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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072
Thermodynamic Analysis of Lithium Bromide-Water(LiBr-H2O) Vapor
Absorption Refrigeration System Based on Solar Energy
Abhishek Ghodeshwar1, Mr.Prashant Sharma2
1M.E.Scholar, Department of Mechanical Engineering, UIT RGPV Bhopal, MP, India
2 Associate Prof. Department of Mechanical Engineering, UIT RGPV Bhopal, MP, India
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract- The continuous and rapid development of
countries ran in a monumental increase in the demand of
energy utilization. For this entailment of renewable energy,
such as solar energy for an eco-friendly process of
refrigeration by Vapor Absorption process is looked to be a
blessing in present scenario. Putting back the electricalenergy
with solar energy will shorten the use of high grade electrical
energy. Solar energy based refrigeration system is one of the
best assuring technology to fulfill the boosting demand for
refrigeration purpose. A solar dr-ivan Lithium-Bromide
absorption cooling system was studied. It was an intermittent
system in which water used as a refrigerant and Li-br used as
a absorber. This paper provides an analytical approach to the
study of the vapor absorption refrigeration system. By the
application of first and second Law of thermodynamics with
Mass and energy balance equation. The main aim of this work
is to study of Lithium Bromide- Water (LiBr-H2O) absorption
System with the Capacity of 1.5 ton. The various components
of VARS system Absorber, Heat-exchanger, Generator,
Condenser, Expansion Valve and Evaporator. the COP of the
system is calculated on the basis of hot water as a heat source.
The basic idea of this work is taken from solar water heating
system.
Key Words- Vapor absorption system, Refrigerants,
Coefficient of performance(COP),Solar heating,
Environments.
1.INTRODUCTION
In 1858 a French scientist named Ferdinand Carré
invented an absorption cooling system using water and
sulphuric acid. In 1922 Baltzar Platen and Carl Munters,
improved the system in principle with a 3-fluid
configuration. This "Platen-Munters" design was capable of
operating without a pump.
During 1926-1933 Einstein and Szilárd joined hands to
improve the technology in the area of domesticrefrigeration.
The two were inspired by newspaper reports of the death of
a Berlin family due to seal failure,which caused a leakage of
toxic fumes into their home. Einstein and Szilárd proposeda
device without moving parts that would eliminate the
potential for seal failure, and worked on its practical
applications for various refrigeration cycles. The two in due
course were granted 45 patents in their names for three
different models.
The main technical problem of solar refrigeration is that the
system is highly dependent upon environmental factors such
ascooling water temperature, air temperature, solarradiation,
wind speed and others. On the other hand, its energy
conversion efficiency is low, and from an economical point of
view, solar cooling and refrigeration are not competitive with
the conventional systems. At the same time by use of solar
energy we can reduce the load of conventional fuels ,which are
directly responsible for environmental pollution. Solarcooling
eliminates the use of refrigerants like CFC, HFC highly
hazardous for Ozone.
In recent developments of thermal engineering the
Refrigeration technologies play an important role in today's
industrial applications [1].
But asfar asCOP of these refrigeration systemsisconcerned,it
is always a challenge to the researchers to significantly
increase the COP for these systems. The most popular
refrigeration and air conditioning systemsat presentarethose
based on the vapor absorption systems. These systems are
popular because they are reliable, relatively inexpensive and
their technology is well established. However, these systems
require high grade energy (mechanical or electrical) for their
operation. Apart from this, the recent discovery that the
conventional working fluids of vapor absorption systems are
causing the ozone layer depletion and greenhouse effects has
forced the scientific researchersto look for alternativesystems
for cooling applications. The natural alternativeisofcoursethe
absorption system, which mainly uses heat energy for its
operation. Moreover, the working fluids of these systems are
environment friendly [2].
A suitable working fluid is probably the single most important
factor in any refrigeration system. The cycle efficiency and
Operating characteristicsof an absorptionrefrigerationsystem
depend on the properties of refrigerant, absorbent and their
mixtures. The most important thermo-physical properties are
heat of vaporization of refrigerant, heat of solution, vapor
pressure of refrigerant and absorbent, solubility of refrigerant
insolvent, heat capacity of solution, viscosity of solution and
surface tension and thermal conductivity of the solution.Apart
from this, the other selection criteria for the working fluidsare
their toxicity, chemical stability and corrosively. Vapor
Absorption Refrigeration Systems belong to the class of vapor
cycles similar to vapor absorption refrigeration systems.
However, unlike vapor absorption refrigeration systems, the
required input to absorption systems is in the form of heat.
Hence, these systems also called as heat operated or thermal
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1365
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072
energy driven systems. Both vapor absorption and
absorption refrigeration cycles accomplish the removal of
heat through the evaporation of a refrigerant at a low
pressure and the rejection of heat through the condensation
of the refrigerant at a higher pressure. The basicdifferenceis
that a vapor absorption system employs a mechanical
compressor to create the pressure differences necessary to
circulate the refrigerant whereas an absorptionsystem uses
heat source and the differences cause an absorption system
to use little to no work input, but energy must be supplied in
the form of heat. This makes the system very attractivewhen
there is a cheap source of heat, such as solar heat or waste
heat from electricity or heat generation [3].
Fig-1. Method of transforming low pressure vapor into
high pressure vapor in a refrigeration system.
Vapor Absorption Systems offer many advantages like it
offers flexibility to utilize any sort of low grade, lowcostheat
energy available to produce cooling and thus giving a high
savings in operating costs. It can operate on steam or any
other waste heat source as the energy source instead of
costly and unreliable electric power. No movingpartsensure
noiseless, vibration-less and trouble free operation.
Moreover maintenance costs are negligible as compared to
power driven mechanical systems. Refrigerating effect is
produced using a clean refrigerant in place of ozone-
depleting chlorine based compounds[2].
2. PRINCIPLE OF ABSORPTION SYSTEM
The working fluid in an absorption refrigeration system is a
binary solution consisting of refrigerant and absorbent. In
Fig. 2(a), two evacuated vessels are connected to each other.
The left vessel contains liquid refrigerant while the right
vessel contains a binary solution of absorbent/refrigerant.
