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Surface Hybrid Nanocomposites
via Friction Stir Processing
Prepared by
Eng. Mohamed Atef Noor El-Deen
Aluminum and Its Alloys are characterized by:
Relatively low density
(2.7 g/cm3 as compared to 7.9
g/cm3 for steel)
High specific strength
(strength to weight ratio)
Low melting point
High electrical and thermal
conductivities
Heat treatable
Not heat treatable
Aluminum alloys.
Deformable
cast wrought
deformation
is not
possible
1xxx pure aluminum Not heat treatable
2xxx Copper Heat treatable
3xxx Manganese Not heat treatable
4xxx Silicon Not heat treatable
5xxx Magnesium Not heat treatable
6xxx Magnesium, silicon Heat treatable
7xxx Zinc Heat treatable
Designation of Wrought Aluminum Alloys
Chemical composition OF AL 6061 ALLOY
Silicon minimum
0.4%, maximum
0.8% by weight
Iron no minimum,
maximum 0.7%
Copper minimum
0.15%, maximum
0.4%
Manganese no
minimum,
maximum 0.15%
Magnesium
minimum 0.8%,
maximum 1.2%
Chromium
minimum 0.04%,
maximum 0.35%
Zinc no minimum,
maximum 0.25%
Titanium no minimum,
maximum 0.15%
Other elements no more than
0.05% each, 0.15% total Remainder Aluminum
(95.85–98.56%)
Friction welding
is a class of solid-state welding
processes that generates heat
through mechanical friction
between a moving workpiece
and a stationary component.
No melt occurs
A specially designed non-consumable
cylindrical tool is rotated and plunged
into the selected area
Tool has a small diameter pin with a
concentric larger diameter shoulder
When tool descended to the
part, the rotating pin contacts
the surface, rapidly friction
produced between tool pin and
metal surface heats and softens
a small column of metal.
When the shoulder contacts the
metal surface, its rotation creates
additional frictional heat and
plasticizes a larger cylindrical
metal column around the
inserted pin.
Axial force
Retreating
side
Trailing
edge of tool
Leading
edge
Working Principle of FSP
Rotating tool
provides:
Continuous heating
of work piece.
Plasticizing
metal.
Transporting metal from the
leading face of the pin to its
trailing edge
• Very good mechanical properties as proven by fatigue, tensile and bend
tests
• No fume, No porosity
• No spatter
• Low shrinkage
• Energy efficient
Advantages
The processed zone cools, without solidification, as there is no liquid, forming a
defect-free recrystallized, fine grain microstructure
limitations
• Welding speeds are moderately slower than those of
some fusion welding
• Work pieces must be rigidly clamped
• Backing bar required
• Keyhole at the end of each weld.
Applications
Shipbuilding and marine industries:
Aluminum
extrusions
Masts
and
booms
Helicopter
landing
platforms.
Railway industry:
Automotive industry
Aerospace industry:
process parameters are grouped in
to two categories:
machine
controlled
parameters
tool controlled
parameters
Spindle rotational
tool traverse
speed
axial force or
plunge force
tool pin profile
shoulder diameter
pin diameter
pin length
tool tilt angle.
Number of passes(1.2.3)
Heat treatment(T6)
Powder type
Graphite,AL2O3,mix,non)
Reviews
Rotational
speed
Ahmed Khalid Hussain
concluded increase in
rotational speed has
resulted in increase on
tensile strength.
S. Rajakumar et.al studied the influence
of process parameters on friction stir
welding of Al 7075 – T6 alloy and
concluded that higher tool rotation
speed resulted in higher heat generation
which caused slower cooling rate and
leads to formation of coarse grains which
in turn produced lower hardness
researchers studied the effect of tool rotational
speed in mechanical properties and concluded
that increase in tool rotational speed
increases both strength and elongation to
maximum and drops down for further increase in
speed
TOOL
profile
Different materials were
welded by different
researchers using various
tool pin profiles and came
to conclusion that the
joints fabricated using
square pin profile
had given the good
mechanical properties
Yan-hua Zhao et.al Concluded
that taper with screw
thread pin has given
good weld without defects.
