Optical Activity
When a compound rotate the plane Polarized Light
than it is said to be optically active and this
phenomenon is called optical activity.
1. Dextrorotatory Isomer (+ compound): A
compound is said to be dextrorotatory when it
rotate plane Polarized Light on right side. Dextro
means right hand.
2. Levororatory Isomer (- compound): A compound
is said to be levorotatory when it rotate plane
Polarized Light on left side. Levo means left hand.
Page 139
Chirality Optical Activity in Glucose
**
Light that vibrates in one plane is
called as Plane Polarized Light
Light can be divided into two types according to
wavelength.
1. Polychromatic Light: Light that composed of
many wavelengths are called as
polychromatic light. All lights Gamma, X-rays,
UV, IR are polychromatic light.
2. Monochromatic Light: Light that composed
of a single wavelength is called as
monochromatic light. Monochromatic light
can be selected for studying of properties of
compounds. For example optical activity.
Page 139
Polarimeter
An instrument that is used for the measurement
of optical activity of a compound is called as
polarimeter
Page 139,140
Plane polarizer are mostly Nicol Prism made up of calcite (CaCO3)
Dextrorotatory
Levorotatory
2. Optical Isomerism
Optical Isomers: Different compounds that are
mirror images of each other and non
superimposable are called as optical isomers.
These isomers are formed due to rotation of Plane
Polarized Light either clockwise Dextrorotatory or
anti clockwise Levororatory. These isomers have
chiral (asymmetric) carbon atom.
Chiral Carbon (Chiral centre)
Carbon that attaches with four different atoms
(groups) is called chiral (asymmetric)carbon.
Chiral means handedness
Page 140
Chiral Compounds are mirror images of each other
Page 140
Chiral means hand
like property. As
left hand is mirror
image of right
hand, similarly
Chiral molecules
are mirror images
of each other
Two types of Lactic Acids (
Dextrorotatory(d) Levorotatory(l)
Optical Isomers are also called as Enantiomers
Page 140

Chapter 16, plane polarized light lec.11

  • 1.
    Optical Activity When acompound rotate the plane Polarized Light than it is said to be optically active and this phenomenon is called optical activity. 1. Dextrorotatory Isomer (+ compound): A compound is said to be dextrorotatory when it rotate plane Polarized Light on right side. Dextro means right hand. 2. Levororatory Isomer (- compound): A compound is said to be levorotatory when it rotate plane Polarized Light on left side. Levo means left hand. Page 139
  • 2.
  • 3.
    Light that vibratesin one plane is called as Plane Polarized Light Light can be divided into two types according to wavelength. 1. Polychromatic Light: Light that composed of many wavelengths are called as polychromatic light. All lights Gamma, X-rays, UV, IR are polychromatic light. 2. Monochromatic Light: Light that composed of a single wavelength is called as monochromatic light. Monochromatic light can be selected for studying of properties of compounds. For example optical activity. Page 139
  • 4.
    Polarimeter An instrument thatis used for the measurement of optical activity of a compound is called as polarimeter Page 139,140
  • 5.
    Plane polarizer aremostly Nicol Prism made up of calcite (CaCO3) Dextrorotatory Levorotatory
  • 6.
    2. Optical Isomerism OpticalIsomers: Different compounds that are mirror images of each other and non superimposable are called as optical isomers. These isomers are formed due to rotation of Plane Polarized Light either clockwise Dextrorotatory or anti clockwise Levororatory. These isomers have chiral (asymmetric) carbon atom. Chiral Carbon (Chiral centre) Carbon that attaches with four different atoms (groups) is called chiral (asymmetric)carbon. Chiral means handedness Page 140
  • 8.
    Chiral Compounds aremirror images of each other Page 140
  • 9.
    Chiral means hand likeproperty. As left hand is mirror image of right hand, similarly Chiral molecules are mirror images of each other
  • 10.
    Two types ofLactic Acids ( Dextrorotatory(d) Levorotatory(l) Optical Isomers are also called as Enantiomers
  • 11.