This document summarizes a study of Cu/ZnO/Al2O3 methanol catalysts prepared by flame combustion synthesis. Small nanoparticles of metal oxides can be generated by combusting volatile precursors in a flame. The study investigates catalysts produced via this flame synthesis method and characterizes them using various techniques. A ternary catalyst with a Cu:Zn:Al ratio of 45:45:10 was found to have the highest catalytic activity for methanol synthesis and was also very selective and stable against thermal deactivation.
This document provides information about gas welding and cutting. It discusses oxy-fuel welding, which uses oxygen and acetylene gases to produce a flame over 5700°F that can melt metals. Cutting uses the flame to preheat and then pure oxygen to burn away metal. The document describes the equipment used, including oxygen and acetylene cylinders, regulators, hoses, and torches. It explains the chemical reactions that produce the high temperature flame and discusses properties of acetylene such as its heat output. Advantages and limitations of oxy-fuel welding are also outlined.
Particulate Sintering of Iron Ore and Empirical Analysis of Sintering Time Ba...IOSR Journals
Particulate sintering of iron ore has been carried out using the necessary ingredients. Empirical
analysis of the sintering time based on the coke breeze input concentration and ignition temperature were also
successfully obtained through first principle application of a derived model which functioned as a evaluative
tool. The derived model;
S = (√T)0.95 + 0.0012α
indicates that amongst ignition temperature and coke breeze input, sintering time is more significantly affected
by the coke breeze input concentration. This is based on the higher correlation it makes with sintering time
compared to applied ignition temperature, all other process parameters being constant. The validity of the
model was rooted in the core expression S – Kα ≈ (√T )N where both sides of the expression are correspondingly
approximately almost equal. Sintering time per unit rise in the operated ignition temperature as obtained from
experiment, derived model and regression model were evaluated as 0.0169, 0.0128 and 0.0159 mins. / 0C
respectively. Similarly, sintering time per unit coke breeze input concentration as obtained from experiment,
derived model and regression model were evaluated as 4.0, 3.0183 and 3.7537 mins./ % respectively indicating a
significant proximate agreement and validity of the model. The standard error (STEYX) incurred in predicting
sintering time for each value of the ignition temperature and coke breeze input concentration considered, as
obtained from the experiment, derived model and regression model are 1.6646, 0.7678 and 2.98 x10-5 % as well
as 2.2128, 1.0264 and 1.2379% respectively. The maximum deviation of mode-predicted results from the
corresponding experimental values was less than 11%.
Reduction of cold start emissions in automotive catalytic converter using the...Asheesh Padiyar
Catalytic converters are used to convert harmful exhaust gases like CO, NOx and unburnt hydrocarbons released by
internal combustion engine of automobiles into less harmful gases like CO2, H2O and N2. During the start-up of engine run, catalytic converters suffer cold start problems as the catalyst does not remain active in cold conditions. This results in emission of unconverted harmful gases into the atmosphere. This work attempts to eliminate cold start problems using a heat storage system to keep the catalytic converter hot even under engine off conditions. A eutectic alloy of Mg-Zn-Al is used as the Phase Change Material (PCM) to store the heat around the catalyst. This alloy has high latent heat of fusion, high specific heat, suitable melting point and high thermal stability. Mg-Zn-Al eutectic alloy changes its state between liquid and solid on application and removal of heat. Thus this phase change material acts as a heat storage mechanism in the catalytic converter. Catalytic converter design also involves Rockwool insulation in order to aid longer heat storage. This thermal energy storage system as a combination of PCM and insulation, keeps the catalytic converter hot for several hours even after the engine is shut of
Flame stability is important for low-NOx combustion systems. Factors that influence flame stability include flame propagation speed, mixing timescales, residence time, and the balance between flow and flame velocities. Various stabilization methods are used, such as bluff bodies, swirl arrangements, and turbulent jets to create recirculation zones or low velocity regions for flame anchoring. Exhaust gas recirculation and other techniques can also enhance flame stability. Industrial burners use different fuel gases and configurations like flat burners, baffle burners, and staged air burners. Safety controls and monitoring are vital for safe burner operation.
The Mintek process is a large-scale batch silicothermic process for extracting magnesium that operates at atmospheric pressure. It aims to overcome issues with an earlier Magnetherm process. In the Mintek process, the furnace must operate above 1600°C, potentially as high as 1800°C, to achieve an economically acceptable rate of magnesium extraction while maintaining low energy consumption. Several factors like temperature, feed recipe, slag depth relative to furnace diameter, and reactions in the arc attachment zone influence the process.
Surfactant-assisted Hydrothermal Synthesis of Ceria-Zirconia Nanostructured M...IOSR Journals
CeO2–ZrO2 oxides were prepared by the surfactant-templated method using cetyl trimethyl ammonium bromide (CTAB) as template and modified with chromium nitrate. These were characterized by XRD, FT-IR, TEM, SEM, BET and TPD-CO2. The XRD data showed that as prepared CeO2-ZrO2 powder particles have single phase cubic fluorite structure. HRTEM shows mesoscopic ordering. Average particle size is 12-13 nm as calculated from particle histogram. The nitrogen adsorption/desorption isotherm were classified to be type IV isotherm, typical of mesoporous material. The presence of uni-modal mesopores are confirmed by the pore size distribution which shows pore distribution at around 60 A°. Catalytic activity was studied towards liquid-phase oxidation of benzene.
1. A melt spinning and spark plasma sintering (MS-SPS) process was used to prepare n-type Bi2(Te1-xSex)3 (x = 0.0-1.0) solid solutions from high purity elemental chunks.
2. Substitution of tellurium with selenium significantly impacted the electrical and thermal transport properties in a way that can be understood using valence bond rules and changes in band gap.
3. The Bi2(Se0.2Te0.8)3 sample achieved the highest ZT of 1.05 at 420K, with an average ZT of around 0.97 in the entire measurement temperature range from 300-500K, representing
Quasi-aligned aluminum nitride (AlN) nanofibers were formed through a nitriding combustion synthesis reaction using aluminum and aluminum nitride powders with yttria and ammonium chloride additives. Scanning electron microscope images showed the aluminum particles maintained their original ball-like shape after combustion, with a thin crust layer on the surface covering quasi-aligned AlN nanofibers grown in the interior. This novel morphology is believed to form through a two-stage process where the crust acts as a micro-reactor allowing nitridation and fiber growth inside the molten aluminum core.
This document provides information about gas welding and cutting. It discusses oxy-fuel welding, which uses oxygen and acetylene gases to produce a flame over 5700°F that can melt metals. Cutting uses the flame to preheat and then pure oxygen to burn away metal. The document describes the equipment used, including oxygen and acetylene cylinders, regulators, hoses, and torches. It explains the chemical reactions that produce the high temperature flame and discusses properties of acetylene such as its heat output. Advantages and limitations of oxy-fuel welding are also outlined.
Particulate Sintering of Iron Ore and Empirical Analysis of Sintering Time Ba...IOSR Journals
Particulate sintering of iron ore has been carried out using the necessary ingredients. Empirical
analysis of the sintering time based on the coke breeze input concentration and ignition temperature were also
successfully obtained through first principle application of a derived model which functioned as a evaluative
tool. The derived model;
S = (√T)0.95 + 0.0012α
indicates that amongst ignition temperature and coke breeze input, sintering time is more significantly affected
by the coke breeze input concentration. This is based on the higher correlation it makes with sintering time
compared to applied ignition temperature, all other process parameters being constant. The validity of the
model was rooted in the core expression S – Kα ≈ (√T )N where both sides of the expression are correspondingly
approximately almost equal. Sintering time per unit rise in the operated ignition temperature as obtained from
experiment, derived model and regression model were evaluated as 0.0169, 0.0128 and 0.0159 mins. / 0C
respectively. Similarly, sintering time per unit coke breeze input concentration as obtained from experiment,
derived model and regression model were evaluated as 4.0, 3.0183 and 3.7537 mins./ % respectively indicating a
significant proximate agreement and validity of the model. The standard error (STEYX) incurred in predicting
sintering time for each value of the ignition temperature and coke breeze input concentration considered, as
obtained from the experiment, derived model and regression model are 1.6646, 0.7678 and 2.98 x10-5 % as well
as 2.2128, 1.0264 and 1.2379% respectively. The maximum deviation of mode-predicted results from the
corresponding experimental values was less than 11%.
