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Version 2 EE IIT, Kharagpur 1
Module
2
Measurement Systems
Version 2 EE IIT, Kharagpur 2
Lesson
4
Temperature
Measurement
Version 2 EE IIT, Kharagpur 3
Instructional Objective
The reader, after going through the lesson would be able to
1. Name different methods for temperature measurement
2. Distinguish between the principles of operation of RTD and thermistor
3. Explain the meaning of lead wire compensation of RTD
4. Differentiate characteristics of a PTC thermistor from a NTC thermistor
5. Select the proper thermocouple for a particular temperature range
6. Design simple cold junction compensation schemes for thermocouples.
1. Introduction
The word temper was used in the seventeenth century to describe the quality of steel. It seems,
after the invention of crude from of thermometer, the word temperature was coined to describe
the degree of hotness or coolness of a material body. It was the beginning of seventeenth century
when the thermometer – a temperature measuring instrument was first developed. Galileo Galilei
is credited with the construction of first thermometer, although a Dutch scientist Drebbel also
made similar instrument independently. The principle was simple. A bulb containing air with
long vertical tube was inverted and dipped into a basin of water or coloured liquid. With the
change in temperature of the bulb, the gas inside expanded or contracted, thus changing the level
of the liquid column inside the vertical tube. A major drawback of the instrument was that it was
sensitive not only to variation of temperature, but also to atmospheric pressure variation.
Successive developments of thermometers came out throughout seventeenth and eighteenth
century. The liquid thermometer was developed during this time. The importance of two
reference fixed temperatures was felt while graduating the temperature scales. Boiling point of
water and melting point of ice provided two easily available references. But some other
references were also tried. Fahrenheit developed a thermometer where, it seems, temperature of
ice and salt mixture was taken as 0o
and temperature of human body as 96o
. These two formed
the reference points, with which, the temperature of melting ice came as 32o
and that of boiling
water as 212o
. In Celsius scale, the melting point of ice was chosen as 0o
and boiling point of
water as 100o
. The concept of Kelvin scale came afterwards, where the absolute temperature of
gas was taken as 00
and freezing point of water as 273o
.
The purpose of early thermometers was to measure the variation of atmospheric or body
temperatures. With the advancement of science and technology, now we require temperature
measurement over a wide range and different atmospheric conditions, and that too with high
accuracy and precision. To cater these varied requirements, temperature sensors based on
different principles have been developed. They can be broadly classified in the following groups:
1. Liquid and gas thermometer
2. Bimetallic strip
3. Resistance thermometers (RTD and Thermistors)
4. Thermocouple
5. Junction semiconductor sensor
6. Radiation pyrometer
Within the limited scope of this course, we shall discuss few of the above mentioned temperature
sensors, that are useful for measurement in industrial environment.
2. Resistance Thermometers
It is well known that resistance of metallic conductors increases with temperature, while that of
semiconductors generally decreases with temperature. Resistance thermometers employing
metallic conductors for temperature measurement are called Resistance Temperature Detector
(RTD), and those employing semiconductors are termed as Thermistors. RTDs are more rugged
and have more or less linear characteristics over a wide temperature range. On the other hand
Thermistors have high temperature sensitivity, but nonlinear characteristics.
Resistance Temperature Detector
The variation of resistance of metals with temperature is normally modeled in the form:
(1)......])tt()tt(1[RR 2
000t +−β+−α+=
where and are the resistance values at ttR 0R o
C and t0
o
C respectively; α, β, etc. are constants
that depends on the metal. For a small range of temperature, the expression can be approximated
as:
(2))]tt(1[RR 00t −α+=
For Copper, .C/00427.0 o
=α
Copper, Nickel and Platinum are mostly used as RTD materials. The range of temperature
measurement is decided by the region, where the resistance-temperature characteristics are
approximately linear. The resistance versus temperature characteristics of these materials is
shown in fig.1, with to
as 0o
C. Platinum has a linear range of operation upto 650o
C, while the
useful range for Copper and Nickel are 120o
C and 300o
C respectively.
Version 2 EE IIT, Kharagpur 4
Fig. 1 Resistance-temperature characteristics of metals
Nickel
Copper
Platinum
6
5
4
3
2
1
0 200 400 600
Temperature (ºC)
Rt/R0
Construction
For industrial use, bare metal wires cannot be used for temperature measurement. They must be
protected from mechanical hazards such as material decomposition, tearing and other physical
damages. The salient features of construction of an industrial RTD are as follows:
• The resistance wire is often put in a stainless steel well for protection against mechanical
hazards. This is also useful from the point of view of maintenance, since a defective
sensor can be replaced by a good one while the plant is in operation.
• Heat conducting but electrical insulating materials like mica is placed in between the well
and the resistance material.
• The resistance wire should be carefully wound over mica sheet so that no strain is
developed due to length expansion of the wire.