The solution in the right vessel will absorb refrigerantvapor
from the left vessel causing pressure to reduce. While the
refrigerant vapor is being absorbed, the temperature of the
remaining refrigerant will reduce as a result of its
vaporization. This causes a refrigeration effect to occur
inside the left vessel. At the same time, solution inside the
right vessel becomes more dilute because of the higher
content of refrigerant absorbed. This is called the “absorption
process”. Normally, the absorption process is an exothermic
process, therefore, it must reject heat out to the surroundingin
order to maintain its absorption capability. Whenever the
solution cannot continue with the absorption process because
of saturation of the refrigerant, the refrigerant must be
separated out from the diluted solution. Heat is normally the
key for this separation process. It is applied to the right vessel
in order to dry the refrigerant from the solution as shown in
Fig. 2(b). The refrigerant vapor will be condensed by
transferring heat to the surroundings. With these processes,
the refrigeration effect can be produced by using heat energy.
Fig.-2(a) Absorption process occurs in right vessel causing
cooling effect in the other;
Fig-2(b) The Refrigerant separation process occurs in the
right vessel as a result of additional heat from outside heat
source.
3. Components of a Vapor Absorption Cooling
System
The components of Vapor Absorption Refrigeration Cooling
System are as[4].
Generator: The purpose of the generator is to deliver the
refrigerant vapor to the rest of the system. It accomplishesthis
by separating refrigerant from the solution. In then generator,
the solution vertically falls over horizontal tubes with high
temperature energy source typically steam or hot water
flowing through the tubes. The solution absorbs heat from the
warmer steam or water, causing the refrigerant to boil
(vaporize) and separate from the absorbent solution. As the
refrigerant is boiled away, the absorbent solution becomes
more concentrated. The concentrated absorbent solution
returns to the absorber and the refrigerant vapor migrates to
the condenser.
Condenser: The purpose of the condenser is to condense the
refrigerant vapors. Inside the condenser, cooling water flows
through tubes and the hot refrigerant vapor fills the
surrounding space. As heat transfers from the refrigerant
vapor to the water, refrigerant condenses on the tube surfaces.
The condensed liquid refrigerant collects in the bottom of the
condenser before travelling to the expansion device. The
cooling water system is connected to a cooling tower.
Expansion Valve: From the condenser, the liquid refrigerant
flows through an expansion device into the evaporator. The
expansion device is used to maintain the pressure difference
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1366
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072
between the high-pressure (condenser) and low-pressure
(evaporator) sides of the refrigeration system. As the high-
pressure liquid refrigerant flows through the expansion
device, it causes a pressure drop that reducestherefrigerant
pressure to that of the evaporator. This pressure reduction
causes a small portion of the liquid refrigerant to boil off,
cooling the remaining refrigerant to the desired evaporator
temperature. The cooled mixture of liquid and vapor
refrigerant then flows into the evaporator.
Evaporator: The purpose of evaporator is to cool the
circulating water. The evaporator containsa bundle oftubes
that carry the system water to be cooled/chilled. At low
pressure existing in the evaporator, the refrigerant absorbs
heat from the circulating water and evaporates. The
refrigerant vapors thusformed tend to increasethepressure
in the vessel. This will in turn increase the boiling
temperature and the desired cooling effect will not be
obtained. So, it is necessary to remove the refrigerantvapors
from the vessel into the lower pressure absorber. Physically,
the evaporator and absorber are contained inside the same
shell, allowing refrigerant vapors generated in the
evaporator to migrate continuously to the absorber.
Absorber: Inside the absorber, the refrigerant vapor is
absorbed by the solution. As the refrigerant vapor is
absorbed, it condenses from a vapor to a liquid, releasingthe
heat it acquired in the evaporator. The heat released from
the condensation of refrigerant vaporsbytheirabsorptionin
the solution is removed by the cooling water circulating
through the absorber tube bundle. The weak absorbent
solution is then pumped to the generator whereheat is used
to drive off the refrigerant. The hot refrigerant vapors
created in the generator migrate to the condenser. The
cooling tower water circulating through thecondenserturns
the refrigerant vapors to a liquid state and picks up the heat
of condensation, which it rejects to the cooling tower. The
liquid refrigerant returns to the evaporator and completes
the cycle.
3. Refrigerent-Absorbent combinations for Vapor
Absorption Cooling Systems
Absorption machines are commercially available today in
two basic configurations. For applications above 500C
(primarily air-conditioning) the cycle uses lithium
bromide/water.
For applications below 500C ammonia/water cycle is
employed with ammonia as the refrigerant and water as the
absorbent.
4.Desirable Properties of Refrigerant-Absorbent
mixtures
Refrigerant-absorbent mixtures for Vapor Absorption
Cooling System should possess some desirable properties
like the refrigerant should be more volatile than the
absorbent in other words the boiling point of refrigerant
should be much lower than the absorbent.
There must be large difference in the boiling points of
refrigerant and absorbent (greater than 2000 0C), so that the
solution in the Generator need only to be heated to the
temperature required to boil off only the refrigerant. This
ensures that only pure refrigerant circulates through
refrigerant circuit (condenser-expansion valve-evaporator).
The refrigerant should exhibit high solubility with solution in
the absorber. The absorbent should have strong affinityforthe
refrigerant. This will minimize the amount of refrigerant to be
circulated. Operating pressures should be preferably low, so
that the wallsof the shellsand connecting pipes need not to be
thick. It should not undergo crystallization or solidification
inside the system. Because crystallization will block the free
flow of solution in the line. The mixture should be safe,
chemically stable, non-corrosive, inexpensive and should be
available easily. The refrigerant should have high heat of
vaporization[5], [6].
5. Refrigerant-Absorbent pairs
The two most commonly used refrigerant-absorbent pairs in
commercial systems are[6]:
5.1. Water-Lithium Bromide (H2O-LiBr) system for
moderate temperatures(above 500C) applications specifically
air conditioning. Here water is the refrigerant and lithium
bromide is the absorbent.
5.2. Ammonia-Water (NH3-H2O) system for low
temperature(less than 500C) refrigeration applications with
ammonia as refrigerant and water as absorbent.
The Lithium Bromide-Water pair satisfies majority of the
above listed properties. For these reasons Li-Br and Water
systems are becoming more popular. Comparison of Lithium
Bromide-Water systems and Ammonia-Water Systems
6. Ammonia-Water Systems
Since the invention of absorption refrigeration system, NH3-
Water has been widely used. Both NH3 (refrigerant) and water
(absorbent) are highly stable for a wide range of operating
temperature and pressure. NH3 has a high latent heat of
vaporization, which is necessary for efficient performance of
the system. It can be used for low temperature applications, as
the freezing point of NH3is -77°C. But since both NH3 andwater
are volatile, the cycle requires a rectifier to strip away water
that normally evaporates with NH3 .Without a rectifier, the
water would accumulate in the evaporator and offset the
system performance. There are other disadvantagessuchasits
high pressure, toxicity, and corrosive action to copper and
copper alloy. Ammonia/Air mixtures are barely inflammable
but may be explosive in the case of high percentages of
ammonia between 15.5 and 27 % by volume[7].