Reduction of cold start emissions in automotive catalytic converter using the...Asheesh Padiyar
Catalytic converters are used to convert harmful exhaust gases like CO, NOx and unburnt hydrocarbons released by
internal combustion engine of automobiles into less harmful gases like CO2, H2O and N2. During the start-up of engine run, catalytic converters suffer cold start problems as the catalyst does not remain active in cold conditions. This results in emission of unconverted harmful gases into the atmosphere. This work attempts to eliminate cold start problems using a heat storage system to keep the catalytic converter hot even under engine off conditions. A eutectic alloy of Mg-Zn-Al is used as the Phase Change Material (PCM) to store the heat around the catalyst. This alloy has high latent heat of fusion, high specific heat, suitable melting point and high thermal stability. Mg-Zn-Al eutectic alloy changes its state between liquid and solid on application and removal of heat. Thus this phase change material acts as a heat storage mechanism in the catalytic converter. Catalytic converter design also involves Rockwool insulation in order to aid longer heat storage. This thermal energy storage system as a combination of PCM and insulation, keeps the catalytic converter hot for several hours even after the engine is shut of
Flame stability is important for low-NOx combustion systems. Factors that influence flame stability include flame propagation speed, mixing timescales, residence time, and the balance between flow and flame velocities. Various stabilization methods are used, such as bluff bodies, swirl arrangements, and turbulent jets to create recirculation zones or low velocity regions for flame anchoring. Exhaust gas recirculation and other techniques can also enhance flame stability. Industrial burners use different fuel gases and configurations like flat burners, baffle burners, and staged air burners. Safety controls and monitoring are vital for safe burner operation.
The Mintek process is a large-scale batch silicothermic process for extracting magnesium that operates at atmospheric pressure. It aims to overcome issues with an earlier Magnetherm process. In the Mintek process, the furnace must operate above 1600°C, potentially as high as 1800°C, to achieve an economically acceptable rate of magnesium extraction while maintaining low energy consumption. Several factors like temperature, feed recipe, slag depth relative to furnace diameter, and reactions in the arc attachment zone influence the process.
Surfactant-assisted Hydrothermal Synthesis of Ceria-Zirconia Nanostructured M...IOSR Journals
CeO2–ZrO2 oxides were prepared by the surfactant-templated method using cetyl trimethyl ammonium bromide (CTAB) as template and modified with chromium nitrate. These were characterized by XRD, FT-IR, TEM, SEM, BET and TPD-CO2. The XRD data showed that as prepared CeO2-ZrO2 powder particles have single phase cubic fluorite structure. HRTEM shows mesoscopic ordering. Average particle size is 12-13 nm as calculated from particle histogram. The nitrogen adsorption/desorption isotherm were classified to be type IV isotherm, typical of mesoporous material. The presence of uni-modal mesopores are confirmed by the pore size distribution which shows pore distribution at around 60 A°. Catalytic activity was studied towards liquid-phase oxidation of benzene.
1. A melt spinning and spark plasma sintering (MS-SPS) process was used to prepare n-type Bi2(Te1-xSex)3 (x = 0.0-1.0) solid solutions from high purity elemental chunks.
2. Substitution of tellurium with selenium significantly impacted the electrical and thermal transport properties in a way that can be understood using valence bond rules and changes in band gap.
3. The Bi2(Se0.2Te0.8)3 sample achieved the highest ZT of 1.05 at 420K, with an average ZT of around 0.97 in the entire measurement temperature range from 300-500K, representing
Quasi-aligned aluminum nitride (AlN) nanofibers were formed through a nitriding combustion synthesis reaction using aluminum and aluminum nitride powders with yttria and ammonium chloride additives. Scanning electron microscope images showed the aluminum particles maintained their original ball-like shape after combustion, with a thin crust layer on the surface covering quasi-aligned AlN nanofibers grown in the interior. This novel morphology is believed to form through a two-stage process where the crust acts as a micro-reactor allowing nitridation and fiber growth inside the molten aluminum core.
Removal of Coke during Steam Reforming of Ethanol over La-CoOx Catalystinventy
Research Inventy : International Journal of Engineering and Science is published by the group of young academic and industrial researchers with 12 Issues per year. It is an online as well as print version open access journal that provides rapid publication (monthly) of articles in all areas of the subject such as: civil, mechanical, chemical, electronic and computer engineering as well as production and information technology. The Journal welcomes the submission of manuscripts that meet the general criteria of significance and scientific excellence. Papers will be published by rapid process within 20 days after acceptance and peer review process takes only 7 days. All articles published in Research Inventy will be peer-reviewed.
Enhanced fluidized bed methanation over a Ni Al2O3 catalyst for production of...Pengcheng Li
This document summarizes a study that investigated the fluidization behavior and CO methanation performance of a Ni/Al2O3 catalyst in a fluidized bed reactor for producing synthetic natural gas. The researchers found that the pure Ni/Al2O3 catalyst failed to properly fluidize on its own due to particle sizes between 10 and 100 μm, but fluidization was improved by adding larger Al2O3 particles. Methanation performance in the fluidized bed reactor increased substantially with the Al2O3 addition. Temperature was found to control the methanation reaction mechanism, with surface reactions dominating at lower temperatures and external diffusion controlling at higher temperatures. Stability tests showed the fluidized bed reactor had higher CO conversion, methane selectivity
Nitrogen containing carbon nanotubes as supports fortshankar20134
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotube surface with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had significantly higher catalytic activity for methanol oxidation compared to a commercial platinum on carbon catalyst.
Nitrogen containing carbon nanotubes as supports for pt–alternate anodes for ...tshankar20134
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotube surface with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had higher catalytic activity for methanol oxidation compared to a conventional platinum on carbon black catalyst.
Nitrogen containing carbon nanotubes as supports formadlovescience
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotube surface with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had higher catalytic activity for methanol oxidation compared to a conventional platinum on carbon black catalyst.
Nitrogen containing carbon nanotubes as supports for pt–alternate anodes for ...madlovescience
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotubes with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had significantly higher catalytic activity for methanol oxidation compared to a conventional platinum on carbon catalyst.
The document discusses an experimental study that tested different metal surfaces as catalysts for enhancing surface chemical reactions. The study measured the activation temperatures of mild steel, nickel, chromium, and copper. A cylindrical chamber was constructed and different metal tubes coated with these catalysts were placed inside and heated. The air-fuel mixtures that passed through showed increased combustion reaction and temperature when exposed to the catalytic surfaces. The activation temperatures obtained from this experiment provided insights into using catalysts to improve combustion in lean-burn engines.
The document summarizes a study that demonstrated the ability to tune the size of large-diameter, few-walled nitrogen-doped carbon nanotubes (N-CNTs) from 50-150 nm by varying the transition metal (TM) used during synthesis. Fe produced the largest tubes, followed by Co and Ni, while Mn resulted in a clot-like morphology. Electrocatalytic activity for the oxygen reduction reaction (ORR) followed the trend Fe > Co > Ni > Mn. Fe-derived N-CNTs exhibited the highest surface area and nitrogen incorporation, contributing to their high ORR activity. This work provides a new route for developing advanced nonprecious metal catalysts by controlling carbon nanot
This document summarizes hot corrosion in gas turbine components. It defines hot corrosion as accelerated corrosion resulting from salt contaminants like Na2SO4 that form molten deposits damaging protective surface oxides. It describes the characteristics of two types of hot corrosion: Type I (high-temperature) involving fused alkali metal salt condensation and chromium depletion; and Type II (low-temperature) associated with sulfidation and internal oxidation. It also provides context on gas turbine engines and factors affecting hot corrosion development.
Exhaust analysis of four stroke single cylinder diesel engine using copper ba...ijsrd.com
Exhaust emissions of much concern are Hydrocarbon (HC), Carbon Monoxide (CO) and Nitrogen Oxide (NOx) from the automotive vehicles. Catalytic converter oxidizes harmful CO and HC emission to CO2 and H2O in the exhaust system and thus the emission is controlled. There are several types of problems associated with noble metal based catalytic converter. These factors encourage for the possible application of non-noble metal based material such as copper as a catalyst, which may by proper improvements be able to show the desired activity and can also offer better durability characteristics due to its poison resistant nature. The present work is aimed at using copper as a catalyst for catalytic converter. Wire mesh copper catalytic converter is developed for a volume of 1.54 m3. The experiment is carried out on four stroke single cylinder CI engine. The optimum values of exhaust emissions found at full load are HC (126 ppm), CO (0.03 %). By using copper based catalytic converter it is found that HC is reduced by 33 % and CO by 66 % at full load.
Temperature fields during the development of combustion in a rapid compressio...John Clarkson
J. Clarkson, J.F. Griffiths, J.P. MacNamara, & B.J. Whitaker, “Temperature Fields During the Development of Combustion in a Rapid Compression Machine”, Combustion and Flame, 125, 1162-1175, 2001.
Nickel and cobalt transfigured natural clay: a green catalyst for low-tempera...Devika Laishram
Soot particulates in engine exhausts pose a severe threat to the environment and human health – causing cancer, affecting the heart and lungs and drives metal processes. This study proposes a practical,
real-world application of transition metal modified natural clay as an environmentally benign, low-cost,
green catalyst for soot oxidation. Ni and Co (NC-Clay) incorporated natural clay catalysts were prepared
by a simple wet impregnation method and meticulously characterized by different characterization
techniques. The catalyst exhibited higher H2 absorption at a lower temperature with similar trends as
observed in O2 TPD that indicated a remarkable redox property, which is useful for applications as a
catalyst in soot oxidation. Excellent catalytic activity with a very low T50 of 358 1C was observed and can
be accredited to the improved surface oxygen vacancies and thermal stability by the metal modification
of clay
International Journal of Engineering Research and Development is an international premier peer reviewed open access engineering and technology journal promoting the discovery, innovation, advancement and dissemination of basic and transitional knowledge in engineering, technology and related disciplines.