Fig. 2 shows the cut away view of an industrial RTD.
Version 2 EE IIT, Kharagpur 5
Resistance wire
Mica
Ceramic powder
Stainless steel well
Fig. 2 Construction of an industrial RTD
Signal conditioning
The resistance variation of the RTD can be measured by a bridge, or directly by volt-ampere
method. But the major constraint is the contribution of the lead wires in the overall resistance
measured. Since the length of the lead wire may vary, this may give a false reading in the
temperature to be measured. There must be some method for compensation so that the effect of
lead wires is resistance measured is eliminated. This can be achieved by using either a three wire
RTD, or a four wire RTD. Both the schemes of measurement are shown in fig. 3. In three wire
method one additional dummy wire taken from the resistance element and connected in a bridge
(fig. 3(a)) so that the two lead wires are connected to two adjacent arms of the bridge, thus
canceling each other’s effect. In fig. 3(b) the four wire method of measurement is shown. It is
similar to a four terminal resistance and two terminals are used for injecting current, while two
others are for measuring voltage.
Version 2 EE IIT, Kharagpur 6
a
b c
RX
a, b, c: lead wires
Fig. 3(a) Three wire RTD
a
a, b, c: lead wires
b
c
d
V
Fig. 3(b) Four wire RTD
Thermistor
Thermistors are semiconductor type resistance thermometers. They have very high sensitivity but
highly nonlinear characteristics. This can be understood from the fact that for a typical 2000 Ω
the resistance change at 25o
C is 80Ω/o
C, whereas for a 2000 Ω platinum RTD the change in
resistance at 25o
C is 7Ω/o
C. Thermistors can be of two types: (a) Negative temperature co-
efficient (NTC) thermistors and (b) Positive temperature co-efficient (PTC) thermistors. Their
resistance-temperature characteristics are shown in fig. 4(a) and 4(b) respectively.
The NTC thermistors, whose characteristics are shown in fig. 4(a) is more common. Essentially,
they are made from oxides of iron, manganese, magnesium etc. Their characteristics can be
expressed as:
)
T
1
T
1
(
0T
0
eRR
−β
= (3)
where,
RT is the resistance at temperature T (K)
R0 is the resistance at temperature T0 (K)
T0 is the reference temperature, normally 25o
C
β is a constant, its value is decided by the characteristics of the material, the nominal
value is taken as 4000.
From (3), the resistance temperature co-efficient can be obtained as:
2
T
T
T
TdT
dR
R
1 β
−==α (4)
It is clear from the above expression that the negative sign of Tα indicates the negative
resistance-temperature characteristics of the NTC thermistor.
Temperature
Resistance
Fig. 4(a) Characteristics of a NTC
thermistor
Temperature
Resistance
Fig. 4(b) Characteristics of a PTC
thermistor
TR
Useful range of themistors is normally -100 to +300o
C. A single thermistor is not suitable for the
whole range of measurement. Moreover, existing thermistors are not interchangeable. There is a
marked spread in nominal resistance and the temperature coefficient between two thermistors of
same type. So, if a defective thermistor is to be replaced by a new thermistor similar type, a fresh
Version 2 EE IIT, Kharagpur 7
calibration has to be carried out before use. Commercially available thermistors have nominal
values of 1K, 2K, 10K, 20K, 100K etc. The nominal values indicate the resistance value at 25o
C.
Thermistors are available in different forms: bead type, rod type disc type etc. The small size of
the sensing element makes it suitable for measurement of temperature at a point. The time
constant is also very small due to the small thermal mass involved.
The nonlinear negative temperature characteristics also give rise to error due to self-heating
effect. When current is flowing through the thermistor, the heat generated due to the -loss
may increase the temperature of the resistance element, which may further decrease the
resistance and increase the current further. This effect, if not tackled properly, may damage the
thermistor permanently. Essentially, the current flowing should be restricted below the specified
value to prevent this damage. Alternatively, the thermistor may be excited by a constant current
source.
RI2
The nonlinear characteristics of thermistors often creates problem for temperature measurement,
and it is often desired to linearise the thermistor characteristics. This can be done by adding one
fixed resistance parallel to the thermistor. The resistance temperature characteristics of the
equivalent resistance would be more linear, but at the cost of sensitivity.
The Positive Temperature Coefficient (PTC) thermistor have limited use and they are
particularly used for protection of motor and transformer widings. As shown in fig. 4(b), they
have low and relatively constant resistance below a threshold temperature TR, beyond which the
resistance increases rapidly. The PTC thermistors are made from compound of barium, lead and
strontium titanate.
3. Thermocouple
Thomas Johan Seeback discovered in 1821 that thermal energy can produce electric current.