For this screw thread taper
pin the tensile strength of
the weld joint can reach
75% of the base material.
Tilt angle
K. Reshad Seighalani et.al carried out an Investigation
on the Effects of the Tool Material, Geometry, and Tilt
Angle on Friction Stir Welding of Pure Titanium and
concluded that at higher tilt say 30 angles the
plasticized material easily escape from
the bottom of the tool shoulder which
leads to the formation of some voids at
the surface.
By reducing the tool tilt
angle to 10, the weld
produced was good
without defects
the general range of tool tilt angle is 1° to 4°.
Macrostructural zones in FSP
Unaffected base metal zone(A)
Heat affected zone(B)
TMAZ(C)
nugget zone(D)
Unaffected base metal zone [A]:
• there is no change in neither property nor micro
structure.
• unaffected by the heat or deformation
Heat affected zone [B]: material is influenced by
heat (thermal cycle) and leads to micro structural
changes.
TMAZ [C]
• this region experiences both temperature and
deformation, which are not sufficient to induce the
recrystallization in the material.
nugget zone [D]:
• The portion where the actual stirring takes place which leads to grain refinement
• Severe plastic deformation during welding in the stirred zone results in a new equiaxed fine
grain structure.
Experimental work
The used machine
Process requirement:
• we need a vertical movement to start the process.
• traverse movement to make the welding area between the two plates
• rotational movement to mix the two plates to make the welding area.
Because of these requirements of SFSW process a vertical milling
Machine is used.
Machine specifications
Rotational speed range
(50-2040RPM)
Traverse speed range
(13-395 mm/min)
Used RPM 1060
Used feed 64mm/min
Tilt angle=2deg
Process steps
2)Making the groove
1 –clamping the wp with the vice
3- Determine the rotational speed of the tool and feed speed
4-Put WP on the special fixture and clamped it using the bolts in the sides of the fixtures.
5- fill the groove with the used powder
6- Start the machine and elevate the work table until the shoulder of tool contact with the surface of wp.
7- Start the rotational speed and feed.
8- When the welding reach to the end of the part, go down with the table and stop the machine.
9- Removing the specimen from the fixture and finishing it
vice
Groove
tool
fixture
Centering the tool
Tool design
Pin material: HSS
Shoulder material: K100
25Ф
M4.5*0.7
3mm
Heat-
treatment
PRECIPITATION HARDENING
steps
1)Solution
heat-
treatment
2)Quenching
3)Precipitation
TTT (AGING)
Solution heat
treatment
βα
45MIN
520C
WATER
8 HOUR
AIR COOLING
175C
240C
520C
Aging FurnaceSolution TTT Furnace
Hardness test
Brinell
(HB)
Spherical
indenter.
Vickers (HV)
pyramid
shaped
diamond
indenter
Rockwell
Diamond
cone
indenter.
Tensile test
Micro-Structure test
Test steps
1.Specimen preparation
2.Etching
4.Microscopic examination
3.Water cleaning & drying
•Cutting a small specimen from the work piece
•Mount specimen in resin
•Grinding and Polishing
Results
Tensile test results
179.6
200
193.5
205.9
91.95
153
159.7
152.54
169.69
189.24
167.5
213.2
100.46
88.03
175
150 151.3
111.44
0
50
100
150
200
250
ULTIMATE TENSILE STRENGTH
0
50
100
150
200
250
first pass second pass third pass
Tensile strength for Non heat-treated specimen
No powder
Alumina
Graphite
Mixture
6061alloy
Linear (6061alloy)
0
50
100
150
200
250
first pass second pass third pass
Tensile strength for Heat-treated specimen
No powder
Alumina
Graphite
Mixture
6060alloy
Linear (6060alloy)
Conclusion
For tensile test
Using alumina powder achieve highest tensile strength with third pass in addtion to
heat-treating.