1. The document describes a plasma arc reactor technology for producing nanopowders. It uses electric arc generators to create low-temperature plasma that allows evaporation and gas-phase chemical reactions of initial materials to produce nanodisperse solid powders.
2. A specific plasma-arc reactor is described that uses a two-jet plasmatron with immobile electrode spots. This allows the initial powder material to be directly fed into the arc discharge for more efficient processing. Testing demonstrated the efficient production of ultrafine silicon carbide powder.
3. Analysis of the produced powder found particles ranging from 5-20 nm in size consisting of crystalline SiC and SiO2 phases as well as amorphous materials. Processing
1) The document discusses heat transfer analysis methods to optimize the water cooling scheme for combustion devices used in torpedo propulsion systems.
2) It describes the components of the combustion chamber including the inner and outer walls that form the coolant passageway. Heat transfer is highest in the nozzle throat region.
3) Methods for calculating heat transfer rates, temperatures, velocities and other parameters on both the gas and coolant sides are presented using equations from heat transfer theory. The analysis can be used to optimize the cooling system design.
Heat Transfer Analysis to Optimize The Water Cooling Scheme For Combustion De...IJERA Editor
Thermal Propulsion system is one kind of propulsion system which is used to drive torpedo. The present study focuses mainly on design of combustion device known to be thrust chamber or thrust cylinder. The chamber and nozzle wall and the injector face plate must be made of metals selected for high strength at elevated temperature coupled with good thermal conductivity, resistance to high temperature oxidation. chemical inertness on the coolant on the coolant side, and suitability for the fabrication method to be employed. In the case of certain monopropellants, the metal must not catalyze the decomposition. Although aluminum and copper alloys have been used successfully for combustion chambers and nozzles, stainless steels and carbon steels are in widest use today.A cooling jacket permits the circulation of a coolant, which, in the case of flight engines is usually one of the propellants. Water is the only coolant recommended. The cooling jacket consists of an inner and outer wall. The combustion chamber forms the inner wall and another concentric but larger cylinder provides the outer wall. The space between the walls serves as the coolant passage. The nozzle throat region usually has the highest heat transfer intensity and is, therefore, the most difficult to cool.
This document summarizes a research article that studied the selective oxidation of styrene using Mg-Co-Al hydrotalcite-like catalysts with air as the oxidant. Several Mg-Co-Al catalysts with varying Co content were synthesized and characterized. The catalysts were tested for styrene oxidation and showed good activity and stability. Both styrene conversion and product selectivity depended on the cobalt substitution level. Cobalt ions within the hydrotalcite lattice acted as active sites for styrene epoxidation.
This document describes a mathematical heat transfer model to predict the heating of steel slabs in a reheating furnace. The model considers heat transfer between the slab and its surroundings, including radiative heat transfer between slabs, skids, furnace gases and walls, as well as convective heat transfer from the gases. The model also predicts the formation and growth of scale on the slab surface over time in order to investigate its effect on slab heating. Preliminary results from the model show reasonable agreement with experimental data and indicate that the presence of scale has a considerable effect on slab heating characteristics.
This document discusses optimum flame theory (OFT), which seeks to establish scientific principles for optimizing flames in cement kilns. OFT is based on combustion aerodynamics and jet mixing laws. It provides guidelines known by the mnemonic "SADAM" to optimize flame size, alignment, dryness, air, and momentum. Properly applying these guidelines can improve output, reduce build-up issues, and improve clinker quality by ensuring complete fuel-air mixing before combustion. The document explains how burner momentum should be calculated based on thermal load, and how swirl can be effectively used to induce internal reverse flow and heat fuels if the swirl is sufficiently strong and contained by axial flow.
This document presents an electrochemical and computational study of oxygen reduction reaction (ORR) on nonprecious transition metal/nitrogen doped carbon nanofiber catalysts. Electrochemical measurements showed that pyrolyzed Fe/N/C catalyst promotes a four-electron ORR pathway, while O2 reduction on Co/N/C occurs mainly via a two-electron pathway. Density functional theory calculations predicted that ORR could occur through a four-electron associative pathway on an FeN4 active site, but may terminate after two electrons on a CoN4 site due to high activation energy for O-O bond splitting. The results suggest that FeN4 and CoN4 clusters may be the main active sites for
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Removal of Coke during Steam Reforming of Ethanol over La-CoOx Catalystinventy
Research Inventy : International Journal of Engineering and Science is published by the group of young academic and industrial researchers with 12 Issues per year. It is an online as well as print version open access journal that provides rapid publication (monthly) of articles in all areas of the subject such as: civil, mechanical, chemical, electronic and computer engineering as well as production and information technology. The Journal welcomes the submission of manuscripts that meet the general criteria of significance and scientific excellence. Papers will be published by rapid process within 20 days after acceptance and peer review process takes only 7 days. All articles published in Research Inventy will be peer-reviewed.
Enhanced fluidized bed methanation over a Ni Al2O3 catalyst for production of...Pengcheng Li
This document summarizes a study that investigated the fluidization behavior and CO methanation performance of a Ni/Al2O3 catalyst in a fluidized bed reactor for producing synthetic natural gas. The researchers found that the pure Ni/Al2O3 catalyst failed to properly fluidize on its own due to particle sizes between 10 and 100 μm, but fluidization was improved by adding larger Al2O3 particles. Methanation performance in the fluidized bed reactor increased substantially with the Al2O3 addition. Temperature was found to control the methanation reaction mechanism, with surface reactions dominating at lower temperatures and external diffusion controlling at higher temperatures. Stability tests showed the fluidized bed reactor had higher CO conversion, methane selectivity
Nitrogen containing carbon nanotubes as supports fortshankar20134
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotube surface with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had significantly higher catalytic activity for methanol oxidation compared to a commercial platinum on carbon catalyst.
Nitrogen containing carbon nanotubes as supports for pt–alternate anodes for ...tshankar20134
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotube surface with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had higher catalytic activity for methanol oxidation compared to a conventional platinum on carbon black catalyst.
Nitrogen containing carbon nanotubes as supports formadlovescience
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotube surface with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had higher catalytic activity for methanol oxidation compared to a conventional platinum on carbon black catalyst.
Nitrogen containing carbon nanotubes as supports for pt–alternate anodes for ...madlovescience
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotubes with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had significantly higher catalytic activity for methanol oxidation compared to a conventional platinum on carbon catalyst.
The document discusses an experimental study that tested different metal surfaces as catalysts for enhancing surface chemical reactions. The study measured the activation temperatures of mild steel, nickel, chromium, and copper. A cylindrical chamber was constructed and different metal tubes coated with these catalysts were placed inside and heated. The air-fuel mixtures that passed through showed increased combustion reaction and temperature when exposed to the catalytic surfaces. The activation temperatures obtained from this experiment provided insights into using catalysts to improve combustion in lean-burn engines.
The document summarizes a study that demonstrated the ability to tune the size of large-diameter, few-walled nitrogen-doped carbon nanotubes (N-CNTs) from 50-150 nm by varying the transition metal (TM) used during synthesis. Fe produced the largest tubes, followed by Co and Ni, while Mn resulted in a clot-like morphology. Electrocatalytic activity for the oxygen reduction reaction (ORR) followed the trend Fe > Co > Ni > Mn. Fe-derived N-CNTs exhibited the highest surface area and nitrogen incorporation, contributing to their high ORR activity. This work provides a new route for developing advanced nonprecious metal catalysts by controlling carbon nanot
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Exhaust emissions of much concern are Hydrocarbon (HC), Carbon Monoxide (CO) and Nitrogen Oxide (NOx) from the automotive vehicles. Catalytic converter oxidizes harmful CO and HC emission to CO2 and H2O in the exhaust system and thus the emission is controlled. There are several types of problems associated with noble metal based catalytic converter. These factors encourage for the possible application of non-noble metal based material such as copper as a catalyst, which may by proper improvements be able to show the desired activity and can also offer better durability characteristics due to its poison resistant nature. The present work is aimed at using copper as a catalyst for catalytic converter. Wire mesh copper catalytic converter is developed for a volume of 1.54 m3. The experiment is carried out on four stroke single cylinder CI engine. The optimum values of exhaust emissions found at full load are HC (126 ppm), CO (0.03 %). By using copper based catalytic converter it is found that HC is reduced by 33 % and CO by 66 % at full load.
Temperature fields during the development of combustion in a rapid compressio...John Clarkson
J. Clarkson, J.F. Griffiths, J.P. MacNamara, & B.J. Whitaker, “Temperature Fields During the Development of Combustion in a Rapid Compression Machine”, Combustion and Flame, 125, 1162-1175, 2001.
