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PREPARED BY MISS SALIHA RAIS
Law of chemical
combination deals with
some empirical laws, that
govern the chemical
changes.
LAW OF
CONSERVATION OF
MASS
LAW OF CONSTANT
COMPOSITION/ LAW
OF DEFINITE
PROPORTION
LAW OF MULTIPLE
PROPORTION
LAW OF RECIPROCAL
PROPORTION
LAWS OF CHEMICAL
COMBINATIONS
Established by French
Chemist LAVOSIER
“ In any chemical reaction, the initial
weight of reacting substances is equal
to the final weight of the product.”
 Lavoisier performed his
experiment in a closed
system. He found that
the total weight of the
system is not changed
in a chemical reaction.
He performed the
decomposition reaction
of the red oxide of
mercury to form
metallic mercury and
oxygen.
The mass of the reactants (starting materials)
equals the mass of the products
2Mg (s) + O2 (g) → 2MgO (s)
48.6 g 32.0 g 80.6 g
For example:
 The law of conservation of mass can be
demonstrated by the union of hydrogen and
oxygen. If the H2O and O2 are weighed before
they unite, it will be found that there
combined weight is equal to the weight of
water formed.
 The Law of Conservation of Mass is also called
“The Law of Indestructibility of Matter.”
 The practical verification of this law was given by
a German Chemist H. Landolt.
 Hence the law of conservation of mass can
also be stated as:
“there is no detectable gain or loss of mass in a
chemical reaction.”
ESTABLISHED BY
LOUIS PROUST
 The law states that:
“ Different samples of the same
compound always contain the same
elements combined together in the
same proportions by mass.
OR,
“A chemical compound contains the
same elements in exactly the same
proportions (ratios) by mass
regardless of the size of the sample
or source of the compound.”
For example, water
always consists of
oxygen and
hydrogen atoms, and
it is always 89
percent oxygen by
mass and 11 percent
hydrogen by mass.
Every sample of
pure water,
though prepared
in the laboratory
or obtained from
rain, river or
water pump,
contains 1 part
hydrogen and 8
parts oxygen by
mass.
Berzelius heated 10g lead (Pb) with various
amounts of sulphur (S). But every time he got
exactly 11.56g of Lead sulphide, and the
excess of sulphur was left over.
This shows the significance of law of constant
composition.
PUBLISHED BY JOHN DALTON
It states that:
“When two elements combine to form
more than one compound, the masses of
one element which combine with a fixed
mass of the other element are in ratios of
small whole numbers or simple multiple
ratio.”
For Example carbon forms 2 stable compounds with
oxygen:
 Carbon monoxide (CO): 12 parts by mass of carbon
combines with 16 parts by mass of oxygen.
 Carbon dioxide (CO2): 12 parts by mass of carbon
combines with 32 parts by mass of oxygen.
 Ratio of the masses of oxygen that combines with a
fixed mass of carbon (12 parts) 16: 32 or 1: 2
 Another illustration of this law is the
formation of Water and Hydrogen Peroxide.
The excellent example of law of multiple
proportions can be seen when the elements
nitrogen and oxygen combine together to
form a series of compounds.
ESTABLISHED BY RITCHER
The law states that:
“When two different element separately
combine with the fixed mass of third
element, the proportion in which they
combine with each other shall be either
in the same ratio or some simple
multiple of it.
 For example, when two
elements C and O combine
separately with H, they form
CH4 (methane) and H2O (water)
respectively.
 Now when C and O combine
with each other they form CO2.
Laws of chemical combinations, prepared by Saliha Rais

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Laws of chemical combinations, prepared by Saliha Rais

  • 1. PREPARED BY MISS SALIHA RAIS
  • 2. Law of chemical combination deals with some empirical laws, that govern the chemical changes.
  • 3. LAW OF CONSERVATION OF MASS LAW OF CONSTANT COMPOSITION/ LAW OF DEFINITE PROPORTION LAW OF MULTIPLE PROPORTION LAW OF RECIPROCAL PROPORTION LAWS OF CHEMICAL COMBINATIONS
  • 5. “ In any chemical reaction, the initial weight of reacting substances is equal to the final weight of the product.”
  • 6.  Lavoisier performed his experiment in a closed system. He found that the total weight of the system is not changed in a chemical reaction. He performed the decomposition reaction of the red oxide of mercury to form metallic mercury and oxygen.
  • 7. The mass of the reactants (starting materials) equals the mass of the products 2Mg (s) + O2 (g) → 2MgO (s) 48.6 g 32.0 g 80.6 g For example:
  • 8.  The law of conservation of mass can be demonstrated by the union of hydrogen and oxygen. If the H2O and O2 are weighed before they unite, it will be found that there combined weight is equal to the weight of water formed.
  • 9.  The Law of Conservation of Mass is also called “The Law of Indestructibility of Matter.”  The practical verification of this law was given by a German Chemist H. Landolt.  Hence the law of conservation of mass can also be stated as: “there is no detectable gain or loss of mass in a chemical reaction.”
  • 10.
  • 12.  The law states that: “ Different samples of the same compound always contain the same elements combined together in the same proportions by mass.
  • 13. OR, “A chemical compound contains the same elements in exactly the same proportions (ratios) by mass regardless of the size of the sample or source of the compound.”
  • 14. For example, water always consists of oxygen and hydrogen atoms, and it is always 89 percent oxygen by mass and 11 percent hydrogen by mass.
  • 15. Every sample of pure water, though prepared in the laboratory or obtained from rain, river or water pump, contains 1 part hydrogen and 8 parts oxygen by mass.
  • 16. Berzelius heated 10g lead (Pb) with various amounts of sulphur (S). But every time he got exactly 11.56g of Lead sulphide, and the excess of sulphur was left over. This shows the significance of law of constant composition.
  • 18. It states that: “When two elements combine to form more than one compound, the masses of one element which combine with a fixed mass of the other element are in ratios of small whole numbers or simple multiple ratio.”
  • 19. For Example carbon forms 2 stable compounds with oxygen:  Carbon monoxide (CO): 12 parts by mass of carbon combines with 16 parts by mass of oxygen.  Carbon dioxide (CO2): 12 parts by mass of carbon combines with 32 parts by mass of oxygen.  Ratio of the masses of oxygen that combines with a fixed mass of carbon (12 parts) 16: 32 or 1: 2
  • 20.  Another illustration of this law is the formation of Water and Hydrogen Peroxide.
  • 21. The excellent example of law of multiple proportions can be seen when the elements nitrogen and oxygen combine together to form a series of compounds.
  • 23. The law states that: “When two different element separately combine with the fixed mass of third element, the proportion in which they combine with each other shall be either in the same ratio or some simple multiple of it.
  • 24.  For example, when two elements C and O combine separately with H, they form CH4 (methane) and H2O (water) respectively.  Now when C and O combine with each other they form CO2.