Alumina powder achieves results that exceeds base metal in all passes, moreover
hear-treating achieves higher values.
Graphite powder with second or third pass achieves high value.
Graphite powder with heat-treating achieves good value with third pass but heat
treating not recommended for first or second pass
Using a mixture between alumina and graphite also achieve good values especially
second and third pass with heat-treating, but first pass not recommended.
The condition without powder also achieved good results in all cases, the highest
with the first pass.
Hardness test results
58.92 58.08
60.12
68.57
61.65
66.1
56.85
63.07
65.57
56.97
54.39
52.4
46.68
27
42.79
65.99
69.72
62.62
30.38
43.37
54.33
0
10
20
30
40
50
60
70
80
Rockwellhardness
HARDNESS RESULTS
pass1 pass2 pass3
no powder 58.92 58.08 60.12
alumina 68.57 61.65 66.1
graphite 56.85 63.07 65.57
mixture 56.97 54.39 52.4
6061 alloy 20 20 20
0
10
20
30
40
50
60
70
80
Hardness without Heat treating
pass1 pass2 pass3
no powder 46.68 27 42.79
alumina 65.99 69.72 62.62
graphite 30.38 43.37 54.33
6061 Alloy 40 40 40
0
10
20
30
40
50
60
70
80
Hardness with Heat treating T6
Conclusion
For Hardness test
Alumina powder in second pass with heat-treating achieves the highest values
Also alumina in the other passes achieve high values with or without hrat-treating
but highest with heat-treating.
Without powder, condition achieves good values in all passes almost the same
values.
Powder mixture condition achieves good values but first pass is better.
Graphite is recommended with third pass but the first pass not recommended in case
of heat-treating.
Heat-treating with graphite reduce hardness.
Micro-structure test results
Micrograph of Heat-treated Specimens with Graphite powder
1st pass 2nd pass shows 3rd pass
Stirring zone
BM
1st pass
Stirring zone
BM
2nd pass
Micrograph of Heat-treated Specimens without powder
shows 3rd pass
Micrograph of Heat-treated Specimens with Alumina powder
SZ
TMAZ
1st pass 2nd pass 3rd pass
Micrograph of Not heat-treated Specimens without powder
SZ
TMAZ
1st pass 2nd pass 3rd pass
Micrograph of Not heat-treated Specimens with graphite powder
1st pass 2nd pass 3rd pass
Micrograph of Not heat-treated Specimens with powder mixture
1st pass 2nd pass 3rd pass
Conclusion
Micro-structure test
FSP cause grain refinement especially
with multi-passes so it is recommended.
Graphite achieves good results because
self-lubrication property

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Surface hybrid nanocomposites via friction stir processing

  • 1. Surface Hybrid Nanocomposites via Friction Stir Processing Prepared by Eng. Mohamed Atef Noor El-Deen
  • 2. Aluminum and Its Alloys are characterized by: Relatively low density (2.7 g/cm3 as compared to 7.9 g/cm3 for steel) High specific strength (strength to weight ratio) Low melting point High electrical and thermal conductivities
  • 3. Heat treatable Not heat treatable Aluminum alloys. Deformable cast wrought deformation is not possible 1xxx pure aluminum Not heat treatable 2xxx Copper Heat treatable 3xxx Manganese Not heat treatable 4xxx Silicon Not heat treatable 5xxx Magnesium Not heat treatable 6xxx Magnesium, silicon Heat treatable 7xxx Zinc Heat treatable Designation of Wrought Aluminum Alloys
  • 4. Chemical composition OF AL 6061 ALLOY Silicon minimum 0.4%, maximum 0.8% by weight Iron no minimum, maximum 0.7% Copper minimum 0.15%, maximum 0.4% Manganese no minimum, maximum 0.15% Magnesium minimum 0.8%, maximum 1.2% Chromium minimum 0.04%, maximum 0.35% Zinc no minimum, maximum 0.25% Titanium no minimum, maximum 0.15% Other elements no more than 0.05% each, 0.15% total Remainder Aluminum (95.85–98.56%)
  • 5. Friction welding is a class of solid-state welding processes that generates heat through mechanical friction between a moving workpiece and a stationary component. No melt occurs
  • 6.