7.LiBr-Water Systems
The use of LiBr-Water for absorption refrigeration systems
began around 1930. Two outstanding features of LiBr-Water
are non-volatility absorbent of LiBr (the need of a rectifier is
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1367
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072
eliminated) and extremely high heat of vaporizationofwater
(refrigerant). However, using water as a refrigerant limits
the low temperature application to that above 0°C. As water
is the refrigerant, the system must be operated under
vacuum conditions. At high concentrations, the solution is
prone to crystallization. One way to prevent thistohappenis
to add one or more extra salts e.g., ZnBr2, ZnCl2 .The
addition of the third component into the basicwater-lithium
bromide solution pushesthe crystallization limitaway from
the normal operating zone. Hence the strong solution can be
cooled in the heat exchanger to near absorber temperature
without salt crystallization, thusimproving theperformance
of the system. COP is high (0.7 to 0.9) as compared to (0.5
to 0.6) for Ammonia-Water systems[8],[9].
8.MATHEMATICAL ANALYSIS OF THE SYSTEM
Thermodynamic analysis of the system involves finding
important parameters like enthalpy, mass flow rates, flow
ratio, Heat and Mass Transfers for the whole system to
finally calculate the system CoefficientofPerformance(COP).
These values are to be then used for design of the system.
First some set of thermodynamic equations have been
derived in terms of massflow rates and enthalpybyapplying
mass and energy balance for each component. Then the
actual system conditions like temperature, pressures,
enthalpies are substituted in the equations to finally obtain
the COP value for the system [10], [11].Thermodynamic
analysis of the system is carried out with the following
assumptions:
A. Steady state and steady flow.
B. No pressure drops due to friction.
C .Only pure refrigerant boils in the generator.
Fig.3 Block diagram of Vapor Absorption Refrigeration
System.
Let,
m = mass flow rate of refrigerant, kg/s
mss = mass flow rate of strong solution, kg/s
mws = mass flow rate of weak solution, kg/
Heat (Q) and Mass (m) balance for each component
For Condenser
m7 =m8=m
Qc =m(h7-h8), kJ/s
For Expansion Valve
m8 =m9=m
h8=h9(isenthalpic), kJ / kg
For Evaporator
m9 =m8=m
Qe=m(h9-h8), kJ/s
For Absorber
From total Mass balance
m+mss=mws
Now
Circulation Ratio,
λ=mss/m
Therefore, mws=(1+λ)m
From Mass balance of pure water
m+(1+ξss)mss=(1+ξws)mws
Solving for λ we get,
λ= ξws/ (ξss- ξws)
and
Qa=mh10+λmh6 -(1+λ)mh1, KJ/s
Solution for Pump
m1=m2=mws
wp=(1+λ)mV sol(pc-pE) kJ/s
where Vsol . is specific volume of solution which can be taken
as approx. 0.00055 m3/kg.
For Heat Exchanger
m2=m3=mws
m4=m5=mss
QHX =(1+λ)m(h3-h2)=λm(h4-h5),kJ/s
For Generator
m3=m4+m7
Heat input to the Generator,
Qg=mh7+λmh4-(1+λ)m3, kJ/s
Coefficient of Performance (COP):
In this system the net refrigerating effect is the heat absorbed
by the refrigerant in the evaporator. The total energy supplied
to the system is the sum of work done by the pump and the
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1368
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072
heat supplied in the generator. Therefore, the Coefficient of
performance (COP) of the system is given by-
COP = Heat Absorbed in the Evaporator
( Work done by pump +Heat
Supplied in the Generator )
COP = Qe/(Qg+Wp)
Neglecting the Pump work
COP=Qe/Qg
Isthe expression for Coefficient of Performance(COP) of the
System.
9.MATHEMATICAL CALCULATIONS FOR EACH
COMPONENT
9.1 The operating temperatures chosen in ℃
Generator Temperature, Tg =60℃
Condenser Temperature, Tc = 28℃
Absorber Temperature, Ta =21℃
Evaporator Temperature, Te =5℃
9.2 The Operating Pressures in mm of Hg
The operating Pressurescan be known correspondingtothe
temperatures. Say for example the saturation pressure for
condensation in the Condenser at 28℃ can be obtainedfrom
steam tables and is equal to 0.03779bar. Also 1bar =
750.06mm of Hg.
Therefore 0.03779bar= 28.50mm of Hg which is also equal
to Generator pressure because Condenser and Generator
operate at same pressure. Now the saturation pressure for
saturated vapors formed in Evaporator at a temperature of
5℃ can again be obtained from steam table which comes to
be 0.00872bar or 6.54mm of Hg which will also be equal to
the Absorber pressure asboth operate undersamepressure.
9.3 Capacity of the system or Refrigerating Effect
(Qe)= 1.5ton = 5.25kW
9.4 Calculation of Enthalpy (h) at every designated
point of the system:
Enthalpy of pure water and of superheated water vapors at
any temperature can be determined from steam tables.
Enthalpies of solutions are calculated from Lithiumbromide
(LiBr) and Water Pressure-Temperature-Concentration-
Enthalpy(P-T-ξ-h) Chart.
Fig.4-LiBr-H2O Pressure-Temperature Concentration-
Enthalpy Chart
Table I: Li-Br-Water Enthalpy-Pressure-Temperature-
Concentration
State Temp.in Pressure Enthalpy Concentration
Points
℃
in mm h ,Kj/kg ξ
of Hg
7 60 28.50 2609.65 -
8 28 28.50 117.30 -
9 28 6.54 117.30 -
10 5.0 6.54 2509.96 -
1 21 6.54 -170.0 0.48
2 21 28.50 -170.0 0.48
3 52.25 28.50 -110.004 0.48
4 60 28.50 -108.0 0.56
5 21 28.50 -178.0 0.56
6 21 6.54 -178.0 0.56
9.5 Calculation of Heat transfers for each component
Evaporator:-Applying the Energy balance
Qe = Refrigerating effect = 5.25kW = m(h10 - h9 )
=m × (2509.96 -117.30)
m = 5.25/ (2509.96- 117.30)
or
m = 2.19421×10-3 kg/s = mass flow rate of refrigerant.