Nickel and cobalt transfigured natural clay: a green catalyst for low-tempera...Devika Laishram
Soot particulates in engine exhausts pose a severe threat to the environment and human health – causing cancer, affecting the heart and lungs and drives metal processes. This study proposes a practical,
real-world application of transition metal modified natural clay as an environmentally benign, low-cost,
green catalyst for soot oxidation. Ni and Co (NC-Clay) incorporated natural clay catalysts were prepared
by a simple wet impregnation method and meticulously characterized by different characterization
techniques. The catalyst exhibited higher H2 absorption at a lower temperature with similar trends as
observed in O2 TPD that indicated a remarkable redox property, which is useful for applications as a
catalyst in soot oxidation. Excellent catalytic activity with a very low T50 of 358 1C was observed and can
be accredited to the improved surface oxygen vacancies and thermal stability by the metal modification
of clay
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3. Analysis of the produced powder found particles ranging from 5-20 nm in size consisting of crystalline SiC and SiO2 phases as well as amorphous materials. Processing
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Heat Transfer Analysis to Optimize The Water Cooling Scheme For Combustion De...IJERA Editor
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A Study Of Cu ZnO Al2O3 Methanol Catalysts Prepared By Nbsp Flame Nbsp Combustion Synthesis
1. Journal of Catalysis 218 (2003) 67–77
www.elsevier.com/locate/jcat
A study of Cu/ZnO/Al2O3 methanol catalysts prepared
by flame combustion synthesis
J.R. Jensen,1
T. Johannessen, S. Wedel, and H. Livbjerg ∗
Interdisciplinary Research Centre for Catalysis (ICAT), Department of Chemical Engineering, Technical University of Denmark, DK-2800 Lyngby, Denmark
Received 25 September 2002; revised 17 January 2003; accepted 20 January 2003
Abstract
The flame combustion synthesis of Cu/ZnO/Al2O3 catalysts for the synthesis of methanol from CO, CO2, and H2 is investigated. The
oxides are generated in a premixed flame from the acetylacetonate vapours of Cu, Zn, and Al mixed with the fuel and air prior to combustion.
The flame-generated powder is examined by X-ray powder diffraction, determination of the specific surface area by the BET method,
determination of the copper dispersion in the reduced catalyst by a novel N2O method, transmission electron microscopy, and testing of the
catalytic properties in a catalytic microreactor. A low peak temperature and quench cooling of the flame tend to increase the dispersion of the
phases and the specific surface area of the particles. Properties of both the ternary composition, the three binary compositions, and the pure
oxides are discussed. The calculation of simultaneous phase and chemical equilibrium is used in the assessment of the phase composition
of the particles. The specific surface area varies from 100 m2/g or a little below for samples without Al to several hundred m2/g for the
respective compositions of pure Al2O3 and ZnAl2O4. Copper dispersion after reduction varies from 1.8 to 14.1%. A ternary catalyst with
the composition of Cu:Zn:Al = 45:45:10 has the highest catalytic activity of all samples tested. This catalyst is also very selective and stable
toward thermal deactivation. The role of the individual catalyst components in the optimal catalyst is discussed.
2003 Elsevier Inc. All rights reserved.
Keywords: Aerosols; Nanoparticles; Flame synthesis; CuO; ZnO; Al2O3; Methanol; Catalyst
1. Introduction
Small nanoparticles of metal oxides can be generated by
flame combustion of volatile precursors. The so-called flame
combustion synthesis, already widely used for materials like
carbon black, fumed silica, and titania [1,2], provides an
alternative route to catalyst manufacture as recently demon-
strated by Stark et al. [3] for V2O5/TiO2 composite particles
with excellent catalytic properties in the SCR process and by
Johannessen and Koutsopoulos [4] for a Pt/TiO2 catalyst for
SO2 oxidation.
Flame synthesis is particularly effective for the genera-
tion of those material structures, which are inherently im-
portant in heterogeneous catalysis, i.e., high specific surface
areas for composite materials and nanostructured phase dis-
* Corresponding author.
E-mail address: hl@olivia.kt.dtu.dk (H. Livbjerg).
1 Present address: Haldor Topsøe A/S, DK-2800 Lyngby, Denmark.
tribution. Jensen et al. [5] showed how to produce ZnAl2O4
spinel with a high surface area by co-combustion of volatile
Zn- and Al-acetylacetonates. The combination of mixing
at the molecular level and an extreme supersaturation for
the metal-oxide molecules formed by combustion ensures
the formation of a spinel phase with a high surface area
during the few milliseconds of residence time in the high-
temperature zone. The traditional wet methods which apply
(co-)precipitation are far more difficult to control and re-
quire subsequent calcination, which is accompanied by an
unavoidable loss of surface area.
This investigation expands the zinc-aluminate synthesis
by the methods of [5] to the flame synthesis of the ternary
CuO/ZnO/Al2O3 samples for the synthesis of methanol.
The Cu/ZnO/Al2O3 catalyst system was chosen since it is
known to be structure sensitive [6]. A novel synthesis route
may lead to unexpected and unique catalyst properties. Fur-
thermore, the system is rather well investigated, which is
advantageous for the characterisation of a new route of syn-
thesis.
0021-9517/03/$ – see front matter 2003 Elsevier Inc. All rights reserved.
doi:10.1016/S0021-9517(03)00047-2
2. 68 J.R. Jensen et al. / Journal of Catalysis 218 (2003) 67–77
The mechanisms of flame aerosol synthesis
During combustion in the flame zone the precursor
species are decomposed at high temperatures. The prod-
ucts are released as vapour molecules, which form particle
seeds by nucleation, when they become supersaturated dur-
ing cooling of the flue gas. The particle seeds grow by
condensation of supersaturated vapours and by coagulation
following interparticle collisions. Concomitantly with parti-
cle growth, processes within the single particles alter their
shape toward compact forms (sintering) and rearrange the
phase composition toward stable crystalline phases by crys-
tal nucleation and growth. A special case arises when fast
combustion reactions generate molecules into a state of ex-
treme supersaturation, which is often followed by collision-
limited growth of particles, leading ultimately to very high
specific surface areas. For more volatile species, condensa-
tion occurs after the temperature eventually has reached the
saturation point. In multicomponent mixtures, the individual
components may condense consecutively, each in its own
temperature range.
The specific surface area, particle morphology, and crys-
talline structure of the particles can be altered by changing,
e.g., the flame peak temperature, the high-temperature zone
residence time, and the precursor concentration. These con-
ditions can be varied within wide limits for a given burner
and further expanded by employing different burner types
and geometries. Pratsinis [1], Jensen et al. [5], and Jensen [7]
provide further details about flame synthesis and references
to the relevant literature.
2. Experimental
2.1. Flame reactor setup
CuO/ZnO/Al2O3 samples are prepared by combustion
synthesis from the volatile precursors consisting of the
acetylacetonates of copper, zinc, and aluminum. The flame
reactor has been designed to obtain particles with large spe-
cific surface areas. A high surface area is favoured by a low
precursor vapour pressure [5], which is obtained in this re-
actor by the combustion of a homogeneous gas in which N2,
O2, and H2 (or CH4) are well mixed with the volatile cata-
lyst precursors prior to ignition. The reactor is also provided
with means for the optional quench cooling of the flame by
the injection of jets of cold air downstream from the ignition
zone. The particles therefore are exposed to the peak tem-
peratures only as long as necessary for the generation of the
desired molecular structures, which reduces the effect of sin-
tering of the coagulated particles [8]. Details of the reactor
setup are shown in Fig. 1.
The reactor feed is mixed from separately controlled
flows of fuel (H2 or CH4), air, and three separate lines with
nitrogen carrier gas containing the precursor vapours. Each
precursor line passes a sublimation unit for the controlled
Fig. 1. Flame reactor system with fuel, air, and precursor feed lines.
addition of the vapours of the acetylacetonate of copper,
zinc, and aluminum, respectively. The precursor powders are
distributed on horizontal trays encased in thermostated alu-
minum boxes with sufficient gas contact to ensure saturation
of the effluent gas with precursor vapours. The vapour con-
tent in the precursor lines is thus independent of the flow rate
of carrier gas and can be controlled by the temperature of the
sublimation unit. The vapour pressures of the precursors are
determined from the precursor weight loss for a given vol-
ume of carrier gas and are shown in Fig. 2 as a function
of temperature. Any desired ternary particle composition is
obtainable by the proper combination of saturator tempera-
tures and carrier gas flow rates. Temperatures in the range
of 90–180 ◦C have been adequate for the present experi-
ments. The copper precursor has the lowest vapour pressure
and its saturation unit was operated solely at its maximum
temperature of 180 ◦C. Above 200 ◦C the precursor starts to
decompose. All gas lines containing precursor vapours are
heated to 200 ◦C to prevent condensation.
