SlideShare a Scribd company logo
(EDTA METHOD)
By : SHREE RAM SHARMA
Principle
Ca+2/Mg+2 + EBT [Ca+2—EBT]
(Wine Red colour/Less stable)
Ca+2/Mg+2 + EDTA [Ca+2—EDTA]
(Colour Less/More stable)
[Ca+2—EBT] [Ca+2—EDTA] + EBT
(BLUE COLOUR)
Procedure
 Preparation of Solution
 Determination of Hardness of Water
 Calculation
Preparation of Solution
I. EDTA Solution
II. EBT Solution
III. Buffer Solution
IV. SHW Solution
Determination of Hardness
 Standardization of EDTA :
10ml SHW + 3ml Buffer + 2 drop EBT
wine red colour
+EDTA
Blue colour
(End Point)
 Determination of Total Hardness :
10ml Water Sample +3ml Buffer + 2 drop EBT
wine red colour
+EDTA
Blue colour
(End Point)
 Determination of Permanent Hardness :
250ml Water Sample boil 50 ml filter Filtrate
make up to 1 lt. by D.W.(Boil Water)
10ml boil water sample + 3ml Buffer + 2 drop EBT
Blue colour +EDTA wine red colour
(End Point)
Calculation
 Standardization of EDTA :
10 ml of SHW = 10mg of CaCO3 eq.
10 ml of SHW = V1 ml of EDTA
10 mg of CaCO3 eq. = V1 ml of EDTA
1 ml of EDTA = 10/ V1 mg of CaCO3 eq.
 Total Hardness :
10 ml H2O sample = V2 ml of EDTA
10 ml H2O sample = V2×10/V1 mg of CaCO3 eq.
1000 ml of H2O sample = (V2/V1)×1000 ppm
 Permanent Hardness :
10 ml boil H2O sample = V3 ml of EDTA
10 ml boil H2O sample = V3×10 mg of CaCO3 eq.
1000ml of boil H2O sample = (V3/V1)×1000 ppm
 Temporary Hardness :
Total Hardness = Temp. H. + Per. H.
Temp. H. = Total H.-Per. H.
=> Temp. H. = {(V2-V3)/V1}×1000 ppm
Advantages
 Greater accuracy
 More rapid procedure
 Convenience
Thank you

More Related Content

What's hot

Water softening ce3
Water softening ce3Water softening ce3
Water softening ce3
RAVI TEJA MULLAPUDI
 
Lime Soda Process - Softening Of Water
Lime Soda Process - Softening Of WaterLime Soda Process - Softening Of Water
Lime Soda Process - Softening Of Water
Vishvaraj Chauhan
 
Ex 6 bod
Ex 6 bodEx 6 bod
Ex 6 bod
zulkarnai
 
Solid matter 1
Solid matter 1Solid matter 1
Solid matter 1
Raz Azad
 
IRJET- Hardness Removal of Groundwater by using Optimum Lime-Soda Process
IRJET-  	  Hardness Removal of Groundwater by using Optimum Lime-Soda ProcessIRJET-  	  Hardness Removal of Groundwater by using Optimum Lime-Soda Process
IRJET- Hardness Removal of Groundwater by using Optimum Lime-Soda Process
IRJET Journal
 
Anilisis Kadar DO dan BOD Pada Perairan
Anilisis Kadar DO dan BOD Pada PerairanAnilisis Kadar DO dan BOD Pada Perairan
Anilisis Kadar DO dan BOD Pada Perairan
RajaYustisia
 
Water supply and sewerage engineering laboratory
Water supply  and sewerage engineering laboratoryWater supply  and sewerage engineering laboratory
Water supply and sewerage engineering laboratory
Taufique Hasan
 
Bod analysis schematic diagram
Bod analysis schematic diagramBod analysis schematic diagram
Bod analysis schematic diagram
Janine Samelo
 
coagulation and flocculation Processes for waste water treatment
coagulation and flocculation Processes for waste water treatmentcoagulation and flocculation Processes for waste water treatment
coagulation and flocculation Processes for waste water treatment
Deep Kotak
 
