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Chemistry:
The Study of Change
Chapter 1
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
1. _________ is anything that occupies space
and has mass.
2. A __________ is a form of matter that has
a definite composition and distinct
properties.
_______________ is the study of matter
and the changes it undergoes
1.4
A ______ is a combination of two or more substances
in which the substances retain their distinct identities.
1. ____________________ – composition of the
mixture is the same throughout.
2. ____________________ – composition is not
uniform throughout.
soft drink, milk, solder
cement,
iron filings in sand
1.4
________________ means can be used to separate
a mixture into its pure components.
magnet
1.4
distillation
An ____________ is a substance that cannot be
separated into simpler substances by chemical
means.
• 115 elements have been identified
• 83 elements occur naturally on Earth
gold, aluminum, lead, oxygen, carbon
• 32 elements have been created by scientists—
like technecium, amerecium, seaborgium
1.4
I expect you to know the names and symbols
of the elements
A _______________ is a substance composed of
atoms of two or more elements chemically united
in fixed proportions.
Compounds can be separated only by __________
means into their pure components (elements).
Water (H2O) Sucrose (C6H12O6)
Ammonia (NH3)
1.4
1.4
Three States of Matter
1.5
Physical or Chemical?
A _________________________ does not alter the
composition or identity of a substance.
A ____________________ alters the composition
or identity of the substance(s) involved.
ice melting
sugar dissolving
in water
hydrogen gas burns in oxygen gas to form water
1.6
_______________ - occupies space and has mass.
____________ – measure of the quantity of matter
SI base unit of mass is the ________________
1 kg = 1000 g = 1 x 103
g
_________ – force that gravity exerts on an object
weight = c x mass
on earth, c = 1.0
on moon, c ~ 0.1
1.7
A 1 kg bar will weigh
1 kg on earth
0.1 kg on moon
Table 1.2 SI Base (or Fundamental) Units
Base Quantity Name of Unit Symbol
Length meter m
Mass kilogram kg
Time second s
Current ampere A
Temperature kelvin K
Amount of substance mole mol
Luminous intensity candela cd
1.7
Know these!
Table 1.3 Prefixes Used with SI Units
Prefix Symbol Meaning
Tera- T 1012
Giga- G 109
Mega- M 106
Kilo- k 103
Deci- d 10-1
Centi- c 10-2
Milli- m 10-3
Micro- µ 10-6
Nano- n 10-9
Pico- p 10-12
1.7
__________________ – SI derived unit for volume
is cubic meter (m3
)
1 cm3
= (1 x 10-2
m)3
= 1 x 10-6
m3
1 dm3
= (1 x 10-1
m)3
= 1 x 10-3
m3
1 L = 1000 mL = 1000 cm3
= 1 dm3
1 mL = 1 cm3
1.7
Density – SI derived unit for density is kg/m3
1 g/cm3
= 1 g/mL = 1000 kg/m3
_______ =
mass
volume d =
m
V
1.7
A piece of platinum metal with a density of 21.5
g/cm3
has a volume of 4.49 cm3
. What is its mass?
d =
m
V
K = 0
C + 273.15
0
F = x 0
C + 329
5
1.7
273 K = 0 0
C
373 K = 100 0
C
32 0
F = 0 0
C
212 0
F = 100 0
C
Know these!
Convert 172.9 0
F to degrees Celsius.
0
F = x 0
C + 329
5
0
F – 32 = x 0
C9
5
x (0
F – 32) = 0
C
9
5
0
C = x (0
F – 32)
9
5
0
C = x (172.9 – 32) = ________
9
5
1.7
1.8
Scientific Notation
The number of atoms in 12 g of carbon:
602,200,000,000,000,000,000,000
6.022 x 1023
The mass of a single carbon atom in grams:
0.0000000000000000000000199
1.99 x 10-23
N x 10n
N is a number
between 1 and 10
n is a positive or
negative integer
Scientific Notation
1.8
568.762
n > 0
568.762 = 5.68762 x 102
move decimal left
0.00000772
n < 0
0.00000772 = 7.72 x 10-6
move decimal right
Addition or Subtraction
1. Write each quantity with
the same exponent n
2. Combine N1 and N2
3. The exponent, n, remains
the same
4.31 x 104
+ 3.9 x 103
=
4.31 x 104
+ 0.39 x 104
=
4.70 x 104
Scientific Notation
1.8
Multiplication
1. Multiply N1 and N2
2. Add exponents n1 and n2
(4.0 x 10-5
) x (7.0 x 103
) =
(4.0 x 7.0) x (10-5+3
) =
28 x 10-2
=
2.8 x 10-1
Division
1. Divide N1 and N2
2. Subtract exponents n1 and n2
8.5 x 104
÷ 5.0 x 109
=
(8.5 ÷ 5.0) x 104-9
=
1.7 x 10-5
Significant Figures
1.8
•Any digit that is not zero is significant
1.234 kg 4 significant figures
•Zeros between nonzero digits are significant
606 m 3 significant figures
•Zeros to the left of the first nonzero digit are not significant
0.08 L 1 significant figure
•If a number is greater than 1, then all zeros to the right of
the decimal point are significant
2.0 mg 2 significant figures
•If a number is less than 1, then only the zeros that are at
the end and in the middle of the number are significant
0.00420 g 3 significant figures
How many significant figures are in
each of the following measurements?