Prior to combustion all feed lines are intimately mixed
in a swirl mixer. Combustion occurs in a flat flame stabi-
3. J.R. Jensen et al. / Journal of Catalysis 218 (2003) 67–77 69
Fig. 2. The vapour pressures of Cu, Al, and Zn acetylacetonate as a function
of temperature. The vapour pressures are determined from the weight loss
of the saturator units due to sublimation of the precursors. The sublimation
enthalpies for Al- and Zn-acetylacetonate are estimated based on the linear
correlation between 1/T and the vapour pressure.
lized by a flame arrestor—a stainless-steel plate of diameter
36 mm perforated by numerous small holes. A cylindrical
quartz tube of length 200 mm and inner diameter of 67 mm
surrounds the flame and shields it from intrusion of the am-
bient air.
A ring, which can be positioned at any given height above
the flame, is placed inside the quartz shield and holds the
nozzles for quench cooling of the flame by cold air. The de-
sign of the quench-cooling device is very critical since the
nozzles must give the jets of cold air a slightly upward and
off-axis direction to create a stabilizing swirl that prevents
the complete distortion of the flame, which would otherwise
occur [8]. This special configuration enables us to quench
cool directly above the flame front without disturbing the
flame below the quenching level.
Inhalation of small particles is potentially health haz-
ardous, so for safety reasons the entire setup is placed in a
fume hood.
It is principally the temperature–time history and the
concentration of precursor vapours of the reacting flow in
the flame which determine the properties of the effluent
aerosol particles. Both sets of flame conditions can be altered
within wide limits to achieve advantageous particle prop-
erties. Table 1 summarizes the experimental design for the
thermal flame conditions, which are altered systematically
by switching on or off the quench cooling and by a change
from a lean hydrogen mixture to a rich methane fuel mixture.
The corresponding axial temperature profiles for the four se-
lected conditions are shown in Fig. 3. They are measured
with a platinum–platinum/10% rhodium thermocouple with
0.3-mm free wires and a welding bead with diameter 1.3 mm
and corrected for radiation influence [7]. The four different
conditions in Table 1 and Fig. 3 combine a significant vari-
ation of the peak temperature—high for methane and low
for hydrogen—with a similarly significant variation in the
flame-cooling rate—a high rate with quench cooling and low
rate without. The methane flame with and without quench
Table 1
Flame operating conditions
Flame
1 2 3 4
(CH4) (CH4, quench) (H2) (H2, quench)
Air (dm3/min)c 10.1 10.1 10.1 10.1
Methane (dm3/min)c 0.986 0.986 0 0
Hydrogen (dm3/min)c 0 0 1.71 1.71
Quenched aira (dm3/min)c 0 5.2 0 5.2
Oxygen/methane ratio 2.15 2.15 – –
Oxygen/hydrogen ratio – – 1.24 1.24
Peak temperature (◦C)b 1464 1398 995 954
a The quench jets are positioned 12.5 mm above the flame arrestor.
b Measured peak temperature corrected for radiation loss.
c All flows are given at 20 ◦C, 1 atm. The carrier gas through the Al-,
Cu-, and Zn-(acac) saturators varies between 0 and 1 dm3/min, depending
on the desired composition.
Fig. 3. Flame temperature profiles measured along the center line of the
burner for the selected standard test conditions (cf. Table 1), which are de-
signed to vary systematically with respect to peak temperature and cooling
rate.
cooling are compared in the photos of Fig. 4. The green light
emitted by Cu above approximately 1000 ◦C illustrates the
changes in the high-temperature zone, which extends high
above the flame front without quench cooling (a) but is con-
fined to the region below the ring during quench cooling (b).
The powder produced in the flame is collected on a
47-mm polycarbonate filter with 1-µm pores through which
the effluent gas is withdrawn by a vacuum pump after being
cooled to 70 ◦C. The particles are subjected to the following
examinations:
The BET surface area is measured by multipoint nitro-
gen adsorption (Gemini 2630, Micromeritics) at 77 K. An
equivalent primary particle diameter can be estimated from
the BET surface SA by
dBET =
6
ρpSA
,
where ρp is the solid phase density.
X-ray diffraction (XRD) is obtained with a Cu-Kα ra-
diation diffractometer (Philips PW1820/3711). The diffrac-
4. 70 J.R. Jensen et al. / Journal of Catalysis 218 (2003) 67–77
(a) (b)
Fig. 4. Photograph of the flame reactor which illustrates the changes in
the high-temperature zone during quench cooling. The flame contains Cu,
which emits green light above approximately 1000 ◦C. (a) Methane–air
flame and (b) quenched methane–air flame.
tograms can be measured expediently directly on the particle
filter cake subject to a correction for a weak background
signal from the filter material. Crystallite dimensions in dif-
ferent crystal directions were estimated from line broad-
ening using the Scherrer equation [9]. The peak widths at
half height were estimated by fitting the peaks to a multiple
Gaussian distribution using a least-squares method. When
the crystallite size gradually becomes smaller, line broad-
ening eventually dominates the diffractogram, which hence
cannot be resolved reasonably. In this case the material ap-
pears X-ray amorphous, although in many cases more or less
perfect nanocrystalline particles and phases may presumably
be present. Further details of the XRD analysis are shown
in [7].
Transmission electron microscopy (TEM) is used for par-
ticles sampled directly from the hot gas by diffusional and
thermophoretic2 deposition on 300-µm mesh Ni TEM grids
with carbon film. The grid is inserted manually by means of
pincers for 5–10 s at the center line of the flame approxi-
mately 100 mm above the diffuser. A Philips 300-kV TEM
was used to image the particles and to measure the overall
chemical composition by EDAX (energy-dispersive X-ray
analysis).
Copper dispersion3 is measured with the N2O method
in which N2O is assumed to react with the surface copper
atoms selectively by the reaction 2Cu + N2O → Cu2O +
N2 [10–12]. We have developed a novel adaption of the N2O
method by which the transient evolvement of N2 in a mi-
croreactor is used to compute the concentration of surface
2 Thermophoresis is the mechanism by which particles are transported
in a fluid with a thermal gradient, i.e., from high temperature to low tem-
perature. Therefore, particles are readily deposited on a cold surface—the
TEM grid—when it is inserted in a hot gas containing the metal oxide par-
ticles.
3 The dispersion of the Cu crystallites is defined as the ratio of surface
Cu atoms to total Cu atoms.
Cu after a correction for a slow diffusion of O into the bulk
material. The measurements are made at ambient pressure
with a constant flow of gas through a fixed bed of cata-
lyst particles by switching the feed gas composition from
pure helium to 2% N2O in helium. The effluent gas passes
through a freeze trap with liquid nitrogen, which selectively
removes unreacted N2O from the gas. Nitrogen evolved by
the oxidation reaction can then be determined accurately by
a calibrated thermal conductivity detector. Prior to the mea-
surements the samples are reduced in pure hydrogen for 1 h
at 220 ◦C. The method is suitable for the small amounts of
catalyst of the present investigation and is applied to the par-
ticles in situ in the catalytic test reactor described below. It
was proved that the N2O treatment does not change the cat-
alytic activity or the Cu dispersion. The N2O treatment is
made at 90 ◦C with 2% (mol/mol) N2O in He. Pretreatment
of the sample, reduction, etc., is made according to the pro-
cedures described in [7].
2.2. Catalyst tests
Measurements of the catalytic properties are made with
the catalytic microreactor shown in Fig. 5. A small amount
of powder sample (∼ 20 mg) collected from the flame gen-
erator is transferred to a Pyrex glass capillary tube with an
internal diameter of 2 mm so that it forms a small bed held
in place by quartz wool plugs at one end of the tube. A con-
striction made in the wall of the capillary tube stabilizes the
innermost wool plug, positioned at the gas outlet from the
bed (cf. Fig. 5)
When a catalyst is tested, its capillary tube is mounted in
a cylindrical recess sealed by Viton o-rings at the upper part
of the reactor assembly. When the reactor is reassembled,
the capillary tube is encased in a cylindrical steel jacket. The
feed gas mixture enters through the cylindrical annulus be-
tween the capillary tube and the surrounding steel jacket in
downward flow and passes the catalyst bed, leaving the reac-
tor in upward flow internally in the capillary tube. The steel
jacket fits into a hole bored in a thermostated cylindrical
block of aluminum–bronze so that one end, containing the
catalyst, is held isothermal due to the high heat conductiv-
ity of the bronze, while the other end protrudes outside the
bronze block and is kept at a lower temperature to protect
the Viton o-ring seals and inlet and outlet gas tubing con-
nections. The reactor operation is trouble-free for catalyst
temperatures up to 400 ◦C.
Due to the miniature catalyst bed and the high heat con-
ductivity of the bronze block, the reactor and the catalyst
bed stay effectively isothermal, which has been confirmed
by measurements of the gas exit temperatures with thin ther-
mocouples inserted into the capillary tube.
