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IRJET- Applications of Anaerobic Baffled Reactor in Wastewater Treatment using Agriculture Wastes
1.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1288 Applications of Anaerobic Baffled Reactor in Wastewater Treatment using Agriculture Wastes Hossam Ahmed1 1Assistant Professor of Sanitary & Environmental Engineering, Faculty of Engineering, Ain Shams University, Cairo, Egypt ----------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - The use of anaerobic baffled reactor for wastewater treatmentalongwithitsdevelopment, applicabilityandpossible future application is presented in this research. The reactor design has been developed since the early 1980s and has several advantages over well-established systems such as the up flow anaerobic sludge blanket and the anaerobic filter. From these advantages are better resilience to hydraulic and organic shock loadings, longer biomass retentiontimes, lowersludge yields, and the ability to partially separate between the various phases of anaerobic catabolism. The latter causes a shift in bacterial populations allowing increased protection against toxic materials and higher resistance tochangesinenvironmental parameters such as pH and temperature. The physical structure of the anaerobic baffled reactor enables important modifications to be made such as the implementing of an aerobic polishing stage, resulting in a reactor that can treat difficult wastewaterswhichcurrently require several units, ultimately significantly reducing capital costs. The main objective of this study is to investigatethebehavior of three reactors and verify the use of the bio- film in improving treatability, to reach the mentioned goal two types of bio-films; ficus fiber and palm fiber were used and investigated. However, during the study manysignificantfactorswereconsideredsuchas: temperatures, number of baffled in reactor, shape baffled and location of reactortoavoidlighting. Foralltestedreactors, influent COD concentration, influent pH, temperature in the reactor effluent COD concentrationeffluent pH andflowrate, inall thereactor stages (start-up, steady state, shock load and final stage), and effluent COD concentration, pH in all compartment from reactors during shock load stage were measured and recorded. Test results revealed that the ABR (C) scenario gave the highest COD % removal comparing with the other two scenarios Key Words: Anaerobic baffled reactor, organic load rate, Biomass, solids retention time, hydraulic retention time 1. INTRODUCTION One of the major investments of Wastewater Treatment Plants are high capital cost of Operation and Maintenance, in return they represent one of the major investments. However, developing countries suffer from a clear obstacle, which is the lack of funding that results in inappropriate operation condition of wastewater treatment plants. Moreover, increase in population densities found in huge residential complexes can be controlled and served by decentralized systems which have simpler techniques and cost effective [1]. Rapid urbanization and increasing population with minimum availabilityoflandhasbecome an obstacle for installing centralized sewage treatment plant, whichbecamea non-reliableoption. Thehugecapital investment of sewerage systems and pumping costs accompanied with centralized systems can be reduced, resulting in increase of the affordability of wastewater management systems. With the improvement of world economic condition, water resources are becoming increasingly deficient and the quality of environment conditions in the world is constantly becoming worse inmost regions. Water protection and waste management are two extremelyimportantglobal issuestoworldpopulation. Therefore,it is necessary to reuse wastes and to implement low-cost methods for wastewater treatment. Wastes from agriculture and industry activities are a major problem caused by the increasing of food demand. The potable water shortage is mainly due to the high costs required for water treatment due to different operation parameters such as; area need, operation techniques difficulties and low investments in such field with the absence of calibres and innovation. To overcome these problems, it has been found that it is necessary important to resort to fast processing techniques. Treatment and disposal of wastewater is presently one of the serious environmental problem contributors. Therefore, there is a desire to developreliabletechnologies for wastewater treatment. Wastewater is commonly used to describe liquid wastes that are collected and