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Chemical Exergy Analysis of Oil Palm Waste and its
Pelletized Derivatives
- Bemgba Bevan Nyakuma -
5th Conference on Emerging Energy and Process Technology
(CONCEPT2016)
7th - 8th December 2016
Ancasa Residences, Port Dickson, Malaysia
2
Arshad Ahmad, Anwar Johari, Tuan Amran T.
Abdullah, Olagoke Oladokun, Habib Alkali
Co-authors
• Introduction
• Experimental
• Results
• Conclusion
3
Contents
4
Introduction
5
• Malaysia  2nd Largest producer &
exporter of Palm Oil
• 5 Million hectares,
• 75 million tons of Fresh Fruit
Bunches (FFB),
• 400 palm oils mills.
• Crude Palm Oil (CPO) >>
• Feedstock/Raw material for
food, confectionary, biodiesel
• Palm Oil Industry  Foreign
exchange, National Pride
Introduction
www.palmoilhealth.org
http://bit.ly/2gaTMeA
6
Solid Waste >> Empty Fruit Bunch (EFB), Palm Kernel Shell
(PKS),Mesocarp Fibre (MCF), Palm Fronds, Palm Kernel Cake, Trunks
7
• CPO production generates
large quantities of waste >>
• 1 kg CPO >> 4 kg of Solid
Waste, 12.4 kg of CO2
• Classification of Oil Palm
Wastes;
• Liquid (POME),
• Solid Biomass Waste
• Solid Wastes >>
Oil Mill and Plantation
www.mpoc.org.my
8
http://bit.ly/2fgR4Fchttp://bit.ly/2fI22Ep
http://bit.ly/2fgSBLshttp://bit.ly/2g8mL53
9
• National Biomass Strategy 2020 est. in 2013
>> NBS-2020.
• 20 million tonnes of OPW by 2020 into higher-value
products and national income GNI by RM 30 billion
• NBS2020 >> meet its renewable energy target and
reduce GHG emissions
Introduction
10
• 200 Million Metric tons of wastes generated
between year 2010 – 2015
• Current conversion technologies – open air burning,
incineration, land filling, boiler fuel
• Inefficient, outdated, hazardous, unsustainable and
expensive
• Increased GHGs, Loss of Biodiversity and
Environmental challenges; eutrophication, leaching
http://bit.ly/2fgR4Fc
11
Pre-Treatment & Valorisation of
Oil Palm EFB 
Largest stock with low Value,
High moisture,
High Alkali, &
Low Bulk Density
Introduction
Drying
Shredding
Pelletization
Torrefaction
Fresh Oil Palm
Fruit Bunches
Pelletized Oil Palm Empty
Fruit Bunches (OPEFB)
Oil Palm Empty fruit
Bunches (OPEFB)
12
Study Objective
13
To examine exergy values of empty fruit bunches (OPEFB), it’s
pelletized and torrefied (torrefaction) derivatives.
To evaluate the effect of physicochemical and thermal
properties on the chemical exergy values.
14
Experimental
15
Experimental
Acquisition of pelletized OPEFB
(Felda Semenchu Oil Palm Mill in Johor.
Pulverization, Characterization & Torrefaction
(Ultimate, proximate and calorific Analysis)
Chemical Exergy Analysis
(Elemental analysis and heating values)
Comparison with other OPEFB Fuels in literature
(Elemental analysis and heating values)
16
Experimental
Where the terms
β = Mass Fraction
ECH, = Chemical Exergy
LHV and HHV, = Heating Value
H, O, N, = Hydrogen, Oxygen and Nitrogen.
𝐸 𝐶𝐻 = 𝛽 × 𝐻𝐻𝑉
𝛽 = 1.0438 + 0.00158
𝐻
𝐶
+ 0.0813
𝑂
𝐶
+ 0.0471
𝑁
𝐶
𝐸 𝐶𝐻
= 1.08𝐻𝐻𝑉 − 22.62𝐻 − 0.86𝑂 + 4.02𝑁
Exergy Equations
17
Results
18
Results
Fuel Properties Results
19
Results
Chemical Exergy Results
20
Conclusion
21
Conclusions
The paper examined the physicochemical, thermal and
chemical exergy values of oil palm empty fruit bunches
(OPEFB) and its torrefied product.