When two conductors made from dissimilar metals are connected forming two common
junctions and the two junctions are exposed to two different temperatures, a net thermal emf is
produced, the actual value being dependent on the materials used and the temperature difference
between hot and cold junctions. The thermoelectric emf generated, in fact is due to the
combination of two effects: Peltier effect and Thomson effect. A typical thermocouple junction is
shown in fig. 5. The emf generated can be approximately expressed by the relationship:
)TT(C)TT(Ce 2
2
2
122110 −+−= μv (5)
where T1 and T2 are hot and cold junction temperatures in K. C1 and C2 are constants depending
upon the materials. For Copper/ Constantan thermocouple, C1=62.1 and C2=0.045.
Version 2 EE IIT, Kharagpur 8
(hot junction) (cold junction)
A
BB
T1 T2
e0
Fig. 5 A typical thermocouple
Thermocouples are extensively used for measurement of temperature in industrial situations. The
major reasons behind their popularity are: (i) they are rugged and readings are consistent, (ii)
they can measure over a wide range of temperature, and (iii) their characteristics are almost
linear with an accuracy of about 0.05%. However, the major shortcoming of thermocouples is
low sensitivity compared to other temperature measuring devices (e.g. RTD, Thermistor).
±
Thermocouple Materials
Theoretically, any pair of dissimilar materials can be used as a thermocouple. But in practice,
only few materials have found applications for temperature measurement. The choice of
materials is influenced by several factors, namely, sensitivity, stability in calibration, inertness in
the operating atmosphere and reproducibility (i.e. the thermocouple can be replaced by a similar
one without any recalibration). Table-I shows the common types of thermocouples, their types,
composition, range, sensitivity etc. The upper range of the thermocouple is normally dependent
on the atmosphere whre it has been put. For example, the upper range of Chromel/ Alumel
thermocouple can be increased in oxidizing atmosphere, while the upper range of Iron/
Constantan thermocouple can be increased in reducing atmosphere.
Table-1 Thermocouple materials and Characteristics
Type Positive
lead
Negative
lead
Temperature
range
Temperature
coeff.variation
μv/o
C
Most linear
range and
sensitivity in
the range
R Platinum-
Rhodium
(87% Pt,
13% Rh)
Platinum 0-1500o
C 5.25-14.1 1100-1500o
C
13.6-14.1
μv/o
C
S Platinum-
Rhodium
(90% Pt,
10% Rh)
Platinum 0-1500o
C 5.4-12.2 1100-1500 o
C
13.6-14.1
μv/o
C
K Chromel
(90%Ni,
10% Cr)
Alumel
(Ni94Al2
Mn3Si)
-200-1300o
C 15.2-42.6 0-1000 o
C
38-42.9 μv/o
C
Version 2 EE IIT, Kharagpur 9
Version 2 EE IIT, Kharagpur 10
E Chromel Constantan
(57%Cu,
43%Ni)
-200-1000o
C 25.1-80.8 300-800 o
C
77.9-80.8
μv/o
C
T Copper Constantan -200-350o
C 15.8-61.8 nonlinear
J Iron Constantan -150-750o
C 21.8-64.6 100-500 o
C
54.4-55.9
Laws of Thermocouple
The Peltier and Thompson effects explain the basic principles of thermoelectric emf generation.
But they are not sufficient for providing a suitable measuring technique at actual measuring
situations. For this purpose, we have three laws of thermoelectric circuits that provide us useful
practical tips for measurement of temperature. These laws are known as law of homogeneous
circuit, law of intermediate metals and law of intermediate temperatures. These laws can be
explained using fig. 6.
The first law can be explained using fig. 6(a). It says that the net thermo-emf generated is
dependent on the materials and the temperatures of two junctions only, not on any intermediate
temperature.
According to the second law, if a third material is introduced at any point (thus forming two
additional junctions) it will not have any effect, if these two additional junctions remain at the
same temperatures (fig. 6(b)). This law makes it possible to insert a measuring device without
altering the thermo-emf.
Same net emf
A
B
B
T1 T2
e
T3
T4
T5
T6
T7
+ -
A
B
B
T1 T2
T8
T9
T10
T11 T12
+ -
(a)
A
B B
T1 T2
e
Same net emf
(b)
A
B
T1
T2
e
T2
T4
T3
C
A
B B
T1
T2
e1
+ -
A
B B
T2
T3
e2
+ -
e3 = e1 + e2
(c)
A
B B
T1
T3
e3
+ -
Fig. 6 Laws of Thermocouple
The third law is related to the calibration of the thermocouple. It says, if a thermocouple
produces emf e1, when its junctions are at T1 and T2, and e2 when its junctions are at T2 and T3;
then it will generate emf e1+e2 when the junction temperatures are at T1 and T3 (fig. 6(c)).