transported to a treatment facility through a system of sewers. Anaerobic process for wastewater treatment has attracted increasing attention in the recent decades. This process has advantages as design simplicity, use of non-sophisticated equipment, high treatment efficiency,lowexcesssludge production and low operating and capital cost (Saktaywin etal.,2005[2]).Thehigh-rateanaerobicprocessescouldbeachieved by separation between the hydraulic retention time (HRT) and the solid retention time (SRT). In addition, stringent environmental legislation is giving the impetus to developing anaerobic wastewater treatment processes due to potential economic and environmental benefits they hold over traditional aerobictechniques.Toachievedifferentlevelsofcontaminant removal, individual waste-watertreatmentproceduresarecombinedintoa varietyofsystems,classifiedasprimary,secondary, and tertiary waste-water treatment. More rigorous treatment of waste-water includestheremoval ofspecificcontaminantsas
2.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1289 well as the removal and control of nutrients. Biological unit processes are used to convert the finely divided and dissolved organic matter in waste-water into flocculent settle able organic and inorganic solids. Biological processes are usually usedin conjunction with physical and chemical processes, for the main objective of reducing the organic content (measured as BOD, TOC or COD) and nutrient content (notably nitrogen and phosphorus) of wastewater. Anaerobic treatment includes decomposing and dissolving complex organics to forming end-products(e.g.,CH4 andCO2),anaerobicdegradationis a complex process. Anaerobic treatment processes include anaerobic suspended growth, up flow and down flow anaerobic attached growth, fluidized-bed attached growth and up flow anaerobic sludge blanket (UASB). General design considerations for anaerobic treatment processes.Thetypeof wastewateranditscharacteristicsareimportant in the evaluation and design of anaerobic processes. The characteristics presentedhereapplytothesuspendedgrowth, sludge blanket, attached growth, and other anaerobic processes. Important factors and wastewater characteristic that need to be considered in the evaluation of anaerobic processes for wastewater treatment are discussed below. Food processing and distillery wastewaters, for example, can have COD concentrations ranging from 3000 to 30000 mg/L. otherconsiderationsthatmayapplytodifferent wastewatersourcesarethe presence of potential toxic stream,flowvariationinorganicconcentration,andseasonal loadvariation.Anaerobicprocessescan respond quickly to wastewater feed after long periods without substrate addition. In some cases, with warmer climates, anaerobic treatment has also been considered for municipal wastewater treatment 1.1 Anaerobic Baffled Reactor In the anaerobic baffled reactor (ABR) process,bafflesareusedtodirecttheflowofwastewaterinanup-flowmodethrougha series of sludge blanket reactors. The sludge in the reactor rises and falls with gas production and flow. But moves through the reactor at a slow rate. Various modifications have been madeto the ABR to improve performance. The modificationsinclude,1) changes to the baffle design, 2) hybrid reactors where a settler has been used to capture and return solids, or, 3) packing has been used in the upper portion of each chamber to capture solids (Barber and Stuckey, [3]). Though granulated sludge is not considered essential for the operation and performance of the ABR process. Several studies have been done with the ABR process at bench and pilot scale for a wide range of wastewaters and temperatures as low as 13oC. An excellent summary of these studies includingorganicloadingrates,temperature,andpercentCODremovalisprovidedby (Barber and Stuckey, [3]). Typical design loadings for the ABR process are presented in Table-1. Many of these studies were operated at T values in the range of 6 to 24 hrs. The reactor volatile solids concentrations varied from 4 to 20 g/liter. Fig -1: Schematic views of alternative sludge blanket processes: (a) anaerobic baffled reactor (ABR) and (b) anaerobic migrating blanket reactor (AMBR) The advantages for the ABR process include simplicity; no packing material, no special gas separation method, no moving parts, no mechanical mixing, and little plugging potential, long SRT possible with low hydraulic retention time HRT and no special biomass characteristic required. The ABR can alsohandle wastewater withawidevariety of constituentcharacteristics can be treated. It is also known for stable performance to shock loads.