Now,
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1369
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072
Circulation Ratio
λ = ξWS/( ξSS- ξWS)
λ = 0.48/(0.56-0.48)
= 6
therefore, mss.= λ × m=13.1652 ×10-3kg/s
and
mws=(1+ λ)m=(1+6) ×2.1942 ×10-3 =15.3594 ×10-3 kg/s
Absorber: Applying the Energy balance
Qa=mh10+mssh6-mwsh1
= (2.19421×10-3 ×2509.96) + (13.1652×10-3 × -178)
- (15.354×10-3 × -170)
= 577435W = 5.7743 KW
Solution Heat Exchanger (HX) Energy balance for Heat
Exchanger,
mws×(h3×-h2)=mss×(h4-h5)
=15.3594×10- 3× (h3+-170)=13.16526×10- 3
× (-108+178)
h3=110.0041 KJ/kg
Generator
QG = mh7 + mssh4 - mwsh3
= (2.19421×10- 3 ×2609.655) + (13.1652×10- 3 × -108)
- (15.3594×10- 3 ×-110.0041)
= 59938W = 5.993KW
Condenser
Qc = m(h7-h8)
= 2.19421×10-3 × (2609.655-117.30)
= 54687W = 5.4687kW
Thus,
COP = QE/ QG
= 5250/5993
= 0.876
9.6 Calculation of solar Collector
Useful energy (energy absorbed by the collector plate) is
given by,
Qu = K x S x A
Where,
K = efficiency of collector plate(assuming k=0.85)
S = average solar heat falling on earth’s surface
= 6kW/hr/m2/day=250W/m2
A = area of collector plates
Now
Heat required in the generator,
Qg = 5993Watt
Hence approximate area of the collector plates required for
providing the above amount of energy
= 5993/ (250xK)
= 5993/(250x0.85)
= 28.20Sq.m
Total area of collector plates A = 28.20Sq.m
Therefore we can use 5 collector plates having dimension of
3x2 Sq.m.
Thus,
Qu = 0.85x 250x 28.20 = 5993W = 5993 J/Sec
The energy absorbed by the collector helps in heating of the
water flowing in the tubes of the collector plates.
U= m x Cp
(T
o
- T
i
)
Let the rate of water flowing through the tubes,
m= 1.2Kg/min
= 0.02kg/s, (example)
Specific heat of water, Cp= 4.187 KJ/KgK
To =outlet temperature of water in the collector
Ti = inlet temperature of water in the collector
plates
= 210C
Therefore,
Qu = 0.02 x 4187 x (To -21) = 5993 = 92.0C
The temperature, To should be the inlet temperature of
generator, but assuming water loses heat while flowing
through the pipes. Also there is certain effectiveness of the
generator as a heat exchanger, less than 100%. Hence net
heating in the generator can be assumed to be taking place at
600C.
Temperature at generator = 600C
This is the net heat input to the system, which is running as a
refrigeration unit of 5.25kW capacity.
COP of the system-
The COP of the unit can be calculated by the following
equation:
COP = Refrigeration effect / heat input in generator
COP = Qe/ Qg
= 5250/59938
= 0.876
The COP of the system including Solar water heater
Net refrigeration effect
heat input at the solar
collector
COP = 0.876
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1370
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072
Heat input at the solar collector = Solar constant x Area
= 250W/m2 x 28.20 m2
= 7050 W
COP = 5250 W/7050 W
= 0.7446
Hence the theoretical COP of the system comes to be
0.7446
10 Results –
The Evaporator is a chamber that has to be maintain at the
low temperature but the main objective of the study isnotto
attain very low value of evaporator temperature but to
provide the desired cooling effect. the Condenser and
Absorber are maintained to be at a temperature of 280C
and 210C respectively. Generator at maintain at the
temperature of 600C.
Table.2. Components Wise heat capacity of Different
systems
11. Conclusion-
A small capacity (1.5ton) intermittent vapor absorption
refrigeration system using LiBr-H2O solution was designed
based on some thermodynamic correlations. By analytical
calculation the COP was 0.876.it was ascertained that the
solar collector efficiency, clearness of sky play a big role for
overall efficiency. The study suggests that, with a accurate
theoretical design and thermodynamics analysis there is a
scope for improving the performance of vapor absorption
refrigeration system applying low grade thermal energy
source. COP of the system is greatly acted upon the system
temperature. The heat input can be provided by solar
collector. It brings into light that solar collector can not only
be used for heating, it can also be used for cooling purpose.
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World Congress – Napoli (I), 15-18 September 2001.
[9] Piyush Mahendru, S.K.Agrawal, P.Pachorkar, " Steady
State Analysis Of Vapor Absorption Refrigeration System
Using Li-Br-H2o As A Refrigerant " International Journal Of
Emerging Technology And Advanced Engineering, Volume 2,
Issue 9, September 2012, Pp 328-332.
[10] Micallef,D. And Micallef, C, "Mathematical Model Of
Vapor Absorption Refrigeration Unit" Int.J Simul Model 9, 2 ,
2010, Pp 86-97.
[11] Subhadip Roy, M.P. Maiya "Analysis Of R134a–Dmac
Vapour Absorption Refrigeration System With Add-On
Components" International Journal Of Sustainable Built
Environment, Sciverse Sciencedirect, 1, 2012, Pp 26–35.
Pp-1248-1254.
