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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 01 | Jan 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2168
"ECONOMICAL WATER PURIFIER USING NATURAL AND WASTE
MATERIALS"
Prof. Fanindra Katre1, Dipali Vaidya2, Akash kamble3, Akhil Patil4, Amar Shrirang5,
Shubham Kodape6
1Asst. Prof. Dept. of Civil Engineering GNIT Nagpur, Maharashtra, India
2,3,4,5,6B.E. Scholar, Department of Civil Engineering, Guru Nanak Institute Of Technology, Nagpur, India
---------------------------------------------------------------------***----------------------------------------------------------------------
Abstract - A primary intention under waste water to
eliminate the pollutants that caninfluencethehumanbeingas
well as existing healthiness. Beneath a area heattoejectedthe
particles, various types of poison's gas as like nitric,
phosphoric and ammonium-ions, stench. In the primary study
of economical water purifier construct waste and natural
materials that is charcoal, zeolite, coconut shell / fiber, alum,
Sea shells with or without crushing, stones, corncobandwood.
Using various test for water quality for suitable of human
being bodies as well as living things and also check the ph
value and turbidity of the best quality of water. Outcome of
this basic investigation of economical water purifier to
implementation of a new water purifier using a natural and
waste material as well as low cost water purifier also may
enrich drinking water with essential mineral.
1. INTRODUCTION
Introduction purpose for analysis, A development and
growing cause drizzle water contains pollutants which will
have an effect on human or object health. The concept of
employing a filter that fabricated from natural material
ought to be acceptable to eliminate or reduced originate
waste matter found of waste water additionally to form it
reasonable by user. A purpose for a public facility and repair
part square measure to be establish future demand for
necessary public facility and services and to correlate the
adequate delivery of those services with future growth
projection. Waterpurificationisthatthemethodof removing
undesirable chemicals, biological contaminants,delaysolids
additionally gases faraway from water. Goal is to supply
water suited specific functions. Most water is refined and
disinfected for human consumption water however water
purification may be disbursed of a spread for alternative
aspiration together with medical pharmacologic, chemical
additionally a industrial application. An appointment
embrace physical operation such a filtration, deposit
additionally distillation, biological operation. Such a slow
sand filter or biologicalactivecarbon,chemical processeslike
activity and chlorination, and also the use of non particulate
radiation like light-weight ultravioletilluminationUVactinic
radiation actinic ray light the concept of employing a filter
that created natural material oughttobeacceptabletofound
of rain water for a reasonable by individual. Asian nation
accounts on account of 245% of the surface area and
additionally four-dimensional of flood resources for the
planet however represents Sixteen Personality Factor
Questionnaire of the planet population. The zoom of
population has exerted a conveyable flood water demand
within which needs exploration for the raw water sources
developingtreatmentandadditionallydistributionSystem.A
raw and rain water property on the market in Asian nation
varies significantly derive of conversion for the traditional
flood treatment theme consisting of aeration chemical
action, activity and deposit, filtration and additionally
medical care. Coconut primarily based agricultural wastes
have gained wide attention as spectacularbisorbentbecause
of low value also as vital surface assimilation potential. A
removal for varied aquatic pollutants for many years
activated charcoal has gained wide employment of the
treatment for waste water from coconut shells in treatment
method of the creation polishedliquidofdrinkingpurposeat
industrial level. Because of their high carbon content and
hardness coconut shell square measure a superb material
supply to supply activated charcoal. Metal sulphate or alum
is employed for a flocculant to get rid of unwanted color and
murkiness from water provides. It's been used since ancient
time for this purpose also because it used along with
filtration is normal apply among standard water treatment
processes round the world. Active charcoal carbon filters
square measure best at removing gas volatile organic
compounds vocs style additionally odour from water. They
comprise idleness at removing minerals salts and dissolved
in chemical compound. Slow sand filters created high
character water while not an use of chemical aids. Passing
floculated water through speedy gravity sand filter strains
out the floc and also the particles unfree inside it,shortening
variety of bacterium and discard a lot of solids. Rice husk
thought about as waste and it high level of element
precursor is compound that is wealthy in carbon through
which kind shift of the rice husk in an inert atmosphere.
