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Fluctuation Theorem Application on 2-D 
Granular Materials Configurations 
S. Viridi, S. N. Khotimah, Novitrian, Widayani 
Nuclear Physics and Biophysics Research Division, 
Institut Teknologi Bandung, Bandung 40132, Indonesia 
Solo, Indonesia, 
16 September 2014 
1 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST)
Outline 
• Fluctuation theorem 
• Brazil nut effect 
• 2-d artificial configuration 
• Observation 
• Summary 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
2
Fluctuation theorem 
• One of the FTs states that (Seifert, 2005) 
p - D 
s = -D 
D 
which holds for finite length of time δt for 
entropy change Δs 
• Constraints: steady state of constant force and 
constant temperature 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
3 
( ) 
( ) 
e s 
p s
Fluctuation theorem (cont.) 
• Second law of thermodynamics predicts that 
the entropy of an isolated system should tend 
to increase until it reaches equilibrium 
• This theorem tells us that reverse process, 
where entropy decrease, could have high 
probability to happen 
• It violates the law (in small scale during finite 
length of time) 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
4
Brazil nut effect (BNE) 
• Mixture of two different size of granular 
materials under vibration will produce 
seggreation  larger grains on top, smaller 
grains on the bottom 
• It holds also for only single intruder 
• It is observed in two- and three-dimension 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
5
Brazil nut effect (BNE) (cont.) 
• It has also the reverse BNE (RBNE) as reported 
(Hong et al., 2001) 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
6
Brazil nut effect (BNE) (cont.) 
• There is a crossover condition 
BNE: ●, RBNE: ▪ 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
7
2-d artificial configuration 
• It is based on real observation 
• Configuration are set artificially (Viridi et al., 
2014) 
• Time series of intruder and granular bed can 
be analyzed 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
8
2-d artificial configuration (cont.) 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
9
Observation 
• Number of contacts between grains are 
observed 
• It is named as contactopy (Herrmann, 1993) 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
10
Observation (cont.) 
• Potential energy 
N 
g i U t m g r t 
• Contact energy 
c ij U t t 
Solo, Indonesia, 
16 September 2014 
g sign x 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
11 
( ) = × 
( ) å= 
i 
1 
  
( ) åå [ ( )] 
= > 
= 
N 
i 
N 
j 
1 1
Observation (cont.) 
• Overlap between grains (Schäfer et al., 1996) 
x max 0, 1 
• Temperature T = mgDα 
• Entropy 
Solo, Indonesia, 
16 September 2014 
Ds = - 1 +d - 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
12 
( ) ( ) ( ) ( ) 
þ ý ü 
î í ì 
  
t = D + D - r t - r t ij i j i j 
2 
[U(t t) U(t)] 
T
Observation (cont.) 
• Center of mass posi-tion 
for mA/mB = 1 
• Intruder movement 
seems to violate 
MPEP 
• Change of COM for 
the whole system 
agrees with MPEP 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
13
Observation (cont.) 
• For mA/mB = 1, γ = 1, and α = 8 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
14
Summary 
• BNE obey second law of thermodynamics 
• RBNE has small probability to occur 
• FT does not violate second law of 
thermodynamics for chosen parameters 
(mA/mB = 1, γ = 1, and α = 8) 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
15
THANK YOU 
Solo, Indonesia, 
16 September 2014 
2nd International Conference on Advanced 
Materials Science and Technology 
(ICAMST) 
16

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Fluctuation Theorem Application on 2-D Granular Materials Configurations

  • 1. Fluctuation Theorem Application on 2-D Granular Materials Configurations S. Viridi, S. N. Khotimah, Novitrian, Widayani Nuclear Physics and Biophysics Research Division, Institut Teknologi Bandung, Bandung 40132, Indonesia Solo, Indonesia, 16 September 2014 1 2nd International Conference on Advanced Materials Science and Technology (ICAMST)
  • 2. Outline • Fluctuation theorem • Brazil nut effect • 2-d artificial configuration • Observation • Summary Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 2
  • 3. Fluctuation theorem • One of the FTs states that (Seifert, 2005) p - D s = -D D which holds for finite length of time δt for entropy change Δs • Constraints: steady state of constant force and constant temperature Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 3 ( ) ( ) e s p s
  • 4. Fluctuation theorem (cont.) • Second law of thermodynamics predicts that the entropy of an isolated system should tend to increase until it reaches equilibrium • This theorem tells us that reverse process, where entropy decrease, could have high probability to happen • It violates the law (in small scale during finite length of time) Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 4
  • 5. Brazil nut effect (BNE) • Mixture of two different size of granular materials under vibration will produce seggreation  larger grains on top, smaller grains on the bottom • It holds also for only single intruder • It is observed in two- and three-dimension Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 5
  • 6. Brazil nut effect (BNE) (cont.) • It has also the reverse BNE (RBNE) as reported (Hong et al., 2001) Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 6
  • 7. Brazil nut effect (BNE) (cont.) • There is a crossover condition BNE: ●, RBNE: ▪ Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 7
  • 8. 2-d artificial configuration • It is based on real observation • Configuration are set artificially (Viridi et al., 2014) • Time series of intruder and granular bed can be analyzed Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 8
  • 9. 2-d artificial configuration (cont.) Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 9
  • 10. Observation • Number of contacts between grains are observed • It is named as contactopy (Herrmann, 1993) Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 10
  • 11. Observation (cont.) • Potential energy N g i U t m g r t • Contact energy c ij U t t Solo, Indonesia, 16 September 2014 g sign x 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 11 ( ) = × ( ) å= i 1   ( ) åå [ ( )] = > = N i N j 1 1
  • 12. Observation (cont.) • Overlap between grains (Schäfer et al., 1996) x max 0, 1 • Temperature T = mgDα • Entropy Solo, Indonesia, 16 September 2014 Ds = - 1 +d - 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 12 ( ) ( ) ( ) ( ) þ ý ü î í ì   t = D + D - r t - r t ij i j i j 2 [U(t t) U(t)] T
  • 13. Observation (cont.) • Center of mass posi-tion for mA/mB = 1 • Intruder movement seems to violate MPEP • Change of COM for the whole system agrees with MPEP Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 13
  • 14. Observation (cont.) • For mA/mB = 1, γ = 1, and α = 8 Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 14
  • 15. Summary • BNE obey second law of thermodynamics • RBNE has small probability to occur • FT does not violate second law of thermodynamics for chosen parameters (mA/mB = 1, γ = 1, and α = 8) Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 15
  • 16. THANK YOU Solo, Indonesia, 16 September 2014 2nd International Conference on Advanced Materials Science and Technology (ICAMST) 16