The result showed that torrefaction improved the fuel
properties of the raw feedstock and theoretical useful
energy available for bioenergy applications.
22
The End
Terima kasih
(Thank you)
23
Acknowledgement
The authors wish to acknowledge the
financial support from Universiti Teknologi
Malaysia through the Research University
Grants; Q.J130000.2509.07H12 and
Q.J130000.2509.13H95.
24
References
[1]Basu, P., Biomass gasification, pyrolysis and torrefaction: practical design and theory. 2013: Academic
Press.
[2]Johnson, E. Goodbye to carbon neutral: Getting biomass footprints right. Environmental impact
assessment review, 29, 2009, 3: 165-168.
[3]Nyakuma, B. B., Johari, A., Ahmad, A., Abdullah, T. A. T. Comparative analysis of the calorific fuel
properties of Empty Fruit Bunch Fiber and Briquette. Energy Procedia, 52, 2014: 466-473.
[4]Bilgen, S. Correlation for estimation of the chemical availability (exergy) from ultimate analysis of pyrolytic
oils obtained from fast pyrolysis of biomass. Energy Sources, Part A: Recovery, Utilization, and
Environmental Effects, 38, 2016, 9: 1286-1292.
[5]Nyakuma, B. B., Ahmad, A., Johari, A., Tuan Abdullah, T. A., Oladokun, O., Aminu, Y. D. Non-Isothermal
Kinetic Analysis of Oil Palm Empty Fruit Bunch Pellets by Thermogravimetric Analysis. Chemical
Engineering Transactions, 45, 2015: 1327-1332.
[6]Oladokun, O., Ahmad, A., Abdullah, T. A. T., Nyakuma, B. B., Bello, A. A.-H., Al-Shatri, A. H.
Multicomponent devolatilization kinetics and thermal conversion of Imperata cylindrica. Applied Thermal
Engineering, 105, 2016: 931-940.
[7]Bilgen, S. Calculation of Thermodynamic Values for Agricultural Residues as Potential Renewable
Energy Resources. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 37, 2015, 12:
1268-1274.

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Chemical exergy analysis of oil palm waste

  • 1. Chemical Exergy Analysis of Oil Palm Waste and its Pelletized Derivatives - Bemgba Bevan Nyakuma - 5th Conference on Emerging Energy and Process Technology (CONCEPT2016) 7th - 8th December 2016 Ancasa Residences, Port Dickson, Malaysia
  • 2. 2 Arshad Ahmad, Anwar Johari, Tuan Amran T. Abdullah, Olagoke Oladokun, Habib Alkali Co-authors
  • 3. • Introduction • Experimental • Results • Conclusion 3 Contents
  • 5. 5 • Malaysia  2nd Largest producer & exporter of Palm Oil • 5 Million hectares, • 75 million tons of Fresh Fruit Bunches (FFB), • 400 palm oils mills. • Crude Palm Oil (CPO) >> • Feedstock/Raw material for food, confectionary, biodiesel • Palm Oil Industry  Foreign exchange, National Pride Introduction www.palmoilhealth.org http://bit.ly/2gaTMeA
  • 6. 6 Solid Waste >> Empty Fruit Bunch (EFB), Palm Kernel Shell (PKS),Mesocarp Fibre (MCF), Palm Fronds, Palm Kernel Cake, Trunks
  • 7. 7 • CPO production generates large quantities of waste >> • 1 kg CPO >> 4 kg of Solid Waste, 12.4 kg of CO2 • Classification of Oil Palm Wastes; • Liquid (POME), • Solid Biomass Waste • Solid Wastes >> Oil Mill and Plantation www.mpoc.org.my
  • 9. 9 • National Biomass Strategy 2020 est. in 2013 >> NBS-2020. • 20 million tonnes of OPW by 2020 into higher-value products and national income GNI by RM 30 billion • NBS2020 >> meet its renewable energy target and reduce GHG emissions Introduction
  • 10. 10 • 200 Million Metric tons of wastes generated between year 2010 – 2015 • Current conversion technologies – open air burning, incineration, land filling, boiler fuel • Inefficient, outdated, hazardous, unsustainable and expensive • Increased GHGs, Loss of Biodiversity and Environmental challenges; eutrophication, leaching http://bit.ly/2fgR4Fc
  • 11. 11 Pre-Treatment & Valorisation of Oil Palm EFB  Largest stock with low Value, High moisture, High Alkali, & Low Bulk Density Introduction Drying Shredding Pelletization Torrefaction Fresh Oil Palm Fruit Bunches Pelletized Oil Palm Empty Fruit Bunches (OPEFB) Oil Palm Empty fruit Bunches (OPEFB)
  • 13. 13 To examine exergy values of empty fruit bunches (OPEFB), it’s pelletized and torrefied (torrefaction) derivatives. To evaluate the effect of physicochemical and thermal properties on the chemical exergy values.