COP = 0.7446
S.No. COMPONENT HEAT TRANSFER
RATE
VALUES
1 Evaporator QE 5.250
2 Absorber QA 5.774
3 Generator QG 5.933
4 Condenser QC 5.468
[12] Dr. Nimai Mukhopadhyay,Er.SomeshwarChowdhury, "
Performance Analysis Of Solar Assisted Cascade
Refrigeration System Of Cold Storage System" International
Journal Of Advanced Research In Electrical, Electronics And
Instrumentation Engineering Vol. 2, Issue 4, April 2013,
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1371

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Thermodynamic Analysis

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072 Thermodynamic Analysis of Lithium Bromide-Water(LiBr-H2O) Vapor Absorption Refrigeration System Based on Solar Energy Abhishek Ghodeshwar1, Mr.Prashant Sharma2 1M.E.Scholar, Department of Mechanical Engineering, UIT RGPV Bhopal, MP, India 2 Associate Prof. Department of Mechanical Engineering, UIT RGPV Bhopal, MP, India ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract- The continuous and rapid development of countries ran in a monumental increase in the demand of energy utilization. For this entailment of renewable energy, such as solar energy for an eco-friendly process of refrigeration by Vapor Absorption process is looked to be a blessing in present scenario. Putting back the electricalenergy with solar energy will shorten the use of high grade electrical energy. Solar energy based refrigeration system is one of the best assuring technology to fulfill the boosting demand for refrigeration purpose. A solar dr-ivan Lithium-Bromide absorption cooling system was studied. It was an intermittent system in which water used as a refrigerant and Li-br used as a absorber. This paper provides an analytical approach to the study of the vapor absorption refrigeration system. By the application of first and second Law of thermodynamics with Mass and energy balance equation. The main aim of this work is to study of Lithium Bromide- Water (LiBr-H2O) absorption System with the Capacity of 1.5 ton. The various components of VARS system Absorber, Heat-exchanger, Generator, Condenser, Expansion Valve and Evaporator. the COP of the system is calculated on the basis of hot water as a heat source. The basic idea of this work is taken from solar water heating system. Key Words- Vapor absorption system, Refrigerants, Coefficient of performance(COP),Solar heating, Environments. 1.INTRODUCTION In 1858 a French scientist named Ferdinand Carré invented an absorption cooling system using water and sulphuric acid. In 1922 Baltzar Platen and Carl Munters, improved the system in principle with a 3-fluid configuration. This "Platen-Munters" design was capable of operating without a pump. During 1926-1933 Einstein and Szilárd joined hands to improve the technology in the area of domesticrefrigeration. The two were inspired by newspaper reports of the death of a Berlin family due to seal failure,which caused a leakage of toxic fumes into their home. Einstein and Szilárd proposeda device without moving parts that would eliminate the potential for seal failure, and worked on its practical applications for various refrigeration cycles. The two in due course were granted 45 patents in their names for three different models. The main technical problem of solar refrigeration is that the system is highly dependent upon environmental factors such ascooling water temperature, air temperature, solarradiation, wind speed and others. On the other hand, its energy conversion efficiency is low, and from an economical point of view, solar cooling and refrigeration are not competitive with the conventional systems. At the same time by use of solar energy we can reduce the load of conventional fuels ,which are directly responsible for environmental pollution. Solarcooling eliminates the use of refrigerants like CFC, HFC highly hazardous for Ozone. In recent developments of thermal engineering the Refrigeration technologies play an important role in today's industrial applications [1]. But asfar asCOP of these refrigeration systemsisconcerned,it is always a challenge to the researchers to significantly increase the COP for these systems. The most popular refrigeration and air conditioning systemsat presentarethose based on the vapor absorption systems. These systems are popular because they are reliable, relatively inexpensive and their technology is well established. However, these systems require high grade energy (mechanical or electrical) for their operation. Apart from this, the recent discovery that the conventional working fluids of vapor absorption systems are causing the ozone layer depletion and greenhouse effects has forced the scientific researchersto look for alternativesystems for cooling applications. The natural alternativeisofcoursethe absorption system, which mainly uses heat energy for its operation. Moreover, the working fluids of these systems are environment friendly [2]. A suitable working fluid is probably the single most important factor in any refrigeration system. The cycle efficiency and Operating characteristicsof an absorptionrefrigerationsystem depend on the properties of refrigerant, absorbent and their mixtures. The most important thermo-physical properties are heat of vaporization of refrigerant, heat of solution, vapor pressure of refrigerant and absorbent, solubility of refrigerant insolvent, heat capacity of solution, viscosity of solution and surface tension and thermal conductivity of the solution.Apart from this, the other selection criteria for the working fluidsare their toxicity, chemical stability and corrosively. Vapor Absorption Refrigeration Systems belong to the class of vapor cycles similar to vapor absorption refrigeration systems. However, unlike vapor absorption refrigeration systems, the required input to absorption systems is in the form of heat. Hence, these systems also called as heat operated or thermal © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1365
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072 energy driven systems. Both vapor absorption and absorption refrigeration cycles accomplish the removal of heat through the evaporation of a refrigerant at a low pressure and the rejection of heat through the condensation of the refrigerant at a higher pressure. The basicdifferenceis that a vapor absorption system employs a mechanical compressor to create the pressure differences necessary to circulate the refrigerant whereas an absorptionsystem uses heat source and the differences cause an absorption system to use little to no work input, but energy must be supplied in the form of heat. This makes the system very attractivewhen there is a cheap source of heat, such as solar heat or waste heat from electricity or heat generation [3]. Fig-1. Method of transforming low pressure vapor into high pressure vapor in a refrigeration system. Vapor Absorption Systems offer many advantages like it offers flexibility to utilize any sort of low grade, lowcostheat energy available to produce cooling and thus giving a high savings in operating costs. It can operate on steam or any other waste heat source as the energy source instead of costly and unreliable electric power. No movingpartsensure noiseless, vibration-less and trouble free operation. Moreover maintenance costs are negligible as compared to power driven mechanical systems. Refrigerating effect is produced using a clean refrigerant in place of ozone- depleting chlorine based compounds[2]. 