Chemical kinetics
Rate of a reaction
O 1) amount of reactant used up/time taken
O 2) amount of product formed/time taken
O 3) volume of gas produced/time taken
Measuring rate of reaction –
volume of gas produced
O Since magnesium reacts with dilute HCl to

form hydrogen gas, the speed of reaction
can hence be determined by measuring
the volume of hydrogen gas produced at
regular time intervals.
Experimentation Time!
O Conduct your own experiment and sketch

out your own vol. of hydrogen vs time
graph!
Graph analysis
O Gradient of graph  speed of reaction
O The steeper the gradient, the faster the

speed of reaction
O Decrease in steepness indicates
decreasing speed of reaction
O Shape of graph  changes/consistency in
speed of reaction as time passes
Measuring speed of reactionchanges in mass
O Allow gas produced to escape and

measure the loss of mass
O Reaction speed determined by measuring
loss of mass at regular time intervals
Factors affecting rate of a
chemical reaction
O Summary:
O Temperature
O Concentration
O Pressure

O Surface area
O Presence of a catalyst
Collision theory
O For a reaction to occur, reacting particles

must
O 1) collide with each other
O 2) possess activation energy
O Note: Orientation of collision must be

correct as well
Factor 1: Temperature
O Increase in temp.  increase in KE 

increase in no. of collisions + increase in
no. of particles with greater than required
amount of activation energy  more
particles react  increase rate of reaction
Put on your thinking cap!
O Can you explain why food should be kept

in deep-freeze compartments in order to
ensure its freshness?
O (answer on next slide)
O Answer:
O The low temperature slows down

chemical reactions which makes the food
turn bad.
Factor 2:
Concentration/Pressure
O High concentration/pressure  more

particles per unit volume  increase in
frequency of collisions  rate of reaction
increases
Factor 3: Surface area
O Increase in surface area/particle size 

increase in exposure to the other reactant
 increase in probability of collisions 
increase in rate of reaction
Factor 4: Presence of Catalyst
O Speeds up rate of reaction through

lowering activation energy needed for
reaction to occur
O Think: What can you infer from the above
statement?
The end
Learn through understanding, not
through memorization.

Chemical kinetics

  • 1.
  • 2.
    Rate of areaction O 1) amount of reactant used up/time taken O 2) amount of product formed/time taken O 3) volume of gas produced/time taken
  • 3.
    Measuring rate ofreaction – volume of gas produced O Since magnesium reacts with dilute HCl to form hydrogen gas, the speed of reaction can hence be determined by measuring the volume of hydrogen gas produced at regular time intervals.
  • 4.
    Experimentation Time! O Conductyour own experiment and sketch out your own vol. of hydrogen vs time graph!
  • 5.
    Graph analysis O Gradientof graph  speed of reaction O The steeper the gradient, the faster the speed of reaction O Decrease in steepness indicates decreasing speed of reaction O Shape of graph  changes/consistency in speed of reaction as time passes
  • 6.
    Measuring speed ofreactionchanges in mass O Allow gas produced to escape and measure the loss of mass O Reaction speed determined by measuring loss of mass at regular time intervals
  • 7.
    Factors affecting rateof a chemical reaction O Summary: O Temperature O Concentration O Pressure O Surface area O Presence of a catalyst
  • 8.
    Collision theory O Fora reaction to occur, reacting particles must O 1) collide with each other O 2) possess activation energy O Note: Orientation of collision must be correct as well
  • 9.
    Factor 1: Temperature OIncrease in temp.  increase in KE  increase in no. of collisions + increase in no. of particles with greater than required amount of activation energy  more particles react  increase rate of reaction
  • 10.
    Put on yourthinking cap! O Can you explain why food should be kept in deep-freeze compartments in order to ensure its freshness? O (answer on next slide)
  • 11.
    O Answer: O Thelow temperature slows down chemical reactions which makes the food turn bad.
  • 12.
    Factor 2: Concentration/Pressure O Highconcentration/pressure  more particles per unit volume  increase in frequency of collisions  rate of reaction increases
  • 13.
    Factor 3: Surfacearea O Increase in surface area/particle size  increase in exposure to the other reactant  increase in probability of collisions  increase in rate of reaction
  • 14.
    Factor 4: Presenceof Catalyst O Speeds up rate of reaction through lowering activation energy needed for reaction to occur O Think: What can you infer from the above statement?
  • 15.
    The end Learn throughunderstanding, not through memorization.