Black rice husk ash (BRHA) was used as AN adsorbent for
purification of water basins contaminated with diesel oil,
water softener is incredibly low-cost it's high ion exchange
capability (CEO). It's 100 percent natural and organic it
additionally contain each macro and small nutrient it
absorbed and holds potential harmful and unhealthful
substance it additionally improves ammonia retention and
reduced N losses.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 01 | Jan 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2169
2. Literature Review
2.1 Politeknik sultan Idris Shah (2018), he worked on
‘Water filter manufacturing the usage of coconut husk
fiber, zeolite, charcoal and membrane for rainwater
harvesting’. Water great for the samples taken from five
unique places is elevated after passing via the filters. There
are a number of parameter which are regarded to be
extended that pH, turbidity, color, organic oxygen demand,
complete suspended solids, nitrate, zinc and sulfate. From
this project, it is observed that rainwater consists a quantity
of chemical compounds such as zinc, nitrate and sulfate. All
samples had been harvested thru roof. There are many
sources of impurities may want to be on the roof such as
birds drop, materials of roof and leaves. Unclean reservoir
may want to be the best location for micro organic growth.
This should lead to excessive BOD reading.
2.2 Giridhar V S S Mittapalli (2016), he also study
conducted on the " Use of Alum for Turbidity Removal in
Synthetic Water" In this the effectiveness of alum used to
be evaluated at room temperature with initial pH (6-7.4)
For 2 coagulant doses 10 mg/l and 20 mg/l in 250 ml
synthetic high turbid water by means of adopting guide
agitation at very low settling Results confirmed that
coagulation technique ought to cast off turbidity effectively
the use of highly low stages of Alum. Studies expose that
turbidity elimination relies upon on pH, coagulantdose,also
as initial turbidity of water. The absolute best turbidity
removal effectivity was 46.15 p.c. over the utilized vary of
turbidity. The outcomes of the cutting-edge learn about can
be used as a baseline information for drinking water cure
facilities which uses Alum as a coagulant.
2.3 Maxim Tyulenev (2016), he also conducted a study on
‘Coal producers waste water purification’ The analysis of
dependence provided in graphics has showed that the
change of oil products concentration C from filtering path L
with high accuracy (R2 is not lower than 0.91) is
approximated by expression:- C = C0 ∙ e-0.016lwhere, C0 -
initial concentration of oil products in the waste waters
discharged for purification, L - filtering path.
2.4 Shilpa S. Ratnoji (2014), conducted a study on ‘astudy
of coconut shell-activated carbon for filtration and it's
comparison with sand filtration’. For conducting the pilot
scale study of filtration different grades of CS-AC VIZ WT
D816, WTE830 and WTE124 depending upon their sizes
were produced from Indo German Carbons Limited, Kerala.
These CSAC were of size 8*16 US mesh size (I, coarser),8*30
US mesh size (II, medium), and 12*40 US mesh size (III,
finer).CS-Ac were maintained at a depth of 4cm in the
column. Reduction in BOD and COD is illustrated is not that
pronounced and reduction in Cod and BOD proves that the
organic compounds can be effectively removed by coconut
shell activated carbon .coconut shell activatedcarboncan be
looked upon for future treatment of water in removing
suspended solids, iron and total organic carbon instead of
sand filtration in the treatment plants and this technique is
highly advantages, inexpensive and cost-effective as well as
turn there will be utilization of a waste which would be
otherwise simply dumped. Thus, this improvisation can be
effected as a novel method as drinking water treatment
taking environment into worry.