3.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1290 Table -1: Design and performance results from bench and pilot scale studies on anaerobic treatment of various wastewater with the ABR process Wastewater Temperature Number of chambers Influent COD mg/L COD loading Kg/m3/d Percent COD Removal Carbohydrate/ protein 35 5 7100-7600 2-10 79-82 Distilling 35 5 51,600 2.2-3.5 90 Carbohydrate/ protein 35 5 4000 1-2 94 Molasses 35 3 115,000-900,000 4.3-28 49-88 Swine manure 35 3 58,500 4.0 62-69 Municipal wastewater 18-28 3 264-906 2.2 90 Slaughterhouse 25-30 4 450-550 0.9-4.7 75-90 Pharmaceutical 35 5 20,000 20 36-68 Domestic /industrial 15 8 315 0.9 70 Glucose 35 5 1000-10,000 2-20 72-99 1.2 Anaerobic migrating blanket reactor The anaerobic migrating blanket reactor (AMBR) process is like ABR with the added features of mechanical mixing in each stage and an operating approach to maintain the sludge in the system without resorting to packing or settlers for additional Solids capture (Figure-1-b). In the AMBR process, the influentfeedpointischangeperiodicallytotheeffluentsideandinreturn the effluent withdrawal point is also changed. In this way the sludge blanket remains more uniform in the anaerobic reactor. The flow is reversed when a significant quantity of solids accumulates in the last stage. The AMBR process has been shown to be feasible from bench –scale testing treating non-fat dry milk at 15 and 20oC. The organic loading rate was varied from 1.0 to 3.0 kg COD/m3/d with hydraulic retention time ranging from 4 to 12hrs.AtthehigherCODloading,theCODremoval efficiency was 59 % at 15oC. At 20oC, COD removals ranged from 80 to 95 % at COD loading of 1 to 2.0 kg/m3/d, [4] 2. MATERIALS AND METHODS Pilot plants used in this study were constructed in the Laboratory of Sanitary Engineering, Civil Engineering Department in Faculty of Engineering Alexandria University. The experimental studies performed were categorized into five main parts; preparation of the samples, design of the reactors, identifying the characteristics of the media used, operation of the reactors and finally analyzing and evaluating. According to (Battistoni, Gava G. & Ruello M.L.), the activated sludge process utilizing a synthetic wastewater was prepared by diluting tap water(1-100)aconcentratedstocksolutioncontaining48g/lglucose,11.65g/lNa3PO412H2Oand8.8g/l(NH4)2SO4. The synthetic wastewater was daily prepared fresh. The diluted solution has average COD concentration equals to 500 mg/L. Three bench scale ABRs were carried out in a parallel mode. ABR is constructed from 5mm thick transparent Perspex, with internal dimensions of 80 cm long, 25 cm width and depth of 50 cm with working volume of 76 l cm3. The reactor is divided by vertical baffles into 5 compartments each one is 15.2l volumes. The width of the up-comer is 12 cm and width of downcomeris 4cm, the lower part of the down- comer baffles was angled at 45 to direct the flow evenly the up comer. Each compartment is equipped with sampling ports.AsindicatedinBoopathy. Anaerobicbaffledreactortheeffectivetreatmentvolumeisthatvolume occupied by the sludge blanket and active biomass. An additional volume exists between the effective volume and the gas collection unit where some additional solids separation occurs, and the biomass are diluting. The designed nominal liquid volume of the reactor based on using an acceptable organic loading. The highest COD concentration equals 1000 mg /l, O.L.R
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1291 equal 2 kg COD/m3/d, and Q equal 1.58 l/h all these criteria from table (1) (Metcalf & eddy [4]). To determine the total liquid volume below the gas collectors, an effectiveness factorisused,whichisthefractionoccupiedbythesludgeblanket.Considering the effectiveness factor, which may vary from 0.8 - 0.9. The experimentalworkwascarriedoutbyoperatingtheactivatedsludge (AS) pilot plant to anaerobic sludge by providing anaerobic conditions in the reactor. Samples were withdrawer from the collection tank after the settling tank for AS. The 38 L of biomass