Water05 (1) (1)
Water05 (1) (1)Water05 (1) (1)
Water05 (1) (1)
Ravi Singh
 
Department of biochemistry cell ad molecular biology (1)
Department of biochemistry cell ad   molecular biology (1)Department of biochemistry cell ad   molecular biology (1)
Department of biochemistry cell ad molecular biology (1)
Samuel Baffoe
 
Unit 03 Photosynthesis Lab Non Inquiry Version General Biology
Unit 03 Photosynthesis Lab Non Inquiry Version General BiologyUnit 03 Photosynthesis Lab Non Inquiry Version General Biology
Unit 03 Photosynthesis Lab Non Inquiry Version General Biology
SUNY Oswego
 
Assessment of the leachability and mechanical stability of mud from a zinc pl...
Assessment of the leachability and mechanical stability of mud from a zinc pl...Assessment of the leachability and mechanical stability of mud from a zinc pl...
Assessment of the leachability and mechanical stability of mud from a zinc pl...
eSAT Publishing House
 
RoHs report of am labels from jizosecurity
RoHs report of am labels from jizosecurityRoHs report of am labels from jizosecurity
RoHs report of am labels from jizosecurity
Cathy Zhu
 
DESH BANDHU GANGWAR, Carbohydrate
DESH BANDHU GANGWAR, CarbohydrateDESH BANDHU GANGWAR, Carbohydrate
DESH BANDHU GANGWAR, Carbohydrate
DESH BANDHU GANGWAR
 
Effect of hardness of water on fixation and total wash off percentage of reac...
Effect of hardness of water on fixation and total wash off percentage of reac...Effect of hardness of water on fixation and total wash off percentage of reac...
Effect of hardness of water on fixation and total wash off percentage of reac...
Elias Khalil (ইলিয়াস খলিল)
 
17 09 08 matter
17 09 08 matter17 09 08 matter
17 09 08 matter
Brian Engel
 
Gravimetry
GravimetryGravimetry
Gravimetry
RenjithaJR1
 
RRLpaperTiSi
RRLpaperTiSiRRLpaperTiSi
RRLpaperTiSi
Suresh C Pillai
 

What's hot (19)

Water softening ce3
Water softening ce3Water softening ce3
Water softening ce3
 
Lime Soda Process - Softening Of Water
Lime Soda Process - Softening Of WaterLime Soda Process - Softening Of Water
Lime Soda Process - Softening Of Water
 
Ex 6 bod
Ex 6 bodEx 6 bod
Ex 6 bod
 
Solid matter 1
Solid matter 1Solid matter 1
Solid matter 1
 
IRJET- Hardness Removal of Groundwater by using Optimum Lime-Soda Process
IRJET-  	  Hardness Removal of Groundwater by using Optimum Lime-Soda ProcessIRJET-  	  Hardness Removal of Groundwater by using Optimum Lime-Soda Process
IRJET- Hardness Removal of Groundwater by using Optimum Lime-Soda Process
 
Anilisis Kadar DO dan BOD Pada Perairan
Anilisis Kadar DO dan BOD Pada PerairanAnilisis Kadar DO dan BOD Pada Perairan
Anilisis Kadar DO dan BOD Pada Perairan
 
Water supply and sewerage engineering laboratory
Water supply  and sewerage engineering laboratoryWater supply  and sewerage engineering laboratory
Water supply and sewerage engineering laboratory
 
Bod analysis schematic diagram
Bod analysis schematic diagramBod analysis schematic diagram
Bod analysis schematic diagram
 
coagulation and flocculation Processes for waste water treatment
coagulation and flocculation Processes for waste water treatmentcoagulation and flocculation Processes for waste water treatment
coagulation and flocculation Processes for waste water treatment
 
Water05 (1) (1)
Water05 (1) (1)Water05 (1) (1)
Water05 (1) (1)
 
Department of biochemistry cell ad molecular biology (1)
Department of biochemistry cell ad   molecular biology (1)Department of biochemistry cell ad   molecular biology (1)
Department of biochemistry cell ad molecular biology (1)
 