2. PRINCIPLE OF ABSORPTION SYSTEM The working fluid in an absorption refrigeration system is a binary solution consisting of refrigerant and absorbent. In Fig. 2(a), two evacuated vessels are connected to each other. The left vessel contains liquid refrigerant while the right vessel contains a binary solution of absorbent/refrigerant. The solution in the right vessel will absorb refrigerantvapor from the left vessel causing pressure to reduce. While the refrigerant vapor is being absorbed, the temperature of the remaining refrigerant will reduce as a result of its vaporization. This causes a refrigeration effect to occur inside the left vessel. At the same time, solution inside the right vessel becomes more dilute because of the higher content of refrigerant absorbed. This is called the “absorption process”. Normally, the absorption process is an exothermic process, therefore, it must reject heat out to the surroundingin order to maintain its absorption capability. Whenever the solution cannot continue with the absorption process because of saturation of the refrigerant, the refrigerant must be separated out from the diluted solution. Heat is normally the key for this separation process. It is applied to the right vessel in order to dry the refrigerant from the solution as shown in Fig. 2(b). The refrigerant vapor will be condensed by transferring heat to the surroundings. With these processes, the refrigeration effect can be produced by using heat energy. Fig.-2(a) Absorption process occurs in right vessel causing cooling effect in the other; Fig-2(b) The Refrigerant separation process occurs in the right vessel as a result of additional heat from outside heat source. 3. Components of a Vapor Absorption Cooling System The components of Vapor Absorption Refrigeration Cooling System are as[4]. Generator: The purpose of the generator is to deliver the refrigerant vapor to the rest of the system. It accomplishesthis by separating refrigerant from the solution. In then generator, the solution vertically falls over horizontal tubes with high temperature energy source typically steam or hot water flowing through the tubes. The solution absorbs heat from the warmer steam or water, causing the refrigerant to boil (vaporize) and separate from the absorbent solution. As the refrigerant is boiled away, the absorbent solution becomes more concentrated. The concentrated absorbent solution returns to the absorber and the refrigerant vapor migrates to the condenser. Condenser: The purpose of the condenser is to condense the refrigerant vapors. Inside the condenser, cooling water flows through tubes and the hot refrigerant vapor fills the surrounding space. As heat transfers from the refrigerant vapor to the water, refrigerant condenses on the tube surfaces. The condensed liquid refrigerant collects in the bottom of the condenser before travelling to the expansion device. The cooling water system is connected to a cooling tower. Expansion Valve: From the condenser, the liquid refrigerant flows through an expansion device into the evaporator. The expansion device is used to maintain the pressure difference © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1366
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072 between the high-pressure (condenser) and low-pressure (evaporator) sides of the refrigeration system. As the high- pressure liquid refrigerant flows through the expansion device, it causes a pressure drop that reducestherefrigerant pressure to that of the evaporator. This pressure reduction causes a small portion of the liquid refrigerant to boil off, cooling the remaining refrigerant to the desired evaporator temperature. The cooled mixture of liquid and vapor refrigerant then flows into the evaporator. Evaporator: The purpose of evaporator is to cool the circulating water. The evaporator containsa bundle oftubes that carry the system water to be cooled/chilled. At low pressure existing in the evaporator, the refrigerant absorbs heat from the circulating water and evaporates. The refrigerant vapors thusformed tend to increasethepressure in the vessel. This will in turn increase the boiling temperature and the desired cooling effect will not be obtained. So, it is necessary to remove the refrigerantvapors from the vessel into the lower pressure absorber. Physically, the evaporator and absorber are contained inside the same shell, allowing refrigerant vapors generated in the evaporator to migrate continuously to the absorber. Absorber: Inside the absorber, the refrigerant vapor is absorbed by the solution. As the refrigerant vapor is absorbed, it condenses from a vapor to a liquid, releasingthe heat it acquired in the evaporator. The heat released from the condensation of refrigerant vaporsbytheirabsorptionin the solution is removed by the cooling water circulating through the absorber tube bundle. The weak absorbent solution is then pumped to the generator whereheat is used to drive off the refrigerant. The hot refrigerant vapors created in the generator migrate to the condenser. The cooling tower water circulating through thecondenserturns the refrigerant vapors to a liquid state and picks up the heat of condensation, which it rejects to the cooling tower. The liquid refrigerant returns to the evaporator and completes the cycle. 3. Refrigerent-Absorbent combinations for Vapor Absorption Cooling Systems Absorption machines are commercially available today in two basic configurations. For applications above 500C (primarily air-conditioning) the cycle uses lithium bromide/water. For applications below 500C ammonia/water cycle is employed with ammonia as the refrigerant and water as the absorbent. 4.Desirable Properties of Refrigerant-Absorbent mixtures Refrigerant-absorbent mixtures for Vapor Absorption Cooling System should possess some desirable properties like the refrigerant should be more volatile than the absorbent in other words the boiling point of refrigerant should be much lower than the absorbent. There must be large difference in the boiling points of refrigerant and absorbent (greater than 2000 0C), so that the solution in the Generator need only to be heated to the temperature required to boil off only the refrigerant. This ensures that only pure refrigerant circulates through refrigerant circuit (condenser-expansion valve-evaporator). The refrigerant should exhibit high solubility with solution in the absorber. The absorbent should have strong affinityforthe refrigerant. This will minimize the amount of refrigerant to be circulated. Operating pressures should be preferably low, so that the wallsof the shellsand connecting pipes need not to be thick. It should not undergo crystallization or solidification inside the system. Because crystallization will block the free flow of solution in the line. The mixture should be safe, chemically stable, non-corrosive, inexpensive and should be available easily. The refrigerant should have high heat of vaporization[5], [6]. 