The reactor material is nickel-free steel. The high-tempe-
rature zone of the steel jacket is furthermore lined inter-
nally with copper. These materials are necessary to avoid
formation of volatile carbonyls, i.e., Ni(CO)4 and Fe(CO)4,
5. J.R. Jensen et al. / Journal of Catalysis 218 (2003) 67–77 71
Fig. 5. Catalytic microreactor for testing of catalyst powder. All external units including pressure and flow controllers, active carbon trap, gas sampling valve,
and the gas chromatograph are omitted from the drawing.
from CO in the feed gas, which pollute the catalyst with Ni
and Fe.
The feed gas is drawn from a cylinder with a synthesis gas
of fixed composition: 10% CO, 10% CO2, and 80% H2 with
an impurity level less than 0.002%. The pressure of the re-
actor is controlled by a two-stage reduction valve at the feed
cylinder. The flow of gas through the reactor is controlled by
a flow controller for constant downstream pressure (Brooks
8842 with needle no. 1) positioned downstream from the re-
actor. The reactor pressure is monitored by manometers after
the reduction valve and before the flow controller, respec-
tively.
The product gas stream leaving the reactor is heated to
110 ◦C to avoid condensation of products. Downstream from
the flow controller, at ambient pressure, the flow rate is mea-
sured by an optical/digital bubble flow meter.
The composition of the effluent gas is analysed by a Shi-
madzu GC-17A gas chromatograph. A 6-way gas sample
valve with a 100-µl sample loop injects a gas sample into
the carrier gas stream in which the organic compounds and
the fixed gases are separated on two capillary columns and
detected by a flame ionization detector and a thermal con-
ductivity detector, respectively.
The GC is calibrated with gas standards of known com-
position.
Nickel carbonyl already forms at ambient temperature
from the nickel in the stainless steel feed lines and the flow
controllers. The feed gas must be purified in an active car-
bon filter to avoid a clearly discernible, gradual decline of
the selectivity due to nickel poisoning of the catalyst (cf.
Fig. 6).
The following standard test procedure is followed: The
standard reaction conditions are 220 ◦C, 16 bar, and approx-
imately 20 mg of catalyst loaded into the reactor. The feed
flow rate is 25 (N cm3)/min. Initially, the sample is reduced
by increasing the temperature (20 ◦C/min) from room tem-
perature to the reaction temperature while flushing the reac-
tor with the feed gas (40 (N cm3)/min).
The sample initially forms a packed bed within the glass
capillary tube. Due to the small particle size, a pressure drop
of several bars builds up to force the gas through the bed.
The sample, however, shrinks on reduction by the reaction
mixture during heating of the reactor, and the bed turns into
a coherent, highly porous pellet with a narrow annular slit
between the pellet and the glass wall for gas passage. The
pressure drop subsequently becomes negligible and the re-
actor in fact is transformed into a single-pellet reactor with a
6. 72 J.R. Jensen et al. / Journal of Catalysis 218 (2003) 67–77
Fig. 6. Long-term test of catalyst activity and selectivity for catalyst “A”
(cf. Table 2). The ordinate denotes the differential rates under the standard
conditions: 220 ◦C, 16 bar, approximately 20 mg of catalyst and 10.0% CO,
10.0% CO2, and 80% H2. The figure also illustrates the influence of nickel
poisoning of the catalyst before the nickel carbonyl trap was installed.
cylindrical pellet with a diameter of 1.8 mm and a length of
20–30 mm.
The reactor is then kept at the standard conditions for 24 h
and it is ascertained that the effluent gas composition has
stabilized before the run is disrupted.
After the activity test, the copper dispersion is measured
by N2O titration, which is initiated by flushing the reactor
with pure hydrogen for 1 h at 220 ◦C and 1 atm. The reac-
tor is then cooled to 90 ◦C, at which temperature the N2O
titration is made as described in [7].
Fig. 7 shows the conversion X4 for the carbon oxides as
a function of temperature and space velocity for sample A
of Table 2, which is the most active of the catalysts tested.
The following two reactions describe the chemical changes
4 The degree of conversion is defined as X = FMf/FCO where FMf is
the effluent methanol molar flow rate and FCO total molar flow rates of
CO + CO2 in the reactor feed.
Fig. 7. X, T diagram for the methanol synthesis (cf. footnote 4).
in the gas:
CO2 + 3H2 ⇆ 3CH3OH + H2O,
CO + H2O ⇆ 3CO2 + H2.
Both are exothermic, reversible reactions. In the X, T di-
agram of Fig. 7, both reactions are at equilibrium on the
equilibrium curve, which for control of the chemical analy-
sis is seen to be nicely approached by the measurements at
high temperature. The activity measurements for the cata-
lyst samples are all made at 220 ◦C and a space velocity of
approximately 20 (N cm3)/(gcat s). At these conditions, X
is less than 2.5% and far below the equilibrium curve for all
samples tested. The observed rate is hence the differential (or
initial) rate measured at 16 bar and a composition approx-
imately equal to the feed gas composition. The measured
activity in Table 2 is shown as the molar rate of methanol
production per gram of unreduced sample, or as the turnover
frequency (TOF) defined as the molar rate of methanol pro-
duction per mole of surface Cu.
We assessed the effect of pore diffusion on the measured
activity by estimating values of the effective diffusivities and
Table 2
Correlations between flame conditions, chemical composition, specific surface area, Cu dispersion, and catalytic properties
Catalyst
Aa Ba Ca Da E
Flame H2, quench H2, quench H2, quench CH4, quench CH4
Atomic ratio Cu:Zn:Al 45:45:10 50:50:0 50:0:50 45:45:10 50:50:0
BET surface area (m2/g) 123 113 195 93 66
BET equiv. particle size (nm) 8.2 8.8 5.9 11.2 15.1
ZnO crystallite dimensions (nm)b 3.4 4.4 – 4.3 15.9
Copper dispersion (%) 8.9 (14.1)c 3.8 1.8 9.7 3.4
Cu surface area (m2/g) 21.4 9.7 5.6 23.3 8.7
Estimated Cu particle sized (nm) 11.6 27 59 10.6 31
Activity (µmol/(gcat s)) 3.66 1.61 0.27 1.99 1.07
TOF (10−3 s−1) 7.1 6.8 2 3.5 5.1
SV (cm3/(gcat s)) (st. T , P ) 19.2 19.2 20.7 19 16.5
a In the quenched flames, the quenched-air flow is 6.8 dm3/min (25 ◦C, 1 atm).
b Dimension of the ZnO crystallites estimated using the Scherrer equation.
c Catalyst A has the Cu dispersion 14.1 when it is not exposed to synthesis gas prior to the N2O titration.
d Based on overall copper content, Cu surface area and a density of solid copper of 8920 kg/m3.
7. J.R. Jensen et al. / Journal of Catalysis 218 (2003) 67–77 73
calculating the effectiveness factor for the actual reaction
conditions, treating the catalyst bed as a cylindrical catalyst
particle with a diameter of 2 mm [7]. The calculated effec-
tiveness factor is between 0.9 and unity for all tests, which
proves that the activity measurements are made under condi-
tions of insignificant influence of pore diffusion. The effect
of external diffusion resistance can also be neglected due to
the narrow space available for gas flow in the cylindrical an-
nulus surrounding the particle.
3. Results and discussion
Preliminary tests of the flame-generated ternary Cu/ZnO/
Al2O3 catalyst prove that they are active and selective
for methanol synthesis. The atomic ratio of Cu:Zn:Al =
45:45:10 represents a flat optimal activity for the flame-
generated catalysts. The flame conditions, however, affect
the observed activity significantly.
To clarify the role of each of the three constituent ele-
ments, we shall compare the ternary catalyst with the pure
oxides and the three binary systems with respect to struc-
ture and catalytic properties for different flame conditions.
Table 2 shows the samples which were prepared and tested
with Cu as one of the components. Only those samples have
potential for use as methanol catalysts. The activity per unit
surface area is very low for both pure copper and pure ZnO,
but in combination with a number of specific oxides and in
particular ZnO, copper exhibits a strongly enhanced activ-
ity due to the so-called synergic promotion [13]. Table 2
includes the standard ternary catalyst and the Cu/ZnO bi-
nary catalyst, both for two different flame conditions and a
single sample of the Cu/Al2O3 binary catalyst. Studies of
flame-generated ZnO/Al2O3 particles are made by Jensen
et al. [5] and particle properties for the pure oxides are stud-
ied by Jensen [7] and Jensen et al. [5].
3.1. Calculation of chemical and phase equilibrium
As an a priori assessment of the volatility and phase com-
position of the particles in the flame, we have calculated
the simultaneous chemical and phase equilibria for the given
overall flue gas composition.
The calculations are made by the method of Michel-
sen [14], which minimizes the total Gibbs free energy of
a multicomponent, multiphase system at constant pressure
and temperature subject to the conditions of a given content
of elements. The gas is assumed ideal. All condensed phases
are assumed immiscible so that each condensed component
forms a separate pure solid or liquid phase. In the calcu-
lations we have attempted to include an exhaustive list of
all possible vapour phase and condensed components which
can be formed by the given elements in the flame. The ther-
mochemical properties needed for the calculations are taken
from published data sources [7]. Examples of equilibrium
calculations are shown in Fig. 8 for the synthesis conditions
of the ternary sample.
