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DEPARMENT OF CHEMISTRY
UNIVERSITY OF KASHMIR
SEMINAR LECTURE ON
PRESENTER : Aadil Ali Wani
ENR. NO : 16062120001
1
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•Green chemistry can also be described as
•Sustainable chemistry.
•Chemistry that is benign by
design.
•Pollution prevention at the
molecular level.
4
5
Designing the Synthesis
6
DESIGNING A SYNTHESIS
• If the chemical reaction of the type
• A + B P + W WASTE
•Find alternate A or B to avoid W
7
Example 1 ; Production of allyl alcohol CH2=CHCH2OH
• Traditional route: Alkaline hydrolysis of allyl chloride, which generates
the product and hydrochloric acid as a by-product
Greener route, to avoid chlorine: Two-step using propylene
(CH2=CHCH3), acetic acid (CH3COOH) and oxygen (O2)
• Added benefit: The acetic acid produced in the 2nd reaction can be
recovered and used again for the 1st reaction, leaving no unwanted by-
product.
CH2=CHCH2Cl + H2O CH2=CHCH2OH + HCl
problem product
CH2=CHCH3 + CH3COOH + 1/2 O2 CH2=CHCH2OCOCH3 + H2O
CH2=CHCH2OCOCH3 + H2O CH2=CHCH2OH + CH3COOH
8
9
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14
Priciple : Atom Economy
15
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References
http://www.epa.gov/greenchemistry/
http://www.epa.gov/greenchemistry/pubs/educat.html
http://www.epa.gov/greenchemistry/
http://www.epa.gov/greenchemistry/pubs/principles.html
http://en.wikipedia.org/wiki/Green_chemistry
http://portal.acs.org/portal/acs/corg/content?_nfpb=true&_pageLabel=PP_TRANSITIONMAIN&node_id=830&use_sec=false&sec_url_var=region1&__uuid=76247a16-94d0-458e-9092-
10de1c35f2c6
http://books.google.com/books?id=ZMjkTMwO3NkC&dq=green+chemistry&printsec=frontcover&source=bl&ots=ZdGD63CxOJ&sig=vM94PxekSEhIX3a9yFOPpDAOXGo&hl=en&ei=mD9RSqSoDq
DMjAfJg4mfBQ&sa=X&oi=book_result&ct=result&resnum=8
http://books.google.com/books?id=ZMjkTMwO3NkC&dq=green+chemistry&printsec=frontcover&source=bl&ots=ZdGD63CxOJ&sig=vM94PxekSEhIX3a9yFOPpDAOXGo&hl=en&ei=mD9RSqSoDq
DMjAfJg4mfBQ&sa=X&oi=book_result&ct=result&resnum=8
29
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Green chemistry

Editor's Notes

  1. http://www.epa.gov/greenchemistry/ http://www.epa.gov/greenchemistry/pubs/educat.html http://www.epa.gov/greenchemistry/ http://www.epa.gov/greenchemistry/pubs/principles.html http://en.wikipedia.org/wiki/Green_chemistry http://portal.acs.org/portal/acs/corg/content?_nfpb=true&_pageLabel=PP_TRANSITIONMAIN&node_id=830&use_sec=false&sec_url_var=region1&__uuid=76247a16-94d0-458e-9092-10de1c35f2c6 http://books.google.com/books?id=ZMjkTMwO3NkC&dq=green+chemistry&printsec=frontcover&source=bl&ots=ZdGD63CxOJ&sig=vM94PxekSEhIX3a9yFOPpDAOXGo&hl=en&ei=mD9RSqSoDqDMjAfJg4mfBQ&sa=X&oi=book_result&ct=result&resnum=8 http://books.google.com/books?id=ZMjkTMwO3NkC&dq=green+chemistry&printsec=frontcover&source=bl&ots=ZdGD63CxOJ&sig=vM94PxekSEhIX3a9yFOPpDAOXGo&hl=en&ei=mD9RSqSoDqDMjAfJg4mfBQ&sa=X&oi=book_result&ct=result&resnum=8