2.5 Karmen Margeta (2013), yet as he additionally
conducted a study on ‘Natural Zeolitesinwatertreatment
- however effective is their Use’ he work represented was
partly supported by the Ministry of Science, Education and
Sports of the Republic of Republic Croatia through the
bilateral project. The distinctive natural process andsurface
assimilation properties, high consistence and glorious
thermal stability of Zeolites create then terribly appropriate
for several applications, additionally in water treatment
processes. Many different studies have incontestable their
effectiveness in reducingthe concentrationsofcontaminants
(metals, anions and organic matter) in water. The
complexness of aquatic systems demands special attention
within the choice and preparation of materials for water
purification. The chemical behavior of natural zeolites in
several binary compound environments, that was
additionally a topic of recent geochemical and technological
studies, to boot proven their pertinency, though watching of
ph and it's changes, remains vital for his or her use of real
environments. Further research should be focused on the
optimization of the surface modificationproceduresto boost
their efficiency and to reinforce the potential of
regeneration. Moreover, detailed characterizationofnatural
and altered zeolites is needed to lifted to understand the
structure- property relationship.
3. CONCLUSION
There are several parameter for the considered to the
improved that are ph, turbidity, color, biological oxygen
demand, total suspended solid, nitrate, Zinc and sulfate. It
may be found that rainwater consist a number of chemical
compound such as zinc, nitrate and sulfate. The impurities
presence in rainwater is caused by the harvesting method
useful. The sample for testing of water collected from river
and harvested through roof. Impure reservoir could be the
good place for micro biological increased. Could lead to high
BODreading. In term of producing a filter that filter have
may be successfully producedcanimprovethequalityofrain
water and waste water. Nevertheless there are some errors
that occur in rain water sample before and after filtered
tested. The result expected is that the improvementof water
quality may be improve the apply of operation. Various
activated carbon from different sources may perform better
if mixed together and used for filtration. The production of
filters from natural Ingradients can be said to be one good
idea and has proven effective in treating and also improving
the quality of rainwater for use in daily life. While the
activated corn cob is good in the removal of some physical
properties. The charcoal used in the required of ammonia
nitrogen concentration and also the quality of raw water
used for affected the rate of removal of contaminants by the
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 01 | Jan 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2170
activated carbon from the various sources.Above papersare
refers to study of water purifier they are used various
material like charcoal, sand, corn husk, rice husk, coconut
shell, zeolite, alum, wood etc. But this paper such material
are used consequently not all at one time and after purifying
the water gives better quality. But our aim is that use of
natural and waste material like charcoal, sand, corn husk,
rice husk, coconut shell, zeolite,alum,wood etc.Usedifferent
material in different purifier and check the quality of water.
And finally all this waste and natural material used in
combine and check the quality of water.
From there expected result is that water gives better quality
after the treatment.
REFERENCES
[1] Ahmadapur, A.; Do, D.D. 96/02594 - Characterizationof
modified activated carbons: Equilibra and dynamic
studies. Fuel & Energy abstracts , Vol 37 (3),1996,184.
[2] Akbar Baghvand, Ali Daryabeigi Z and, NasserMehrdadi
and Abdolreza Karbassi, “Optimizing Coagulation
Process for Low to High Turbidity Waters Using
Aluminum and Iron Salts”, American Journal of
Environmental Sciences 6, 2010.
[3] Bhatnagar A, Sillanpaa M (2011) A review of emerging
adsorbents for nitrateremoval fromwater.Chem.Engin.
J. 168:493-504.
[4] Camachoa LM, Parrab RR, Denga Sh (2011) Arsenic
removal from groundwater by MnO2-modified natural
clinoptilolite zeolite: Effects of pH and initial feed
concentration. J.Hazard.Mater. 189:286–293.
[5] Dávila -Jiménez MM, Elizalde -González MP, Mattusch J,
Morgenstern P, Pérez -Cruz MA, Reyes-Ortega Y,
Wennrich R, Yee-Madeira H (2008) In situ and ex situ
study of the enhanced modification with iron of
clinoptilolite- rich zeolitic tuff for arsenic sorption from
aqueous solutions. J.Colloid.Interf. Sci. 322:2:527-536.
[6] Endang Setyowati (2008). "Mening katkan Kaulitas Air
Sungai Dengan Katalisat or Batuan Dan Arang Kasus
Pemukinan PinggirKota DiDusunGrobogan".University
Widya Mataram Yogyakarta.