  • 7. A specially designed non-consumable cylindrical tool is rotated and plunged into the selected area Tool has a small diameter pin with a concentric larger diameter shoulder When tool descended to the part, the rotating pin contacts the surface, rapidly friction produced between tool pin and metal surface heats and softens a small column of metal. When the shoulder contacts the metal surface, its rotation creates additional frictional heat and plasticizes a larger cylindrical metal column around the inserted pin. Axial force Retreating side Trailing edge of tool Leading edge
  • 9. Rotating tool provides: Continuous heating of work piece. Plasticizing metal. Transporting metal from the leading face of the pin to its trailing edge
  • 10. • Very good mechanical properties as proven by fatigue, tensile and bend tests • No fume, No porosity • No spatter • Low shrinkage • Energy efficient Advantages The processed zone cools, without solidification, as there is no liquid, forming a defect-free recrystallized, fine grain microstructure
  • 11. limitations • Welding speeds are moderately slower than those of some fusion welding • Work pieces must be rigidly clamped • Backing bar required • Keyhole at the end of each weld.
  • 12. Applications Shipbuilding and marine industries: Aluminum extrusions Masts and booms Helicopter landing platforms.
  • 16. process parameters are grouped in to two categories: machine controlled parameters tool controlled parameters Spindle rotational tool traverse speed axial force or plunge force tool pin profile shoulder diameter pin diameter pin length tool tilt angle. Number of passes(1.2.3) Heat treatment(T6) Powder type Graphite,AL2O3,mix,non)
  • 17.
  • 18. Reviews Rotational speed Ahmed Khalid Hussain concluded increase in rotational speed has resulted in increase on tensile strength. S. Rajakumar et.al studied the influence of process parameters on friction stir welding of Al 7075 – T6 alloy and concluded that higher tool rotation speed resulted in higher heat generation which caused slower cooling rate and leads to formation of coarse grains which in turn produced lower hardness researchers studied the effect of tool rotational speed in mechanical properties and concluded that increase in tool rotational speed increases both strength and elongation to maximum and drops down for further increase in speed
  • 19. TOOL profile Different materials were welded by different researchers using various tool pin profiles and came to conclusion that the joints fabricated using square pin profile had given the good mechanical properties Yan-hua Zhao et.al Concluded that taper with screw thread pin has given good weld without defects. For this screw thread taper pin the tensile strength of the weld joint can reach 75% of the base material.
  • 20. Tilt angle K. Reshad Seighalani et.al carried out an Investigation on the Effects of the Tool Material, Geometry, and Tilt Angle on Friction Stir Welding of Pure Titanium and concluded that at higher tilt say 30 angles the plasticized material easily escape from the bottom of the tool shoulder which leads to the formation of some voids at the surface. By reducing the tool tilt angle to 10, the weld produced was good without defects the general range of tool tilt angle is 1° to 4°.
  • 21. Macrostructural zones in FSP Unaffected base metal zone(A) Heat affected zone(B) TMAZ(C) nugget zone(D)
  • 22. Unaffected base metal zone [A]: • there is no change in neither property nor micro structure. • unaffected by the heat or deformation Heat affected zone [B]: material is influenced by heat (thermal cycle) and leads to micro structural changes. TMAZ [C] • this region experiences both temperature and deformation, which are not sufficient to induce the recrystallization in the material. nugget zone [D]: • The portion where the actual stirring takes place which leads to grain refinement • Severe plastic deformation during welding in the stirred zone results in a new equiaxed fine grain structure.
  • 23. Experimental work The used machine Process requirement: • we need a vertical movement to start the process. • traverse movement to make the welding area between the two plates • rotational movement to mix the two plates to make the welding area. Because of these requirements of SFSW process a vertical milling Machine is used.
