Alkenes are unsaturated hydrocarbons containing a carbon-carbon double bond. They are more reactive than alkanes due to the availability of pi electrons. Alkenes undergo addition reactions and can be prepared through dehydration of alcohols, dehydrogenation of alkyl halides, and cracking of alkanes. Their properties include being less dense than water and soluble in nonpolar solvents.
B.Pharm I Year II Sem. SN1 and SN2 reactions, kinetics, order of reactivity of alkyl halides, stereochemistry and rearrangement of carbocations.
SN1 versus SN2 reactions, Factors affecting SN1 and SN2 reactions.
Structure and uses of ethylchloride, Chloroform, trichloroethylene, tetrachloroethylene,
dichloromethane, tetrachloromethane and iodoform.
Alcohols, Qualitative tests for Alcohol, Structure and uses of Ethyl alcohol, chlorobutanol, Cetosterylalcohol, Benzyl alcohol, Glycerol, Propylene glycol
B.Pharm I Year II Sem. SN1 and SN2 reactions, kinetics, order of reactivity of alkyl halides, stereochemistry and rearrangement of carbocations.
SN1 versus SN2 reactions, Factors affecting SN1 and SN2 reactions.
Structure and uses of ethylchloride, Chloroform, trichloroethylene, tetrachloroethylene,
dichloromethane, tetrachloromethane and iodoform.
Alcohols, Qualitative tests for Alcohol, Structure and uses of Ethyl alcohol, chlorobutanol, Cetosterylalcohol, Benzyl alcohol, Glycerol, Propylene glycol
Alkanes, Alkenes, Alkynes, Alkyl Halides, Alicyclic Hydrocarbons, Alcohols,
Ethers and Epoxides, Aldehydes and Ketones, Carboxylic Acids and their
Functional Derivatives
In organic chemistry, a carbonyl group is a functional group composed of a carbon atom double-bonded to an oxygen atom: C=O. It is common to several classes of organic compounds, as part of many larger functional groups. A compound containing a carbonyl group is often referred to as a carbonyl compound.
In organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond. The simplest acyclic alkynes with only one triple bond and no other functional groups form a homologous series with the general chemical formula CₙH₂ₙ−2
Alkanes, Alkenes, Alkynes, Alkyl Halides, Alicyclic Hydrocarbons, Alcohols,
Ethers and Epoxides, Aldehydes and Ketones, Carboxylic Acids and their
Functional Derivatives
In organic chemistry, a carbonyl group is a functional group composed of a carbon atom double-bonded to an oxygen atom: C=O. It is common to several classes of organic compounds, as part of many larger functional groups. A compound containing a carbonyl group is often referred to as a carbonyl compound.
In organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond. The simplest acyclic alkynes with only one triple bond and no other functional groups form a homologous series with the general chemical formula CₙH₂ₙ−2
Here's a sample self-introduction for a pageant that incorporates a saying:
Begin with a warm greeting and introduce yourself by name and hometown.
Example: "Good evening everyone! My name is [Your Name], and I'm proudly representing [Your Hometown]."
Share a personal anecdote or experience that reflects your personality and interests.
Example: "I've always been someone who believes in the power of community. As Maya Angelou said, 'We are all a little weird and life's a little weird. And when we find someone whose weirdness is compatible with ours, we join up with them and fall in mutual weirdness and call it love.' That's how I approach life – finding ways to connect and create positive change alongside others."
Connect your anecdote or experience to the pageant's platform or your advocacy.
Example: "This passion for community building is what led me to [Your Advocacy/Platform]. I believe that [Your Belief about the Advocacy/Platform], and I'm excited to use this platform to..."
End by confidently stating your aspiration.
Example: ".I'm honored to be here tonight, and I aspire to be a role model who empowers others to embrace their weirdness and create positive change in the world."
Remember to practice your introduction beforehand to ensure a smooth and confident delivery.
* https://www.lobels.com/
* https://thedickinsonian.com/life-style/2015/12/03/a-peek-inside-dickinsons-sororities-kappa-alpha-theta/
Thank you for this incredible opportunity.