Unit 03 Photosynthesis Lab Non Inquiry Version General Biology
Unit 03 Photosynthesis Lab Non Inquiry Version General BiologyUnit 03 Photosynthesis Lab Non Inquiry Version General Biology
Unit 03 Photosynthesis Lab Non Inquiry Version General Biology
 
Assessment of the leachability and mechanical stability of mud from a zinc pl...
Assessment of the leachability and mechanical stability of mud from a zinc pl...Assessment of the leachability and mechanical stability of mud from a zinc pl...
Assessment of the leachability and mechanical stability of mud from a zinc pl...
 
RoHs report of am labels from jizosecurity
RoHs report of am labels from jizosecurityRoHs report of am labels from jizosecurity
RoHs report of am labels from jizosecurity
 
DESH BANDHU GANGWAR, Carbohydrate
DESH BANDHU GANGWAR, CarbohydrateDESH BANDHU GANGWAR, Carbohydrate
DESH BANDHU GANGWAR, Carbohydrate
 
Effect of hardness of water on fixation and total wash off percentage of reac...
Effect of hardness of water on fixation and total wash off percentage of reac...Effect of hardness of water on fixation and total wash off percentage of reac...
Effect of hardness of water on fixation and total wash off percentage of reac...
 
17 09 08 matter
17 09 08 matter17 09 08 matter
17 09 08 matter
 
Gravimetry
GravimetryGravimetry
Gravimetry
 
RRLpaperTiSi
RRLpaperTiSiRRLpaperTiSi
RRLpaperTiSi
 

Viewers also liked

Complexation titration (1) (1)
Complexation titration (1) (1)Complexation titration (1) (1)
Complexation titration (1) (1)
Leshan Usgodaarachchi
 
Complexometric titration
Complexometric titrationComplexometric titration
Complexometric titration
Azhar_Ansari
 
Edta
EdtaEdta
Complexomety in analytical study
Complexomety  in analytical studyComplexomety  in analytical study
Complexomety in analytical study
P.K. Mani
 
Complexometric titration
Complexometric titrationComplexometric titration
Complexometric titration
Wolkite University
 
Complexometric titrations
Complexometric titrationsComplexometric titrations
Complexometric titrations
Obydulla (Al Mamun)
 
Types of titrations
Types of titrationsTypes of titrations
Types of titrations
Suresh Selvaraj
 

Viewers also liked (7)

Complexation titration (1) (1)
Complexation titration (1) (1)Complexation titration (1) (1)
Complexation titration (1) (1)
 
Complexometric titration
Complexometric titrationComplexometric titration
Complexometric titration
 
Edta
EdtaEdta
Edta
 
Complexomety in analytical study
Complexomety  in analytical studyComplexomety  in analytical study
Complexomety in analytical study
 
Complexometric titration
Complexometric titrationComplexometric titration
Complexometric titration
 
Complexometric titrations
Complexometric titrationsComplexometric titrations
Complexometric titrations
 
Types of titrations
Types of titrationsTypes of titrations
Types of titrations
 

Similar to Complexometric method

Determination of hardness in water .pdf
Determination of hardness in water .pdfDetermination of hardness in water .pdf
Determination of hardness in water .pdf
Mausumi Adhya
 
Dyeing
DyeingDyeing
Presentation1 edta mg
Presentation1 edta mg Presentation1 edta mg
Presentation1 edta mg
Dr Robert Craig PhD
 
22CYL13 & Chemistry Laboratory for FT (FT-Ca & Mg).ppt
22CYL13 & Chemistry Laboratory for FT (FT-Ca & Mg).ppt22CYL13 & Chemistry Laboratory for FT (FT-Ca & Mg).ppt
22CYL13 & Chemistry Laboratory for FT (FT-Ca & Mg).ppt
KrishnaveniKrishnara1
 
WATER and ITS TREATMENT.pdf
WATER and ITS TREATMENT.pdfWATER and ITS TREATMENT.pdf
WATER and ITS TREATMENT.pdf
ssuserdeaeaf
 