5. Refrigerant-Absorbent pairs The two most commonly used refrigerant-absorbent pairs in commercial systems are[6]: 5.1. Water-Lithium Bromide (H2O-LiBr) system for moderate temperatures(above 500C) applications specifically air conditioning. Here water is the refrigerant and lithium bromide is the absorbent. 5.2. Ammonia-Water (NH3-H2O) system for low temperature(less than 500C) refrigeration applications with ammonia as refrigerant and water as absorbent. The Lithium Bromide-Water pair satisfies majority of the above listed properties. For these reasons Li-Br and Water systems are becoming more popular. Comparison of Lithium Bromide-Water systems and Ammonia-Water Systems 6. Ammonia-Water Systems Since the invention of absorption refrigeration system, NH3- Water has been widely used. Both NH3 (refrigerant) and water (absorbent) are highly stable for a wide range of operating temperature and pressure. NH3 has a high latent heat of vaporization, which is necessary for efficient performance of the system. It can be used for low temperature applications, as the freezing point of NH3is -77°C. But since both NH3 andwater are volatile, the cycle requires a rectifier to strip away water that normally evaporates with NH3 .Without a rectifier, the water would accumulate in the evaporator and offset the system performance. There are other disadvantagessuchasits high pressure, toxicity, and corrosive action to copper and copper alloy. Ammonia/Air mixtures are barely inflammable but may be explosive in the case of high percentages of ammonia between 15.5 and 27 % by volume[7]. 7.LiBr-Water Systems The use of LiBr-Water for absorption refrigeration systems began around 1930. Two outstanding features of LiBr-Water are non-volatility absorbent of LiBr (the need of a rectifier is © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1367
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072 eliminated) and extremely high heat of vaporizationofwater (refrigerant). However, using water as a refrigerant limits the low temperature application to that above 0°C. As water is the refrigerant, the system must be operated under vacuum conditions. At high concentrations, the solution is prone to crystallization. One way to prevent thistohappenis to add one or more extra salts e.g., ZnBr2, ZnCl2 .The addition of the third component into the basicwater-lithium bromide solution pushesthe crystallization limitaway from the normal operating zone. Hence the strong solution can be cooled in the heat exchanger to near absorber temperature without salt crystallization, thusimproving theperformance of the system. COP is high (0.7 to 0.9) as compared to (0.5 to 0.6) for Ammonia-Water systems[8],[9]. 8.MATHEMATICAL ANALYSIS OF THE SYSTEM Thermodynamic analysis of the system involves finding important parameters like enthalpy, mass flow rates, flow ratio, Heat and Mass Transfers for the whole system to finally calculate the system CoefficientofPerformance(COP). These values are to be then used for design of the system. First some set of thermodynamic equations have been derived in terms of massflow rates and enthalpybyapplying mass and energy balance for each component. Then the actual system conditions like temperature, pressures, enthalpies are substituted in the equations to finally obtain the COP value for the system [10], [11].Thermodynamic analysis of the system is carried out with the following assumptions: A. Steady state and steady flow. B. No pressure drops due to friction. C .Only pure refrigerant boils in the generator. Fig.3 Block diagram of Vapor Absorption Refrigeration System. Let, m = mass flow rate of refrigerant, kg/s mss = mass flow rate of strong solution, kg/s mws = mass flow rate of weak solution, kg/ Heat (Q) and Mass (m) balance for each component For Condenser m7 =m8=m Qc =m(h7-h8), kJ/s For Expansion Valve m8 =m9=m h8=h9(isenthalpic), kJ / kg For Evaporator m9 =m8=m Qe=m(h9-h8), kJ/s For Absorber From total Mass balance m+mss=mws Now Circulation Ratio, λ=mss/m Therefore, mws=(1+λ)m From Mass balance of pure water m+(1+ξss)mss=(1+ξws)mws Solving for λ we get, λ= ξws/ (ξss- ξws) and Qa=mh10+λmh6 -(1+λ)mh1, KJ/s Solution for Pump m1=m2=mws wp=(1+λ)mV sol(pc-pE) kJ/s where Vsol . is specific volume of solution which can be taken as approx. 0.00055 m3/kg. For Heat Exchanger m2=m3=mws m4=m5=mss QHX =(1+λ)m(h3-h2)=λm(h4-h5),kJ/s For Generator m3=m4+m7 Heat input to the Generator, Qg=mh7+λmh4-(1+λ)m3, kJ/s Coefficient of Performance (COP): In this system the net refrigerating effect is the heat absorbed by the refrigerant in the evaporator. The total energy supplied to the system is the sum of work done by the pump and the © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1368
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072 heat supplied in the generator. Therefore, the Coefficient of performance (COP) of the system is given by- COP = Heat Absorbed in the Evaporator ( Work done by pump +Heat Supplied in the Generator ) COP = Qe/(Qg+Wp) Neglecting the Pump work COP=Qe/Qg Isthe expression for Coefficient of Performance(COP) of the System. 9.MATHEMATICAL CALCULATIONS FOR EACH COMPONENT 9.1 The operating temperatures chosen in ℃ Generator Temperature, Tg =60℃ Condenser Temperature, Tc = 28℃ Absorber Temperature, Ta =21℃ Evaporator Temperature, Te =5℃ 9.2 The Operating Pressures in mm of Hg The operating Pressurescan be known correspondingtothe temperatures. Say for example the saturation pressure for condensation in the Condenser at 28℃ can be obtainedfrom steam tables and is equal to 0.03779bar. Also 1bar = 750.06mm of Hg. Therefore 0.03779bar= 28.50mm of Hg which is also equal to Generator pressure because Condenser and Generator operate at same pressure. Now the saturation pressure for saturated vapors formed in Evaporator at a temperature of 5℃ can again be obtained from steam table which comes to be 0.00872bar or 6.54mm of Hg which will also be equal to the Absorber pressure asboth operate undersamepressure. 9.3 Capacity of the system or Refrigerating Effect (Qe)= 1.5ton = 5.25kW 9.4 Calculation of Enthalpy (h) at every designated point of the system: Enthalpy of pure water and of superheated water vapors at any temperature can be determined from steam tables. Enthalpies of solutions are calculated from Lithiumbromide (LiBr) and Water Pressure-Temperature-Concentration- Enthalpy(P-T-ξ-h) Chart. Fig.4-LiBr-H2O Pressure-Temperature Concentration- Enthalpy Chart Table I: Li-Br-Water Enthalpy-Pressure-Temperature- Concentration State Temp.in Pressure Enthalpy Concentration Points ℃ in mm h ,Kj/kg ξ of Hg 7 60 28.50 2609.65 - 8 28 28.50 117.30 - 9 28 6.54 117.30 - 10 5.0 6.54 2509.96 - 1 21 6.54 -170.0 0.48 2 21 28.50 -170.0 0.48 3 52.25 28.50 -110.004 0.48 4 60 28.50 -108.0 0.56 5 21 28.50 -178.0 0.56 6 21 6.54 -178.0 0.56 9.5 Calculation of Heat transfers for each component Evaporator:-Applying the Energy balance Qe = Refrigerating effect = 5.25kW = m(h10 - h9 ) =m × (2509.96 -117.30) m = 5.25/ (2509.96- 117.30) or m = 2.19421×10-3 kg/s = mass flow rate of refrigerant. Now, © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1369