The third law is particularly important from the point of view of reference junction
compensation. The calibration chart of a thermocouple is prepared taking the cold or reference
junction temperature as 0o
C. But in actual measuring situation, seldom the reference junction
temperature is kept at that temperature, it is normally kept at ambient temperature. The third law
helps us to compute the actual temperature using the calibration chart. This can be explained
from the following example.
Example-1
The following table has been prepared from the calibration chart of iron-constantan
thermocouple, with reference temperature at 0o
C.
Version 2 EE IIT, Kharagpur 11
Temperature
(o
C)
15 30 40 .…….. 180 190 200 208 210
emf (mv) 0.778 1.56 2.11 ……… 9.64 10.25 10.74 11.20 11.32
Suppose, the temperature of the hot junction is measured with a iron-constantan thermocouple,
with the reference junction temperature at 30o
C. If the voltage measured is 9.64mv, find the
actual temperature of the hot junction.
Solution
Referring fig. 6(c), for this problem, T1 is the unknown temperature, T2= 30o
C, T3= 0o
C. The
voltages are e1=9.64mv (measured) and e2= 1.56mv (from chart). Therefore, e3= e1+e2=
11.20mv. Hence, from the calibration chart, the actual hot junction temperature is T1 = 208o
C.
Reference Junction Compensation
From above discussions, it is imminent that the thermocouple output voltage will vary if the
reference junction temperature changes. So, for measurement of temperature, it is desirable that
the cold junction of the thermocouple should be maintained at a constant temperature. Ice bath
can be used for this purpose, but it is not practical solution for industrial situation. An alternative
is to use a thermostatically controlled constant temperature oven. In this case, a fixed voltage
must be added to the voltage generated by the thermocouple, to obtain the actual temperature.
But the most common case is where the reference junction is placed at ambient temperature. For
high temperature measurement, the error introduced due to variation of reference junction
temperature is not appreciable. For example, with a thermocouple measuring 1500o
C, if the
ambient temperature variation is within 25 15± o
C, then the error introduced in the reading due to
this variation would be around 1%. Such a typical scheme is shown in fig. 7. Here a constant
voltage corresponding to the ambient temperature is added through the offset of the op-amp. The
thermocouple voltage is also amplified by the same op-amp.
A more accurate method for reference junction temperature compensation is shown in fig. 8.
Here a thermistor, or a RTD is used to measure the ambient temperature and compensate the
error through a bridge circuit. The bridge circuit is balanced at 0o
C. When the ambient
temperature goes above 0o
C, the emf generated in the thermocouple is reduced; at the same time
bridge unbalanced voltage is added to it in order to maintain the overall voltage at the same
value.
Version 2 EE IIT, Kharagpur 12
R1
R2
Hot
junction Cold
junction
Offset adjust
+
-
Fig.7 Simple method for reference junction compensation
RP
R
Hot
junction Cold
junction
To amplifierR
Thermistor
Fig. 8 Compensation scheme using wheatstone bridge
As referred to Fig.8, the cold junction compensation is normally kept along with the signal
conditioning circuits, away from the measuring point. This may require use of long
thermocouple wires to the compensation circuit. In order to reduce the length of costly
thermocouple wires (platinum in some case) low-cost compensating wires are normally used in
between the thermocouple and the compensation circuit. These wires are so selected that their
temperature emf characteristics match closely to those of the thermocouple wires around the
ambient temperature.
4. Conclusion
Temperature is the most important process variable that requires continuous measurement and
monitoring in a process industry. Among the different types of temperature transducers, the most
commonly used ones are RTDs and thermocouples. Their popularity is mainly due to their
ruggedness, repeatability and wide range of operation. Bare RTDs and thermocouples are rarely
used in practice; instead, they are put in protective metallic sheaths. The signal conditioning
circuits should be properly designed, so as to avoid the errors due to lead wires in RTDs and
variation of cold junction temperatures in thermocouples. There are several cases where the
temperature to be measured is more than 2000o
C, the conventional measuring techniques fail to
measure the high temperature. Instead, the measurement is carried out from a distance. Radiation
pyrometers are used in these situations. However, its principle of operation has not been included
in this lesson.
Review Exercise
1. Name the materials commonly used for RTDs. Which one has the most linear
characteristics?
2. What do you mean by lead wire compensation of RTD. How can they be achieved?
3. PT-100 is a Platinum RTD whose resistance at 0o
C is 100Ω. If the resistance
4. temperature co-efficient of Platinum is 3
3.91 10X −
/o
C, then find its resistance at 100o
C.
5. What is the difference between a NTC thermistor and a PTC thermistor?
6. A thermistor is more suitable for measurement of temperature within a small range-
justify.
Version 2 EE IIT, Kharagpur 13
7. Name three types thermocouples and their suitable temperature range.
8. State and explain the laws of thermocouple.
9. What do you mean by cold junction compensation of a thermocouple? Suggest two
methods for compensation.