[7] Farías T, Ruiz -Salvador AR, Velazco L, Charles de
Ménorval L, Rivera A (2009) Preparation of natural
zeolitic supports for potential biomedical applications.
Mater.Chem.Phy.118:322-328.

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  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 01 | Jan 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2168 "ECONOMICAL WATER PURIFIER USING NATURAL AND WASTE MATERIALS" Prof. Fanindra Katre1, Dipali Vaidya2, Akash kamble3, Akhil Patil4, Amar Shrirang5, Shubham Kodape6 1Asst. Prof. Dept. of Civil Engineering GNIT Nagpur, Maharashtra, India 2,3,4,5,6B.E. Scholar, Department of Civil Engineering, Guru Nanak Institute Of Technology, Nagpur, India ---------------------------------------------------------------------***---------------------------------------------------------------------- Abstract - A primary intention under waste water to eliminate the pollutants that caninfluencethehumanbeingas well as existing healthiness. Beneath a area heattoejectedthe particles, various types of poison's gas as like nitric, phosphoric and ammonium-ions, stench. In the primary study of economical water purifier construct waste and natural materials that is charcoal, zeolite, coconut shell / fiber, alum, Sea shells with or without crushing, stones, corncobandwood. Using various test for water quality for suitable of human being bodies as well as living things and also check the ph value and turbidity of the best quality of water. Outcome of this basic investigation of economical water purifier to implementation of a new water purifier using a natural and waste material as well as low cost water purifier also may enrich drinking water with essential mineral. 1. INTRODUCTION Introduction purpose for analysis, A development and growing cause drizzle water contains pollutants which will have an effect on human or object health. The concept of employing a filter that fabricated from natural material ought to be acceptable to eliminate or reduced originate waste matter found of waste water additionally to form it reasonable by user. A purpose for a public facility and repair part square measure to be establish future demand for necessary public facility and services and to correlate the adequate delivery of those services with future growth projection. Waterpurificationisthatthemethodof removing undesirable chemicals, biological contaminants,delaysolids additionally gases faraway from water. Goal is to supply water suited specific functions. Most water is refined and disinfected for human consumption water however water purification may be disbursed of a spread for alternative aspiration together with medical pharmacologic, chemical additionally a industrial application. An appointment embrace physical operation such a filtration, deposit additionally distillation, biological operation. Such a slow sand filter or biologicalactivecarbon,chemical processeslike activity and chlorination, and also the use of non particulate radiation like light-weight ultravioletilluminationUVactinic radiation actinic ray light the concept of employing a filter that created natural material oughttobeacceptabletofound of rain water for a reasonable by individual. Asian nation accounts on account of 245% of the surface area and additionally four-dimensional of flood resources for the planet however represents Sixteen Personality Factor Questionnaire of the planet population. The zoom of population has exerted a conveyable flood water demand within which needs exploration for the raw water sources developingtreatmentandadditionallydistributionSystem.A raw and rain water property on the market in Asian nation varies significantly derive of conversion for the traditional flood treatment theme consisting of aeration chemical action, activity and deposit, filtration and additionally medical care. Coconut primarily based agricultural wastes have gained wide attention as spectacularbisorbentbecause of low value also as vital surface assimilation potential. A removal for varied aquatic pollutants for many years activated charcoal has gained wide employment of the treatment for waste water from coconut shells in treatment method of the creation polishedliquidofdrinkingpurposeat industrial level. Because of their high carbon content and hardness coconut shell square measure a superb material supply to supply activated charcoal. Metal sulphate or alum is employed for a flocculant to get rid of unwanted color and murkiness from water provides. It's been used since ancient time for this purpose also because it used along with filtration is normal apply among standard water treatment processes round the world. Active charcoal carbon filters square measure best at removing gas volatile