  • 6. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072 Circulation Ratio λ = ξWS/( ξSS- ξWS) λ = 0.48/(0.56-0.48) = 6 therefore, mss.= λ × m=13.1652 ×10-3kg/s and mws=(1+ λ)m=(1+6) ×2.1942 ×10-3 =15.3594 ×10-3 kg/s Absorber: Applying the Energy balance Qa=mh10+mssh6-mwsh1 = (2.19421×10-3 ×2509.96) + (13.1652×10-3 × -178) - (15.354×10-3 × -170) = 577435W = 5.7743 KW Solution Heat Exchanger (HX) Energy balance for Heat Exchanger, mws×(h3×-h2)=mss×(h4-h5) =15.3594×10- 3× (h3+-170)=13.16526×10- 3 × (-108+178) h3=110.0041 KJ/kg Generator QG = mh7 + mssh4 - mwsh3 = (2.19421×10- 3 ×2609.655) + (13.1652×10- 3 × -108) - (15.3594×10- 3 ×-110.0041) = 59938W = 5.993KW Condenser Qc = m(h7-h8) = 2.19421×10-3 × (2609.655-117.30) = 54687W = 5.4687kW Thus, COP = QE/ QG = 5250/5993 = 0.876 9.6 Calculation of solar Collector Useful energy (energy absorbed by the collector plate) is given by, Qu = K x S x A Where, K = efficiency of collector plate(assuming k=0.85) S = average solar heat falling on earth’s surface = 6kW/hr/m2/day=250W/m2 A = area of collector plates Now Heat required in the generator, Qg = 5993Watt Hence approximate area of the collector plates required for providing the above amount of energy = 5993/ (250xK) = 5993/(250x0.85) = 28.20Sq.m Total area of collector plates A = 28.20Sq.m Therefore we can use 5 collector plates having dimension of 3x2 Sq.m. Thus, Qu = 0.85x 250x 28.20 = 5993W = 5993 J/Sec The energy absorbed by the collector helps in heating of the water flowing in the tubes of the collector plates. U= m x Cp (T o - T i ) Let the rate of water flowing through the tubes, m= 1.2Kg/min = 0.02kg/s, (example) Specific heat of water, Cp= 4.187 KJ/KgK To =outlet temperature of water in the collector Ti = inlet temperature of water in the collector plates = 210C Therefore, Qu = 0.02 x 4187 x (To -21) = 5993 = 92.0C The temperature, To should be the inlet temperature of generator, but assuming water loses heat while flowing through the pipes. Also there is certain effectiveness of the generator as a heat exchanger, less than 100%. Hence net heating in the generator can be assumed to be taking place at 600C. Temperature at generator = 600C This is the net heat input to the system, which is running as a refrigeration unit of 5.25kW capacity. COP of the system- The COP of the unit can be calculated by the following equation: COP = Refrigeration effect / heat input in generator COP = Qe/ Qg = 5250/59938 = 0.876 The COP of the system including Solar water heater Net refrigeration effect heat input at the solar collector COP = 0.876 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1370
  • 7. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 01 | Jan-2018 www.irjet.net p-ISSN: 2395-0072 Heat input at the solar collector = Solar constant x Area = 250W/m2 x 28.20 m2 = 7050 W COP = 5250 W/7050 W = 0.7446 Hence the theoretical COP of the system comes to be 0.7446 10 Results – The Evaporator is a chamber that has to be maintain at the low temperature but the main objective of the study isnotto attain very low value of evaporator temperature but to provide the desired cooling effect. the Condenser and Absorber are maintained to be at a temperature of 280C and 210C respectively. Generator at maintain at the temperature of 600C. Table.2. Components Wise heat capacity of Different systems 11. Conclusion- A small capacity (1.5ton) intermittent vapor absorption refrigeration system using LiBr-H2O solution was designed based on some thermodynamic correlations. By analytical calculation the COP was 0.876.it was ascertained that the solar collector efficiency, clearness of sky play a big role for overall efficiency. The study suggests that, with a accurate theoretical design and thermodynamics analysis there is a scope for improving the performance of vapor absorption refrigeration system applying low grade thermal energy source. COP of the system is greatly acted upon the system temperature. The heat input can be provided by solar collector. It brings into light that solar collector can not only be used for heating, it can also be used for cooling purpose. REFERENCES [1] Mr. S. S. Mali , Prof.M.M.Wagh, Prof. N. N. Shinde, " Review Of Design Of Single Effect Solar Powered Vapour Absorption Air Conditioning System " InternationalJournal Of Advance Research In Science And Engineering,Vol.No.2, Issue No.7, July, 2013, Pp 44-52. [2] Anil Sharma, Bimal Kumar Mishra,AbhinavDinesh,Ashok Misra, "Configuration Of A 2 Kw Capacity Absorption Refrigeration System Driven By Low Grade Energy Source" International Journal Of Metallurgical & Materials Science And Engineering (Ijmmse) Vol. 2 Issue 4 Dec - 2012 1-10, Pp 1-9. [3] Minh, Nguyen Q.; Hewitt, Neil James; And Eames, Philip charles, "Improved Vapor Absorption Refrigeration Cycles: Literature Review And Their Application To Heat Pumps" International Refrigeration And Air ConditioningConference, 2006 Paper 795, P1-8 [4] Pongsid Srikhirin, Satha Aphornratana, Supachart Chungpaibulpatana, "A Review Of Absorption Refrigeration Technologies" Renewable And Sustainable Energy Reviews 5,2001 Pp-343–372. [5] Rotchana Prapainop, K O Suen, " Effects Of Refrigerant Properties On Refrigerant Performance Comparison: A Review" International Journal Of Engineering Research And Applications (Ijera) Vol. 2, Issue 4, July-August 2012, Pp.486- 493. [6] G. Ali Mansoori And Vinod Patel, "Thermodynamic Basis For The Choice Of Working Fluids For Solar Absorption Cooling Systems " Solar Energy, Volume 22, Issue 6, 1979, Pp 483-491. [7] José A. Manrique, "A Solar Air-Cooled Water-Ammonia Absorption Chiller" 61st Ati National Congress–International Session “Solar Heating And Cooling”Pp 1-5. [8] Soteris Kalogirou, George Florides, Savvas Tassou, Louis Wrobel" Design And Construction Of A Lithium Bromide Water Absorption Refrigerator" Clima 2000/Napoli 2001 World Congress – Napoli (I), 15-18 September 2001. [9] Piyush Mahendru, S.K.Agrawal, P.Pachorkar, " Steady State Analysis Of Vapor Absorption Refrigeration System Using Li-Br-H2o As A Refrigerant " International Journal Of Emerging Technology And Advanced Engineering, Volume 2, Issue 9, September 2012, Pp 328-332. [10] Micallef,D. And Micallef, C, "Mathematical Model Of Vapor Absorption Refrigeration Unit" Int.J Simul Model 9, 2 , 2010, Pp 86-97. [11] Subhadip Roy, M.P. Maiya "Analysis Of R134a–Dmac Vapour Absorption Refrigeration System With Add-On Components" International Journal Of Sustainable Built Environment, Sciverse Sciencedirect, 1, 2012, Pp 26–35. Pp-1248-1254. COP = 0.7446 S.No. COMPONENT HEAT TRANSFER RATE VALUES 1 Evaporator QE 5.250 2 Absorber QA 5.774 3 Generator QG 5.933 4 Condenser QC 5.468 [12] Dr. Nimai Mukhopadhyay,Er.SomeshwarChowdhury, " Performance Analysis Of Solar Assisted Cascade Refrigeration System Of Cold Storage System" International Journal Of Advanced Research In Electrical, Electronics And Instrumentation Engineering Vol. 2, Issue 4, April 2013, © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1371