10. A thermocouple has a linear sensitivity of 30µv/o
C, calibrated at a cold junction
temperature of 0o
C. It is used measure an unknown temperature with the cold junction
temperature of 30o
C. Find the actual hot junction temperature if the emf generated is 3.0
mv.
Answers
1. Platinum, Copper, Nickel; Platinum.
3. 139 .Ω
9. 130o
C.
Version 2 EE IIT, Kharagpur 14

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L 04(ss)(ia&c) ((ee)nptel)

  • 1. Version 2 EE IIT, Kharagpur 1 Module 2 Measurement Systems
  • 2. Version 2 EE IIT, Kharagpur 2 Lesson 4 Temperature Measurement
  • 3. Version 2 EE IIT, Kharagpur 3 Instructional Objective The reader, after going through the lesson would be able to 1. Name different methods for temperature measurement 2. Distinguish between the principles of operation of RTD and thermistor 3. Explain the meaning of lead wire compensation of RTD 4. Differentiate characteristics of a PTC thermistor from a NTC thermistor 5. Select the proper thermocouple for a particular temperature range 6. Design simple cold junction compensation schemes for thermocouples. 1. Introduction The word temper was used in the seventeenth century to describe the quality of steel. It seems, after the invention of crude from of thermometer, the word temperature was coined to describe the degree of hotness or coolness of a material body. It was the beginning of seventeenth century when the thermometer – a temperature measuring instrument was first developed. Galileo Galilei is credited with the construction of first thermometer, although a Dutch scientist Drebbel also made similar instrument independently. The principle was simple. A bulb containing air with long vertical tube was inverted and dipped into a basin of water or coloured liquid. With the change in temperature of the bulb, the gas inside expanded or contracted, thus changing the level of the liquid column inside the vertical tube. A major drawback of the instrument was that it was sensitive not only to variation of temperature, but also to atmospheric pressure variation. Successive developments of thermometers came out throughout seventeenth and eighteenth century. The liquid thermometer was developed during this time. The importance of two reference fixed temperatures was felt while graduating the temperature scales. Boiling point of water and melting point of ice provided two easily available references. But some other references were also tried. Fahrenheit developed a thermometer where, it seems, temperature of ice and salt mixture was taken as 0o and temperature of human body as 96o . These two formed the reference points, with which, the temperature of melting ice came as 32o and that of boiling water as 212o . In Celsius scale, the melting point of ice was chosen as 0o and boiling point of water as 100o . The concept of Kelvin scale came afterwards, where the absolute temperature of gas was taken as 00 and freezing point of water as 273o . The purpose of early thermometers was to measure the variation of atmospheric or body temperatures. With the advancement of science and technology, now we require temperature measurement over a wide range and different atmospheric conditions, and that too with high accuracy and precision. To cater these varied requirements, temperature sensors based on different principles have been developed. They can be broadly classified in the following groups: 1. Liquid and gas thermometer 2. Bimetallic strip 3. Resistance thermometers (RTD and Thermistors) 4. Thermocouple
  • 4. 5. Junction semiconductor sensor 6. Radiation pyrometer Within the limited scope of this course, we shall discuss few of the above mentioned temperature sensors, that are useful for measurement in industrial environment. 2. Resistance Thermometers It is well known that resistance of metallic conductors increases with temperature, while that of semiconductors generally decreases with temperature. Resistance thermometers employing metallic conductors for temperature measurement are called Resistance Temperature Detector (RTD), and those employing semiconductors are termed as Thermistors. RTDs are more rugged and have more or less linear characteristics over a wide temperature range. On the other hand Thermistors have high temperature sensitivity, but nonlinear characteristics. Resistance Temperature Detector The variation of resistance of metals with temperature is normally modeled in the form: (1)......])tt()tt(1[RR 2 000t +−β+−α+= where and are the resistance values at ttR 0R o C and t0 o C respectively; α, β, etc. are constants that depends on the metal. For a small range of temperature, the expression can be approximated as: (2))]tt(1[RR 00t −α+= For Copper, .C/00427.0 o =α Copper, Nickel and Platinum are mostly used as RTD materials. The range of temperature measurement is decided by the region, where the resistance-temperature characteristics are approximately linear. The resistance versus temperature characteristics of these materials is shown in fig.1, with to as 0o C. Platinum has a linear range of operation upto 650o C, while the useful range for Copper and Nickel are 120o C and 300o C respectively. Version 2 EE IIT, Kharagpur 4