Determination of hardness of water
Determination of hardness of waterDetermination of hardness of water
Determination of hardness of water
Anand Prithviraj
 
water technology.pptx
water technology.pptxwater technology.pptx
water technology.pptx
ShilpiiKabiraj
 
Assay of calcium gluconate
Assay of calcium gluconateAssay of calcium gluconate
Assay of calcium gluconate
smita shelke
 
Water analysis_Hardness.pptx
Water analysis_Hardness.pptxWater analysis_Hardness.pptx
Water analysis_Hardness.pptx
NaamkaranShukla
 
Quanti4
Quanti4Quanti4
Module 5 Chemistry notes and assignment notes
Module 5 Chemistry notes and assignment notesModule 5 Chemistry notes and assignment notes
Module 5 Chemistry notes and assignment notes
muhammedhasinnk
 
Water technology
Water technologyWater technology
Water technology
vraju6
 
Water by aluru jaideep reddy
Water by aluru jaideep reddyWater by aluru jaideep reddy
Water by aluru jaideep reddy
Aluru Jaideep Reddy
 
Engineering chemistry.pptx
Engineering chemistry.pptxEngineering chemistry.pptx
Engineering chemistry.pptx
21BD1A058RSahithi
 

Similar to Complexometric method (14)

Determination of hardness in water .pdf
Determination of hardness in water .pdfDetermination of hardness in water .pdf
Determination of hardness in water .pdf
 
Dyeing
DyeingDyeing
Dyeing
 
Presentation1 edta mg
Presentation1 edta mg Presentation1 edta mg
Presentation1 edta mg
 
22CYL13 & Chemistry Laboratory for FT (FT-Ca & Mg).ppt
22CYL13 & Chemistry Laboratory for FT (FT-Ca & Mg).ppt22CYL13 & Chemistry Laboratory for FT (FT-Ca & Mg).ppt
22CYL13 & Chemistry Laboratory for FT (FT-Ca & Mg).ppt
 
WATER and ITS TREATMENT.pdf
WATER and ITS TREATMENT.pdfWATER and ITS TREATMENT.pdf
WATER and ITS TREATMENT.pdf
 
Determination of hardness of water
Determination of hardness of waterDetermination of hardness of water
Determination of hardness of water
 
water technology.pptx
water technology.pptxwater technology.pptx
water technology.pptx
 
Assay of calcium gluconate
Assay of calcium gluconateAssay of calcium gluconate
Assay of calcium gluconate
 
Water analysis_Hardness.pptx
Water analysis_Hardness.pptxWater analysis_Hardness.pptx
Water analysis_Hardness.pptx
 
Quanti4
Quanti4Quanti4
Quanti4
 
Module 5 Chemistry notes and assignment notes
Module 5 Chemistry notes and assignment notesModule 5 Chemistry notes and assignment notes
Module 5 Chemistry notes and assignment notes
 
Water technology
Water technologyWater technology
Water technology
 
Water by aluru jaideep reddy
Water by aluru jaideep reddyWater by aluru jaideep reddy
Water by aluru jaideep reddy
 
Engineering chemistry.pptx
Engineering chemistry.pptxEngineering chemistry.pptx
Engineering chemistry.pptx
 

Recently uploaded

Object Oriented Analysis and Design - OOAD
Object Oriented Analysis and Design - OOADObject Oriented Analysis and Design - OOAD
Object Oriented Analysis and Design - OOAD
PreethaV16
 
openshift technical overview - Flow of openshift containerisatoin
openshift technical overview - Flow of openshift containerisatoinopenshift technical overview - Flow of openshift containerisatoin
openshift technical overview - Flow of openshift containerisatoin
snaprevwdev
 
一比一原版(uoft毕业证书)加拿大多伦多大学毕业证如何办理
一比一原版(uoft毕业证书)加拿大多伦多大学毕业证如何办理一比一原版(uoft毕业证书)加拿大多伦多大学毕业证如何办理
一比一原版(uoft毕业证书)加拿大多伦多大学毕业证如何办理
sydezfe
 