The calculations ignore both surface energy effects,
which are potentially important for the stability of nanoparti-
cles, and kinetic and diffusional effects, which may delay the
actual attainment of equilibrium. However, in spite of these
shortcomings, equilibrium calculations may still point to
the likely identity of crystalline phases and volatile species
formed at different temperatures and at least approximately
identify the temperature ranges for the phase transforma-
tions. The limitations of the equilibrium approach is illus-
trated, though, by the fact that we have never identified the
stable form of alumina, α-alumina, in the flame-generated
nanoparticles. Evidently, the nucleation or stability of this
alumina form is hindered in the small particles. α-Alumina
is therefore not included in the calculations.
At the particle formation temperatures from 600 to
1500 ◦C, water has no influence on the thermodynamic sta-
Fig. 8. Equilibrium distribution of elements in the CuO/ZnO/Al2O3 system between solids and an ideal gas phase as a function of temperature. The solid
phases are shown in part A whereas the gas phase species are shown in part B. In this calculation α-Al2O3 is excluded from the possible phases. The moles of
copper in the phases containing copper are normalized by the total moles of copper. The copper-containing phases therefore add up to 1. The zinc-containing
species are normalized the same way. Phases containing aluminum only add up to unity at temperatures where none of the aluminum is bound in Cu- and
Zn-containing species.
8. 74 J.R. Jensen et al. / Journal of Catalysis 218 (2003) 67–77
Fig. 9. X-ray powder diffractograms for the five samples of Table 2.
bility of the particles, and it is neglected in the equilibrium
calculations.
3.2. Identification of phases
Fig. 9 shows the powder diffractograms for samples A–
E of Table 2. The ZnO phase gives the strongest diffraction
signal. In fact, almost all the identifiable peaks can be re-
ferred to ZnO. The same difference in signal intensity is seen
for the binary samples. Only for sample E, separate CuO
peaks are detectable in the diffractogram. The dispersion of
the different phases increases when the flame temperature is
decreased and when alumina is added to the sample.
3.3. ZnO/Al2O3 system
We have investigated the premixed-flame synthesis of
particles of this binary composition quite thoroughly [5,7].
For the pure oxides ZnO and Al2O3 the specific surface area
of the generated particles can be maximized by decreasing
the flame temperature or decreasing the precursor vapour
pressure. For Al2O3, surface areas in excess of 400 m2/g
can readily be obtained. The crystal structure is γ -alumina or
X-ray amorphous depending upon the primary particle size.
Particles synthesized in flames are usually crystallized in
metastable phases such as γ - and δ-aluminas [1]. The struc-
tures of δ- and γ -alumina are related in that the long-range
order has increased in δ-alumina. Further heat treatment of
the δ alumina leads to formation of the stable α-phase. How-
ever, only the γ -phase was detected with certainty in this
work. For ZnO the attainable surface areas are much smaller,
i.e., in the range of 30–50 m2/g. In XRD ZnO is wurtzite.
Particles of the binary ZnO/Al2O3 composition are char-
acterized by the formation of the spinel phase of zinc alu-
minate ZnAl2O4, which for any overall composition appears
to be formed to the full extent possible. The specific surface
area increases considerably compared to that of pure ZnO
when the overall composition contains even small amounts
of Al2O3 and quite high and thermally stable ZnAl2O4 sur-
faces can be made in the premixed flame. Equilibrium cal-
culations [7] substantiate that the ZnAl2O4 spinel is the
most stable phase below approximately 2000 ◦C (provided
α-Al2O3 is excluded from the calculation). The readiness
and high yield with which ZnAl2O4 is formed in a single
step from a homogeneous gas mixture proves the potentiality
of the premixed flame for the synthesis of composite mate-
rials with high surface areas. The contribution of ZnAl2O4
to an increased surface area and thermal stability is a likely
explanation of the beneficial role of alumina in the methanol
synthesis catalyst.
3.4. CuO/Al2O3 system (sample C of Table 2)
The phase stability of this system resembles that of the
ZnO/Al2O3 system. Equilibrium calculations show that ei-
ther copper(II) aluminate (CuAl2O4) or copper(I) aluminate
(Cu2Al2O4) form stable solid phases for temperatures be-
low 2200 ◦C [7]. The formation of CuAl2O4 is confirmed
by XRD and seems to take place to the full extent possi-
ble for the given precursor composition [7]. Due to the low
vapour pressures of the aluminates, the flame-synthesized
particles consistently have high specific surface areas, which
is the case indeed for the sample C subjected to catalytic
test in Table 2. Evidently copper aluminate is an advan-
tageous precursor for highly dispersed Cu because disper-
sions in the order of 25% was measured on samples of the
CuO/Al2O3 particles after being cautiously reduced by He-
diluted H2 [7]. Therefore, the CuO/Al2O3 sample at first
sight appears highly promising for Cu-catalyzed reactions
and was indeed proven very active for the dehydrogenation
of ethanol to acetaldehyde and ethyl acetate [7]. Unfortu-
nately, the high Cu surface area rapidly deteriorates when
exposed to elevated hydrogen partial pressures and in partic-
ular to the methanol reactant mixture [7]. In Table 2, sam-
ple C, in spite of a high BET surface area, has the lowest Cu
dispersion. Although Cu/Al2O3 shows methanol synthesis
activity, the Cu-based turnover frequency is clearly inferior
to that of the ZnO-containing catalysts. The overall catalytic
activity of sample C is therefore poor and the CuO/Al2O3
sample is of little interest for methanol synthesis.
3.5. CuO/ZnO system (samples B and E of Table 2)
Equilibrium calculations for this binary system [7] indi-
cate that the solid phases are formed almost simultaneously
9. J.R. Jensen et al. / Journal of Catalysis 218 (2003) 67–77 75
from the gas species Zn(g) and CuO(g) when the flame tem-
perature is cooled below approximately 1000◦C. The stable
solids are ZnO, CuO (T < 600 ◦C) and Cu2O (T > 600 ◦C),
of which ZnO is identified in the particles by XRD (Fig. 9)—
CuO in sample E and vestigially in sample B.
There are no stable mixed oxide phases, but there seems
to be a certain, although limited, solubility of CuO in
ZnO [13], but basically the oxide phases of the two metals
remain segregated either in separate particles or in composite
particles with possibly only two different crystallites grown
together.
For pure CuO the specific surface area is only moderately
high and comparable to that of pure ZnO [7]. However, the
binary particles tend to have surfaces larger than those of
the pure oxides, probably because the immiscibility of the
two oxide phases blocks for sintering at the contact points
between unlike particles [7].
Two binary samples were included in the tests shown in
Table 2. Both samples have a composition of CuO:ZnO =
1:1 but were synthesized at different temperatures and there-
fore subjected to different degrees of sintering. Sample E
was synthesized in a high-temperature flame and has a lower
BET surface area (66 m2/g) than sample B (113 m2/g), syn-
thesized in a low-temperature flame.
Evidently, the higher temperature principally affects the
ZnO phase of sample E because the ZnO crystallite size in-
creases disproportionately more than the BET surface area
decreases (Table 2). The CuO phase is probably less af-
fected by sintering as evidenced by the comparable Cu dis-
persion (after reduction) for samples B and E. The growth
of ZnO crystallites in the high-temperature flame possibly
occurs subsequent to the initial particle formation as a sec-
ondary transport of vapours from small to large particles
(Ostwald ripening). This was observed for the ZnO/Al2O3
system under similar conditions with ZnO in excess of
that needed for the formation of aluminate [5]. In the low-
temperature flame the secondary growth of ZnO crystallites
is suppressed, not due to the lower peak temperature but
rather to the faster cooling rate of the quenched hydrogen
flame.
The high dispersion of the phases and the high specific
surface area for sample B emphasize the importance of con-
trolling the peak temperature of the flame to the lowest ad-
equate level to avoid unnecessary sintering. The Scherrer
crystallite size for ZnO is less than the equivalent particle
size based on the BET area, which indicates that each parti-
cle consists of several crystallites grown together. For sam-
ple E there are identifiable XRD peaks for CuO (cf. Fig. 9).
Their Scherrer crystallite size is 18.9 nm [7]. Thus, for sam-
ple E, generated at a high temperature, the crystallite sizes of
ZnO and CuO and the BET-equivalent size are all three in the
range of 15.1–18.9 nm, which seems to further illustrate the
effects of excessive sintering in the high-temperature flame.
This is also seen in Fig. 10 (right) where large, faceted crys-
tals of ZnO appear on the TEM image. After reduction of
Fig. 10. Transmission electron micrographs of particles of samples A and E
from Table 2, which shows the influence of aluminum and flame temper-
ature on the phase dispersion. Sample A is generated at a low flame tem-
perature with quenching and 10% aluminum and sample E at high flame
temperature without quenching and no aluminum. In sample A the particles
form dendritic clusters of coagulated very small primary particles. Sample E
consists of separated individual crystals of ZnO (faceted, regular) and CuO
(irregular). The chemical composition of the individual particles in sample
A cannot be resolved due to limitations in resolution of the instrument.
sample E, the equivalent copper diameter is increased to
31 nm, so reduction of CuO to Cu for this catalyst is accom-
panied by an increase in size, probably by the coalescence
of adjacent particles.