organic compounds vocs style additionally odour from water. They comprise idleness at removing minerals salts and dissolved in chemical compound. Slow sand filters created high character water while not an use of chemical aids. Passing floculated water through speedy gravity sand filter strains out the floc and also the particles unfree inside it,shortening variety of bacterium and discard a lot of solids. Rice husk thought about as waste and it high level of element precursor is compound that is wealthy in carbon through which kind shift of the rice husk in an inert atmosphere. Black rice husk ash (BRHA) was used as AN adsorbent for purification of water basins contaminated with diesel oil, water softener is incredibly low-cost it's high ion exchange capability (CEO). It's 100 percent natural and organic it additionally contain each macro and small nutrient it absorbed and holds potential harmful and unhealthful substance it additionally improves ammonia retention and reduced N losses.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 01 | Jan 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2169 2. Literature Review 2.1 Politeknik sultan Idris Shah (2018), he worked on ‘Water filter manufacturing the usage of coconut husk fiber, zeolite, charcoal and membrane for rainwater harvesting’. Water great for the samples taken from five unique places is elevated after passing via the filters. There are a number of parameter which are regarded to be extended that pH, turbidity, color, organic oxygen demand, complete suspended solids, nitrate, zinc and sulfate. From this project, it is observed that rainwater consists a quantity of chemical compounds such as zinc, nitrate and sulfate. All samples had been harvested thru roof. There are many sources of impurities may want to be on the roof such as birds drop, materials of roof and leaves. Unclean reservoir may want to be the best location for micro organic growth. This should lead to excessive BOD reading. 2.2 Giridhar V S S Mittapalli (2016), he also study conducted on the " Use of Alum for Turbidity Removal in Synthetic Water" In this the effectiveness of alum used to be evaluated at room temperature with initial pH (6-7.4) For 2 coagulant doses 10 mg/l and 20 mg/l in 250 ml synthetic high turbid water by means of adopting guide agitation at very low settling Results confirmed that coagulation technique ought to cast off turbidity effectively the use of highly low stages of Alum. Studies expose that turbidity elimination relies upon on pH, coagulantdose,also as initial turbidity of water. The absolute best turbidity removal effectivity was 46.15 p.c. over the utilized vary of turbidity. The outcomes of the cutting-edge learn about can be used as a baseline information for drinking water cure facilities which uses Alum as a coagulant. 2.3 Maxim Tyulenev (2016), he also conducted a study on ‘Coal producers waste water purification’ The analysis of dependence provided in graphics has showed that the change of oil products concentration C from filtering path L with high accuracy (R2 is not lower than 0.91) is approximated by expression:- C = C0 ∙ e-0.016lwhere, C0 - initial concentration of oil products in the waste waters discharged for purification, L - filtering path. 2.4 Shilpa S. Ratnoji (2014), conducted a study on ‘astudy of coconut shell-activated carbon for filtration and it's comparison with sand filtration’. For conducting the pilot scale study of filtration different grades of CS-AC VIZ WT D816, WTE830 and WTE124 depending upon their sizes were produced from Indo German Carbons Limited, Kerala. These CSAC were of size 8*16 US mesh size (I, coarser),8*30 US mesh size (II, medium), and 12*40 US mesh size (III, finer).CS-Ac were maintained at a depth of 4cm in the column. Reduction in BOD and COD is illustrated is not that pronounced and reduction in Cod and BOD proves that the organic compounds can be effectively removed by coconut shell activated carbon .coconut shell activatedcarboncan be looked upon for future treatment of water in removing suspended solids, iron and total organic carbon instead of sand filtration in the treatment plants and this technique is highly advantages, inexpensive and cost-effective as well as turn there will be utilization of a waste which would be otherwise simply dumped. Thus, this improvisation can be effected as a novel method as drinking water treatment taking environment into worry. 