24 mL
3001 g
0.0320 m3
6.4 x 104
molecules
560 kg
1.8
Significant Figures
1.8
Addition or Subtraction
The answer cannot have more digits to the right of the
decimal point than any of the original numbers.
89.332
1.1+
90.432 round off to 90.4
one significant figure after decimal point
3.70
-2.9133
0.7867
two significant figures after decimal point
round off to 0.79
Significant Figures
1.8
Multiplication or Division
The number of significant figures in the result is set by the original
number that has the smallest number of significant figures
4.51 x 3.6666 = 16.536366 = 16.5
3 sig figs round to
3 sig figs
6.8 ÷ 112.04 = 0.0606926
2 sig figs round to
2 sig figs
= 0.061
Significant Figures
1.8
Exact Numbers
Numbers from definitions or numbers of objects are
considered to have an infinite number of significant figures
The average of three measured lengths; 6.64, 6.68 and 6.70?
6.64 + 6.68 + 6.70
3
= 6.67333 = 6.67
Because 3 is an exact number
= 7
_____________ – how close a measurement is to the true value
__________ – how close a set of measurements are to each other
accurate
&
precise
precise
but
not accurate
not accurate
&
not precise
1.8
1.9
Factor-Label Method of Solving Problems
1. Determine which unit conversion factor(s) are needed
2. Carry units through calculation
3. If all units cancel except for the desired unit(s), then the
problem was solved correctly.
1 L = 1000 mL
How many mL are in 1.63 L?
1L
1000 mL
1.63 L x = 1630 mL
1L
1000 mL
1.63 L x = 0.001630
L2
mL
The speed of sound in air is about 343 m/s. What is
this speed in miles per hour?
1 mi = 1609 m 1 min = 60 s 1 hour = 60 min
meters to miles
seconds to hours
1.9

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C mchap01 chang3ed handout

  • 1. Chemistry: The Study of Change Chapter 1 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
  • 2. 1. _________ is anything that occupies space and has mass. 2. A __________ is a form of matter that has a definite composition and distinct properties. _______________ is the study of matter and the changes it undergoes 1.4
  • 3. A ______ is a combination of two or more substances in which the substances retain their distinct identities. 1. ____________________ – composition of the mixture is the same throughout. 2. ____________________ – composition is not uniform throughout. soft drink, milk, solder cement, iron filings in sand 1.4
  • 4. ________________ means can be used to separate a mixture into its pure components. magnet 1.4 distillation
  • 5. An ____________ is a substance that cannot be separated into simpler substances by chemical means. • 115 elements have been identified • 83 elements occur naturally on Earth gold, aluminum, lead, oxygen, carbon • 32 elements have been created by scientists— like technecium, amerecium, seaborgium 1.4 I expect you to know the names and symbols of the elements
  • 6. A _______________ is a substance composed of atoms of two or more elements chemically united in fixed proportions. Compounds can be separated only by __________ means into their pure components (elements). Water (H2O) Sucrose (C6H12O6) Ammonia (NH3) 1.4
  • 7. 1.4
  • 8. Three States of Matter 1.5
  • 9. Physical or Chemical? A _________________________ does not alter the composition or identity of a substance. A ____________________ alters the composition or identity of the substance(s) involved. ice melting sugar dissolving in water hydrogen gas burns in oxygen gas to form water 1.6
  • 10. _______________ - occupies space and has mass. ____________ – measure of the quantity of matter SI base unit of mass is the ________________ 1 kg = 1000 g = 1 x 103 g _________ – force that gravity exerts on an object weight = c x mass on earth, c = 1.0 on moon, c ~ 0.1 1.7 A 1 kg bar will weigh 1 kg on earth 0.1 kg on moon
  • 11. Table 1.2 SI Base (or Fundamental) Units Base Quantity Name of Unit Symbol Length meter m Mass kilogram kg Time second s Current ampere A Temperature kelvin K Amount of substance mole mol Luminous intensity candela cd 1.7 Know these!