Alkenes Final chemicals can lead to the opposite product result, but the reactive-intermediate structures and mechanisms are different.Hydrobromic acid in particular is prone to forming radicals in the presence of various impurities or even atmospheric oxygen, leading to the reversal of the Markovnikov result.
Alkenes are a class of hydrocarbons (e.g, containing only carbon and hydrogen) unsaturated compounds with at least one carbon-to-carbon double bond. Another term used to describe alkenes is olefins. Alkenes are more reactive than alkanes due to the presence of the double bond.
Alkanes, Alkenes, Alkynes, Alkyl Halides, Alicyclic Hydrocarbons, Alcohols,
Ethers and Epoxides, Aldehydes and Ketones, Carboxylic Acids and their
Functional Derivatives
Alkanes, Alkenes, Alkynes, Alkyl Halides, Alicyclic Hydrocarbons, Alcohols,
Ethers and Epoxides, Aldehydes and Ketones, Carboxylic Acids and their
Functional Derivatives
➣ Electron Drift Velocity
➣➣➣ Charge Velocity and
Velocity of Field Propagation
➣➣➣ The Idea of Electric Potential
Resistance
➣➣➣ Unit of Resistance
➣➣➣ Law of Resistance
➣➣➣ Units of Resistivity
Conductance and
Conductivity
➣➣➣ Temperature Coefficient of
Resistance
➣➣➣ Value of α at Different
Temperatures
➣➣➣ Variation of Resistivity with
Temperature
➣➣➣ Ohm’s Law
➣➣➣ Resistance in Series
➣➣➣ Voltage Divider Rule
➣➣➣ Resistance in Parallel
➣➣➣ Types of Resistors
➣➣➣ Nonlinear Resistors
➣➣➣ Varistor
➣➣➣ Short and Open Circuits
➣➣➣ ‘Shorts’ in a Series Circuit
➣➣➣ ‘Opens’ in Series Circuit
➣➣➣ ‘Open’s in a Parallel Circuit
➣➣➣ ‘Shorts’ in Parallel Circuits
➣➣➣ Division of Current in Parallel
Circuits
➣➣➣ Equivalent Resistance
➣➣➣ Duality Between Series and
Parallel Circuits
➣➣➣ Relative Potential
Model Attribute Check Company Auto PropertyCeline George
In Odoo, the multi-company feature allows you to manage multiple companies within a single Odoo database instance. Each company can have its own configurations while still sharing common resources such as products, customers, and suppliers.
How to Make a Field invisible in Odoo 17Celine George
It is possible to hide or invisible some fields in odoo. Commonly using “invisible” attribute in the field definition to invisible the fields. This slide will show how to make a field invisible in odoo 17.
How to Split Bills in the Odoo 17 POS ModuleCeline George
Bills have a main role in point of sale procedure. It will help to track sales, handling payments and giving receipts to customers. Bill splitting also has an important role in POS. For example, If some friends come together for dinner and if they want to divide the bill then it is possible by POS bill splitting. This slide will show how to split bills in odoo 17 POS.
We all have good and bad thoughts from time to time and situation to situation. We are bombarded daily with spiraling thoughts(both negative and positive) creating all-consuming feel , making us difficult to manage with associated suffering. Good thoughts are like our Mob Signal (Positive thought) amidst noise(negative thought) in the atmosphere. Negative thoughts like noise outweigh positive thoughts. These thoughts often create unwanted confusion, trouble, stress and frustration in our mind as well as chaos in our physical world. Negative thoughts are also known as “distorted thinking”.
Students, digital devices and success - Andreas Schleicher - 27 May 2024..pptxEduSkills OECD
Andreas Schleicher presents at the OECD webinar ‘Digital devices in schools: detrimental distraction or secret to success?’ on 27 May 2024. The presentation was based on findings from PISA 2022 results and the webinar helped launch the PISA in Focus ‘Managing screen time: How to protect and equip students against distraction’ https://www.oecd-ilibrary.org/education/managing-screen-time_7c225af4-en and the OECD Education Policy Perspective ‘Students, digital devices and success’ can be found here - https://oe.cd/il/5yV
Instructions for Submissions thorugh G- Classroom.pptxJheel Barad
This presentation provides a briefing on how to upload submissions and documents in Google Classroom. It was prepared as part of an orientation for new Sainik School in-service teacher trainees. As a training officer, my goal is to ensure that you are comfortable and proficient with this essential tool for managing assignments and fostering student engagement.