2.5 Karmen Margeta (2013), yet as he additionally conducted a study on ‘Natural Zeolitesinwatertreatment - however effective is their Use’ he work represented was partly supported by the Ministry of Science, Education and Sports of the Republic of Republic Croatia through the bilateral project. The distinctive natural process andsurface assimilation properties, high consistence and glorious thermal stability of Zeolites create then terribly appropriate for several applications, additionally in water treatment processes. Many different studies have incontestable their effectiveness in reducingthe concentrationsofcontaminants (metals, anions and organic matter) in water. The complexness of aquatic systems demands special attention within the choice and preparation of materials for water purification. The chemical behavior of natural zeolites in several binary compound environments, that was additionally a topic of recent geochemical and technological studies, to boot proven their pertinency, though watching of ph and it's changes, remains vital for his or her use of real environments. Further research should be focused on the optimization of the surface modificationproceduresto boost their efficiency and to reinforce the potential of regeneration. Moreover, detailed characterizationofnatural and altered zeolites is needed to lifted to understand the structure- property relationship. 3. CONCLUSION There are several parameter for the considered to the improved that are ph, turbidity, color, biological oxygen demand, total suspended solid, nitrate, Zinc and sulfate. It may be found that rainwater consist a number of chemical compound such as zinc, nitrate and sulfate. The impurities presence in rainwater is caused by the harvesting method useful. The sample for testing of water collected from river and harvested through roof. Impure reservoir could be the good place for micro biological increased. Could lead to high BODreading. In term of producing a filter that filter have may be successfully producedcanimprovethequalityofrain water and waste water. Nevertheless there are some errors that occur in rain water sample before and after filtered tested. The result expected is that the improvementof water quality may be improve the apply of operation. Various activated carbon from different sources may perform better if mixed together and used for filtration. The production of filters from natural Ingradients can be said to be one good idea and has proven effective in treating and also improving the quality of rainwater for use in daily life. While the activated corn cob is good in the removal of some physical properties. The charcoal used in the required of ammonia nitrogen concentration and also the quality of raw water used for affected the rate of removal of contaminants by the
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 01 | Jan 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2170 activated carbon from the various sources.Above papersare refers to study of water purifier they are used various material like charcoal, sand, corn husk, rice husk, coconut shell, zeolite, alum, wood etc. But this paper such material are used consequently not all at one time and after purifying the water gives better quality. But our aim is that use of natural and waste material like charcoal, sand, corn husk, rice husk, coconut shell, zeolite,alum,wood etc.Usedifferent material in different purifier and check the quality of water. And finally all this waste and natural material used in combine and check the quality of water. From there expected result is that water gives better quality after the treatment. REFERENCES [1] Ahmadapur, A.; Do, D.D. 96/02594 - Characterizationof modified activated carbons: Equilibra and dynamic studies. Fuel & Energy abstracts , Vol 37 (3),1996,184. [2] Akbar Baghvand, Ali Daryabeigi Z and, NasserMehrdadi and Abdolreza Karbassi, “Optimizing Coagulation Process for Low to High Turbidity Waters Using Aluminum and Iron Salts”, American Journal of Environmental Sciences 6, 2010. [3] Bhatnagar A, Sillanpaa M (2011) A review of emerging adsorbents for nitrateremoval fromwater.Chem.Engin. J. 168:493-504. [4] Camachoa LM, Parrab RR, Denga Sh (2011) Arsenic removal from groundwater by MnO2-modified natural clinoptilolite zeolite: Effects of pH and initial feed concentration. J.Hazard.Mater. 189:286–293. [5] Dávila -Jiménez MM, Elizalde -González MP, Mattusch J, Morgenstern P, Pérez -Cruz MA, Reyes-Ortega Y, Wennrich R, Yee-Madeira H (2008) In situ and ex situ study of the enhanced modification with iron of clinoptilolite- rich zeolitic tuff for arsenic sorption from aqueous solutions. J.Colloid.Interf. Sci. 322:2:527-536. [6] Endang Setyowati (2008). "Mening katkan Kaulitas Air Sungai Dengan Katalisat or Batuan Dan Arang Kasus Pemukinan PinggirKota DiDusunGrobogan".University Widya Mataram Yogyakarta. [7] Farías T, Ruiz -Salvador AR, Velazco L, Charles de Ménorval L, Rivera A (2009) Preparation of natural zeolitic supports for potential biomedical applications. Mater.Chem.Phy.118:322-328.