Tools & Techniques for Commissioning and Maintaining PV Systems W-Animations ...
Tools & Techniques for Commissioning and Maintaining PV Systems W-Animations ...Tools & Techniques for Commissioning and Maintaining PV Systems W-Animations ...
Tools & Techniques for Commissioning and Maintaining PV Systems W-Animations ...
Transcat
 
Asymmetrical Repulsion Magnet Motor Ratio 6-7.pdf
Asymmetrical Repulsion Magnet Motor Ratio 6-7.pdfAsymmetrical Repulsion Magnet Motor Ratio 6-7.pdf
Asymmetrical Repulsion Magnet Motor Ratio 6-7.pdf
felixwold
 
Mechanical Engineering on AAI Summer Training Report-003.pdf
Mechanical Engineering on AAI Summer Training Report-003.pdfMechanical Engineering on AAI Summer Training Report-003.pdf
Mechanical Engineering on AAI Summer Training Report-003.pdf
21UME003TUSHARDEB
 
Digital Image Processing Unit -2 Notes complete
Digital Image Processing Unit -2 Notes completeDigital Image Processing Unit -2 Notes complete
Digital Image Processing Unit -2 Notes complete
shubhamsaraswat8740
 
SCALING OF MOS CIRCUITS m .pptx
SCALING OF MOS CIRCUITS m                 .pptxSCALING OF MOS CIRCUITS m                 .pptx
SCALING OF MOS CIRCUITS m .pptx
harshapolam10
 
Null Bangalore | Pentesters Approach to AWS IAM
Null Bangalore | Pentesters Approach to AWS IAMNull Bangalore | Pentesters Approach to AWS IAM
Null Bangalore | Pentesters Approach to AWS IAM
Divyanshu
 
Blood finder application project report (1).pdf
Blood finder application project report (1).pdfBlood finder application project report (1).pdf
Blood finder application project report (1).pdf
Kamal Acharya
 
Height and depth gauge linear metrology.pdf
Height and depth gauge linear metrology.pdfHeight and depth gauge linear metrology.pdf
Height and depth gauge linear metrology.pdf
q30122000
 
Transformers design and coooling methods
Transformers design and coooling methodsTransformers design and coooling methods
Transformers design and coooling methods
Roger Rozario
 
Ericsson LTE Throughput Troubleshooting Techniques.ppt
Ericsson LTE Throughput Troubleshooting Techniques.pptEricsson LTE Throughput Troubleshooting Techniques.ppt
Ericsson LTE Throughput Troubleshooting Techniques.ppt
wafawafa52
 
Beckhoff Programmable Logic Control Overview Presentation
Beckhoff Programmable Logic Control Overview PresentationBeckhoff Programmable Logic Control Overview Presentation
Beckhoff Programmable Logic Control Overview Presentation
VanTuDuong1
 
OOPS_Lab_Manual - programs using C++ programming language
OOPS_Lab_Manual - programs using C++ programming languageOOPS_Lab_Manual - programs using C++ programming language
OOPS_Lab_Manual - programs using C++ programming language
PreethaV16
 
Supermarket Management System Project Report.pdf
Supermarket Management System Project Report.pdfSupermarket Management System Project Report.pdf
Supermarket Management System Project Report.pdf
Kamal Acharya
 
Introduction to Computer Networks & OSI MODEL.ppt
Introduction to Computer Networks & OSI MODEL.pptIntroduction to Computer Networks & OSI MODEL.ppt
Introduction to Computer Networks & OSI MODEL.ppt
Dwarkadas J Sanghvi College of Engineering
 
Impartiality as per ISO /IEC 17025:2017 Standard
Impartiality as per ISO /IEC 17025:2017 StandardImpartiality as per ISO /IEC 17025:2017 Standard
Impartiality as per ISO /IEC 17025:2017 Standard
MuhammadJazib15
 
