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Need of tertiary treatment for anaerobic wastewater treatment
1. LLeeccttuurree oonn
Need of tertiary treatment for
anaerobic wastewater treatment
by
Dr. Arvind Kumar Mungray
B. Tech., M. Tech., Ph.D.
CHEMICAL ENGINEERING DEPARTMENT
SARDAR VALLABHBHAI NATIONAL INSTITUTE OF TECHNOLOGY,
SURAT 395 007
21. Anaerobic degradation process
Step General process Description Notes
1
HHyyddrroollyyssiiss
Acid
production
Methane
production
Carbohydrates, lipids, proteins
broken down to low molecular weight
compounds by enzymes.
Acidogenesis – amino acids
converted to volatile fatty acids
(VFAs)
Acetogenesis – VFAs, lactic acid etc
converted to acetic acid, H2, CO2
Acetotrophic methanogensis – Acetic
acid converted to CO2 and CH4
Hydrogenotrophic methanogensis –
H2 and CO2 converted to CO2 and CH4
2
3
Rate limiting.
Temperature
dependant
Not rate
limiting
Rate
limiting.
Temperature
dependant
23. Types of anaerobic reactors
Low rate anaerobic reactors High rate anaerobic reactors
Anaerobic pond
Septic tank
Imhoff tank
Standard rate
anaerobic digester
Slurry type bioreactor, temperature,
mixing, SRT or other environmental
conditions are not regulated. Loading
of 1-2 kg COD/m3-day..
Anaerobic contact process
Anaerobic filter (AF)
Upflow anaerobic slugde
Blanket (UASB)
Fluidized bed Reactor
Hybrid reactor: UASB/AF
Anaerobic Sequencing Batch
Reactor (ASBR)
Able to retain very high concentration of
active biomass in the reactor. Thus
extremely high SRT could be maintained
irrespective of HRT. Load 5-20 kg COD/m3-d
COD removal efficiency : 80-90% .
40. Development of UASB
Technology in India
Bilateral cooperation between India and Netherlands in 1985 led to
the design and construction of first successful full scale UASB reactor
for domestic sewage at Kanpur. This demonstration plant was designed
to treat 5 ML/d of raw sewage at 6 h HRT with influent BOD and COD
of 200 and 500 mg/L respectively.
One more UASB based treatment plant (36 ML/d) built in Kanpur to
treat the wastewater of approximately 180 tanneries after dilution with
domestic wastewater in a ratio of 1:3 is in operation since April 1994.
41. UASB TREATMENT PLANTS
under Ganga Action Plan
5 MLD UASB Demonstration PPllaanntt aatt
KKaannppuurr
1144 MMLLDD UUAASSBB SSTTPP aatt MMiirrzzaappuurr
3366 MMLLDD UUAASSBB CCEETTPP aatt KKaannppuurr
52. Main limitations of anaerobic systems
(1) Limitations regarding organic matter
Does not follow the discharge standards in terms of BOD, COD
Requires post treatment step.
UASB Effluent BOD: 60-120 mg/L
BOD removal Efficiency: 55 - 75%
53. (2)Limitations regarding nitrogen and phosphorous
Discharge of nutrients in to surface water may caused
increased algal biomass = eutrophication
1.0 Kg of phosphorous can result in the reconstruction of
111 Kg of biomass = which corresponds to approx. 138 Kg of COD
1 Kg of Nitrogen can result in the reconstruction of Approx.
20 Kg COD under the form of dead algae
54. (3) Limitations regarding
microbiological indicators
Pathogens = 10,000 MPN/100 ml
(Maximum)
= 1000 MPN/100 ml
(Desirable)
69. ¨ INDIA
D UASB, Vadodara
¨ UASB, Surat
D
Locations of STPs selected for the study with their treatment capacities.
43 ML/d UASB, Vadodara
100 ML/d UASB, Surat
74. Feed Tank
( FT)
Gas
Collection
Chamber
Peristaltic
Pump
UASB
Reactor
Cascade Sponge Reactor (CSR)
Final
Effluent
FIG.16
Schematic flow-diagram of Experiment.
75. FIG.17 FIG.18
Prior to start up of CSR
(Cascade Sponge Reactor)
After accumulation of biomass on
CSR (Cascade Sponge Reactor)
76. SEM images of clean
Sponge at 7 x.
SEM images of accumulation
of biomass on Sponge at 7 x.
77. SEM images of measurement of pore size of Sponge at 50 x.
78. y = 0.9971x - 0.1533
R2 = 0.9926
3
2.5
2
1.5
1
0.5
0
0 1 2 3
OLR (KgCOD/m3.d)
COD Removal
Rate(KgCODm3.d)
FIG.68
Variation of COD removal rate according to OLR (Organic
Loading Rate)
79. (A) (B) (C)
Appearance of (A) Raw sewage (B) UASB effluent (C) CSR effluent
80. Conclusions
Of all the anaerobic wastewater treatment process
currently being used, the UASB process has excellent potential to
become highly competitive for municipal wastewater treatment.
However treated effluent from UASB contains significant
amounts of organics, nutrients, sulphide and fecal coliform. When
discharge to the environment creates risk to aquatic and terrestrial
region. So there is a need of post treatment for the UASB effluent
before discharging it to the surface water or terrestrial region. It
can be concluded that all these technologies are feasible for the
post treatment of UASB effluents for satisfying the discharge
standards in surface waters.
Based on this wastewater separation a treatment scheme is proposed here only for concentrated wastewater. [community on site]
Concentrated wastewater is sent to the digester (of which type has to be decided on site, depending on the objective). Several products can be derived after digestion (again depending which type of system is used): treated effluent still rich in organics and nutrient, stabilised sludge rich in organics and nutrients (in some cases safe for reuse), and biogas. Depending on a scale of application reusable. Depending on legislation, objective a secondary step(s) can be applied