  • 5. Fig. 1 Resistance-temperature characteristics of metals Nickel Copper Platinum 6 5 4 3 2 1 0 200 400 600 Temperature (ºC) Rt/R0 Construction For industrial use, bare metal wires cannot be used for temperature measurement. They must be protected from mechanical hazards such as material decomposition, tearing and other physical damages. The salient features of construction of an industrial RTD are as follows: • The resistance wire is often put in a stainless steel well for protection against mechanical hazards. This is also useful from the point of view of maintenance, since a defective sensor can be replaced by a good one while the plant is in operation. • Heat conducting but electrical insulating materials like mica is placed in between the well and the resistance material. • The resistance wire should be carefully wound over mica sheet so that no strain is developed due to length expansion of the wire. Fig. 2 shows the cut away view of an industrial RTD. Version 2 EE IIT, Kharagpur 5
  • 6. Resistance wire Mica Ceramic powder Stainless steel well Fig. 2 Construction of an industrial RTD Signal conditioning The resistance variation of the RTD can be measured by a bridge, or directly by volt-ampere method. But the major constraint is the contribution of the lead wires in the overall resistance measured. Since the length of the lead wire may vary, this may give a false reading in the temperature to be measured. There must be some method for compensation so that the effect of lead wires is resistance measured is eliminated. This can be achieved by using either a three wire RTD, or a four wire RTD. Both the schemes of measurement are shown in fig. 3. In three wire method one additional dummy wire taken from the resistance element and connected in a bridge (fig. 3(a)) so that the two lead wires are connected to two adjacent arms of the bridge, thus canceling each other’s effect. In fig. 3(b) the four wire method of measurement is shown. It is similar to a four terminal resistance and two terminals are used for injecting current, while two others are for measuring voltage. Version 2 EE IIT, Kharagpur 6 a b c RX a, b, c: lead wires Fig. 3(a) Three wire RTD a a, b, c: lead wires b c d V Fig. 3(b) Four wire RTD
  • 7. Thermistor Thermistors are semiconductor type resistance thermometers. They have very high sensitivity but highly nonlinear characteristics. This can be understood from the fact that for a typical 2000 Ω the resistance change at 25o C is 80Ω/o C, whereas for a 2000 Ω platinum RTD the change in resistance at 25o C is 7Ω/o C. Thermistors can be of two types: (a) Negative temperature co- efficient (NTC) thermistors and (b) Positive temperature co-efficient (PTC) thermistors. Their resistance-temperature characteristics are shown in fig. 4(a) and 4(b) respectively. The NTC thermistors, whose characteristics are shown in fig. 4(a) is more common. Essentially, they are made from oxides of iron, manganese, magnesium etc. Their characteristics can be expressed as: ) T 1 T 1 ( 0T 0 eRR −β = (3) where, RT is the resistance at temperature T (K) R0 is the resistance at temperature T0 (K) T0 is the reference temperature, normally 25o C β is a constant, its value is decided by the characteristics of the material, the nominal value is taken as 4000. From (3), the resistance temperature co-efficient can be obtained as: 2 T T T TdT dR R 1 β −==α (4) It is clear from the above expression that the negative sign of Tα indicates the negative resistance-temperature characteristics of the NTC thermistor. Temperature Resistance Fig. 4(a) Characteristics of a NTC thermistor Temperature Resistance Fig. 4(b) Characteristics of a PTC thermistor TR Useful range of themistors is normally -100 to +300o C. A single thermistor is not suitable for the whole range of measurement. Moreover, existing thermistors are not interchangeable. There is a marked spread in nominal resistance and the temperature coefficient between two thermistors of same type. So, if a defective thermistor is to be replaced by a new thermistor similar type, a fresh Version 2 EE IIT, Kharagpur 7
  • 8. calibration has to be carried out before use. Commercially available thermistors have nominal values of 1K, 2K, 10K, 20K, 100K etc. The nominal values indicate the resistance value at 25o C. Thermistors are available in different forms: bead type, rod type disc type etc. The small size of the sensing element makes it suitable for measurement of temperature at a point. The time constant is also very small due to the small thermal mass involved. The nonlinear negative temperature characteristics also give rise to error due to self-heating effect. When current is flowing through the thermistor, the heat generated due to the -loss may increase the temperature of the resistance element, which may further decrease the resistance and increase the current further. This