Energy required to beak a chemical bond, almost same amount of energy is used to form the same bond between reactants. Bond energies can be used to predict exothermic and endothermic nature of chemical reactions
1. Bond Energies
Dr. K. Shahzad. Baig
Memorial University of Newfoundland
(MUN), Canada
Petrucci, et al. 2011. General Chemistry: Principles and Modern Applications. Pearson Canada Inc., Toronto, Ontario.
Tro, N.J. 2010. Principles of Chemistry. : a molecular approach. Pearson Education, Inc
2. Bond Energies
Bond dissociation energy, D, is the quantity of energy required to break one mole of
covalent bonds in a gaseous species. The SI units are kJ/mole of bonds.
The bond-dissociation energy can be considered as an enthalpy change or a heat of
reaction
π»2 π β 2π» (π) βπ» = π· π» β π» = +435.93 ππ½/πππ
2π» π β π»2 π βπ» = βπ· π» β π» = β435.93 ππ½/πππ
Bond breakage:
Bond formation:
the bond-dissociation energy of a diatomic molecule can be expressed rather precisely, but
with a polyatomic molecule, the situation is different
The energy needed to dissociate one mole of H atoms by breaking one O β H bond per
H2 molecule
π» β ππ» π β π» π + ππ» π βπ» = π· π» β ππ» = +498.7 kJ/mol
3. is different from the energy required to dissociate one mole of H atoms by breaking the
bonds in [OH (g)]:
π β π» π β π» π + π π βπ» = π· π β π» = +428.0 ππ½/πππ
The two O β H bonds in H2O are identical; therefore, they should have identical
energies.
This energy, which we can call the bond energy in is the average of the two values listed
above: [(498.7 + 428.0)/2 = 463.35]= 463.35 kJ / mol
The bond dissociation energy for O β H bond in CH3OH = 436.8 kJ/mol
An average bond energy is the average of bond-dissociation energies for a number of
different species containing the particular bond. (these values are not precise)
4.
5. βπ»ππ₯π = βπ» (ππππ πππππππ) + βπ» (ππππ ππππππ‘πππ)
β π΅πΈ (πππππ‘πππ‘π ) β π΅π (πππππ’ππ‘π )
Enthalpy of reaction from bond energies
6. Calculating an Enthalpy of Reaction from Bond Energies
Example 10-15
The reaction of methane and chlorine produces a mixture of products called chloromethanes.
One of these is monochloromethane, used in the preparation of silicones. Calculate for the
reaction
πΆπ»4 π + πΆπ2 π β πΆπ»3 πΆπ π + π»πΆπ π
draw structural formulas (or Lewis structures)
Solution
Bonds that are broken are shown in red and bonds that are formed, in blue. Bonds that remain
unchanged are black.
7. It is required to break four C β H bonds and one Cl β Cl bond and form three C β H bonds,
one C β Cl bond, and one H β Cl bond. The net change, however, is the breaking of one C
β H bond and one Cl β Cl bond, followed by the formation of one C Cl bond and one H β
Cl bond
βH for net bond breakage: 1 mol C β H bond +414 kJ
1 mol Cl β Cl bond +243 kJ
Sum +657 kJ
βH for net bond formation: 1 mol C β Cl bonds -339 kJ
1 mol H β Cl bond -431 kJ
Sum - 770 kJ
Enthalpy of reaction: βπ» = 657 β 770 = β113 ππ½
8. Using Bond Energies to Predict Exothermic and Endothermic
Reactions
Example
One of the steps in the formation of monochloromethane (Example 10-15) is the reaction of a
gaseous chlorine atom (a chlorine radical) with a molecule of methane. The products are an
unstable methyl radical and HCl(g). Is this reaction endothermic or exothermic?
πΆπ»4 π + πΆπ π β πΆπ»3 π + π»πΆπ π
Solution
In the reaction, one C β H bond is broken for every C β H bond formed. Thus, we must
compare the bond energies for the C- H and H β Cl bonds to decide whether the reaction
is endothermic or exothermic.
Bond breaking (C β H) =
414 kJ /mol of bonds
Bond formation (H β Cl) =
434 kJ /mol of bonds
Because more energy
is released, Therefore,
Exothermic
Editor's Notes
Bond energy, bond length, and bond order are interrelated properties in this sense: the higher the bond order, the shorter the bond between two atoms and the greater the bond energy.
Energy is released when isolated atoms join to form a covalent bond, and energy must be absorbed to break apart covalently bonded atoms.