was divided evenly between each of the five compartments within each reactor (i.e. 7.2 liter /compartment). The sludge contains MLSS = 25000 mg/l, and MLVSS = 19875 mg/l. First the wastewater flowed from the top to the down flow section in the first compartment, clown through thefirstbiomassbedand then up through the biomass bed in the up-flow section of the compartment. The wastewater then spilled over the upcoming baffle into the following compartment and repeated the process, eventually exiting from the exit port at the top of the up-flow section of the five compartments. The recycle fraction was drawn from the top sample port in the final up-flow section. The reactor effluent exited through the outlet port and flowed collection tank. The reactorwasoperatedundermesophiliccondition maintained constant at 35 oC (Metcalf & eddy [4], and N don, et al [5]). Keep the temperature by a temperature regulator (Heater) placed in each chambers reactor. Synthetic wastewater was prepared daily on fresh basis. The feeding takes place through a tank that distributes synthetic wastewater to three constant head tanks. These tanks maintaining the hydraulic head and thus ensureevenly distribution of wastewater andavalvecalibratingtheinflowdischarge.Usetheconstantheadtankswith system instead of peristaltic pump to avoid power outage. 3. RESULTS A simple experimental set-up was used to study the treatability aspect of wastewater. Three types of scenario, i) convention anaerobic baffled reactor {ABR (A)}, ii) anaerobic baffled reactor with ficus fiber used {ABR(B)}, iii) anaerobic baffled reactor with palm fiber used {ABR(C)}, where experimental under different organic load rate (1.0, 1.1, 1.2, 1.4, 1.6, 1.8, 2.0 and 4.0 kg COD /m3/d), constant flow rate 38 l/d with initial COD concentration 500 mg/l. pH value effect on treatability was also investigated. The ABR (C) system gave the highest COD % removal comparing with the other two systems. Result showed that decreased effluent of pH value had an adverse effect on treatment efficiency for all cases. 3.1 Convention anaerobic baffled reactor The COD removal efficiency ranged between 23.97 to 79.53% with averagevalue55.1%after27workingdaysinstart-upstage, for influent COD concentration ranged between 500 to 1000 mg/l and flow rate 38 l/d. The COD removal efficiency ranged between 73 to 84.48 % with average value 73.48% after 13 working days in steady state stage for influent COD concentration 1000 mg/l and flow rate 38 l/d, ranged between 17.66 to 59.57% with average value 30% after 6 working days in shock load stage forinfluent COD concentration 2000 mg/land flow rate38l/d. The COD removal efficiency ranged between 18to38.42% after 13 working days in final stage for COD concentration 1000 mg/l and flow rate 38 l/d. The effluent pH value ranged between 6.91 to 7.05 in start-up stageforinfluentCODconcentrationrangedbetween500to1000 mg/l, ranged between 6.3 to 7.02 in steady state stage forinfluent CODconcentration 1000 mg/l, ranged between 5.45 to 6.4in shock load stage for influent COD concentration 2000 mg/l and ranged between 5.5 to 5.8 in final stage for influent COD concentration 1000 mg/l. 3.2 For Anaerobic baffled reactor with ficus fiber bio-film The COD removal efficiency ranged between 48.28 to 83.05% with average value 64.22 % after 27 working days in start-up stage, for influent COD concentration between 500 to 1000 mg/l and flow rate 38 l/d. The COD removal efficiency ranged between 83.1 to 89.9% with average value 88.37% after 13 working days in steady state stage for influent COD concentration 1000 mg/l and flow rate 38 l/d, ranged between 13.3 to 33.41% with average value 22.6% after 6 working days in shock load stage forinfluent COD concentration 2000 mg/landflowrate38l/d.TheCODremovalefficiencyrangedbetween15.7to35.98% after 13 working days in final stage for COD concentration 1000 mg/l and flow rate 38 l/d. The effluent pH value ranged between 7.05 to 7.6 in start-up stage for influent COD concentration ranged between 500 to 1000 mg/l, ranged between 6.9 to 7.12 in steady