Classical conditioning involves involuntary behaviors learned through association. Pavlov's work with dogs demonstrated that a neutral stimulus could become a conditioned stimulus through repeated pairing with an unconditioned stimulus that elicits an innate response. Key terms in classical conditioning include unconditioned stimulus, unconditioned response, conditioned stimulus, and conditioned response. Cognitive processes and biological constraints can influence classical conditioning. Processes like acquisition, extinction, spontaneous recovery, generalization, and discrimination further describe classical conditioning.