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DISACCHARIDES
The disaccharides consists of two
monosaccharide units joined covalently by an
O-glycosidic linkage.
SUCROSE
Saccharose or table sugar
On hydrolysis yields one molecule each of D-glucose
and D- fructose.
Sucrose contains no free anomeric carbon
atom,therefore it is without reducing
properties,NON REDUCING SUGAR.
INVERT SUGAR
Sucrose is dextrorotatory,because glucose
and fructose(furanose form) are
dextrorotatory.
When sucrose is hydrolysed it becomes
levorotatory(its fructose is released in
pyranose form that is levorotatory).
Levorotatory activity of fructose is more than
glucose.
Because rotation is reversed the process is
called INVERSION and the products are called
INVERT SUGAR.
Inversion can be brought about by hydrolysis
with dilute acids or with specific enzyme called
invertase or sucrase(Mucosal lining the small
intestine).
Honey is rich in invert sugar.
Invert sugar is more sweeter than sucrose due
to the presence of free fructose.
Jams and jellies also contain invert sugar.
Source of sucrose is sugar beets
and sugar cane.
Caramel is solid residue produced by
heating sucrose.
used pharmaceutically to make syrups.
MALTOSE
It is formed by O-glycosidic linkage between one
molecule of α-D- glucose with another molecule of α-
D- glucose

Because of presence of free anomeric carbon
it is reducing sugar.
Malt sugar,present in germinating seeds.
Formed in vivo by the action of salivary
amylase on starch and in vitro by the partial
hydrolysis of starch by acids.
Used as fementive reagent.
ISOMALTOSE
Isomaltose is a disaccharide similar to
maltose, but with a α-(1-6)-linkage instead of
the α-(1-4)-linkage.
It is a reducing sugar.
The linkage between the sugars is 1,6.
LACTOSE
Contains O-glycosidic linkage between one
molecule of galactose with another molecule
of glucose.
Milk sugar,cows milk contains 5%
lactose,human milk contains 7%.
Contains free anomeric carbon so its reducing
sugar.
Lactase in mucosal cells hydrolyzes lactose to
its constituent monosaccharides.
Lactulose
galactose-b-(1,4)-fructose
a semi-synthetic disaccharide (not naturally
occurring)
not absorbed in the GI tract
used as a laxative to treat constipation.
Cellobiose consists of 2 molecules of glucose linked by a beta-1,4 glycosidic bond
It is usually obtained by the partial hydrolysis of cellulose
Trehalose is a disaccharide that occurs naturally in insects, plants, fungi, and bacteria.
The
major dietary source is mushrooms. Trehalose is used in bakery goods, beverages,
confectionery, fruit jam, breakfast cereals, rice, and noodles as a texturizer, stabilizer,
humectant, or formulation aid with a low sweetening intensity
Trehalose
O
CH2OH
H
O O
H
H
H
HO
H
OH
OH
H
OH H
H
OH
OH
H
HOH2C
TREHALOSE
OLIGOSACCHARIDES

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Disaccharides

  • 1. DISACCHARIDES The disaccharides consists of two monosaccharide units joined covalently by an O-glycosidic linkage.
  • 2.
  • 3. SUCROSE Saccharose or table sugar On hydrolysis yields one molecule each of D-glucose and D- fructose.
  • 4. Sucrose contains no free anomeric carbon atom,therefore it is without reducing properties,NON REDUCING SUGAR.
  • 5. INVERT SUGAR Sucrose is dextrorotatory,because glucose and fructose(furanose form) are dextrorotatory. When sucrose is hydrolysed it becomes levorotatory(its fructose is released in pyranose form that is levorotatory).
  • 6. Levorotatory activity of fructose is more than glucose. Because rotation is reversed the process is called INVERSION and the products are called INVERT SUGAR.
  • 7. Inversion can be brought about by hydrolysis with dilute acids or with specific enzyme called invertase or sucrase(Mucosal lining the small intestine). Honey is rich in invert sugar. Invert sugar is more sweeter than sucrose due to the presence of free fructose. Jams and jellies also contain invert sugar.
  • 8. Source of sucrose is sugar beets and sugar cane. Caramel is solid residue produced by heating sucrose. used pharmaceutically to make syrups.
  • 9. MALTOSE It is formed by O-glycosidic linkage between one molecule of α-D- glucose with another molecule of α- D- glucose 
  • 10. Because of presence of free anomeric carbon it is reducing sugar. Malt sugar,present in germinating seeds. Formed in vivo by the action of salivary amylase on starch and in vitro by the partial hydrolysis of starch by acids. Used as fementive reagent.
  • 11. ISOMALTOSE Isomaltose is a disaccharide similar to maltose, but with a α-(1-6)-linkage instead of the α-(1-4)-linkage. It is a reducing sugar. The linkage between the sugars is 1,6.
  • 12. LACTOSE Contains O-glycosidic linkage between one molecule of galactose with another molecule of glucose.
  • 13. Milk sugar,cows milk contains 5% lactose,human milk contains 7%. Contains free anomeric carbon so its reducing sugar. Lactase in mucosal cells hydrolyzes lactose to its constituent monosaccharides.
  • 14. Lactulose galactose-b-(1,4)-fructose a semi-synthetic disaccharide (not naturally occurring) not absorbed in the GI tract used as a laxative to treat constipation.
  • 15. Cellobiose consists of 2 molecules of glucose linked by a beta-1,4 glycosidic bond It is usually obtained by the partial hydrolysis of cellulose
  • 16. Trehalose is a disaccharide that occurs naturally in insects, plants, fungi, and bacteria. The major dietary source is mushrooms. Trehalose is used in bakery goods, beverages, confectionery, fruit jam, breakfast cereals, rice, and noodles as a texturizer, stabilizer, humectant, or formulation aid with a low sweetening intensity Trehalose O CH2OH H O O H H H HO H OH OH H OH H H OH OH H HOH2C TREHALOSE