  • 15. 15 Experimental Acquisition of pelletized OPEFB (Felda Semenchu Oil Palm Mill in Johor. Pulverization, Characterization & Torrefaction (Ultimate, proximate and calorific Analysis) Chemical Exergy Analysis (Elemental analysis and heating values) Comparison with other OPEFB Fuels in literature (Elemental analysis and heating values)
  • 16. 16 Experimental Where the terms β = Mass Fraction ECH, = Chemical Exergy LHV and HHV, = Heating Value H, O, N, = Hydrogen, Oxygen and Nitrogen. 𝐸 𝐶𝐻 = 𝛽 × 𝐻𝐻𝑉 𝛽 = 1.0438 + 0.00158 𝐻 𝐶 + 0.0813 𝑂 𝐶 + 0.0471 𝑁 𝐶 𝐸 𝐶𝐻 = 1.08𝐻𝐻𝑉 − 22.62𝐻 − 0.86𝑂 + 4.02𝑁 Exergy Equations
  • 21. 21 Conclusions The paper examined the physicochemical, thermal and chemical exergy values of oil palm empty fruit bunches (OPEFB) and its torrefied product. The result showed that torrefaction improved the fuel properties of the raw feedstock and theoretical useful energy available for bioenergy applications.
  • 23. 23 Acknowledgement The authors wish to acknowledge the financial support from Universiti Teknologi Malaysia through the Research University Grants; Q.J130000.2509.07H12 and Q.J130000.2509.13H95.
  • 24. 24 References [1]Basu, P., Biomass gasification, pyrolysis and torrefaction: practical design and theory. 2013: Academic Press. [2]Johnson, E. Goodbye to carbon neutral: Getting biomass footprints right. Environmental impact assessment review, 29, 2009, 3: 165-168. [3]Nyakuma, B. B., Johari, A., Ahmad, A., Abdullah, T. A. T. Comparative analysis of the calorific fuel properties of Empty Fruit Bunch Fiber and Briquette. Energy Procedia, 52, 2014: 466-473. [4]Bilgen, S. Correlation for estimation of the chemical availability (exergy) from ultimate analysis of pyrolytic oils obtained from fast pyrolysis of biomass. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 38, 2016, 9: 1286-1292. [5]Nyakuma, B. B., Ahmad, A., Johari, A., Tuan Abdullah, T. A., Oladokun, O., Aminu, Y. D. Non-Isothermal Kinetic Analysis of Oil Palm Empty Fruit Bunch Pellets by Thermogravimetric Analysis. Chemical Engineering Transactions, 45, 2015: 1327-1332. [6]Oladokun, O., Ahmad, A., Abdullah, T. A. T., Nyakuma, B. B., Bello, A. A.-H., Al-Shatri, A. H. Multicomponent devolatilization kinetics and thermal conversion of Imperata cylindrica. Applied Thermal Engineering, 105, 2016: 931-940. [7]Bilgen, S. Calculation of Thermodynamic Values for Agricultural Residues as Potential Renewable Energy Resources. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 37, 2015, 12: 1268-1274.

Editor's Notes

  1. For every 1 kg of palm oil produced, 4 kg of waste is produced.