Prediction of Electrical Energy Efficiency Using Information on Consumer's Ac...
Prediction of Electrical Energy Efficiency Using Information on Consumer's Ac...Prediction of Electrical Energy Efficiency Using Information on Consumer's Ac...
Prediction of Electrical Energy Efficiency Using Information on Consumer's Ac...
PriyankaKilaniya
 
1FIDIC-CONSTRUCTION-CONTRACT-2ND-ED-2017-RED-BOOK.pdf
1FIDIC-CONSTRUCTION-CONTRACT-2ND-ED-2017-RED-BOOK.pdf1FIDIC-CONSTRUCTION-CONTRACT-2ND-ED-2017-RED-BOOK.pdf
1FIDIC-CONSTRUCTION-CONTRACT-2ND-ED-2017-RED-BOOK.pdf
MadhavJungKarki
 

Recently uploaded (20)

Object Oriented Analysis and Design - OOAD
Object Oriented Analysis and Design - OOADObject Oriented Analysis and Design - OOAD
Object Oriented Analysis and Design - OOAD
 
openshift technical overview - Flow of openshift containerisatoin
openshift technical overview - Flow of openshift containerisatoinopenshift technical overview - Flow of openshift containerisatoin
openshift technical overview - Flow of openshift containerisatoin
 
一比一原版(uoft毕业证书)加拿大多伦多大学毕业证如何办理
一比一原版(uoft毕业证书)加拿大多伦多大学毕业证如何办理一比一原版(uoft毕业证书)加拿大多伦多大学毕业证如何办理
一比一原版(uoft毕业证书)加拿大多伦多大学毕业证如何办理
 
Tools & Techniques for Commissioning and Maintaining PV Systems W-Animations ...
Tools & Techniques for Commissioning and Maintaining PV Systems W-Animations ...Tools & Techniques for Commissioning and Maintaining PV Systems W-Animations ...
Tools & Techniques for Commissioning and Maintaining PV Systems W-Animations ...
 
Asymmetrical Repulsion Magnet Motor Ratio 6-7.pdf
Asymmetrical Repulsion Magnet Motor Ratio 6-7.pdfAsymmetrical Repulsion Magnet Motor Ratio 6-7.pdf
Asymmetrical Repulsion Magnet Motor Ratio 6-7.pdf
 
Mechanical Engineering on AAI Summer Training Report-003.pdf
Mechanical Engineering on AAI Summer Training Report-003.pdfMechanical Engineering on AAI Summer Training Report-003.pdf
Mechanical Engineering on AAI Summer Training Report-003.pdf
 
Digital Image Processing Unit -2 Notes complete
Digital Image Processing Unit -2 Notes completeDigital Image Processing Unit -2 Notes complete
Digital Image Processing Unit -2 Notes complete
 
SCALING OF MOS CIRCUITS m .pptx
SCALING OF MOS CIRCUITS m                 .pptxSCALING OF MOS CIRCUITS m                 .pptx
SCALING OF MOS CIRCUITS m .pptx
 
Null Bangalore | Pentesters Approach to AWS IAM
Null Bangalore | Pentesters Approach to AWS IAMNull Bangalore | Pentesters Approach to AWS IAM
Null Bangalore | Pentesters Approach to AWS IAM
 
Blood finder application project report (1).pdf
Blood finder application project report (1).pdfBlood finder application project report (1).pdf
Blood finder application project report (1).pdf
 
Height and depth gauge linear metrology.pdf
Height and depth gauge linear metrology.pdfHeight and depth gauge linear metrology.pdf
Height and depth gauge linear metrology.pdf
 
Transformers design and coooling methods
Transformers design and coooling methodsTransformers design and coooling methods
Transformers design and coooling methods
 
Ericsson LTE Throughput Troubleshooting Techniques.ppt
Ericsson LTE Throughput Troubleshooting Techniques.pptEricsson LTE Throughput Troubleshooting Techniques.ppt
Ericsson LTE Throughput Troubleshooting Techniques.ppt
 
Beckhoff Programmable Logic Control Overview Presentation
Beckhoff Programmable Logic Control Overview PresentationBeckhoff Programmable Logic Control Overview Presentation
Beckhoff Programmable Logic Control Overview Presentation
 