effect, if not tackled properly, may damage the thermistor permanently. Essentially, the current flowing should be restricted below the specified value to prevent this damage. Alternatively, the thermistor may be excited by a constant current source. RI2 The nonlinear characteristics of thermistors often creates problem for temperature measurement, and it is often desired to linearise the thermistor characteristics. This can be done by adding one fixed resistance parallel to the thermistor. The resistance temperature characteristics of the equivalent resistance would be more linear, but at the cost of sensitivity. The Positive Temperature Coefficient (PTC) thermistor have limited use and they are particularly used for protection of motor and transformer widings. As shown in fig. 4(b), they have low and relatively constant resistance below a threshold temperature TR, beyond which the resistance increases rapidly. The PTC thermistors are made from compound of barium, lead and strontium titanate. 3. Thermocouple Thomas Johan Seeback discovered in 1821 that thermal energy can produce electric current. When two conductors made from dissimilar metals are connected forming two common junctions and the two junctions are exposed to two different temperatures, a net thermal emf is produced, the actual value being dependent on the materials used and the temperature difference between hot and cold junctions. The thermoelectric emf generated, in fact is due to the combination of two effects: Peltier effect and Thomson effect. A typical thermocouple junction is shown in fig. 5. The emf generated can be approximately expressed by the relationship: )TT(C)TT(Ce 2 2 2 122110 −+−= μv (5) where T1 and T2 are hot and cold junction temperatures in K. C1 and C2 are constants depending upon the materials. For Copper/ Constantan thermocouple, C1=62.1 and C2=0.045. Version 2 EE IIT, Kharagpur 8
  • 9. (hot junction) (cold junction) A BB T1 T2 e0 Fig. 5 A typical thermocouple Thermocouples are extensively used for measurement of temperature in industrial situations. The major reasons behind their popularity are: (i) they are rugged and readings are consistent, (ii) they can measure over a wide range of temperature, and (iii) their characteristics are almost linear with an accuracy of about 0.05%. However, the major shortcoming of thermocouples is low sensitivity compared to other temperature measuring devices (e.g. RTD, Thermistor). ± Thermocouple Materials Theoretically, any pair of dissimilar materials can be used as a thermocouple. But in practice, only few materials have found applications for temperature measurement. The choice of materials is influenced by several factors, namely, sensitivity, stability in calibration, inertness in the operating atmosphere and reproducibility (i.e. the thermocouple can be replaced by a similar one without any recalibration). Table-I shows the common types of thermocouples, their types, composition, range, sensitivity etc. The upper range of the thermocouple is normally dependent on the atmosphere whre it has been put. For example, the upper range of Chromel/ Alumel thermocouple can be increased in oxidizing atmosphere, while the upper range of Iron/ Constantan thermocouple can be increased in reducing atmosphere. Table-1 Thermocouple materials and Characteristics Type Positive lead Negative lead Temperature range Temperature coeff.variation μv/o C Most linear range and sensitivity in the range R Platinum- Rhodium (87% Pt, 13% Rh) Platinum 0-1500o C 5.25-14.1 1100-1500o C 13.6-14.1 μv/o C S Platinum- Rhodium (90% Pt, 10% Rh) Platinum 0-1500o C 5.4-12.2 1100-1500 o C 13.6-14.1 μv/o C K Chromel (90%Ni, 10% Cr) Alumel (Ni94Al2 Mn3Si) -200-1300o C 15.2-42.6 0-1000 o C 38-42.9 μv/o C Version 2 EE IIT, Kharagpur 9
  • 10. Version 2 EE IIT, Kharagpur 10 E Chromel Constantan (57%Cu, 43%Ni) -200-1000o C 25.1-80.8 300-800 o C 77.9-80.8 μv/o C T Copper Constantan -200-350o C 15.8-61.8 nonlinear J Iron Constantan -150-750o C 21.8-64.6 100-500 o C 54.4-55.9 Laws of Thermocouple The Peltier and Thompson effects explain the basic principles of thermoelectric emf generation. But they are not sufficient for providing a suitable measuring technique at actual measuring situations. For this purpose, we have three laws of thermoelectric circuits that provide us useful practical tips for measurement of temperature. These laws are known as law of homogeneous circuit, law of intermediate metals and law of intermediate temperatures. These laws can be explained using fig. 6. The first law can be explained using fig. 6(a). It says that the net thermo-emf generated is dependent on the materials and the temperatures of two junctions only, not on any intermediate temperature. According to the second law, if a third material is introduced at any point (thus forming two additional junctions) it will not have any effect, if these two additional junctions remain at the same temperatures (fig. 6(b)). This law makes it possible to insert a measuring device without altering the thermo-emf.