The reduction of the CuO/ZnO samples (samples B
and E) yields Cu dispersions considerably higher than that
of the CuO/Al2O3 sample (sample C) in spite of the fact
that the BET surface area of the latter sample is much larger.
Together with the higher turnover frequency of catalysts B
and E compared to catalyst C, this allows us to conclude
that ZnO stabilizes the Cu crystallites formed by reduction
and simultaneously modifies them chemically to be more
catalytically active. The latter observation confirms a signif-
icant synergic promotion of ZnO in the flame-synthesized
catalyst. The cause of the intensely investigated synergy be-
tween Cu and ZnO in the low-pressure methanol catalysts is
as yet unsolved and is still open to the widely different in-
terpretations (cf., e.g., [6,13,15]). These can be grouped into
two classes: one in which the activity is related to the ex-
posed surface area of the Cu crystallites, although the copper
surface is modified by the presence of ZnO, and the other in
which the active sites are Cu+ cations dissolved in the ZnO
crystals and the activity therefore is not related directly to
the Cu surface area as determined by the N2O method, but
rather to the surface of ZnO. Catalysts B and E have very
similar copper dispersions while the ZnO crystallite size is
much larger for catalyst E. Since the copper-based turnover
frequency is only slightly smaller for catalyst E than for cat-
alyst B, the activity obviously does not depend on the ZnO
surface, which is vastly different for the two catalyst sam-
ples.
10. 76 J.R. Jensen et al. / Journal of Catalysis 218 (2003) 67–77
3.6. CuO/ZnO/Al2O3 system (samples A and D of Table 2)
The ternary samples were synthesized in a high-tempera-
ture flame (D) and a low-temperature flame (A) with an
overall composition of Cu:Zn:Al = 45:45:10. These two
catalysts have the highest activity of all. The copper disper-
sion is approximately 10% for both reduced samples but the
turnover frequency is higher for the catalyst synthesized at
the low temperature, which thus yields the highest activity
of the five catalyst samples.
Fig. 8 shows the calculated phase distribution at equilib-
rium for the overall composition of the ternary sample under
the conditions in the flames, again with α-alumina excluded
from the calculations. At temperatures above 1300 ◦C the
aluminates ZnAl2O4 or ZnAl2O4 + CuAl2O4 are the only
stable solid phases (Fig. 8A). Between 1300 and 1700◦C
ZnAl2O4 is the most stable solid phase. Due to the molar
ratio of zinc, copper, and aluminum (Zn:Cu:Al = 3:3:4) in
the equilibrium calculation, CuAl2O4 is not present at equi-
librium since all aluminum is bound as ZnAl2O4. Above
1700 ◦C CuAl2O4 appears in the equilibrium distribution in
that Zn is vaporized. Below 1200 ◦C the volatility becomes
negligible (Fig. 8B), and the oxides of Zn, Cu(II), and Cu(I)
appear as additional, segregated solid phases (Fig. 8A). This
provides the following likely mechanism for the gas-to-solid
transformation in the flame: Immediately upon combustion
solid ZnAl2O4 starts to form from the highly supersaturated
Al species in the gas. This leads to dendritic aggregates of
small coagulated primary aluminate particles (cf. Fig. 10,
left). As the flue gas cools, the saturation points for the
pure oxides of Zn and Cu are reached and the oxides start
to condense, however in a more gradual way, controlled by
the cooling rate. The oxides presumably nucleate and grow
at the large surface of the initially formed aggregates of
ZnAl2O4. The final pelletized sample thus attains a struc-
ture with a ZnAl2O4 skeleton with alternating crystallites of
CuO and ZnO intimately mixed along its surface.
This structure combines the beneficial features discussed
above for the CuO/ZnO and CuO/Al2O3 samples and the
ZnO/Al2O3 system. It ensures an intimate contact between
Cu and ZnO and a large and stable surface area of ZnAl2O4,
which binds Al, so that the formation of copper aluminate
with its poor catalytic properties is prevented. The copper
particle size after reduction is close to the BET-equivalent
diameter for samples A and D. Evidently, the ternary cata-
lyst, to a higher degree than the other catalysts, protects the
copper particles from growing during reduction from CuO
to Cu.
The theory, that CuxO nucleates independently of the
other species at temperatures well below the peak tempera-
tures of the flame, is corroborated by the fact that the copper
dispersion is almost independent of the flame conditions for
both the CuO/ZnO (samples B and E of Table 2) and the
CuO/ZnO/Al2O3 catalyst sample (samples A and D). In
both the binary and the ternary sample, however, the ZnO
crystallite size is larger in the methane flame than in the hy-
drogen flame. This can be explained by a secondary growth
of the ZnO crystals in the ternary system equivalent to that of
the binary case as discussed above. The turnover frequency
is moderately lower for the catalyst from the methane flame
for both the binary and the ternary catalyst, which may be
caused by the larger ZnO crystallite size. It explains why
catalyst D has the poorer activity of the two ternary cata-
lysts, in spite of the fact that they have approximately the
same copper dispersion.
The contribution of aluminum and a low flame temper-
ature in the creation of a high dispersion of the phases is
evident from Fig. 10, which compares the TEM images of
samples A and E.
3.7. Catalyst stability
Catalyst A of Table 2 in addition to the standard activity
test has been subjected to further tests as shown in Figs. 6
and 7. The stability of the catalyst was measured over a
4-day period, during which the reactor was operated contin-
uously at the standard test conditions. The differential rate
of reaction as a function of time is shown in Fig. 6. The fig-
ure also shows the effect of Ni-carbonyl poisoning of the
catalyst which gave rise to installment of the active carbon
trap. Without the trap installed, the activity slowly decreases
and the undesired methane production increases. With the
trap installed, the activity after an initial increase over 24 h
remains constant for the whole test period. The test was con-
cluded by a 4-h rise of the temperature to 290 ◦C, which
has no effect on the activity measured subsequently at the
standard temperature. Fig. 6 also demonstrates the excellent
selectivity of the catalyst. Methane, which is the only de-
tectable by-product of the reaction, is produced in minute
amounts unless the catalyst is contaminated by Ni.
3.8. Future work
Future work on this catalyst may include an attempt to
optimize the catalytic properties of the prepared samples
by adjustment of the flame synthesis conditions. This study
would also require a more careful control of the reduction
process in that the activity of the final catalyst presumably is
very sensitive to the reduction conditions.
4. Conclusion
Flame combustion synthesis has been proven to be a ver-
satile method for producing metal-oxide catalysts with large
specific surface areas.
The specific surface area, structure, and phase compo-
sition of the product materials are significantly affected by
the flame conditions and the burner design. Thus, immedi-
ate alterations in the properties of the effluent particles can
be effected by simple adjustments of the operating condi-
tions. There are many possibilities for optimizing product
11. J.R. Jensen et al. / Journal of Catalysis 218 (2003) 67–77 77
properties and developing materials, tailormade for specific
purposes.
The premixed flame, in which fuel, air, and several dif-
ferent volatile precursor species are all mixed together prior
to combustion, provides a homogeneous temperature envi-
ronment for the particle synthesis since all precursor species
traverse the high-temperature zone. The premixed flame is
shown to be ideally suited for the synthesis of nanostructured
mixed oxide phases like, e.g., spinels, which are produced in
a single step, which means that no further, surface reducing
thermal treatment is necessary. The material properties ob-
tainable by combustion synthesis are particularly attractive
for catalytic materials.
It is shown in this study that flame combustion synthesis
can generate a Cu/ZnO/Al2O3 catalyst for methanol syn-
thesis with very high activity, selectivity, and stability. The
study also demonstrates how the versatility of the flame reac-
tor can be used to affect fast, systematic changes in catalyst
composition and structure, which is useful in the study of
how the structure of a catalyst affects its catalytic behaviour.
Flame synthesis of catalysts may find a more widespread
use in catalytic research due to the versatility of the method.
It is, as yet, quite untested in large-scale catalyst manufac-
ture. In the laboratory, the process presently appears rather
expensive and has a rather low production rate. However, to-
day some materials (TiO2, carbon black, SiO2) are already
manufactured in large quantities by industrial flame synthe-
sis. An optimized scale-up of the laboratory process possibly
may lead to competitive manufacturing processes also for
catalytic materials.
It is also possible that flame combustion may find a spe-
cial application in the manufacture of, e.g., catalysed hard-
ware, i.e., surfaces of process equipment with thin coatings
of catalyst, or catalytic membranes. Both applications are
presently under investigation in our laboratory.
Acknowledgment
This work was funded by the Danish National Research
Councils.
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