  • 12. Table 1.3 Prefixes Used with SI Units Prefix Symbol Meaning Tera- T 1012 Giga- G 109 Mega- M 106 Kilo- k 103 Deci- d 10-1 Centi- c 10-2 Milli- m 10-3 Micro- µ 10-6 Nano- n 10-9 Pico- p 10-12 1.7
  • 13. __________________ – SI derived unit for volume is cubic meter (m3 ) 1 cm3 = (1 x 10-2 m)3 = 1 x 10-6 m3 1 dm3 = (1 x 10-1 m)3 = 1 x 10-3 m3 1 L = 1000 mL = 1000 cm3 = 1 dm3 1 mL = 1 cm3 1.7
  • 14. Density – SI derived unit for density is kg/m3 1 g/cm3 = 1 g/mL = 1000 kg/m3 _______ = mass volume d = m V 1.7 A piece of platinum metal with a density of 21.5 g/cm3 has a volume of 4.49 cm3 . What is its mass? d = m V
  • 15. K = 0 C + 273.15 0 F = x 0 C + 329 5 1.7 273 K = 0 0 C 373 K = 100 0 C 32 0 F = 0 0 C 212 0 F = 100 0 C Know these!
  • 16. Convert 172.9 0 F to degrees Celsius. 0 F = x 0 C + 329 5 0 F – 32 = x 0 C9 5 x (0 F – 32) = 0 C 9 5 0 C = x (0 F – 32) 9 5 0 C = x (172.9 – 32) = ________ 9 5 1.7
  • 17. 1.8 Scientific Notation The number of atoms in 12 g of carbon: 602,200,000,000,000,000,000,000 6.022 x 1023 The mass of a single carbon atom in grams: 0.0000000000000000000000199 1.99 x 10-23 N x 10n N is a number between 1 and 10 n is a positive or negative integer
  • 18. Scientific Notation 1.8 568.762 n > 0 568.762 = 5.68762 x 102 move decimal left 0.00000772 n < 0 0.00000772 = 7.72 x 10-6 move decimal right Addition or Subtraction 1. Write each quantity with the same exponent n 2. Combine N1 and N2 3. The exponent, n, remains the same 4.31 x 104 + 3.9 x 103 = 4.31 x 104 + 0.39 x 104 = 4.70 x 104
  • 19. Scientific Notation 1.8 Multiplication 1. Multiply N1 and N2 2. Add exponents n1 and n2 (4.0 x 10-5 ) x (7.0 x 103 ) = (4.0 x 7.0) x (10-5+3 ) = 28 x 10-2 = 2.8 x 10-1 Division 1. Divide N1 and N2 2. Subtract exponents n1 and n2 8.5 x 104 ÷ 5.0 x 109 = (8.5 ÷ 5.0) x 104-9 = 1.7 x 10-5
  • 20. Significant Figures 1.8 •Any digit that is not zero is significant 1.234 kg 4 significant figures •Zeros between nonzero digits are significant 606 m 3 significant figures •Zeros to the left of the first nonzero digit are not significant 0.08 L 1 significant figure •If a number is greater than 1, then all zeros to the right of the decimal point are significant 2.0 mg 2 significant figures •If a number is less than 1, then only the zeros that are at the end and in the middle of the number are significant 0.00420 g 3 significant figures
  • 21. How many significant figures are in each of the following measurements? 24 mL 3001 g 0.0320 m3 6.4 x 104 molecules 560 kg 1.8
  • 22. Significant Figures 1.8 Addition or Subtraction The answer cannot have more digits to the right of the decimal point than any of the original numbers. 89.332 1.1+ 90.432 round off to 90.4 one significant figure after decimal point 3.70 -2.9133 0.7867 two significant figures after decimal point round off to 0.79
  • 23. Significant Figures 1.8 Multiplication or Division The number of significant figures in the result is set by the original number that has the smallest number of significant figures 4.51 x 3.6666 = 16.536366 = 16.5 3 sig figs round to 3 sig figs 6.8 ÷ 112.04 = 0.0606926 2 sig figs round to 2 sig figs = 0.061
  • 24. Significant Figures 1.8 Exact Numbers Numbers from definitions or numbers of objects are considered to have an infinite number of significant figures The average of three measured lengths; 6.64, 6.68 and 6.70? 6.64 + 6.68 + 6.70 3 = 6.67333 = 6.67 Because 3 is an exact number = 7
  • 25. _____________ – how close a measurement is to the true value __________ – how close a set of measurements are to each other accurate & precise precise but not accurate not accurate & not precise 1.8
  • 26. 1.9 Factor-Label Method of Solving Problems 1. Determine which unit conversion factor(s) are needed 2. Carry units through calculation 3. If all units cancel except for the desired unit(s), then the problem was solved correctly. 1 L = 1000 mL How many mL are in 1.63 L? 1L 1000 mL 1.63 L x = 1630 mL 1L 1000 mL 1.63 L x = 0.001630 L2 mL
  • 27. The speed of sound in air is about 343 m/s. What is this speed in miles per hour? 1 mi = 1609 m 1 min = 60 s 1 hour = 60 min meters to miles seconds to hours 1.9