OOPS_Lab_Manual - programs using C++ programming language
OOPS_Lab_Manual - programs using C++ programming languageOOPS_Lab_Manual - programs using C++ programming language
OOPS_Lab_Manual - programs using C++ programming language
 
Supermarket Management System Project Report.pdf
Supermarket Management System Project Report.pdfSupermarket Management System Project Report.pdf
Supermarket Management System Project Report.pdf
 
Introduction to Computer Networks & OSI MODEL.ppt
Introduction to Computer Networks & OSI MODEL.pptIntroduction to Computer Networks & OSI MODEL.ppt
Introduction to Computer Networks & OSI MODEL.ppt
 
Impartiality as per ISO /IEC 17025:2017 Standard
Impartiality as per ISO /IEC 17025:2017 StandardImpartiality as per ISO /IEC 17025:2017 Standard
Impartiality as per ISO /IEC 17025:2017 Standard
 
Prediction of Electrical Energy Efficiency Using Information on Consumer's Ac...
Prediction of Electrical Energy Efficiency Using Information on Consumer's Ac...Prediction of Electrical Energy Efficiency Using Information on Consumer's Ac...
Prediction of Electrical Energy Efficiency Using Information on Consumer's Ac...
 
1FIDIC-CONSTRUCTION-CONTRACT-2ND-ED-2017-RED-BOOK.pdf
1FIDIC-CONSTRUCTION-CONTRACT-2ND-ED-2017-RED-BOOK.pdf1FIDIC-CONSTRUCTION-CONTRACT-2ND-ED-2017-RED-BOOK.pdf
1FIDIC-CONSTRUCTION-CONTRACT-2ND-ED-2017-RED-BOOK.pdf
 

Complexometric method

  • 1. (EDTA METHOD) By : SHREE RAM SHARMA
  • 2. Principle Ca+2/Mg+2 + EBT [Ca+2—EBT] (Wine Red colour/Less stable) Ca+2/Mg+2 + EDTA [Ca+2—EDTA] (Colour Less/More stable) [Ca+2—EBT] [Ca+2—EDTA] + EBT (BLUE COLOUR)
  • 3. Procedure  Preparation of Solution  Determination of Hardness of Water  Calculation
  • 4. Preparation of Solution I. EDTA Solution II. EBT Solution III. Buffer Solution IV. SHW Solution
  • 5. Determination of Hardness  Standardization of EDTA : 10ml SHW + 3ml Buffer + 2 drop EBT wine red colour +EDTA Blue colour (End Point)
  • 6.  Determination of Total Hardness : 10ml Water Sample +3ml Buffer + 2 drop EBT wine red colour +EDTA Blue colour (End Point)
  • 7.  Determination of Permanent Hardness : 250ml Water Sample boil 50 ml filter Filtrate make up to 1 lt. by D.W.(Boil Water) 10ml boil water sample + 3ml Buffer + 2 drop EBT Blue colour +EDTA wine red colour (End Point)
  • 8. Calculation  Standardization of EDTA : 10 ml of SHW = 10mg of CaCO3 eq. 10 ml of SHW = V1 ml of EDTA 10 mg of CaCO3 eq. = V1 ml of EDTA 1 ml of EDTA = 10/ V1 mg of CaCO3 eq.
  • 9.  Total Hardness : 10 ml H2O sample = V2 ml of EDTA 10 ml H2O sample = V2×10/V1 mg of CaCO3 eq. 1000 ml of H2O sample = (V2/V1)×1000 ppm
  • 10.  Permanent Hardness : 10 ml boil H2O sample = V3 ml of EDTA 10 ml boil H2O sample = V3×10 mg of CaCO3 eq. 1000ml of boil H2O sample = (V3/V1)×1000 ppm
  • 11.  Temporary Hardness : Total Hardness = Temp. H. + Per. H. Temp. H. = Total H.-Per. H. => Temp. H. = {(V2-V3)/V1}×1000 ppm
  • 12. Advantages  Greater accuracy  More rapid procedure  Convenience