  • 11. Same net emf A B B T1 T2 e T3 T4 T5 T6 T7 + - A B B T1 T2 T8 T9 T10 T11 T12 + - (a) A B B T1 T2 e Same net emf (b) A B T1 T2 e T2 T4 T3 C A B B T1 T2 e1 + - A B B T2 T3 e2 + - e3 = e1 + e2 (c) A B B T1 T3 e3 + - Fig. 6 Laws of Thermocouple The third law is related to the calibration of the thermocouple. It says, if a thermocouple produces emf e1, when its junctions are at T1 and T2, and e2 when its junctions are at T2 and T3; then it will generate emf e1+e2 when the junction temperatures are at T1 and T3 (fig. 6(c)). The third law is particularly important from the point of view of reference junction compensation. The calibration chart of a thermocouple is prepared taking the cold or reference junction temperature as 0o C. But in actual measuring situation, seldom the reference junction temperature is kept at that temperature, it is normally kept at ambient temperature. The third law helps us to compute the actual temperature using the calibration chart. This can be explained from the following example. Example-1 The following table has been prepared from the calibration chart of iron-constantan thermocouple, with reference temperature at 0o C. Version 2 EE IIT, Kharagpur 11
  • 12. Temperature (o C) 15 30 40 .…….. 180 190 200 208 210 emf (mv) 0.778 1.56 2.11 ……… 9.64 10.25 10.74 11.20 11.32 Suppose, the temperature of the hot junction is measured with a iron-constantan thermocouple, with the reference junction temperature at 30o C. If the voltage measured is 9.64mv, find the actual temperature of the hot junction. Solution Referring fig. 6(c), for this problem, T1 is the unknown temperature, T2= 30o C, T3= 0o C. The voltages are e1=9.64mv (measured) and e2= 1.56mv (from chart). Therefore, e3= e1+e2= 11.20mv. Hence, from the calibration chart, the actual hot junction temperature is T1 = 208o C. Reference Junction Compensation From above discussions, it is imminent that the thermocouple output voltage will vary if the reference junction temperature changes. So, for measurement of temperature, it is desirable that the cold junction of the thermocouple should be maintained at a constant temperature. Ice bath can be used for this purpose, but it is not practical solution for industrial situation. An alternative is to use a thermostatically controlled constant temperature oven. In this case, a fixed voltage must be added to the voltage generated by the thermocouple, to obtain the actual temperature. But the most common case is where the reference junction is placed at ambient temperature. For high temperature measurement, the error introduced due to variation of reference junction temperature is not appreciable. For example, with a thermocouple measuring 1500o C, if the ambient temperature variation is within 25 15± o C, then the error introduced in the reading due to this variation would be around 1%. Such a typical scheme is shown in fig. 7. Here a constant voltage corresponding to the ambient temperature is added through the offset of the op-amp. The thermocouple voltage is also amplified by the same op-amp. A more accurate method for reference junction temperature compensation is shown in fig. 8. Here a thermistor, or a RTD is used to measure the ambient temperature and compensate the error through a bridge circuit. The bridge circuit is balanced at 0o C. When the ambient temperature goes above 0o C, the emf generated in the thermocouple is reduced; at the same time bridge unbalanced voltage is added to it in order to maintain the overall voltage at the same value. Version 2 EE IIT, Kharagpur 12 R1 R2 Hot junction Cold junction Offset adjust + - Fig.7 Simple method for reference junction compensation
  • 13. RP R Hot junction Cold junction To amplifierR Thermistor Fig. 8 Compensation scheme using wheatstone bridge As referred to Fig.8, the cold junction compensation is normally kept along with the signal conditioning circuits, away from the measuring point. This may require use of long thermocouple wires to the compensation circuit. In order to reduce the length of costly thermocouple wires (platinum in some case) low-cost compensating wires are normally used in between the thermocouple and the compensation circuit. These wires are so selected that their temperature emf characteristics match closely to those of the thermocouple wires around the ambient temperature. 4. Conclusion Temperature is the most important process variable that requires continuous measurement and monitoring in a process industry. Among the different types of temperature transducers, the most commonly used ones are RTDs and thermocouples. Their popularity is mainly due to their ruggedness, repeatability and wide range of operation. Bare RTDs and thermocouples are rarely used in practice; instead, they are put in protective metallic sheaths. The signal conditioning circuits should be properly designed, so as to avoid the errors due to lead wires in RTDs and variation of cold junction temperatures in thermocouples. There are several cases where the temperature to be measured is more than 2000o C, the conventional measuring techniques fail to measure the high temperature. Instead, the measurement is carried out from a distance. Radiation pyrometers are used in these situations. However, its principle of operation has not been included in this lesson. Review Exercise 1. Name the materials commonly used for RTDs. Which one has the most linear characteristics? 2. What do you mean by lead wire compensation of RTD. How can they be achieved? 3. PT-100 is a Platinum RTD whose resistance at 0o C is 100Ω. If the resistance 4. temperature co-efficient of Platinum is 3 3.91 10X − /o C, then find its resistance at 100o C. 5. What is the difference between a NTC thermistor and a PTC thermistor? 6. A thermistor is more suitable for measurement of temperature within a small range- justify. Version 2 EE IIT, Kharagpur 13
  • 14. 7. Name three types thermocouples and their suitable temperature range. 8. State and explain the laws of thermocouple. 9. What do you mean by cold junction compensation of a thermocouple? Suggest two methods for compensation. 10. A thermocouple has a linear sensitivity of 30µv/o C, calibrated at a cold junction temperature of 0o C. It is used measure an unknown temperature with the cold junction temperature of 30o C. Find the actual hot junction temperature if the emf generated is 3.0 mv. Answers 1. Platinum, Copper, Nickel; Platinum. 3. 139 .Ω 9. 130o C. Version 2 EE IIT, Kharagpur 14