  • 24. Machine specifications Rotational speed range (50-2040RPM) Traverse speed range (13-395 mm/min) Used RPM 1060 Used feed 64mm/min Tilt angle=2deg
  • 25. Process steps 2)Making the groove 1 –clamping the wp with the vice 3- Determine the rotational speed of the tool and feed speed 4-Put WP on the special fixture and clamped it using the bolts in the sides of the fixtures. 5- fill the groove with the used powder 6- Start the machine and elevate the work table until the shoulder of tool contact with the surface of wp. 7- Start the rotational speed and feed. 8- When the welding reach to the end of the part, go down with the table and stop the machine. 9- Removing the specimen from the fixture and finishing it
  • 26. vice
  • 30. Tool design Pin material: HSS Shoulder material: K100 25Ф M4.5*0.7 3mm
  • 31.
  • 32.
  • 34.
  • 41.
  • 44. Test steps 1.Specimen preparation 2.Etching 4.Microscopic examination 3.Water cleaning & drying •Cutting a small specimen from the work piece •Mount specimen in resin •Grinding and Polishing
  • 45.
  • 46.
  • 50. 0 50 100 150 200 250 first pass second pass third pass Tensile strength for Non heat-treated specimen No powder Alumina Graphite Mixture 6061alloy Linear (6061alloy)
  • 51. 0 50 100 150 200 250 first pass second pass third pass Tensile strength for Heat-treated specimen No powder Alumina Graphite Mixture 6060alloy Linear (6060alloy)
  • 53. Using alumina powder achieve highest tensile strength with third pass in addtion to heat-treating. Alumina powder achieves results that exceeds base metal in all passes, moreover hear-treating achieves higher values. Graphite powder with second or third pass achieves high value. Graphite powder with heat-treating achieves good value with third pass but heat treating not recommended for first or second pass Using a mixture between alumina and graphite also achieve good values especially second and third pass with heat-treating, but first pass not recommended. The condition without powder also achieved good results in all cases, the highest with the first pass.
  • 56. pass1 pass2 pass3 no powder 58.92 58.08 60.12 alumina 68.57 61.65 66.1 graphite 56.85 63.07 65.57 mixture 56.97 54.39 52.4 6061 alloy 20 20 20 0 10 20 30 40 50 60 70 80 Hardness without Heat treating
  • 57. pass1 pass2 pass3 no powder 46.68 27 42.79 alumina 65.99 69.72 62.62 graphite 30.38 43.37 54.33 6061 Alloy 40 40 40 0 10 20 30 40 50 60 70 80 Hardness with Heat treating T6
  • 59. Alumina powder in second pass with heat-treating achieves the highest values Also alumina in the other passes achieve high values with or without hrat-treating but highest with heat-treating. Without powder, condition achieves good values in all passes almost the same values. Powder mixture condition achieves good values but first pass is better. Graphite is recommended with third pass but the first pass not recommended in case of heat-treating. Heat-treating with graphite reduce hardness.
  • 61. Micrograph of Heat-treated Specimens with Graphite powder 1st pass 2nd pass shows 3rd pass
  • 62. Stirring zone BM 1st pass Stirring zone BM 2nd pass Micrograph of Heat-treated Specimens without powder shows 3rd pass
  • 63. Micrograph of Heat-treated Specimens with Alumina powder SZ TMAZ 1st pass 2nd pass 3rd pass
  • 64. Micrograph of Not heat-treated Specimens without powder SZ TMAZ 1st pass 2nd pass 3rd pass
  • 65. Micrograph of Not heat-treated Specimens with graphite powder 1st pass 2nd pass 3rd pass
  • 66. Micrograph of Not heat-treated Specimens with powder mixture 1st pass 2nd pass 3rd pass
  • 68. FSP cause grain refinement especially with multi-passes so it is recommended. Graphite achieves good results because self-lubrication property