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2. Thermodynamics
A branch of physics in which thermal
effects are studied using macroscopic
quantities.
Macroscopic quantities are:
• Pressure
• Temperature
• Volume
• Internal energy
2
3. Kinetic Theory
Kinetic theory is also concerned with
thermal effects.
But here we assume the existence of
atoms and molecules.
The laws of mechanics and statistics are
applied to a large number of these
molecules.
Microscopic level
3
4. Thermal Equilibrium
If a body (X) at a higher temperature is in
contact with a body (Y) at a lower temperature,
then X will transfer heat energy to the lower
temp object (Y)
This process will continue till the objects attain
the same temperature.
The temp of both objects will become same.
This thermal state in which both bodies are at
the same temp is called thermal equilibrium.
4
5. Using Physical Properties to
Measure Temperature
Many physical properties change with
temperature
• Change in volume (e.g. expansion of a liquid)
• Change in length of a mercury column
• Change in resistance of a wire
• Change in pressure of a gas at constant volume
All these properties can be used in different
types of thermometers
A thermometer is an instrument for
measurement of temperature.
5
6. Imp Definitions
The physical property on which a particular
thermometer is based is called the
thermometric property.
Thermometric substance is the material used in
the thermometer, whose property varies with
temperature
Thermometric property should vary linearly
with temp over a reasonable range of temp
The range of linearity of the thermometric
property is called the thermometric range.
E.g., mercury is a thermometric substance
6
7. Temperature Scales
Each type of thermometer can be used to
establish its own temp scale.
How is this done?
• Every substance changes state at a fixed
temperature. E.g., solid-to-liquid OR liquid-
to-gas
• These fixed temperatures can be used to
define reference temperatures. These
reference temperatures are called fixed
points.
7
8. Temperature Scales
We take the value of the thermometric
property at the two fixed points and
divide the range into a number of EQUAL
steps or degrees.
This way we set up an “empirical scale”
of thermometer.
Empirical => ‘derived from experiment’
8
9. Temperature Scales
E.g., suppose we consider the fixed
points as the melting point of ice (00) and
boiling point of water (1000)
Divide the range from 0 to 100 into 100
equal degrees. This gives the empirical
scale of temperature for that
thermometer.
9
10. Disagreement between Thermometers
The choice of thermometric susbstance
and thermometric property and the
assumed relation between the property
and temperature leads to an individual
temp scale.
Measurements made with such a
thermometer may not agree with
measurements made by any other temp
scale
10
11. Disagreement between Thermometers
This disagreement is removed by the
following:
• Using a particular thermometric substance
• Using a particular thermometric property
• A particular relation between that property
and the temp scale. E.g., a linear relation
between length of a mercury column and
temp
11
12. Determining an unknown Temp
Consider the following graph which shows
the variation of a property P with temp.
Thermometric range
P100
= t2 – t1
Pt
P0
t1 0 t 100 t2
12
Degrees C
13. Determining an unknown Temp
From the st line graph, we get:
P100 - P0
= const
100 - 0
Pt - P0
= const
t-0
13
15. Determining an unknown Temp
Equating the LHS of these eqns we get
100 x (Pt – P0)
t =
(P100 – P0)
15
16. Thermometric Properties
Length varies linearly with temperature
• Give formula
• Used in liquid-in-glass thermometers
Pressure varies linearly with temperature
• Give formula
• Used in constant volume gas thermometers
Volume varies linearly with temperature
• Give formula
• Used in constant pressure gas thermometers
16
17. Thermometric Properties
Resistance varies linearly with temp
• Give formula
• Used platinum resistance thermometers
17
18. Thermometers
Factors to consider while choosing a thermometer
• Accuracy
• Sensitivity (distance between divisions on the scale)
• Range of temps it can measure
• Speed of response – measure rapidly varying
temperatures
• Sensitive part of the thermometer should be small so
that it does not absorb much heat from the object
• It shuld be easy to read – no complicated
calibrations / settings
18
19. Platinum Wire Thermometers
These are based on the variation of electrical resistance
due to temperature
Resistance of a metal wire increases with increase in
temp.
Rt = R0 ( 1 + α t)
Range of temp they can measure is from -260 C to
1700 C
Temp sensor or material is a coil of fine platinum wire
19
20. Platinum Wire Thermometers
Advantages of platinum resistance thermometers:
• High accuracy
• L ow drift
• Wide operating range
Disadvantages of Platinum Thermometers
• Not very sensitive to small changes in temp
• Slow response time
20
21. Thermistor
A thermistor is a type of resistor whose resisatnce
changes with temperature
Therm (heat / temp) + Resistor = Thermistor
Semiconductors are used in these devices
The electrical resistance decreases very rapidly with
increasing temp.
Thus, we say that thermistors have a negative temp
coeff. of resistance (NTC)
21
22. Thermistors
Advantages of thermistors:
• Sensitivity is high
• Their size is very small – hence can be used to measure temp
of small objects
Disadvantages of Thermistors
• Their scale is non-linear
22
23. Thermocouple
This makes use of the thermoelectric effect
Thermoelectric device - A thermoelectric device creates a
voltage when there is a different temperature on each side
When the junctions of two different conductors, such as copper
and constantan wire are at different temperatures, an emf
(voltage) is developed.
The relation between emf and temp diff is not linear.
The emf generated is small – typically about 5 mV for a temp diff
of 100 C
Advantages:
• Can be used to measure rapidly changing temps.
• Can be used to measure temp of small objects
23