EVA & crumb rubber obtained from waste tyres increases the stiffness and improves temperature susceptibility of bitumen. The primary objective of polymer modified bitumen is to provide extra life to pavement, roads and construction designs. The polymer that is added is styrene butadiene styrene (SBS) and Ethylene vinyl acetate (EVA)bothofthese acts as a binder modification agent and the qualities exhibited by these polymers are: Higher rigidity, resistance to deformations, Increased resistance to cracks and stripping, Better water resistance properties, High durability. 3. MATERIALS REQUIRED  BASE BITUMEN- Bitumen (grade80/100)isusedto perform multiple test on bitumen.  Aggregate – Aggregates used for the Marshall stability test according to the calibration chart available with the machinery to perform the Marshall stability test.  Ethylene Vinyl Acetate (EVA) - Ethylene vinyl acetate (EVA) is the copolymerof ethyleneandvinyl acetate. Which exhibits low temperature toughness and water proofing properties. The chemical structure of the EVA is Fig-1: EVA  Styrene butadiene styrene (SBS) - Styrene butadiene styrene is a copolymer of polystyrene as well as of polybutadiene provides increase in stiffness as well as great temperaturesusceptibility. The chemical structure of SBS is Fig-2: SBS 4. EXPERIMENTATIONS  The behaviour of Bitumen (grade 80/100) is studied by varying the percentage of SBS and EVA polymer (2 ,4,6 & 8 %) then we performed these tests on the bitumen sample -  Penetration Test  Softening Point Test  Ductility Test  Marshall Stability Test 3. RESULTS AND DISCUSSIONS  The effect of polymers are studied through various experimentations on the bitumen sample.  The graph in the figure no. 1 shows the penetration value decreases that shows increase in stiffness.  The graph in the figure no. 2 shows the softening point of bitumen increases with the increase in the polymer content.  The graph in the figure no. 3 shows ductility value of bitumen is improved in comparison to conventional bitumen.  The graph shows that the optimum content of bitumen is found at 6 percent for both EVA and SBS polymer. PENETRATION TEST RESULTS
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4852 SOFTENING POINT RESULTS 41.9 43 53 65 75 41.9 45.6 57 69 78 0 20 40 60 80 100 0 2 4 6 8 10 SOFTENINGPOINT(°C) ADDITIVE CONTENT (%) EVA SBS DUCTILITY TEST RESULTS MARSHALL STABILITY VALUES(KN) %Bitumen in the sample 4.5 5 5.5 Polymer modified bitumen 2% SBS 4.472 5.092 4.316 2% EVA 4.056 4.446 3.691 4% SBS 4.316 5.340 3.145 4% EVA 3.925 4.498 3.405 6% SBS 5.340 7.694 4.316 6% EVA 4.836 5.436 3.925 8% SBS 2.885 4.758 4.186 8% EVA 3.535 4.212 3.405
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4853 FLOW VALUE RESULTS %Bitumen in the sample 4.5 5 5.5 Polymer modified bitumen 2% SBS 4.5 5.7 6.2 2% EVA 4.3 5.7 5.8 4% SBS 7.5 8.1 10.1 4% EVA 5 6.5 7 6% SBS 7.3 7.9 8.9 6% EVA 6.6 6.9 7.5 8% SBS 5.9 6.7 7.5 8% EVA 5.6 6.4 6.9 3 5 7 9 3 4 5 6 FLOWVALUE(mm) % BITUMEN 2% PMB SBS EVA STANDARD BITUMEN
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4854 4. CONCLUSIONS  The Sample of EVA and SBS at 2,4,6,8 % with respect to the bitumen, showed only little variation in the readings of Ductility, softening point and penetration test.  The Flow value of SBS modified bitumen sample at 5.4 % unexpectedly increased, in Marshall Stability Test.  The Optimum value of Marshall Stability is found to be at 6 percent for both EVA and SBS.  As the cost of EVA polymer is 160 Rs/kg with respect to the SBS polymer which costs at the rate of 220 Rs/KG according to the Indian market, we found out that EVA polymer is way more economical than SBS polymer to enhance the properties of bitumen .  This study also reveals that the polymer modified bitumen offer better engineering properties there by increasing the durability of the road to a certain extent and their usage will also serve as a means of managing the waste menace properly. REFERENCES  IRC SP: 53(2002). “Guidelines on Use of Polymer and Rubber Modified BitumeninRoad Construction”, Indian Road Congress, New Delhi.  IS 1203 (1978). “Methods for Testing Tar and BituminousMaterials,Penetrationtest”,Bureau of Indian Standards, New Delhi.  IS 1205 (1978). “Methods for Testing Tar and Bituminous Materials, Softening Point Test”, Bureau of Indian Standards, New Delhi.  IS 1208 (1978). “Methods for Testing Tar and Bituminous Materials,DuctilityTest”,Bureauof Indian Standards, New Delhi.  M. Murphy, M. O’ Mahony, C. Lycett and I. Jamison, “Bitumen Modified with Recycled Polymers”, Material and Structures, vol. 36, pp. 438-444. 2003.  Sinan Hınıslıoglu, Emine Agar, “Use of Waste High Density Polyethylene as BitumenModifier in Asphalt Concrete Mix” Materials Letters 58, pp 267– 271. 2004.  Esmaeil Ahmadinia , Majid Zargar, Mohamed Rehan Karim, Mahrez Abdelaziz, Payam Shafigh, “Using Waste Plastic Bottles as Additive for Stone Mastic Asphalt” Materials and Design 32 , pp 4844–4849. 2011.  M. Naskar, T. K. Chaki and K.S Reddy, “Effect of Waste Plastic as Modifier on Thermal Stability and Degradation Kinetics of Bitumen/Waste Plastics Blend” Thermochimica Acta 509, pp 128–134. 2010.  Parveen Kumar, H.C. Mehndiratta,K.Lakshman Singh, “Rheological PropertiesofCrumbRubber Modified Bitumen-A Lab Study”, Journal of Scientific and Industrial Research, vol.68, pp. 812-816.2009.  ASTM D 2872 (2004), “Standard Test Method for Effect of Heat and Air on a Moving Film of Asphalt (Rolling Thin-Film Oven Test)”  ASTM D 4402. (2006). “Standard Test Method for Viscosity Determination of Asphalt at Elevated Temperatures Using a Rotational Viscometer”.  Gonzalez, O., Muno, M. and Santama, A. (2004). “Rheology and Stability of Bitumen-EVA Blends”, European Polymer Journal, Elsevier Science Ltd, 40, 2365-2372.