The document proposes a novel method to characterize nonlinear channels in OFDM systems using spectral notch signals. The method involves transmitting OFDM frames with and without spectral notches and analyzing the difference signal. This allows the estimation of frequency-domain Volterra kernels to be decomposed into independent subtasks involving fewer coefficients, improving accuracy and reducing complexity compared to conventional methods. Simulations validate that the proposed method has lower computational complexity than existing approaches for estimating kernels of cubically nonlinear channels in real baseband OFDM systems.