Synthetic Fiber Construction in lab .pptxPavel ( NSTU)
Synthetic fiber production is a fascinating and complex field that blends chemistry, engineering, and environmental science. By understanding these aspects, students can gain a comprehensive view of synthetic fiber production, its impact on society and the environment, and the potential for future innovations. Synthetic fibers play a crucial role in modern society, impacting various aspects of daily life, industry, and the environment. ynthetic fibers are integral to modern life, offering a range of benefits from cost-effectiveness and versatility to innovative applications and performance characteristics. While they pose environmental challenges, ongoing research and development aim to create more sustainable and eco-friendly alternatives. Understanding the importance of synthetic fibers helps in appreciating their role in the economy, industry, and daily life, while also emphasizing the need for sustainable practices and innovation.
2. Alkenes
• Alkenes are unsaturated hydrocarbons containing
carbon-carbon double bond (C=C) in their molecules.
General formula of alkene is CnH2n. They are
commonly known as olefins because lower members
form oil products with chlorine or bromine (Latin
Oleum=Oil; ficane = to make).
• Ethylene and propylene are the first and second
members of this series respectively.
• Double bonded carbon in alkenes is sp2hybridised. The
Carbon-Carbon double bond in alkene consists of one
sigma (σ) and one pi (π) bond. Sigma bond is formed by
overlapping of sp2 hybrid orbital of each carbon and π
bond is formed by overlapping of unhybridised p-
orbitals.
• The two carbon atoms which are double bonded in
alkanes are held more tightly together than inalkane with
the result C=C bond length in alkene is less (1.34Ao)
than C-C bond length inalkanes.
• Alkenes are more reactive than alkanes this is due to the
availability of more exposed π-electrons
3. Methods of preparation of Alkenes
• Dehydration of Alcohols: When an alcohol is heated with
concentrated sulphuric acid at 100oC or with phosphoric acid
at 200oC or by passing alcohol vapour over alumina, P2O5 or
anhydrous zinc chloride at 350-400oC a molecule of water is
eliminated and alkene is formed.
• The ease of dehydration follows the following order. 3o
alcohol >2 o alcohol >1 o alcohol
• Dehydration of unsymmetrical 2o or 1 o alcohol can proceed
in two ways and mixture of alkene is formed for example
dehydration of 2-butanol yields mixture of 2-butene.(major
product) and 1-butene (minor product). In such cases major
products can be predicted by Saytzeff’s rule. Which states that
“Hydrogen is preferentially eliminated from the carbon atom
with fewer number of hydrogen atoms.” Thus 2-butene is the
major product in above example. In other words Saytzeff’s
rule states that “Greater the number of alkyl groups attached
to the double bonded carbon atoms, the more stable is the
Alkene.” Hence more substituted alkene is preferentially
formed. The ease of formation of alkene is , R2C=CR2 >
R2C=CHR > R2C=CH2 > RCH=CHR > RCH=CH2
• This can be explained on the basis of more stability of more
substituted carbonium ion formed.
4. By dehydrogenation of Alkyl halides to form alkenes
• By dehydrogenation of Alkyl halides: when an alkyl halide is heated with alcoholic
NaOH or KOH, one molecule of hydrogen halide (HX) is eliminated to give alkene.
• The ease of dehydrogenation of alkyl halide is 3o alkyl halide>2 o alkyl halide >1 o
alkyl halide
• In case of dehydrogenation of 2 o and 3o alkyl halides the major product can be
predicted according to Saytzeff’s rule.