state stage forinfluent CODconcentration1000mg/l,rangedbetween4.97to5.56 in shock load stage for influent COD concentration 2000 mg/l and ranged between 5.5 to 5.9 in final stage for influent COD concentration 1000 mg/l. 3.3 Anaerobic baffled reactor with palm fiber bio-film The COD removal efficiency ranged between 40.11 to 88.00% with average value 61.18 % after 27 working days in start-up stage, for influent COD concentration between 500 to 1000 mg/l and flow rate 38 l/d. The COD removal efficiency ranged between 90.88 to 94.95 % with average value 93.07% after 13 workingdaysinsteadystatestageforinfluentCODconcentration
5.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1292 1000 mg/l and flow rate 38 l/d, ranged between 19.25 to 81.11% with average value 40.9% after 6 working days in shock load stage for influent COD concentration 2000 mg/l and flow rate 38l/d. The COD removal efficiency ranged between 20.36 to 39.94% after 13 working days in final stage for COD concentration 1000 mg/l and flow rate 38 l/d. The effluent pH value ranged between 6.97 to 7.5 in start-up stage for influent COD concentration ranged between 500 to 1000 mg/l, ranged between 6.99 to7.12 in steady state stage forinfluent COD concentration 1000 mg/l, ranged between 5.52to6.97 in shock load stage for influent COD concentration 2000 mg/l and ranged between 5.42 to 5.88 in final stage for influent COD concentration 1000 mg/l. Chart -1: Removal Efficiency of COD for the three reactors (A, B, and C) in Steady State Stage Chart -2: Effluent pH for the three reactors (A, B, and C) in Steady State Stage 4. CONCLUSIONS In this paper we have reviewed different techniques for the anaerobic wastewater treatment using agriculture wastes. The anaerobic baffled reactor with palm fiber bio- film ABR(C) system gave the highest COD% removal comparing with the other systems (conventionalanaerobic baffled reactor andanaerobic baffledreactorwithficusfiberbio-film)duetolargevoidratioin palm fiber media, also may be surface type for this media Creates a suitable surface for the breeding of bacteria. The sudden increase in the influent COD concentration (shock load) decreased the COD removal efficiency in all scenarios. Also, the COD removal efficiency decreased with time. The use of backing media in the anaerobic baffled reactor improves the removal efficiency according to the type of media. Palm fiber improves the removal efficiency by 27 %, while the ficus fiber improves the removal efficiency of the anaerobic reactorby 20 %. The use of media in the anaerobic baffled reactor gives an acceptable efficiencyinallcompartmentsduetothepresenceof media. Increasing the influent COD concentration decreases the effluent pH value. Also, thepHvaluedecreasedwithtimewhich leads to decrees the COD % removal. It must maintain on the temperature and pH during the period of treatment and keep the characteristics of attached media for order to be ABR (c) the highest COD % removal. Results showed that decreasing pH value had an adverse effect on treatment efficiency for all cases.
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1293 REFERENCES [1] Allawi, R., Ahmad, A., Ismail, N., and Kadir, M., ―Anaerobic co-digestion of palm oil mill effluent with rumen fluid as a co- substrate‖ Desalination, V. 269, November.2011, pp. 50-57. [2] Saktaywin, W., Tsung, H., Nagore, H., Soyama, T., and Weerapakkaroon J. ―Advanced sewage treatment process with excess sludge reduction and phosphorus recovery‖. Water Recourse, V. 39, (2005), pp 902-910. [3] Barber, W., and Stuckey, D., ―The Use of the Anaerobic Baffled Reactor (ABR) for wastewater Treatment: A Review, ‖ Water Research, V. 33, (1999), pp. 1559-1578. [4] Metcalf & eddy, ―Wastewater EngineeringTreatmentand Reuse,‖McGrawHill Book CO.,New York,International Edition, 2003. [5] Ndon, U., and Daegu, R., ―Effects of Temperature and Hydraulic Retention Time on Anaerobic Sequencing Batch Reactor Treatment of Low-Strength Wastewater‖ Water Research, V. 10, (1997), pp. 2455-2466
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