5. By Dehydro Halogenation of Vicinal
Dihalide to form alkene
• By Dehydro Halogenation of Vicinal Dihalide: when vicinal
dihalides (containing two halogen atoms at adjacent carbon) are
heated with zinc dust in alcohol alkenes are produced.
6. By Kolbe’s electrolytic method to form
alkenes
• By Kolbe’s electrolytic method: electrolysis of aqueous solution of
sodium or potassium salt of saturated dicarboxylic acids yields
alkene.
7. Preparation of Alkenes by controlled
Hydrogenation of Alkyne
• By controlled Hydrogenation of Alkyne: Alkyne is presence of Lindlar Catalyst
react with Hydrogen in controlled manners to give alkene. In Lidlar catalyst Pd
is deactivated with CaCO3 and quinoline.
8. Cracking of Alkanes to form alkenes
• Cracking of Alkanes: Paraffins on heating at 500-800°C in absence of
air get decomposed to lower molecular weight alkene, alkanes and
hydrogen.
9. Physical Properties of Alkenes
1) The first three members are gases at ordinary temperature, next 14 are liquids and the higher
ones are solids. Except ethylene all members are colourless and odorless. Ethylene is pleasant
smelling gas.
2) Alkenes are only slightly soluble in water but soluble in non polar solvents.
3) Generally, their boiling points, melting points and specific gravities rise with increase of
molecular weights. Further like alkanes, the branched chain alkenes have lower boiling points than
the corresponding n-alkenes.
4) Like alkanes, alkenes are generally non polar, but certain alkenes due to their unsymmetrical
structure are weakly polar. Trans alkene has a smaller dipole moment than cis-isomer because
trans isomer is relatively more symmetrical than cis-alkene. Due to 10 poorer symmetry molecules
of cis-alkenes do not fit into the crystal lattice so well as in the trans-isomer with the result cis
akenes have generally lower melting points than the trans.
10. Chemical Properties of Alkenes
• Chemical properties: Alkenes are
more reactive than alkanes due to the
presence of π-bond.
• The π electrons constituting π bond
are located much farther the carbon
nuclei and are easily available for
reaction when needed. The overlap
of atomic orbital forming π-bond is
not as effective as that in σ bonds.
Thus π bond is weaker than σ bond
and can be easily broken.
11. Adition reaction of alkenes
• Addition reactions are
the most important
reactions of the
carbon-carbon double
bond. π electrons of
double bond are easily
available to the
reagent. Thus carbon-
carbon double bond
acts as a source of
electrons for
electrophilic reagents
and undergoes
electrophilic addition
reaction.
12. Oxidation of Alkenes with ozone
• Oxidation with ozone: Ozone adds to
an alkene molecule to form an
ozonide. Ozonide on warming with
zinc and water hydrolysed to yield
smaller carbonyl fragments.
• The process of preparing the
Ozonide and then decomposing it to
get the carbonyl compound is called
Ozonolysis.
13. Peroxide Effect - Anti markovnikov addition
• Peroxide Effect - Anti markovnikov addition:
Kharasch and Mayo 1933) discovered that
addition of HBr to propane or other
unsymmertrical alkene in presence of organic
peroxide (R_x0002_O-OR) yields mainly n-alkyl
bromide(anti markonikov’s product). This effect
is known as peroxide effect or Kharasch effect.
But it does not apply to addition involving HCl,
HI or HF.In presence o f peroxide the addition
takes place via a free radical mechanism rather
than the ionic mechanism. This addition of free
radical to double bond involves the intermediate
formation of more stable free radical.
15. Substitution of Alkenes by Halogens
• Substitution of Alkenes by Halogens: Alkenes having alkyl group
undergo substitution, when treated Cl2 or Br2 at high temperature.
One of the allylic hydrogen is replaced by halogen atom. For
example
16. Polymerization of alkenes
• Polymerization: The process in
which simple molecule join together
to form a large molecule without the
elimination of anything is known as
polymerization. Simple alkene
molecules undergo polymerization to
form long chain polymers. For
example
• These reactions are catalyzed by HF,
H2SO4 or organic peroxide and
conditions of high temperature and
pressure are generally required